FR2385671A1 - Procede d'hydroformylation utilisant un complexe catalytique a base de rhodium et de ligands diphosphino - Google Patents

Procede d'hydroformylation utilisant un complexe catalytique a base de rhodium et de ligands diphosphino

Info

Publication number
FR2385671A1
FR2385671A1 FR7809347A FR7809347A FR2385671A1 FR 2385671 A1 FR2385671 A1 FR 2385671A1 FR 7809347 A FR7809347 A FR 7809347A FR 7809347 A FR7809347 A FR 7809347A FR 2385671 A1 FR2385671 A1 FR 2385671A1
Authority
FR
France
Prior art keywords
diphosphino
rhodium
hydroformylation process
degrees
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7809347A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Publication of FR2385671A1 publication Critical patent/FR2385671A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Procédé d'hydroformylation d'un composé à insaturation éthylénique afin de produire un dérivé substitué par un groupe formylé, catalysé par du rhodium hydrido carbonyle en association complexe avec un ligand de type diphosphino, caractérisé en ce qu'on utilise comme ligand de type diphosphino un ,composé cyclique optiquement inactif contenant dans le noyau deux atomes de carbone adjacents entre les positions trans desquels les angles dièdres minimum et maximum pouvant être obtenus sont respectivement non inférieur à 90 degrés environ et non supérieur à 180 degrés environ, chacun desdits atomes de carbone adjacents étant substitué par un groupe phosphinométhyle, les groupes phosphinométhyle étant en relation trans l'un par rapport à l'autre.
FR7809347A 1977-03-31 1978-03-30 Procede d'hydroformylation utilisant un complexe catalytique a base de rhodium et de ligands diphosphino Withdrawn FR2385671A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/783,121 US4139565A (en) 1977-03-31 1977-03-31 Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands

Publications (1)

Publication Number Publication Date
FR2385671A1 true FR2385671A1 (fr) 1978-10-27

Family

ID=25128225

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7809347A Withdrawn FR2385671A1 (fr) 1977-03-31 1978-03-30 Procede d'hydroformylation utilisant un complexe catalytique a base de rhodium et de ligands diphosphino

Country Status (13)

Country Link
US (1) US4139565A (fr)
JP (1) JPS53121711A (fr)
AU (1) AU516767B2 (fr)
BE (1) BE865548A (fr)
BR (1) BR7801930A (fr)
DE (1) DE2813963A1 (fr)
ES (1) ES468343A1 (fr)
FR (1) FR2385671A1 (fr)
GB (1) GB1594056A (fr)
IT (1) IT1094049B (fr)
NL (1) NL7803158A (fr)
SE (1) SE7803621L (fr)
ZA (1) ZA781861B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996003363A1 (fr) * 1994-07-27 1996-02-08 Hoechst Aktiengesellschaft Procede d'hydroformylation de composes olefiniquement insatures

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4230641A (en) * 1977-11-21 1980-10-28 Air Products And Chemicals, Inc. Hydroformylation of olefins
US4221744A (en) * 1978-12-01 1980-09-09 Celanese Corporation Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents
US4593141A (en) * 1979-02-12 1986-06-03 Exxon Research And Engineering Co. Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes
US4329511A (en) * 1979-06-18 1982-05-11 Celanese Corporation Hydroformylation process improved by choice of reaction solvent and control of product stripping parameters
US4332971A (en) * 1979-08-09 1982-06-01 Celanese Corporation Process for the oxidation of olefinically unsaturated hydrocarbons to aldehydes using attrition resistant catalysts
JPS5626830A (en) * 1979-08-10 1981-03-16 Kuraray Co Ltd Hydroformylation of lower olefin
US4687874A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts
US4593011A (en) * 1981-08-17 1986-06-03 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4522933A (en) * 1981-08-17 1985-06-11 Union Carbide Corporation Hydroformylation catalyst containing bisphosphine monooxide ligands
US4400548A (en) * 1981-08-17 1983-08-23 Union Carbide Corporation Hydroformylation process using bisphosphine monooxide ligands
US4491675A (en) * 1981-08-17 1985-01-01 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
ATE49010T1 (de) * 1983-04-06 1990-01-15 Shell Int Research Verfahren zur herstellung von polyketonen.
US4528278A (en) * 1984-04-11 1985-07-09 Sun Tech, Inc. Catalyst for hydroformylation of olefins
US4625068A (en) * 1985-03-20 1986-11-25 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of internal olefins
US4879008A (en) * 1987-11-09 1989-11-07 Eastman Kodak Company Preparation of bidentate ligands
US4879416A (en) * 1987-11-23 1989-11-07 Eastman Kodak Company Preparation of bidentate ligands
US5026886A (en) * 1988-01-25 1991-06-25 Eastman Kodak Company Preparation of bidentate ligands
CA1327365C (fr) * 1988-06-29 1994-03-01 Stephen R. Stobart Procede pour l'hydroformylation catalytique
US5332846A (en) * 1993-06-01 1994-07-26 Eastman Kodak Company Hydroformylation process using novel phosphine-rhodium catalyst system
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5567856A (en) * 1995-05-30 1996-10-22 Hoechst Celanese Corporation Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands
US7279606B1 (en) * 2007-04-02 2007-10-09 Lyondell Chemical Technology, L.P. Hydroformylation process
EP2208719A1 (fr) 2009-01-15 2010-07-21 Sasol Solvents Germany GmbH Procédé de production d'alcools inférieurs par hydratation d'oléfine

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2208872A1 (en) * 1972-12-06 1974-06-28 Inst Francais Du Petrole Asymmetric olefin hydroformylation - using rhodium or cobalt complex of asymmetric diphosphine as catalyst
FR2219141A1 (fr) * 1972-12-04 1974-09-20 Pino Piero

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3239566A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
FR2230654B1 (fr) * 1973-05-21 1975-11-21 Rhone Poulenc Ind
BE840906A (fr) * 1975-04-21 1976-10-20 Catalyseur d'hydroformylation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2219141A1 (fr) * 1972-12-04 1974-09-20 Pino Piero
GB1402832A (en) * 1972-12-04 1975-08-13 Pino P Asymmetric hydroformylation
FR2208872A1 (en) * 1972-12-06 1974-06-28 Inst Francais Du Petrole Asymmetric olefin hydroformylation - using rhodium or cobalt complex of asymmetric diphosphine as catalyst

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996003363A1 (fr) * 1994-07-27 1996-02-08 Hoechst Aktiengesellschaft Procede d'hydroformylation de composes olefiniquement insatures

Also Published As

Publication number Publication date
JPS53121711A (en) 1978-10-24
GB1594056A (en) 1981-07-30
AU3447678A (en) 1979-09-27
SE7803621L (sv) 1978-11-17
BE865548A (fr) 1978-10-02
ZA781861B (en) 1979-11-28
AU516767B2 (en) 1981-06-18
IT7821845A0 (it) 1978-03-31
BR7801930A (pt) 1979-04-03
IT1094049B (it) 1985-07-26
NL7803158A (nl) 1978-10-03
DE2813963A1 (de) 1978-10-12
US4139565A (en) 1979-02-13
ES468343A1 (es) 1978-12-16

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