FR2459971A1 - Capteur d'oxygene du type en pellicule mince et plate - Google Patents
Capteur d'oxygene du type en pellicule mince et plate Download PDFInfo
- Publication number
- FR2459971A1 FR2459971A1 FR8014114A FR8014114A FR2459971A1 FR 2459971 A1 FR2459971 A1 FR 2459971A1 FR 8014114 A FR8014114 A FR 8014114A FR 8014114 A FR8014114 A FR 8014114A FR 2459971 A1 FR2459971 A1 FR 2459971A1
- Authority
- FR
- France
- Prior art keywords
- layer
- oxygen sensor
- electrolyte
- electrode layer
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000001301 oxygen Substances 0.000 claims abstract description 79
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 79
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000003792 electrolyte Substances 0.000 claims abstract description 37
- 238000000926 separation method Methods 0.000 claims abstract description 34
- 238000005259 measurement Methods 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 claims description 244
- 239000007784 solid electrolyte Substances 0.000 claims description 30
- 239000011241 protective layer Substances 0.000 claims description 21
- -1 oxygen ion Chemical class 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 14
- 239000007789 gas Substances 0.000 abstract description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 52
- 229910052697 platinum Inorganic materials 0.000 description 23
- 238000000034 method Methods 0.000 description 20
- 230000001143 conditioned effect Effects 0.000 description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 18
- 239000011195 cermet Substances 0.000 description 17
- 239000000919 ceramic Substances 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000004922 lacquer Substances 0.000 description 12
- 239000012749 thinning agent Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- 239000004020 conductor Substances 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000007750 plasma spraying Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 241000235789 Hyperoartia Species 0.000 description 1
- 229910004369 ThO2 Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 239000006181 electrochemical material Substances 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052839 forsterite Inorganic materials 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910003465 moissanite Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4075—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4071—Cells and probes with solid electrolytes for investigating or analysing gases using sensor elements of laminated structure
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4077—Means for protecting the electrolyte or the electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- Pathology (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- General Chemical & Material Sciences (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7973679A JPS564047A (en) | 1979-06-26 | 1979-06-26 | Lamination type membrane-covered oxygen sensor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2459971A1 true FR2459971A1 (fr) | 1981-01-16 |
| FR2459971B1 FR2459971B1 (show.php) | 1984-03-09 |
Family
ID=13698485
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8014114A Granted FR2459971A1 (fr) | 1979-06-26 | 1980-06-25 | Capteur d'oxygene du type en pellicule mince et plate |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US4347114A (show.php) |
| JP (1) | JPS564047A (show.php) |
| DE (1) | DE3024077C2 (show.php) |
| FR (1) | FR2459971A1 (show.php) |
| GB (1) | GB2054163B (show.php) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6034064B2 (ja) * | 1979-12-18 | 1985-08-06 | 日産自動車株式会社 | 積層型膜構造酸素センサ |
| JPS57137849A (en) * | 1981-02-19 | 1982-08-25 | Nissan Motor Co Ltd | Element of film construction oxygen sensor |
| US4500412A (en) * | 1981-08-07 | 1985-02-19 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Oxygen sensor with heater |
| JPS5827056A (ja) * | 1981-08-12 | 1983-02-17 | Mitsubishi Electric Corp | 酸素ガスセンサ |
| JPS6193944A (ja) * | 1984-10-13 | 1986-05-12 | Ngk Spark Plug Co Ltd | ガス検出素子 |
| JPH01134252U (show.php) * | 1988-03-09 | 1989-09-13 | ||
| US5102750A (en) * | 1990-12-18 | 1992-04-07 | Bell Communications Research, Inc. | Efficiency enhancement for solid-electrolyte fuel cell |
| US5250169A (en) * | 1991-06-07 | 1993-10-05 | Ford Motor Company | Apparatus for sensing hydrocarbons and carbon monoxide |
| US5221641A (en) * | 1991-06-21 | 1993-06-22 | Rohm Co., Ltd. | Process for making light emitting diodes |
| GB9116385D0 (en) * | 1991-07-30 | 1991-09-11 | British Gas Plc | Oxygen sensor |
| JP3281925B2 (ja) * | 1991-08-06 | 2002-05-13 | 大阪瓦斯株式会社 | サーメット電極及びその製造方法 |
| DE4305930C2 (de) * | 1993-02-26 | 1997-07-17 | Roth Technik Gmbh | Festelektrolytsensor zur Messung gasförmiger Anhydride |
| US5660661A (en) * | 1993-04-13 | 1997-08-26 | Nippondenso Co., Ltd. | Oxygen sensor |
| US5827415A (en) * | 1994-09-26 | 1998-10-27 | The Board Of Trustees Of Leland Stanford Jun. Univ. | Oxygen sensor |
| DE19701418A1 (de) * | 1997-01-17 | 1998-07-23 | Univ Ilmenau | Sensitive Schicht für den Einsatz in Halbleiter-Gassensoren |
| US6153071A (en) * | 1998-06-03 | 2000-11-28 | Ford Global Technologies, Inc. | Exhaust oxygen sensing |
| JP3149849B2 (ja) * | 1998-06-04 | 2001-03-26 | 株式会社村田製作所 | 固体電解質型燃料電池 |
| US6080294A (en) * | 1998-07-15 | 2000-06-27 | Atwood Industries, Inc. | Gas sensor with dual electrolytes |
| US20050016848A1 (en) * | 2003-05-30 | 2005-01-27 | Muhammad Sahimi | Oxygen sensor with a solid-state reference and manufacturing thereof |
| JP5057018B2 (ja) * | 2006-06-30 | 2012-10-24 | 独立行政法人産業技術総合研究所 | 電気化学セル方式ガスセンサー |
| DE102008054617A1 (de) * | 2008-12-15 | 2010-06-17 | Robert Bosch Gmbh | Strukturierte Elektrode für keramische Sensorelemente |
| DE102013204463A1 (de) * | 2013-03-14 | 2014-09-18 | Robert Bosch Gmbh | Sensorvorrichtung und Verfahren zum Erfassen eines Gases in einem Gasgemisch |
| JP6541728B2 (ja) * | 2017-07-24 | 2019-07-10 | カルソニックカンセイ株式会社 | 接合方法 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1582347A (show.php) * | 1967-09-28 | 1969-09-26 | ||
| US4040929A (en) * | 1975-09-15 | 1977-08-09 | Universal Oil Products Company | Oxygen sensor having thin film electrolyte |
| FR2350598A1 (fr) * | 1976-05-07 | 1977-12-02 | Thomson Csf | Senseur de concentration d'une espece dans un fluide |
| DE2742278A1 (de) * | 1976-09-22 | 1978-03-23 | Nissan Motor | Sauerstoff-sensor |
| DE2746381A1 (de) * | 1976-10-14 | 1978-04-20 | Nissan Motor | Sauerstoff-sensor |
| DE2718907A1 (de) * | 1977-04-28 | 1978-11-02 | Bosch Gmbh Robert | Messfuehler zur bestimmung des sauerstoffgehalts in abgasen |
| FR2428840A1 (fr) * | 1978-06-16 | 1980-01-11 | Nissan Motor | Dispositif de mesure de la concentration d'oxygene dans un fluide |
| DE2830778A1 (de) * | 1978-07-13 | 1980-01-31 | Bosch Gmbh Robert | Elektrochemischer messfuehler mit verbesserter haftfestigkeit des elektrodensystems auf dem festelektrolyten |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR96061E (fr) * | 1967-11-02 | 1972-05-19 | Gen Electric | Corps composé et procédé pour son faÇonnage, notamment utilisable comme corps électrode-électrolyte. |
| US3719564A (en) * | 1971-05-10 | 1973-03-06 | Philip Morris Inc | Method of determining a reducible gas concentration and sensor therefor |
| US4021326A (en) * | 1972-06-02 | 1977-05-03 | Robert Bosch G.M.B.H. | Electro-chemical sensor |
| US3843400A (en) * | 1972-09-18 | 1974-10-22 | Westinghouse Electric Corp | Solid electrolyte cell |
| FR2252041A5 (show.php) | 1973-11-16 | 1975-06-13 | Thomson Csf | |
| JPS5296092A (en) * | 1976-02-09 | 1977-08-12 | Toyota Motor Co Ltd | Airrfuel ratio detector |
| JPS55156858A (en) * | 1979-05-25 | 1980-12-06 | Nissan Motor Co Ltd | Lamination-type film structure oxygen sensor |
-
1979
- 1979-06-26 JP JP7973679A patent/JPS564047A/ja active Granted
-
1980
- 1980-06-23 US US06/162,001 patent/US4347114A/en not_active Expired - Lifetime
- 1980-06-24 GB GB8020587A patent/GB2054163B/en not_active Expired
- 1980-06-25 FR FR8014114A patent/FR2459971A1/fr active Granted
- 1980-06-26 DE DE3024077A patent/DE3024077C2/de not_active Expired
-
1982
- 1982-04-16 US US06/369,079 patent/US4407057A/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1582347A (show.php) * | 1967-09-28 | 1969-09-26 | ||
| US4040929A (en) * | 1975-09-15 | 1977-08-09 | Universal Oil Products Company | Oxygen sensor having thin film electrolyte |
| FR2350598A1 (fr) * | 1976-05-07 | 1977-12-02 | Thomson Csf | Senseur de concentration d'une espece dans un fluide |
| DE2742278A1 (de) * | 1976-09-22 | 1978-03-23 | Nissan Motor | Sauerstoff-sensor |
| DE2746381A1 (de) * | 1976-10-14 | 1978-04-20 | Nissan Motor | Sauerstoff-sensor |
| DE2718907A1 (de) * | 1977-04-28 | 1978-11-02 | Bosch Gmbh Robert | Messfuehler zur bestimmung des sauerstoffgehalts in abgasen |
| FR2428840A1 (fr) * | 1978-06-16 | 1980-01-11 | Nissan Motor | Dispositif de mesure de la concentration d'oxygene dans un fluide |
| DE2830778A1 (de) * | 1978-07-13 | 1980-01-31 | Bosch Gmbh Robert | Elektrochemischer messfuehler mit verbesserter haftfestigkeit des elektrodensystems auf dem festelektrolyten |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2054163A (en) | 1981-02-11 |
| JPS615097B2 (show.php) | 1986-02-15 |
| US4407057A (en) | 1983-10-04 |
| US4347114A (en) | 1982-08-31 |
| JPS564047A (en) | 1981-01-16 |
| DE3024077A1 (de) | 1981-01-08 |
| GB2054163B (en) | 1983-06-08 |
| FR2459971B1 (show.php) | 1984-03-09 |
| DE3024077C2 (de) | 1984-02-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |