ES468343A1 - Un procedimiento mejorado de hidroformilacion de un compues-to etilenicamente insaturado. - Google Patents

Un procedimiento mejorado de hidroformilacion de un compues-to etilenicamente insaturado.

Info

Publication number
ES468343A1
ES468343A1 ES468343A ES468343A ES468343A1 ES 468343 A1 ES468343 A1 ES 468343A1 ES 468343 A ES468343 A ES 468343A ES 468343 A ES468343 A ES 468343A ES 468343 A1 ES468343 A1 ES 468343A1
Authority
ES
Spain
Prior art keywords
rhodium
ligand
carbon atoms
adjacent carbon
hydroformylation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES468343A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Publication of ES468343A1 publication Critical patent/ES468343A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Un procedimiento mejorado de hidroformilación de un compuesto etilénicamente insaturado, que tiene desde 2 hasta alrededor de 25 átomos de carbono y exento de átomos substituyentes además del oxígeno y el nitrógeno con hidrógeno y monóxido de carbono en una zona de reacción en fase líquida para producir un derivado de aldehido de dicho compuesto etilénicamente insaturado, catalizándose dicha hidroformilación con hidruro de carbonilo de rodio en una composición compleja con un ligador difosfino a una temperatura de desde alrededor de 50ºC., hasta alrededor de 200ºC., bajo una presión combinada parcial de hidrógeno y monóxido de carbono de cuando menos un atmósfera y siendo la presión parcial de hidrógeno respecto aquella del monóxido de carbono de desde alrededor de 10:1 hasta alrededor de 1:10, en el que la mejora comprende: emplear como dicho ligador difosfino un compuesto cíclico óptimamente inactivo que tiene en el anillo dos átomos de carbono adyacentes entre las posiciones trans de las cuales los ángulo di-hédricos mínimos y máximo son, respectivamente, no menores de 90º y no mayores de alrededor de 180º, substituyénsode cada uno de dichos átomos de carbono adyacentes con un grupo fosfinometilo estando dichos grupos fosfinometilo en una relación trans uno respecto al otro.
ES468343A 1977-03-31 1978-03-30 Un procedimiento mejorado de hidroformilacion de un compues-to etilenicamente insaturado. Expired ES468343A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/783,121 US4139565A (en) 1977-03-31 1977-03-31 Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands

Publications (1)

Publication Number Publication Date
ES468343A1 true ES468343A1 (es) 1978-12-16

Family

ID=25128225

Family Applications (1)

Application Number Title Priority Date Filing Date
ES468343A Expired ES468343A1 (es) 1977-03-31 1978-03-30 Un procedimiento mejorado de hidroformilacion de un compues-to etilenicamente insaturado.

Country Status (13)

Country Link
US (1) US4139565A (es)
JP (1) JPS53121711A (es)
AU (1) AU516767B2 (es)
BE (1) BE865548A (es)
BR (1) BR7801930A (es)
DE (1) DE2813963A1 (es)
ES (1) ES468343A1 (es)
FR (1) FR2385671A1 (es)
GB (1) GB1594056A (es)
IT (1) IT1094049B (es)
NL (1) NL7803158A (es)
SE (1) SE7803621L (es)
ZA (1) ZA781861B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4230641A (en) * 1977-11-21 1980-10-28 Air Products And Chemicals, Inc. Hydroformylation of olefins
US4221744A (en) * 1978-12-01 1980-09-09 Celanese Corporation Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents
US4593141A (en) * 1979-02-12 1986-06-03 Exxon Research And Engineering Co. Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes
US4329511A (en) * 1979-06-18 1982-05-11 Celanese Corporation Hydroformylation process improved by choice of reaction solvent and control of product stripping parameters
US4332971A (en) * 1979-08-09 1982-06-01 Celanese Corporation Process for the oxidation of olefinically unsaturated hydrocarbons to aldehydes using attrition resistant catalysts
JPS5626830A (en) * 1979-08-10 1981-03-16 Kuraray Co Ltd Hydroformylation of lower olefin
US4687874A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts
US4522933A (en) * 1981-08-17 1985-06-11 Union Carbide Corporation Hydroformylation catalyst containing bisphosphine monooxide ligands
US4491675A (en) * 1981-08-17 1985-01-01 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4593011A (en) * 1981-08-17 1986-06-03 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4400548A (en) * 1981-08-17 1983-08-23 Union Carbide Corporation Hydroformylation process using bisphosphine monooxide ligands
DE3480845D1 (de) * 1983-04-06 1990-02-01 Shell Int Research Verfahren zur herstellung von polyketonen.
US4528278A (en) * 1984-04-11 1985-07-09 Sun Tech, Inc. Catalyst for hydroformylation of olefins
US4625068A (en) * 1985-03-20 1986-11-25 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of internal olefins
US4879008A (en) * 1987-11-09 1989-11-07 Eastman Kodak Company Preparation of bidentate ligands
US4879416A (en) * 1987-11-23 1989-11-07 Eastman Kodak Company Preparation of bidentate ligands
US5026886A (en) * 1988-01-25 1991-06-25 Eastman Kodak Company Preparation of bidentate ligands
CA1327365C (en) * 1988-06-29 1994-03-01 Stephen R. Stobart Process for catalytic hydroformylation
US5332846A (en) * 1993-06-01 1994-07-26 Eastman Kodak Company Hydroformylation process using novel phosphine-rhodium catalyst system
DE4426577C2 (de) * 1994-07-27 1998-01-22 Hoechst Ag Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5567856A (en) * 1995-05-30 1996-10-22 Hoechst Celanese Corporation Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands
US7279606B1 (en) * 2007-04-02 2007-10-09 Lyondell Chemical Technology, L.P. Hydroformylation process
EP2208719A1 (en) 2009-01-15 2010-07-21 Sasol Solvents Germany GmbH Process for the production of lower alcohols by olefin hydration

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3239566A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
DE2359101A1 (de) * 1972-12-04 1974-06-06 Piero Prof Dr Pino Verfahren zur asymmetrischen hydroformylierung
FR2208872A1 (en) * 1972-12-06 1974-06-28 Inst Francais Du Petrole Asymmetric olefin hydroformylation - using rhodium or cobalt complex of asymmetric diphosphine as catalyst
FR2230654B1 (es) * 1973-05-21 1975-11-21 Rhone Poulenc Ind
BE840906A (fr) * 1975-04-21 1976-10-20 Catalyseur d'hydroformylation

Also Published As

Publication number Publication date
FR2385671A1 (fr) 1978-10-27
IT7821845A0 (it) 1978-03-31
BE865548A (fr) 1978-10-02
BR7801930A (pt) 1979-04-03
IT1094049B (it) 1985-07-26
GB1594056A (en) 1981-07-30
SE7803621L (sv) 1978-11-17
AU3447678A (en) 1979-09-27
US4139565A (en) 1979-02-13
NL7803158A (nl) 1978-10-03
JPS53121711A (en) 1978-10-24
ZA781861B (en) 1979-11-28
AU516767B2 (en) 1981-06-18
DE2813963A1 (de) 1978-10-12

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