GB994208A - Production of hydrogen-containing gas - Google Patents
Production of hydrogen-containing gasInfo
- Publication number
- GB994208A GB994208A GB22975/63A GB2297563A GB994208A GB 994208 A GB994208 A GB 994208A GB 22975/63 A GB22975/63 A GB 22975/63A GB 2297563 A GB2297563 A GB 2297563A GB 994208 A GB994208 A GB 994208A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkali metal
- steam
- metal compound
- reaction
- carbonaceous material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/57—Gasification using molten salts or metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/74—Construction of shells or jackets
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
- C10J3/845—Quench rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/094—Char
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
- C10J2300/0976—Water as steam
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1253—Heating the gasifier by injecting hot gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Abstract
A hydrogen-containing gas is produced by reacting a solid carbonaceous material and steam in a molten reaction medium comprising an alkali metal compound. Carbonaceous materials mentioned are coal (various grades), lignite, coke (from coal or petroleum), peat graphite, charcoal, wood, sawdust, non-wood, material (e.g. bagasse, cotton stalks), sugar and cellulose waste, and may be in lump, granular or pulverized form. The alkali metal compound may be one or more of the alkali metal carbonates and hydroxides, but any alkali metal compound convertible under the reaction conditions to an equilibrium mixture of the carbonate and hydroxide, e.g. sulphates, chlorides, nitrates and oxides may be used. Alkaline earth metal compounds may be included in the melt. The process may be worked continuously, the molten compound being circulated between the reaction zone and a heating zone, and the carbonaceous material and the steam supplied separately or together to one or more points in the reaction zone, e.g. pulverized material may be entrained in a stream of steam, e.g. by delivering a slurry of the material in water to the zone. The melt may be heated in the heating zone by burning coal in preheated air in the melt, or the reaction zone may be heated, e.g. electrically. Alternatively, the alkali metal compound may be mixed with the carbonaceous material before melting, and eight specific examples of this method of operation are described. The temperature of the reaction should be 800 DEG to 1,800 DEG F., preferably 1,000 DEG to 1,700 DEG F., and pressures of 15 to 1,000 p.s.i.a., preferably 200 to 850 p.s.i.a., are mentioned. A steam/carbon mol. ratio of 1 to 5 and a weight ratio ranging from 2 to 25 for the molten salt to carbonaceous material are mentioned. An ash-rich stream is continuously or intermittently discharged, and may be treated with water to recover alkali metal.ALSO:A hydrogen-containing gas is produced by reacting a solid carbonaceous material and steam in a molten reaction medium comprising an alkali metal compound. Carbonaceous materials mentioned are coal (various grades), lignite, coke (from coal or petroleum), peat, graphite, charcoal, wood, sawdust, non-woody material (e.g. bagasse, cotton stalks), sugar and cellulose waste, and may be in lump, granular or pulverized form. The alkali metal compound may be one or more of the alkali metal carbonates and hydroxides, but any alkali metal compound convertible under the reaction conditions to an equilibrium mixture of the carbonate and hydroxide, e.g. sulphates, chlorides, nitrates and oxides may be used. Alkaline earth metal compounds may be include in the melt. The process may be worked continuously, the molten compound being circulated between the reaction zone and a heating zone, and the carbonaceous material and the steam supplied separately or together to one or more points in the reaction zone, e.g. pulverized material may be entrained in a stream of steam, e.g. by delivering a slurry of the material in water to the zone. The melt may be heated in the heating zone by burning coal in preheated air in the melt, or the reaction zone may be heated, e.g. electrically. Alternatively, the alkali metal compound may be mixed with the carbonaceous material before melting, and eight specific examples of this method of operation are described. The temperature of the reaction should be 800 DEG to 1800 DEG F., preferably 1000 DEG to 1700 DEG F., and pressures of 15 to 1000 p.s.i.a., preferably 200 to 850 p.s.i.a., are mentioned. A steam/carbon mole ratio of 1 to 5 and a weight ratio ranging from 2 to 25 for the molten salt to carbonaceous material are mentioned. An ash-rich stream is continuously or intermittently discharged, and may be treated with water to recover alkali metal.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201534A US3252773A (en) | 1962-06-11 | 1962-06-11 | Gasification of carbonaceous fuels |
Publications (1)
Publication Number | Publication Date |
---|---|
GB994208A true GB994208A (en) | 1965-06-02 |
Family
ID=22746221
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB22975/63A Expired GB994208A (en) | 1962-06-11 | 1963-06-10 | Production of hydrogen-containing gas |
Country Status (2)
Country | Link |
---|---|
US (1) | US3252773A (en) |
GB (1) | GB994208A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2549488A1 (en) * | 1983-07-23 | 1985-01-25 | Metallgesellschaft Ag | METHOD FOR OPERATING A GASIFICATION FACILITY FOR SOLID FUELS |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3505204A (en) * | 1967-04-10 | 1970-04-07 | Univ Of Wyoming The | Direct conversion of carbonaceous material to hydrocarbons |
US3759036A (en) * | 1970-03-01 | 1973-09-18 | Chevron Res | Power generation |
US3890432A (en) * | 1970-05-05 | 1975-06-17 | Chevron Res | Catalytic hydrogen manufacture |
US3775072A (en) * | 1970-12-14 | 1973-11-27 | Chevron Res | Gas production |
US3770399A (en) * | 1971-10-22 | 1973-11-06 | Sun Research Development | Coal gasification process |
US3929431A (en) * | 1972-09-08 | 1975-12-30 | Exxon Research Engineering Co | Catalytic reforming process |
US3916617A (en) * | 1974-03-29 | 1975-11-04 | Rockwell International Corp | Process for production of low BTU gas |
US3989480A (en) * | 1974-09-05 | 1976-11-02 | The United States Of America As Represented By The United States Energy Research And Development Administration | Decomposition of carbohydrate wastes |
US3966582A (en) * | 1974-10-07 | 1976-06-29 | Clean Energy Corporation | Solubilization and reaction of coal and like carbonaceous feedstocks to hydrocarbons and apparatus therefor |
US3966583A (en) * | 1974-10-07 | 1976-06-29 | Clean Energy Corporation | Coal treatment process and apparatus |
US4158697A (en) * | 1975-12-29 | 1979-06-19 | Clean Energy Corporation | Coal treatment apparatus |
US4074980A (en) * | 1976-07-02 | 1978-02-21 | Horizons Research Incorporated | Process for production of carbon monoxide and hydrogen |
US4455153A (en) * | 1978-05-05 | 1984-06-19 | Jakahi Douglas Y | Apparatus for storing solar energy in synthetic fuels |
ZA793440B (en) * | 1978-07-17 | 1980-07-30 | Exxon Research Engineering Co | Catalytic coal gasification process |
DE2837952A1 (en) * | 1978-08-31 | 1980-03-13 | Ght Hochtemperaturreak Tech | COAL GASIFICATION |
BR7902079A (en) * | 1979-04-04 | 1980-10-21 | E Oliveira | METHANOL SYNTHESIS PROCESS |
US4366045A (en) * | 1980-01-22 | 1982-12-28 | Rollan Swanson | Process for conversion of coal to gaseous hydrocarbons |
US4421631A (en) * | 1981-10-02 | 1983-12-20 | Rockwell International Corporation | Hydrocarbon treatment process |
US4468316A (en) * | 1983-03-03 | 1984-08-28 | Chemroll Enterprises, Inc. | Hydrogenation of asphaltenes and the like |
US4558027A (en) * | 1984-05-25 | 1985-12-10 | The United States Of America As Represented By The United States Department Of Energy | Catalysts for carbon and coal gasification |
DE3434004A1 (en) * | 1984-09-15 | 1986-05-22 | Dornier System Gmbh, 7990 Friedrichshafen | METHOD AND DEVICE FOR MUEL GASIFICATION |
US4668494A (en) * | 1984-12-24 | 1987-05-26 | Foster Wheeler Energy Corporation | Method of using solar energy in a chemical synthesis process |
US4865625A (en) * | 1988-05-02 | 1989-09-12 | Battelle Memorial Institute | Method of producing pyrolysis gases from carbon-containing materials |
DE19722059A1 (en) * | 1997-05-27 | 1998-12-03 | Boehlke Eckard | Recovery of gas mixtures containing hydrogen@ and carbon mon:oxide |
EP0991734B1 (en) * | 1997-06-12 | 2001-08-29 | PAC Holding S.A. | Method for the disposal of waste products containing hydrocarbons and/or halogenated waste products |
NL1008832C2 (en) * | 1998-04-07 | 1999-10-08 | Univ Delft Tech | A method of converting a carbon-containing material, a method of operating a fuel cell and a method of operating a fuel cell stack. |
US20050163704A1 (en) * | 2004-01-23 | 2005-07-28 | Ovonic Battery Company | Base-facilitated production of hydrogen from biomass |
CN1965061B (en) * | 2003-12-19 | 2010-06-16 | 国际壳牌研究有限公司 | Systems and methods of producing a crude product |
NL1027775C2 (en) * | 2003-12-19 | 2008-06-10 | Shell Int Research | Systems and methods for preparing a crude product. |
US20060289340A1 (en) * | 2003-12-19 | 2006-12-28 | Brownscombe Thomas F | Methods for producing a total product in the presence of sulfur |
US20070012595A1 (en) * | 2003-12-19 | 2007-01-18 | Brownscombe Thomas F | Methods for producing a total product in the presence of sulfur |
US20050133405A1 (en) | 2003-12-19 | 2005-06-23 | Wellington Scott L. | Systems and methods of producing a crude product |
MX2008015820A (en) * | 2006-06-22 | 2009-01-09 | Shell Int Research | Methods for producing a total product with selective hydrocarbon production. |
RU2009101916A (en) * | 2006-06-22 | 2010-07-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | METHODS FOR PRODUCING UNCLEANED PRODUCT FROM SELECTED RAW MATERIALS |
DE102006040662B3 (en) * | 2006-08-30 | 2008-03-27 | Pac Holding S.A. | Process and device for recycling oxygen-containing polymers |
US20080141591A1 (en) * | 2006-12-19 | 2008-06-19 | Simulent Inc. | Gasification of sulfur-containing carbonaceous fuels |
DE102008028788B4 (en) * | 2008-06-17 | 2010-04-22 | Forschungszentrum Karlsruhe Gmbh | Apparatus and method for converting biomass into gaseous products |
US9605219B2 (en) | 2012-02-07 | 2017-03-28 | Regents Of The University Of Minnesota | Solar gasifier |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US701186A (en) * | 1901-07-25 | 1902-05-27 | William J Faulkner | Apparatus for generating gas. |
GB191007718A (en) * | 1909-07-07 | 1911-03-30 | Otto Dieffenbach | Improvements in the Production of Hydrogen. |
GB322959A (en) * | 1929-02-20 | 1929-12-19 | Theodor Lichtenberger | A process for the extraction of gases from and for the gasification of fuels |
US1921711A (en) * | 1929-03-14 | 1933-08-08 | Wangemann Paul | Process of producing water gas |
US2031987A (en) * | 1934-09-13 | 1936-02-25 | Standard Oil Co | Conversion of hydrocarbons |
GB465548A (en) * | 1936-07-06 | 1937-05-10 | Theodor Lichtenberger | An improved process for obtaining water gas |
US2647045A (en) * | 1948-12-06 | 1953-07-28 | Rummel Roman | Gasification of combustible materials |
US2794709A (en) * | 1952-12-20 | 1957-06-04 | Houdry Process Corp | Preparation of carbon black and hydrogen |
-
1962
- 1962-06-11 US US201534A patent/US3252773A/en not_active Expired - Lifetime
-
1963
- 1963-06-10 GB GB22975/63A patent/GB994208A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2549488A1 (en) * | 1983-07-23 | 1985-01-25 | Metallgesellschaft Ag | METHOD FOR OPERATING A GASIFICATION FACILITY FOR SOLID FUELS |
GB2143844A (en) * | 1983-07-23 | 1985-02-20 | Metallgesellschaft Ag | Process for operating a plant for gasifying solid fuels |
Also Published As
Publication number | Publication date |
---|---|
US3252773A (en) | 1966-05-24 |
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