ES468343A1 - Un procedimiento mejorado de hidroformilacion de un compues-to etilenicamente insaturado. - Google Patents
Un procedimiento mejorado de hidroformilacion de un compues-to etilenicamente insaturado.Info
- Publication number
- ES468343A1 ES468343A1 ES468343A ES468343A ES468343A1 ES 468343 A1 ES468343 A1 ES 468343A1 ES 468343 A ES468343 A ES 468343A ES 468343 A ES468343 A ES 468343A ES 468343 A1 ES468343 A1 ES 468343A1
- Authority
- ES
- Spain
- Prior art keywords
- rhodium
- ligand
- carbon atoms
- adjacent carbon
- hydroformylation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Un procedimiento mejorado de hidroformilación de un compuesto etilénicamente insaturado, que tiene desde 2 hasta alrededor de 25 átomos de carbono y exento de átomos substituyentes además del oxígeno y el nitrógeno con hidrógeno y monóxido de carbono en una zona de reacción en fase líquida para producir un derivado de aldehido de dicho compuesto etilénicamente insaturado, catalizándose dicha hidroformilación con hidruro de carbonilo de rodio en una composición compleja con un ligador difosfino a una temperatura de desde alrededor de 50ºC., hasta alrededor de 200ºC., bajo una presión combinada parcial de hidrógeno y monóxido de carbono de cuando menos un atmósfera y siendo la presión parcial de hidrógeno respecto aquella del monóxido de carbono de desde alrededor de 10:1 hasta alrededor de 1:10, en el que la mejora comprende: emplear como dicho ligador difosfino un compuesto cíclico óptimamente inactivo que tiene en el anillo dos átomos de carbono adyacentes entre las posiciones trans de las cuales los ángulo di-hédricos mínimos y máximo son, respectivamente, no menores de 90º y no mayores de alrededor de 180º, substituyénsode cada uno de dichos átomos de carbono adyacentes con un grupo fosfinometilo estando dichos grupos fosfinometilo en una relación trans uno respecto al otro.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/783,121 US4139565A (en) | 1977-03-31 | 1977-03-31 | Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands |
Publications (1)
Publication Number | Publication Date |
---|---|
ES468343A1 true ES468343A1 (es) | 1978-12-16 |
Family
ID=25128225
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES468343A Expired ES468343A1 (es) | 1977-03-31 | 1978-03-30 | Un procedimiento mejorado de hidroformilacion de un compues-to etilenicamente insaturado. |
Country Status (13)
Country | Link |
---|---|
US (1) | US4139565A (es) |
JP (1) | JPS53121711A (es) |
AU (1) | AU516767B2 (es) |
BE (1) | BE865548A (es) |
BR (1) | BR7801930A (es) |
DE (1) | DE2813963A1 (es) |
ES (1) | ES468343A1 (es) |
FR (1) | FR2385671A1 (es) |
GB (1) | GB1594056A (es) |
IT (1) | IT1094049B (es) |
NL (1) | NL7803158A (es) |
SE (1) | SE7803621L (es) |
ZA (1) | ZA781861B (es) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4230641A (en) * | 1977-11-21 | 1980-10-28 | Air Products And Chemicals, Inc. | Hydroformylation of olefins |
US4221744A (en) * | 1978-12-01 | 1980-09-09 | Celanese Corporation | Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents |
US4593141A (en) * | 1979-02-12 | 1986-06-03 | Exxon Research And Engineering Co. | Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes |
US4329511A (en) * | 1979-06-18 | 1982-05-11 | Celanese Corporation | Hydroformylation process improved by choice of reaction solvent and control of product stripping parameters |
US4332971A (en) * | 1979-08-09 | 1982-06-01 | Celanese Corporation | Process for the oxidation of olefinically unsaturated hydrocarbons to aldehydes using attrition resistant catalysts |
JPS5626830A (en) * | 1979-08-10 | 1981-03-16 | Kuraray Co Ltd | Hydroformylation of lower olefin |
US4687874A (en) * | 1980-02-12 | 1987-08-18 | Exxon Research And Engineering Company | Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts |
US4522933A (en) * | 1981-08-17 | 1985-06-11 | Union Carbide Corporation | Hydroformylation catalyst containing bisphosphine monooxide ligands |
US4491675A (en) * | 1981-08-17 | 1985-01-01 | Union Carbide Corporation | Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands |
US4593011A (en) * | 1981-08-17 | 1986-06-03 | Union Carbide Corporation | Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands |
US4400548A (en) * | 1981-08-17 | 1983-08-23 | Union Carbide Corporation | Hydroformylation process using bisphosphine monooxide ligands |
DE3480845D1 (de) * | 1983-04-06 | 1990-02-01 | Shell Int Research | Verfahren zur herstellung von polyketonen. |
US4528278A (en) * | 1984-04-11 | 1985-07-09 | Sun Tech, Inc. | Catalyst for hydroformylation of olefins |
US4625068A (en) * | 1985-03-20 | 1986-11-25 | Exxon Chemical Patents Inc. | Rhodium catalyzed hydroformylation of internal olefins |
US4879008A (en) * | 1987-11-09 | 1989-11-07 | Eastman Kodak Company | Preparation of bidentate ligands |
US4879416A (en) * | 1987-11-23 | 1989-11-07 | Eastman Kodak Company | Preparation of bidentate ligands |
US5026886A (en) * | 1988-01-25 | 1991-06-25 | Eastman Kodak Company | Preparation of bidentate ligands |
CA1327365C (en) * | 1988-06-29 | 1994-03-01 | Stephen R. Stobart | Process for catalytic hydroformylation |
US5332846A (en) * | 1993-06-01 | 1994-07-26 | Eastman Kodak Company | Hydroformylation process using novel phosphine-rhodium catalyst system |
DE4426577C2 (de) * | 1994-07-27 | 1998-01-22 | Hoechst Ag | Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen |
US5675041A (en) * | 1995-01-18 | 1997-10-07 | Exxon Research & Engineering Company | Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene |
US5516965A (en) * | 1995-01-18 | 1996-05-14 | Exxon Research And Engineering Company | Unsaturates recovery and recycle process |
US5520722A (en) * | 1995-01-18 | 1996-05-28 | Exxon Research And Engineering Company | Multiunsaturates removal process |
US5567856A (en) * | 1995-05-30 | 1996-10-22 | Hoechst Celanese Corporation | Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands |
US7279606B1 (en) * | 2007-04-02 | 2007-10-09 | Lyondell Chemical Technology, L.P. | Hydroformylation process |
EP2208719A1 (en) | 2009-01-15 | 2010-07-21 | Sasol Solvents Germany GmbH | Process for the production of lower alcohols by olefin hydration |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3239566A (en) * | 1960-07-22 | 1966-03-08 | Shell Oil Co | Hydroformylation of olefins |
US3527809A (en) * | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
DE2359101A1 (de) * | 1972-12-04 | 1974-06-06 | Piero Prof Dr Pino | Verfahren zur asymmetrischen hydroformylierung |
FR2208872A1 (en) * | 1972-12-06 | 1974-06-28 | Inst Francais Du Petrole | Asymmetric olefin hydroformylation - using rhodium or cobalt complex of asymmetric diphosphine as catalyst |
FR2230654B1 (es) * | 1973-05-21 | 1975-11-21 | Rhone Poulenc Ind | |
BE840906A (fr) * | 1975-04-21 | 1976-10-20 | Catalyseur d'hydroformylation |
-
1977
- 1977-03-31 US US05/783,121 patent/US4139565A/en not_active Expired - Lifetime
-
1978
- 1978-03-17 GB GB10697/78A patent/GB1594056A/en not_active Expired
- 1978-03-23 NL NL7803158A patent/NL7803158A/xx not_active Application Discontinuation
- 1978-03-23 AU AU34476/78A patent/AU516767B2/en not_active Expired
- 1978-03-28 JP JP3493778A patent/JPS53121711A/ja active Pending
- 1978-03-29 BR BR7801930A patent/BR7801930A/pt unknown
- 1978-03-30 SE SE7803621A patent/SE7803621L/xx unknown
- 1978-03-30 ES ES468343A patent/ES468343A1/es not_active Expired
- 1978-03-30 FR FR7809347A patent/FR2385671A1/fr not_active Withdrawn
- 1978-03-31 BE BE186445A patent/BE865548A/xx unknown
- 1978-03-31 DE DE19782813963 patent/DE2813963A1/de not_active Withdrawn
- 1978-03-31 ZA ZA00781861A patent/ZA781861B/xx unknown
- 1978-03-31 IT IT21845/78A patent/IT1094049B/it active
Also Published As
Publication number | Publication date |
---|---|
FR2385671A1 (fr) | 1978-10-27 |
IT7821845A0 (it) | 1978-03-31 |
BE865548A (fr) | 1978-10-02 |
BR7801930A (pt) | 1979-04-03 |
IT1094049B (it) | 1985-07-26 |
GB1594056A (en) | 1981-07-30 |
SE7803621L (sv) | 1978-11-17 |
AU3447678A (en) | 1979-09-27 |
US4139565A (en) | 1979-02-13 |
NL7803158A (nl) | 1978-10-03 |
JPS53121711A (en) | 1978-10-24 |
ZA781861B (en) | 1979-11-28 |
AU516767B2 (en) | 1981-06-18 |
DE2813963A1 (de) | 1978-10-12 |
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