FR2378085A1 - Procede de conversion d'une matiere de charge carbonee solide en presence d'un catalyseur contenant un metal alcalin - Google Patents

Procede de conversion d'une matiere de charge carbonee solide en presence d'un catalyseur contenant un metal alcalin

Info

Publication number
FR2378085A1
FR2378085A1 FR7801725A FR7801725A FR2378085A1 FR 2378085 A1 FR2378085 A1 FR 2378085A1 FR 7801725 A FR7801725 A FR 7801725A FR 7801725 A FR7801725 A FR 7801725A FR 2378085 A1 FR2378085 A1 FR 2378085A1
Authority
FR
France
Prior art keywords
alkali metal
converting
catalyst containing
filler material
alkaline metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7801725A
Other languages
English (en)
Other versions
FR2378085B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of FR2378085A1 publication Critical patent/FR2378085A1/fr
Application granted granted Critical
Publication of FR2378085B1 publication Critical patent/FR2378085B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0986—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C10J2300/1823—Recycle loops, e.g. gas, solids, heating medium, water for synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1853—Steam reforming, i.e. injection of steam only
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un procécé de conversion d'une matière de charge carbonée solide en présence d'un catalyseur contenant un métal alcalin en liquides et/ou en gaz. Ce procédé consiste : a. à mélanger les résidus de métaux alcalins avec un composé solide contenant du calcium pour former un mélange de solides; b. à chauffer le mélange de solides à une température suffisamment élevée pour que l'oxyde de calcium puisse réagir avec les aluminosilicates de métaux alcalins dans les résidus de métaux alcalins; c. à mettre en contact les produits de réaction avec l'eau; d.à abaisser suffisamment le pH de la solution aqueuse; et e. à utiliser les constituants de métaux alcalins provenant de la solution aqueuse formée dans l'opération d, dans le procédé de conversion. Application à la gazéification ou liquéfaction de la houille.
FR7801725A 1977-01-24 1978-01-20 Procede de conversion d'une matiere de charge carbonee solide en presence d'un catalyseur contenant un metal alcalin Granted FR2378085A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US76254877A 1977-01-24 1977-01-24

Publications (2)

Publication Number Publication Date
FR2378085A1 true FR2378085A1 (fr) 1978-08-18
FR2378085B1 FR2378085B1 (fr) 1983-11-25

Family

ID=25065376

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7801725A Granted FR2378085A1 (fr) 1977-01-24 1978-01-20 Procede de conversion d'une matiere de charge carbonee solide en presence d'un catalyseur contenant un metal alcalin

Country Status (8)

Country Link
JP (1) JPS6039116B2 (fr)
AU (1) AU511653B2 (fr)
BR (1) BR7800385A (fr)
CA (1) CA1119542A (fr)
DE (1) DE2802825A1 (fr)
FR (1) FR2378085A1 (fr)
GB (1) GB1595612A (fr)
ZA (1) ZA78154B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0046829A1 (fr) * 1980-09-02 1982-03-10 Exxon Research And Engineering Company Récupération de constituants de métaux alcalins à partir de résidus de conversion de charbon

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4439304A (en) * 1982-07-09 1984-03-27 Conoco Inc. Process for beneficiating high sulfur, high fluidity coal
JPS62149792A (ja) * 1985-12-25 1987-07-03 Mitsubishi Heavy Ind Ltd ガス化装置
JPS63716A (ja) * 1986-06-20 1988-01-05 Matsushita Electric Works Ltd 温風器の温度制御装置
US7922782B2 (en) * 2006-06-01 2011-04-12 Greatpoint Energy, Inc. Catalytic steam gasification process with recovery and recycle of alkali metal compounds
CN101910374B (zh) * 2007-12-28 2015-11-25 格雷特波因特能源公司 用于催化气化的石油焦炭组合物
CN103952184B (zh) * 2014-05-14 2016-08-24 北京神雾环境能源科技集团股份有限公司 煤催化气化制备竖炉用还原气的方法和系统
CN104043485B (zh) * 2014-06-09 2016-03-23 新奥科技发展有限公司 一种催化剂回收及负载方法
CN110624581B (zh) * 2018-06-25 2022-04-15 中国石油化工股份有限公司 一种回收煤气化催化剂的方法
US10464872B1 (en) 2018-07-31 2019-11-05 Greatpoint Energy, Inc. Catalytic gasification to produce methanol
US10344231B1 (en) 2018-10-26 2019-07-09 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with improved carbon utilization
US10435637B1 (en) 2018-12-18 2019-10-08 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with improved carbon utilization and power generation
US10618818B1 (en) 2019-03-22 2020-04-14 Sure Champion Investment Limited Catalytic gasification to produce ammonia and urea

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2130474A1 (fr) * 1971-03-18 1972-11-03 Exxon Research Engineering Co
US3998607A (en) * 1975-05-12 1976-12-21 Exxon Research And Engineering Company Alkali metal catalyst recovery process

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2141132A (en) * 1936-06-11 1938-12-20 Cowles Detergent Company Process of treating siliceous materials

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2130474A1 (fr) * 1971-03-18 1972-11-03 Exxon Research Engineering Co
US3998607A (en) * 1975-05-12 1976-12-21 Exxon Research And Engineering Company Alkali metal catalyst recovery process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CA1976 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0046829A1 (fr) * 1980-09-02 1982-03-10 Exxon Research And Engineering Company Récupération de constituants de métaux alcalins à partir de résidus de conversion de charbon

Also Published As

Publication number Publication date
ZA78154B (en) 1978-12-27
AU511653B2 (en) 1980-08-28
BR7800385A (pt) 1978-08-22
JPS5394305A (en) 1978-08-18
JPS6039116B2 (ja) 1985-09-04
CA1119542A (fr) 1982-03-09
AU3249978A (en) 1979-07-26
FR2378085B1 (fr) 1983-11-25
GB1595612A (en) 1981-08-12
DE2802825A1 (de) 1978-07-27

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