FR2398695A1 - Procede de production d'hydrogene et de monoxyde de carbone par decomposition catalytique du methanol - Google Patents

Procede de production d'hydrogene et de monoxyde de carbone par decomposition catalytique du methanol

Info

Publication number
FR2398695A1
FR2398695A1 FR7818919A FR7818919A FR2398695A1 FR 2398695 A1 FR2398695 A1 FR 2398695A1 FR 7818919 A FR7818919 A FR 7818919A FR 7818919 A FR7818919 A FR 7818919A FR 2398695 A1 FR2398695 A1 FR 2398695A1
Authority
FR
France
Prior art keywords
hydrogen
production
carbon monoxide
methanol
catalytic decomposition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7818919A
Other languages
English (en)
Inventor
William John Ball
David Gordon Stewart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP PLC filed Critical BP PLC
Publication of FR2398695A1 publication Critical patent/FR2398695A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)

Abstract

La présente invention concerne la production d'un gaz de synthèse constitué par un mélange de monoxyde de carbone et d'hydrogène. Ce gaz est obtenu en mettant en contact le méthanol, en phase vapeur avec un catalyseur comprenant, sur support, un métal du groupe VIII du tableau périodique, seul ou en combinaison avec un ou plusieurs, métaux des groupes I à VIII, à une température de 200 à 600 degrés C et à une pression de 0 à 50 bars; les meilleurs résultats sont obtenus avec un mélange de rhodium et de cuivre sur support de silice. Application à la production de gaz de synthèse, tels que l'oxyde de carbone et hydrogène.
FR7818919A 1977-07-27 1978-06-23 Procede de production d'hydrogene et de monoxyde de carbone par decomposition catalytique du methanol Withdrawn FR2398695A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB31538/77A GB1577069A (en) 1977-07-27 1977-07-27 Process for the production of synthesis gas by the catalysed decomposition of methanol

Publications (1)

Publication Number Publication Date
FR2398695A1 true FR2398695A1 (fr) 1979-02-23

Family

ID=10324606

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7818919A Withdrawn FR2398695A1 (fr) 1977-07-27 1978-06-23 Procede de production d'hydrogene et de monoxyde de carbone par decomposition catalytique du methanol

Country Status (10)

Country Link
US (1) US4175115A (fr)
JP (1) JPS5425294A (fr)
BE (1) BE869280A (fr)
CA (1) CA1084709A (fr)
DE (1) DE2832136A1 (fr)
FR (1) FR2398695A1 (fr)
GB (1) GB1577069A (fr)
IT (1) IT1096490B (fr)
NL (1) NL7806278A (fr)
ZA (1) ZA782958B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0385857A1 (fr) * 1989-03-02 1990-09-05 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procédé et installation de production de monoxyde de carbone
EP0405958A1 (fr) * 1989-06-29 1991-01-02 E.I. Du Pont De Nemours And Company Catalyseurs de dissociation du méthanol

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1130265A (fr) * 1978-10-06 1982-08-24 William J. Ball Methode de production d'aluminosilicates, et leur emploi a titre d'agents catalyseurs
DE2918405A1 (de) * 1979-05-08 1980-11-20 Metallgesellschaft Ag Verfahren zur erzeugung von kohlenmonoxid und wasserstoff aus methanol
DE2950251A1 (de) * 1979-12-13 1981-06-19 Kraftwerk Union AG, 4330 Mülheim Verfahren zur umwandlung von waermeenergie in chemisch gebundene energie
NZ196836A (en) * 1980-04-23 1983-06-17 British Petroleum Co Production of synthesis gas from methanol
US4407238A (en) * 1981-10-26 1983-10-04 Conoco Inc. Methanol dissociation using a copper-chromium-manganese catalyst
JPS59152205A (ja) * 1983-02-14 1984-08-30 Mitsubishi Gas Chem Co Inc メタノ−ルの水蒸気改質法
DE3314932A1 (de) * 1983-04-25 1984-10-25 Conoco Inc., Stamford, Conn. Methanolspaltung unter verwendung eines kupfer-chrom-mangan-katalysators
GB8321255D0 (en) * 1983-08-06 1983-09-07 British Petroleum Co Plc Methanol conversion process
US4600529A (en) * 1983-09-19 1986-07-15 Gas Research Institute Dehydrogenation of alcohols using alkali carbonate catalysts
DE3340569A1 (de) * 1983-11-09 1985-05-23 Sued Chemie Ag Katalysator zur herstellung von synthesegas bzw. von wasserstoff und verfahren zu dessen herstellung
DE3403987A1 (de) * 1984-02-04 1985-10-10 Nicolai, Stephan Peter, 4230 Wesel Verfahren zur herstellung von halbsynthetischen schutz- und reaktionsgasen, insbesondere zur waermebehandlung von stahl- und metallwerkstoffen, bestehend aus einer mischung unterschiedlich waehlbarer mengen von stickstoff, wasserstoff, kohlenmonoxyd, kohlendioxyd sowie wasserdampf
US4595396A (en) * 1984-05-14 1986-06-17 Phillips Petroleum Company Composition comprising 1,3,5-trioxane
AU4695985A (en) * 1984-09-04 1986-03-13 Mitsubishi Jukogyo Kabushiki Kaisha Process for reforming methanol
GB8501146D0 (en) * 1985-01-17 1985-02-20 British Petroleum Co Plc Synthesis gas conversion catalyst
US4946667A (en) * 1985-06-10 1990-08-07 Engelhard Corporation Method of steam reforming methanol to hydrogen
US4676972A (en) * 1985-07-29 1987-06-30 The Standard Oil Company Process for the conversion of alcohols to gaseous products
GB8521953D0 (en) * 1985-09-04 1985-10-09 Johnson Matthey Plc Catalytic hydrogen generator
DE19902926C2 (de) * 1999-01-26 2001-01-04 Daimler Chrysler Ag Reaktoranlage und Betriebsverfahren hierfür
US6781014B1 (en) 1999-11-01 2004-08-24 Acetex (Cyprus) Limited Methanol plant retrofit for manufacture of acetic acid
US6274096B1 (en) 1999-11-01 2001-08-14 Acetex (Cyprus) Limited Methanol plant retrofit
JP3759406B2 (ja) * 1999-12-15 2006-03-22 日産自動車株式会社 メタノール改質触媒、メタノール改質装置及びメタノール改質方法
US6531630B2 (en) * 2000-12-29 2003-03-11 Kenneth Ebenes Vidalin Bimodal acetic acid manufacture
US6599491B2 (en) 2001-01-22 2003-07-29 Kenneth Ebenes Vidalin Bimodal hydrogen manufacture
MY146697A (en) 2004-07-09 2012-09-14 Acetex Cyprus Ltd Preparation of syngas for acetic acid synthesis by partial oxidation of methanol feedstock
CN110292924A (zh) * 2019-04-16 2019-10-01 北京氦舶科技有限责任公司 一种甲醇低温裂解催化剂及其制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2010427A (en) * 1933-01-14 1935-08-06 Carbide & Carbon Chem Corp Dehydrogenation of methanol
GB1010574A (en) * 1963-04-23 1965-11-17 British Petroleum Co Production of hydrogen-containing gases
US3338681A (en) * 1963-12-18 1967-08-29 Union Carbide Corp Apparatus for hydrogen generation
DE1567785A1 (de) * 1965-03-13 1970-05-27 Siemens Ag Verfahren zur Herstellung eines Katalysators fuer die Gewinnung von Wasserstoff durch katalytische Umsetzung von Kohlenwasserstoffen und deren sauerstoffhaltigen Derivaten mit Wasserdampf
US3469944A (en) * 1968-05-13 1969-09-30 Joseph P Bocard Process and apparatus for the manufacture of hydrogen for fuel cells
JPS5231995A (en) * 1975-09-08 1977-03-10 Nissan Motor Co Ltd Gas generator
US4046522A (en) * 1976-06-25 1977-09-06 Mobil Oil Corporation Pre-engine converter for use with fuels containing oxygenated compounds
US4091086A (en) * 1976-12-20 1978-05-23 Engelhard Minerals & Chemicals Corporation Process for production of hydrogen

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0385857A1 (fr) * 1989-03-02 1990-09-05 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procédé et installation de production de monoxyde de carbone
FR2643894A1 (fr) * 1989-03-02 1990-09-07 Air Liquide Procede et installation de production de monoxyde de carbone
US5059411A (en) * 1989-03-02 1991-10-22 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploration Des Procedes Georges Claude Process and apparatus for the production of carbon monoxide
EP0405958A1 (fr) * 1989-06-29 1991-01-02 E.I. Du Pont De Nemours And Company Catalyseurs de dissociation du méthanol
US5106810A (en) * 1989-06-29 1992-04-21 E. I. Du Pont De Nemours And Company Methanol dissociation catalysts

Also Published As

Publication number Publication date
ZA782958B (en) 1980-01-30
DE2832136A1 (de) 1979-02-08
BE869280A (fr) 1979-01-26
IT7824693A0 (it) 1978-06-19
IT1096490B (it) 1985-08-26
JPS5425294A (en) 1979-02-26
US4175115A (en) 1979-11-20
GB1577069A (en) 1980-10-15
CA1084709A (fr) 1980-09-02
NL7806278A (nl) 1979-01-30

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Legal Events

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ST Notification of lapse