FR2511707A1 - Composition et procede pour l'electrodeposition de depots d'alliages zinc-nickel - Google Patents
Composition et procede pour l'electrodeposition de depots d'alliages zinc-nickel Download PDFInfo
- Publication number
- FR2511707A1 FR2511707A1 FR8214424A FR8214424A FR2511707A1 FR 2511707 A1 FR2511707 A1 FR 2511707A1 FR 8214424 A FR8214424 A FR 8214424A FR 8214424 A FR8214424 A FR 8214424A FR 2511707 A1 FR2511707 A1 FR 2511707A1
- Authority
- FR
- France
- Prior art keywords
- zinc
- nickel
- bath
- composition according
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical group [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229910000990 Ni alloy Inorganic materials 0.000 title claims abstract description 33
- 239000000203 mixture Substances 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims description 25
- 238000004070 electrodeposition Methods 0.000 title abstract description 36
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 110
- 239000011701 zinc Substances 0.000 claims abstract description 57
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 55
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 48
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 47
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 238000007670 refining Methods 0.000 claims abstract description 4
- -1 ammonium ions Chemical class 0.000 claims description 35
- 230000008021 deposition Effects 0.000 claims description 20
- 238000009713 electroplating Methods 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 12
- BWHOZHOGCMHOBV-UHFFFAOYSA-N Benzalacetone Natural products CC(=O)C=CC1=CC=CC=C1 BWHOZHOGCMHOBV-UHFFFAOYSA-N 0.000 claims description 7
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- BWHOZHOGCMHOBV-BQYQJAHWSA-N trans-benzylideneacetone Chemical group CC(=O)\C=C\C1=CC=CC=C1 BWHOZHOGCMHOBV-BQYQJAHWSA-N 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 6
- 150000003934 aromatic aldehydes Chemical class 0.000 claims description 5
- 150000002009 diols Chemical class 0.000 claims description 5
- QNDQILQPPKQROV-UHFFFAOYSA-N dizinc Chemical compound [Zn]=[Zn] QNDQILQPPKQROV-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 150000008365 aromatic ketones Chemical class 0.000 claims description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- 238000005282 brightening Methods 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 9
- 230000007797 corrosion Effects 0.000 abstract description 9
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract description 3
- VIQCGTZFEYDQMR-UHFFFAOYSA-N fluphenazine decanoate Chemical compound C1CN(CCOC(=O)CCCCCCCCC)CCN1CCCN1C2=CC(C(F)(F)F)=CC=C2SC2=CC=CC=C21 VIQCGTZFEYDQMR-UHFFFAOYSA-N 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000151 deposition Methods 0.000 description 20
- 238000005868 electrolysis reaction Methods 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 229910000831 Steel Inorganic materials 0.000 description 7
- 150000001805 chlorine compounds Chemical class 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 238000007747 plating Methods 0.000 description 5
- KRIOVPPHQSLHCZ-UHFFFAOYSA-N propiophenone Chemical compound CCC(=O)C1=CC=CC=C1 KRIOVPPHQSLHCZ-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 229920002359 Tetronic® Polymers 0.000 description 3
- JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Inorganic materials [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 2
- FPYUJUBAXZAQNL-UHFFFAOYSA-N 2-chlorobenzaldehyde Chemical compound ClC1=CC=CC=C1C=O FPYUJUBAXZAQNL-UHFFFAOYSA-N 0.000 description 2
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229940117916 cinnamic aldehyde Drugs 0.000 description 2
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002193 fatty amides Chemical class 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- QCCDLTOVEPVEJK-UHFFFAOYSA-N phenylacetone Chemical compound CC(=O)CC1=CC=CC=C1 QCCDLTOVEPVEJK-UHFFFAOYSA-N 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- GBKGJMYPQZODMI-SNAWJCMRSA-N (e)-4-(furan-2-yl)but-3-en-2-one Chemical compound CC(=O)\C=C\C1=CC=CO1 GBKGJMYPQZODMI-SNAWJCMRSA-N 0.000 description 1
- CWKVFRNCODQPDB-UHFFFAOYSA-N 1-(2-aminoethylamino)propan-2-ol Chemical compound CC(O)CNCCN CWKVFRNCODQPDB-UHFFFAOYSA-N 0.000 description 1
- LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical class CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- GBKGJMYPQZODMI-UHFFFAOYSA-N 4-(furan-2-yl)but-3-en-2-one Chemical compound CC(=O)C=CC1=CC=CO1 GBKGJMYPQZODMI-UHFFFAOYSA-N 0.000 description 1
- AVPYQKSLYISFPO-UHFFFAOYSA-N 4-chlorobenzaldehyde Chemical compound ClC1=CC=C(C=O)C=C1 AVPYQKSLYISFPO-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000009089 cytolysis Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- YCKGQDCCGJMDFD-UHFFFAOYSA-N ethane-1,2-diamine;prop-1-ene Chemical compound CC=C.NCCN YCKGQDCCGJMDFD-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- LAIZPRYFQUWUBN-UHFFFAOYSA-L nickel chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Ni+2] LAIZPRYFQUWUBN-UHFFFAOYSA-L 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229950003429 sorbitan palmitate Drugs 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- FZUJWWOKDIGOKH-UHFFFAOYSA-N sulfuric acid hydrochloride Chemical compound Cl.OS(O)(=O)=O FZUJWWOKDIGOKH-UHFFFAOYSA-N 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56130341A JPS6012434B2 (ja) | 1981-08-21 | 1981-08-21 | 亜鉛−ニツケル合金電気めつき液 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2511707A1 true FR2511707A1 (fr) | 1983-02-25 |
| FR2511707B1 FR2511707B1 (it) | 1985-05-03 |
Family
ID=15032062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8214424A Granted FR2511707A1 (fr) | 1981-08-21 | 1982-08-20 | Composition et procede pour l'electrodeposition de depots d'alliages zinc-nickel |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS6012434B2 (it) |
| KR (1) | KR880001584B1 (it) |
| AU (1) | AU534369B2 (it) |
| BR (1) | BR8204892A (it) |
| CA (1) | CA1210732A (it) |
| DE (1) | DE3231054A1 (it) |
| ES (1) | ES515149A0 (it) |
| FR (1) | FR2511707A1 (it) |
| GB (1) | GB2104920B (it) |
| IN (1) | IN157700B (it) |
| IT (1) | IT1156492B (it) |
| MX (1) | MX158623A (it) |
| NL (1) | NL184070C (it) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4578158A (en) * | 1983-11-01 | 1986-03-25 | Nippon Steel Corporation | Process for electroplating a metallic material with an iron-zinc alloy |
| JPS60228693A (ja) * | 1984-04-25 | 1985-11-13 | Kawasaki Steel Corp | Ｚｎ−Ｎｉ合金めつき鋼板の製造方法 |
| JPS61110794A (ja) * | 1984-11-06 | 1986-05-29 | Mitsui Mining & Smelting Co Ltd | 銅箔の表面処理方法 |
| JPS622776U (it) * | 1985-06-21 | 1987-01-09 | ||
| JPS6236178U (it) * | 1985-08-21 | 1987-03-03 | ||
| US4666791A (en) * | 1985-12-06 | 1987-05-19 | Bethlehem Steel Corporation Of Delaware | Ni-Zn electroplated product resistant to paint delamination |
| US4772362A (en) * | 1985-12-09 | 1988-09-20 | Omi International Corporation | Zinc alloy electrolyte and process |
| JPS62113272U (it) * | 1985-12-31 | 1987-07-18 | ||
| JPS6353285A (ja) * | 1986-08-22 | 1988-03-07 | Nippon Hyomen Kagaku Kk | 亜鉛−ニツケル合金めつき液 |
| KR100417930B1 (ko) * | 1996-12-26 | 2004-03-31 | 주식회사 포스코 | 아연-니켈합금전기도금액 |
| KR100417931B1 (ko) * | 1996-12-26 | 2004-03-30 | 주식회사 포스코 | 아연-니켈합금전기도금액 |
| KR100368221B1 (ko) * | 1998-09-01 | 2003-04-21 | 주식회사 포스코 | 염화물욕가용성양극을사용한아연-니켈합금전기도금용액및이용액을이용한아연-니켈합금전기도금강판의제조방법 |
| KR20020010046A (ko) * | 2000-07-28 | 2002-02-02 | 이구택 | 아연-니켈 도금강판의 오염 방지제 |
| US7442286B2 (en) | 2004-02-26 | 2008-10-28 | Atotech Deutschland Gmbh | Articles with electroplated zinc-nickel ternary and higher alloys, electroplating baths, processes and systems for electroplating such alloys |
| CN103451693B (zh) * | 2013-07-29 | 2015-08-26 | 山东建筑大学 | 一种镍含量稳定的碱性锌镍合金脉冲电镀方法 |
| CN105002532A (zh) * | 2015-08-21 | 2015-10-28 | 哈尔滨工业大学 | 一种低泡型弱酸性氯化物锌镍合金电镀液 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE27999E (en) * | 1966-05-28 | 1974-04-30 | Certificate of correction | |
| SU571528A1 (ru) * | 1975-09-17 | 1977-09-05 | Pavlov Anatolij V | Электролит дл осаждени сплавов на основе цинка |
| US4070256A (en) * | 1975-06-16 | 1978-01-24 | Minnesota Mining And Manufacturing Company | Acid zinc electroplating bath and process |
| SU827608A1 (ru) * | 1978-05-12 | 1981-05-07 | Предприятие П/Я В-8173 | Электролит дл осаждени покрытийиз СплАВА циНК-НиКЕль |
| US4268364A (en) * | 1980-03-18 | 1981-05-19 | Inco Research & Development Center Inc. | Nickel-zinc alloy deposition from a sulfamate bath |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE470874A (it) * | 1940-12-21 | |||
| US3420754A (en) * | 1965-03-12 | 1969-01-07 | Pittsburgh Steel Co | Electroplating a ductile zinc-nickel alloy onto strip steel |
| US3558442A (en) * | 1969-01-31 | 1971-01-26 | Wheeling Pittsburgh Steel Corp | Electroplating a ductile zinc-nickel alloy onto strip steel |
| JPS5128533A (en) * | 1974-09-04 | 1976-03-10 | Matsushita Electric Ind Co Ltd | Aen nitsukerugokin metsukyodenkaieki |
| US4313802A (en) * | 1979-02-15 | 1982-02-02 | Sumitomo Metal Industries, Ltd. | Method of plating steel strip with nickel-zinc alloy |
| JPS5839236B2 (ja) * | 1979-03-30 | 1983-08-29 | 住友金属工業株式会社 | 合金電気メッキ方法 |
| US4282073A (en) * | 1979-08-22 | 1981-08-04 | Thomas Steel Strip Corporation | Electro-co-deposition of corrosion resistant nickel/zinc alloys onto steel substrates |
-
1981
- 1981-08-21 JP JP56130341A patent/JPS6012434B2/ja not_active Expired
-
1982
- 1982-08-11 AU AU87056/82A patent/AU534369B2/en not_active Ceased
- 1982-08-19 NL NLAANVRAGE8203266,A patent/NL184070C/xx not_active IP Right Cessation
- 1982-08-20 CA CA000409819A patent/CA1210732A/en not_active Expired
- 1982-08-20 BR BR8204892A patent/BR8204892A/pt unknown
- 1982-08-20 FR FR8214424A patent/FR2511707A1/fr active Granted
- 1982-08-20 ES ES515149A patent/ES515149A0/es active Granted
- 1982-08-20 IN IN970/CAL/82A patent/IN157700B/en unknown
- 1982-08-20 KR KR8203747A patent/KR880001584B1/ko active
- 1982-08-20 DE DE3231054A patent/DE3231054A1/de active Granted
- 1982-08-20 MX MX194081A patent/MX158623A/es unknown
- 1982-08-20 IT IT68027/82A patent/IT1156492B/it active
- 1982-08-23 GB GB08224176A patent/GB2104920B/en not_active Expired
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE27999E (en) * | 1966-05-28 | 1974-04-30 | Certificate of correction | |
| US4070256A (en) * | 1975-06-16 | 1978-01-24 | Minnesota Mining And Manufacturing Company | Acid zinc electroplating bath and process |
| US4070256B1 (it) * | 1975-06-16 | 1983-03-01 | ||
| SU571528A1 (ru) * | 1975-09-17 | 1977-09-05 | Pavlov Anatolij V | Электролит дл осаждени сплавов на основе цинка |
| SU827608A1 (ru) * | 1978-05-12 | 1981-05-07 | Предприятие П/Я В-8173 | Электролит дл осаждени покрытийиз СплАВА циНК-НиКЕль |
| US4268364A (en) * | 1980-03-18 | 1981-05-19 | Inco Research & Development Center Inc. | Nickel-zinc alloy deposition from a sulfamate bath |
Non-Patent Citations (2)
| Title |
|---|
| GALVANOTECHNIK, volume 68, no. 11, 1977, page 1033, SAULGAU (DE) & SU-A-571 528 A1 * |
| GALVANOTECHNIK, volume 72, no. 9, septembre 1981, SAULGAU (DE) page 1012, & SU-A-827 608 A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3231054A1 (de) | 1983-03-03 |
| GB2104920B (en) | 1985-02-27 |
| AU534369B2 (en) | 1984-01-26 |
| NL184070C (nl) | 1989-04-03 |
| NL184070B (nl) | 1988-11-01 |
| NL8203266A (nl) | 1983-03-16 |
| IT8268027A0 (it) | 1982-08-20 |
| AU8705682A (en) | 1983-02-24 |
| BR8204892A (pt) | 1983-08-02 |
| IN157700B (it) | 1986-05-24 |
| ES8308366A1 (es) | 1983-08-16 |
| FR2511707B1 (it) | 1985-05-03 |
| ES515149A0 (es) | 1983-08-16 |
| GB2104920A (en) | 1983-03-16 |
| IT1156492B (it) | 1987-02-04 |
| KR840001231A (ko) | 1984-03-28 |
| JPS6012434B2 (ja) | 1985-04-01 |
| CA1210732A (en) | 1986-09-02 |
| KR880001584B1 (ko) | 1988-08-24 |
| MX158623A (es) | 1989-02-20 |
| DE3231054C2 (it) | 1989-04-27 |
| JPS5834189A (ja) | 1983-02-28 |
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