FR2405914A1 - Procede de preparation de p-alkyl-phenols - Google Patents
Procede de preparation de p-alkyl-phenolsInfo
- Publication number
- FR2405914A1 FR2405914A1 FR7828849A FR7828849A FR2405914A1 FR 2405914 A1 FR2405914 A1 FR 2405914A1 FR 7828849 A FR7828849 A FR 7828849A FR 7828849 A FR7828849 A FR 7828849A FR 2405914 A1 FR2405914 A1 FR 2405914A1
- Authority
- FR
- France
- Prior art keywords
- alkyl
- phenols
- catalyst
- reaction
- degrees
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Abstract
L'invention est relative à un procédé de préparation de p-alkyl-phénols. Selon l'invention, dans un premier stade de réaction on conduit l'alkylation à une température de 80 à 140 degrés C en présence d'un catalyseur en suspension, en introduisant par le bas dans le mélange réactionnel les oléfines à l'état gazeux avec une vitesse de 3 à 20 cm/s rapportée à la section libre du réacteur vide, sur la base d'un volume molaire de 25 litres par mole d'oléfine, tandis que dans un deuxième stade de réaction, on fait passer sur un catalyseur disposé de façon fixe le produit de réaction liquide obtenu, à une température de 80 à 140 degrés C et que l'on utilise aux deux stades de réaction un catalyseur dont la capacité d'échange est de 70 à 120 millivalences/100 ml. Le procédé permet d'obtenir de p-alkyl-phénols de haute qualité avec une grande sélectivité et un grand rendement.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2745589A DE2745589C3 (de) | 1977-10-11 | 1977-10-11 | Verfahren zur Herstellung von p-Alkylphenolen |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2405914A1 true FR2405914A1 (fr) | 1979-05-11 |
FR2405914B1 FR2405914B1 (fr) | 1983-11-25 |
Family
ID=6021128
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7828849A Granted FR2405914A1 (fr) | 1977-10-11 | 1978-10-10 | Procede de preparation de p-alkyl-phenols |
Country Status (10)
Country | Link |
---|---|
US (1) | US4236033A (fr) |
JP (1) | JPS5461130A (fr) |
BE (1) | BE871105A (fr) |
BR (1) | BR7806690A (fr) |
DE (1) | DE2745589C3 (fr) |
FR (1) | FR2405914A1 (fr) |
GB (1) | GB2007224B (fr) |
IT (1) | IT1157363B (fr) |
NL (1) | NL7810189A (fr) |
SU (1) | SU1178321A3 (fr) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4380677A (en) * | 1981-05-11 | 1983-04-19 | Uop Inc. | Preparation of 2,6-di-tert-butyl-4-alkylphenols |
US4418222A (en) * | 1981-05-26 | 1983-11-29 | Chevron Research Company | Continuous phenol alkylation process |
US4391998A (en) * | 1981-10-21 | 1983-07-05 | Mobil Oil Corporation | Production of para-isopropylphenol |
DE3151693A1 (de) * | 1981-12-29 | 1983-07-07 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von p-tert.-octylphenol durch katalytische alkylierung von phenol |
DE3443736A1 (de) * | 1984-11-30 | 1986-06-05 | Hüls AG, 4370 Marl | Verfahren zur gleichzeitigen herstellung von ortho-, para- und 2.4-di-tert.-butylphenol |
CN1056597C (zh) * | 1996-01-25 | 2000-09-20 | 中国石油化工总公司 | 烷基酚制备工艺 |
GB9722719D0 (en) | 1997-10-29 | 1997-12-24 | Fmc Corp Uk Ltd | Production of phosphate esters |
US6124512A (en) * | 1998-09-18 | 2000-09-26 | Occidental Chemical Corporation | Ring halogenation of aromatic compounds |
US6339177B1 (en) | 2000-05-24 | 2002-01-15 | Sea Lion Technology, Inc. | Dinitroalkyl aromatics polymerization retarders or inhibitors and methods for making and for using same |
JP2003040822A (ja) * | 2001-07-30 | 2003-02-13 | Dainippon Ink & Chem Inc | 4−ターシャリーブチルフェノールの製造方法 |
TWI624450B (zh) * | 2009-12-04 | 2018-05-21 | Si集團股份有限公司 | 從c萃餘物之物流製造三級丁基酚之方法 |
JP6885487B1 (ja) | 2020-03-30 | 2021-06-16 | 住友大阪セメント株式会社 | リチウムイオン二次電池用正極材料、リチウムイオン二次電池用正極及びリチウムイオン二次電池 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3257467A (en) * | 1960-07-21 | 1966-06-21 | Monsanto Co | Continuous methods for effecting ring substitution of phenols |
DE1443346A1 (de) * | 1960-10-12 | 1968-10-31 | Union Carbide Corp | Verfahren zur Alkylierung von Arylhydroxyden |
US3422157A (en) * | 1966-04-18 | 1969-01-14 | Union Carbide Corp | Process for continuous alkylation of arylhydroxides using ion exchange resins |
FR2228749A1 (en) * | 1973-05-08 | 1974-12-06 | Sidobre Sinnova Produit Chimiq | Para-(octyl or tert-butyl) phenol prodn. - from phenol and diisobutylene over cation exchanger pref. with anhydrous catalyst |
DE2346273B1 (de) * | 1973-09-14 | 1975-01-23 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Alkylphenolen |
DE2526644A1 (de) * | 1975-06-14 | 1976-12-30 | Basf Ag | Verfahren zur herstellung von p-alkylphenolen |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL123464C (fr) * | 1960-04-13 | |||
US3308168A (en) * | 1961-03-02 | 1967-03-07 | Monsanto Co | Method for effecting alkyl ring substitution of phenols employing a sulfonated polyvinyl aryl resin derivative as a catalyst |
-
1977
- 1977-10-11 DE DE2745589A patent/DE2745589C3/de not_active Expired
-
1978
- 1978-10-04 US US05/948,609 patent/US4236033A/en not_active Expired - Lifetime
- 1978-10-06 SU SU782670054A patent/SU1178321A3/ru active
- 1978-10-09 BE BE190991A patent/BE871105A/fr not_active IP Right Cessation
- 1978-10-09 IT IT51414/78A patent/IT1157363B/it active
- 1978-10-09 JP JP12367178A patent/JPS5461130A/ja active Granted
- 1978-10-10 FR FR7828849A patent/FR2405914A1/fr active Granted
- 1978-10-10 NL NL7810189A patent/NL7810189A/xx not_active Application Discontinuation
- 1978-10-10 BR BR7806690A patent/BR7806690A/pt unknown
- 1978-10-11 GB GB7840205A patent/GB2007224B/en not_active Expired
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3257467A (en) * | 1960-07-21 | 1966-06-21 | Monsanto Co | Continuous methods for effecting ring substitution of phenols |
DE1443346A1 (de) * | 1960-10-12 | 1968-10-31 | Union Carbide Corp | Verfahren zur Alkylierung von Arylhydroxyden |
US3422157A (en) * | 1966-04-18 | 1969-01-14 | Union Carbide Corp | Process for continuous alkylation of arylhydroxides using ion exchange resins |
FR2228749A1 (en) * | 1973-05-08 | 1974-12-06 | Sidobre Sinnova Produit Chimiq | Para-(octyl or tert-butyl) phenol prodn. - from phenol and diisobutylene over cation exchanger pref. with anhydrous catalyst |
DE2346273B1 (de) * | 1973-09-14 | 1975-01-23 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Alkylphenolen |
DE2526644A1 (de) * | 1975-06-14 | 1976-12-30 | Basf Ag | Verfahren zur herstellung von p-alkylphenolen |
FR2314167A1 (fr) * | 1975-06-14 | 1977-01-07 | Basf Ag | Procede de preparation de para-alkylphenols |
Also Published As
Publication number | Publication date |
---|---|
JPS6237617B2 (fr) | 1987-08-13 |
IT7851414A0 (it) | 1978-10-09 |
DE2745589B2 (de) | 1979-07-12 |
GB2007224B (en) | 1982-05-06 |
JPS5461130A (en) | 1979-05-17 |
NL7810189A (nl) | 1979-04-17 |
DE2745589C3 (de) | 1980-03-27 |
BR7806690A (pt) | 1979-05-02 |
GB2007224A (en) | 1979-05-16 |
DE2745589A1 (de) | 1979-04-12 |
US4236033A (en) | 1980-11-25 |
FR2405914B1 (fr) | 1983-11-25 |
IT1157363B (it) | 1987-02-11 |
BE871105A (fr) | 1979-04-09 |
SU1178321A3 (ru) | 1985-09-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |