FR2395246A1 - Procede d'hydroformylation catalytique - Google Patents
Procede d'hydroformylation catalytiqueInfo
- Publication number
- FR2395246A1 FR2395246A1 FR7818565A FR7818565A FR2395246A1 FR 2395246 A1 FR2395246 A1 FR 2395246A1 FR 7818565 A FR7818565 A FR 7818565A FR 7818565 A FR7818565 A FR 7818565A FR 2395246 A1 FR2395246 A1 FR 2395246A1
- Authority
- FR
- France
- Prior art keywords
- olefin
- group
- straight chain
- catalytic hydroformylation
- reaction medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 238000007037 hydroformylation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 239000012429 reaction media Substances 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
La présente invention concerne un procédé d'hydroformylation catalytique d'oléfines internes. Des aldéhydes à chaîne droite sont produits à partir d'un oléfine en faisant réagir cet oléfine dans un milieu de réaction liquide avec de l'hydrogène et du monoxyde de carbone sous une pression totale inférieure à 34, 47 bars en présence d'un complexe de Rh(I) en solution dans ce milieu et un co-catalyseur homogène dissous dans ce milieu de réaction comprenant un complexe de coordination d'un métal de transition autre que le rhodium choisi dans le groupe 6 ou dans le groupe 8 du tableau périodique. L'invention est utilisable pour la fabrication d'aldéhydes à chaîne droite.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2585777 | 1977-06-21 | ||
GB3492077 | 1977-08-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2395246A1 true FR2395246A1 (fr) | 1979-01-19 |
FR2395246B1 FR2395246B1 (fr) | 1984-07-06 |
Family
ID=26257916
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7818565A Granted FR2395246A1 (fr) | 1977-06-21 | 1978-06-21 | Procede d'hydroformylation catalytique |
Country Status (8)
Country | Link |
---|---|
US (1) | US4200592A (fr) |
JP (1) | JPS5416418A (fr) |
CA (1) | CA1102823A (fr) |
DE (1) | DE2827300A1 (fr) |
FR (1) | FR2395246A1 (fr) |
GB (1) | GB2000124B (fr) |
NL (1) | NL7806623A (fr) |
SG (1) | SG46682G (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2459683A1 (fr) * | 1979-06-22 | 1981-01-16 | Ugine Kuhlmann | Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene |
FR2544713A1 (fr) * | 1983-04-22 | 1984-10-26 | Ugine Kuhlmann | Systeme catalytique pour l'hydroformylation des olefines. procede d'hydroformylation |
EP0697391A1 (fr) * | 1994-08-19 | 1996-02-21 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilisation des ligands phosphites dans le procédé d'hydroformylation |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4388477A (en) * | 1981-06-02 | 1983-06-14 | Eastman Kodak Company | Hydroformylation process employing unmodified rhodium-cobalt catalyst |
ATE26696T1 (de) * | 1982-06-11 | 1987-05-15 | Davy Mckee London | Hydroformylierungsverfahren. |
DE3361212D1 (en) * | 1982-06-11 | 1985-12-19 | Davy Mckee London | Hydroformylation process |
US4528404A (en) * | 1983-03-16 | 1985-07-09 | Exxon Research And Engineering Co. | High temperature hydroformylation in the presence of triarylphosphine rhodium carbonyl hydride complex catalyst systems |
JPS6099772U (ja) * | 1983-12-14 | 1985-07-08 | 日本電子株式会社 | 直接試料導入装置 |
JPS62127648U (fr) * | 1986-02-05 | 1987-08-13 | ||
CA1327365C (fr) * | 1988-06-29 | 1994-03-01 | Stephen R. Stobart | Procede pour l'hydroformylation catalytique |
IT1229512B (it) * | 1989-01-27 | 1991-09-03 | Eniricerche Spa | Procedimento per la idroformilazione catalitica di.olefine |
US5233093A (en) * | 1992-07-20 | 1993-08-03 | Arco Chemical Technology, L.P. | Hydroformylation process and bimetallic catalyst therefor |
US5817883A (en) * | 1996-04-24 | 1998-10-06 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for producing hydroxyaldehydes |
US5821389A (en) * | 1996-04-24 | 1998-10-13 | Union Carbide Chemicals & Technology Corporation | Processes for producing hydroxyaldehydes |
US5925754A (en) * | 1997-04-15 | 1999-07-20 | Union Carbide Chemicals & Plastics Technology Corporation | Epsilon caprolactam compositions |
GB0106219D0 (en) * | 2001-03-14 | 2001-05-02 | Ici Plc | Improvements in and relating to the production of oxygenated organic compounds |
US6831035B2 (en) | 2002-01-22 | 2004-12-14 | Eastman Kodak Company | Stabilization of fluorophosphite-containing catalysts |
US7674937B2 (en) * | 2008-05-28 | 2010-03-09 | Eastman Chemical Company | Hydroformylation catalysts |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1171390A (fr) * | 1956-01-11 | 1959-01-26 | Exxon Research Engineering Co | Réaction de synthèse par carbonylation |
US3631111A (en) * | 1968-12-17 | 1971-12-28 | Gulf Research Development Co | Oxo process |
US3989759A (en) * | 1970-07-01 | 1976-11-02 | Atlantic Richfield Company | Hydroformylation process over catalyst having silica alumina support with separate alumina phase and noble metal and cobalt or nickel |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL98500C (fr) * | 1956-01-11 | |||
US3378590A (en) * | 1964-05-27 | 1968-04-16 | Toa Nenryo Kogyo Kk | Production of aldehydes and/or alcohols from compound having olefinic double bonds |
US3488296A (en) * | 1967-02-06 | 1970-01-06 | Exxon Research Engineering Co | Oxonation process |
GB1338225A (en) * | 1969-12-31 | 1973-11-21 | Johnson Matthey Co Ltd | Catalytic reactions |
US4143075A (en) * | 1976-08-12 | 1979-03-06 | Union Carbide Corporation | Control of condensation products in hydroformylation process |
DE2650829A1 (de) * | 1976-11-06 | 1978-05-11 | Basf Ag | Verfahren zur reindarstellung von oxo-aldehyden |
-
1978
- 1978-06-14 GB GB7826881A patent/GB2000124B/en not_active Expired
- 1978-06-19 CA CA305,731A patent/CA1102823A/fr not_active Expired
- 1978-06-19 US US05/916,535 patent/US4200592A/en not_active Expired - Lifetime
- 1978-06-20 NL NL7806623A patent/NL7806623A/xx not_active Application Discontinuation
- 1978-06-21 DE DE19782827300 patent/DE2827300A1/de active Granted
- 1978-06-21 FR FR7818565A patent/FR2395246A1/fr active Granted
- 1978-06-21 JP JP7529278A patent/JPS5416418A/ja active Granted
-
1982
- 1982-09-23 SG SG46682A patent/SG46682G/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1171390A (fr) * | 1956-01-11 | 1959-01-26 | Exxon Research Engineering Co | Réaction de synthèse par carbonylation |
US3631111A (en) * | 1968-12-17 | 1971-12-28 | Gulf Research Development Co | Oxo process |
US3989759A (en) * | 1970-07-01 | 1976-11-02 | Atlantic Richfield Company | Hydroformylation process over catalyst having silica alumina support with separate alumina phase and noble metal and cobalt or nickel |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2459683A1 (fr) * | 1979-06-22 | 1981-01-16 | Ugine Kuhlmann | Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene |
US4306086A (en) | 1979-06-22 | 1981-12-15 | Chimiques Ugine Kuhlmann | Hydroformylation catalyst system and processes |
FR2544713A1 (fr) * | 1983-04-22 | 1984-10-26 | Ugine Kuhlmann | Systeme catalytique pour l'hydroformylation des olefines. procede d'hydroformylation |
WO1984004299A1 (fr) * | 1983-04-22 | 1984-11-08 | Cdf Chemie Spec | Systeme catalytique pour l'hydroformylation des olefines; procede d'hydroformylation |
EP0127501A1 (fr) * | 1983-04-22 | 1984-12-05 | Cdf Chimie Specialites | Système catalytique pour l'hydroformylation des oléfines. Procédé d'hydroformylation |
US4599323A (en) * | 1983-04-22 | 1986-07-08 | Cdf Chimie Specialites | Catalytic system for the hydroformylation of olefins process of hydroformylation |
EP0697391A1 (fr) * | 1994-08-19 | 1996-02-21 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilisation des ligands phosphites dans le procédé d'hydroformylation |
Also Published As
Publication number | Publication date |
---|---|
GB2000124B (en) | 1982-03-24 |
CA1102823A (fr) | 1981-06-09 |
DE2827300C2 (fr) | 1989-09-14 |
US4200592A (en) | 1980-04-29 |
GB2000124A (en) | 1979-01-04 |
FR2395246B1 (fr) | 1984-07-06 |
SG46682G (en) | 1983-02-25 |
JPS6123172B2 (fr) | 1986-06-04 |
NL7806623A (nl) | 1978-12-27 |
JPS5416418A (en) | 1979-02-07 |
DE2827300A1 (de) | 1979-01-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
FR2395246A1 (fr) | Procede d'hydroformylation catalytique | |
FR2419268A1 (fr) | Procede pour la preparation d'aldehydes par hydroformylation d'olefines | |
ATE16475T1 (de) | Hydroformylierungsverfahren. | |
FR2435460A1 (fr) | Procede pour preparer des composes biphenyliques | |
MY112954A (en) | Process for the carbonylation of an alcohol | |
FR2375139A1 (fr) | Procede perfectionne d'obtention d'hydrogene par conversion catalytique d'hydrocarbures en presence de vapeur et appareil pour la mise en oeuvre du procede | |
FR2398695A1 (fr) | Procede de production d'hydrogene et de monoxyde de carbone par decomposition catalytique du methanol | |
FR2385671A1 (fr) | Procede d'hydroformylation utilisant un complexe catalytique a base de rhodium et de ligands diphosphino | |
JPS61148141A (ja) | 重水素化アクリル酸メチルまたは重水素化メタクリル酸メチルの製造法 | |
FR2395245A1 (fr) | Procede de fabrication d'aldehydes a chaine droite a partir d'olefines | |
JPH09500106A (ja) | ループ型装置で実施する発熱方法 | |
TW334421B (en) | Process for the production of acetic acid by the carbonylation of dimethyl ether | |
FR2370024A1 (fr) | Procede catalytique de production d'acides carboxyliques par carbonylation | |
FR2429198A1 (fr) | Procede de preparation d'esters de l'acide oxalique | |
FR2421918A1 (fr) | Procede pour la preparation de polyoxyphenylenes | |
FR2444661A1 (fr) | Procede de preparation d'amines | |
ES288401A1 (es) | Un procedimiento para la preparación de compuestos carbonílicos | |
FR2365549A1 (fr) | Procede pour la preparation d'esters alcoyliques d'acide a-formylpropionique | |
GB1440413A (en) | Process for producing butyraldehydes | |
JPS60208945A (ja) | 第2のエステルの製造方法 | |
FR2434793A1 (fr) | Procede de synthese d'hydrocarbures | |
FR2397389A1 (fr) | Procede de preparation d'alcoylesters d'acides carboxyliques | |
EP0106656A1 (fr) | Préparation d'acides carboxyliques et leurs esters | |
CA2058043C (fr) | Procede de preparation de l'acide adipique par hydroxycarboxylation d'acides penteniques | |
ATE34733T1 (de) | Herstellungsverfahren von perfluoralkanolen. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |