FR2375284A1 - Compositions elastoplastiques de caoutchouc butyle reticule et de resine de polyolefine - Google Patents

Compositions elastoplastiques de caoutchouc butyle reticule et de resine de polyolefine

Info

Publication number
FR2375284A1
FR2375284A1 FR7738792A FR7738792A FR2375284A1 FR 2375284 A1 FR2375284 A1 FR 2375284A1 FR 7738792 A FR7738792 A FR 7738792A FR 7738792 A FR7738792 A FR 7738792A FR 2375284 A1 FR2375284 A1 FR 2375284A1
Authority
FR
France
Prior art keywords
polyolefin resin
butyl rubber
compositions
cross
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7738792A
Other languages
English (en)
Other versions
FR2375284B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of FR2375284A1 publication Critical patent/FR2375284A1/fr
Application granted granted Critical
Publication of FR2375284B1 publication Critical patent/FR2375284B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/283—Halogenated homo- or copolymers of iso-olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Compositions élastoplastiques. Ces compositions comprennent un mélange d'une résine de polyoléfine thermoplastique cristalline, du caoutchouc butyle réticulé en proportion telle qu'il contienne au moins 2 x 10**-5 mole de réticulations effectives par millilitre et, éventuellement, de l'huiler d'extension; la quantité de résine de polyoléfine est suffisante pour conférer la thermoplasticité à la composition et la quantite de caoutchouc butyle est suffisante pour conférer une élasticité caoutchouteuse à la composition, cette quantité allant jusqu'à 80 % en poids du poids combiné de la résine, du caoutchouc et de l'huile. La présente invention est particulièrement utile pour fournir des compositions thermoplastiques, formées de résine polyoléfinique et de caoutchouc butyle réticulé.
FR7738792A 1976-12-27 1977-12-22 Compositions elastoplastiques de caoutchouc butyle reticule et de resine de polyolefine Granted FR2375284A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/754,412 US4130534A (en) 1976-12-27 1976-12-27 Elastoplastic compositions of butyl rubber and polyolefin resin

Publications (2)

Publication Number Publication Date
FR2375284A1 true FR2375284A1 (fr) 1978-07-21
FR2375284B1 FR2375284B1 (fr) 1984-09-07

Family

ID=25034686

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7738792A Granted FR2375284A1 (fr) 1976-12-27 1977-12-22 Compositions elastoplastiques de caoutchouc butyle reticule et de resine de polyolefine

Country Status (13)

Country Link
US (1) US4130534A (fr)
JP (1) JPS5382846A (fr)
AU (1) AU514444B2 (fr)
BE (1) BE862160A (fr)
BR (1) BR7708591A (fr)
CA (1) CA1096986A (fr)
DE (1) DE2757430A1 (fr)
ES (1) ES465202A1 (fr)
FR (1) FR2375284A1 (fr)
GB (1) GB1556631A (fr)
IT (1) IT1089349B (fr)
NL (1) NL183523C (fr)
SE (1) SE422072B (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0172645A2 (fr) * 1984-07-11 1986-02-26 Advanced Elastomer Systems, L.P. Composition polyoléfinique, thermoplastique rétrécissant à la chaleur
EP0287282A1 (fr) * 1987-04-07 1988-10-19 Tonen Chemical Corporation Composition élastomère thermoplastique
EP0363208A2 (fr) * 1988-10-06 1990-04-11 Exxon Chemical Patents Inc. Caoutchouc butyl halogéné
WO1990014389A2 (fr) * 1989-05-26 1990-11-29 Advanced Elastomer Systems, L.P. Alliages dynamiquement vulcanises comportant deux copolymeres dans la phase reticulee ainsi qu'une matrice cristalline

Families Citing this family (79)

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US4202801A (en) * 1977-12-30 1980-05-13 Uniroyal, Inc. Thermoplastic elastomer composition
NL7905700A (nl) * 1979-07-24 1981-01-27 Stamicarbon Thermoplastische elastomere compositie en werkwijze ter bereiding daarvan.
US4271049A (en) * 1979-09-10 1981-06-02 Monsanto Company Elastoplastic compositions of cured diene rubber and polypropylene
US4300988A (en) * 1980-07-25 1981-11-17 Radiation Dynamics, Inc. Polybutylene and conjugated diene butyl polymer blends
IT1193549B (it) * 1980-08-19 1988-07-08 Montedison Spa Procedimento per la preparazione di composizioni plasto-elastomeriche poliolefiniche,mediante vulcanizzazione dinamica
CA1187779A (fr) * 1982-03-15 1985-05-28 Eric G. Kent Procede permettant de coller une epaisseur de caoutchouc sur un support
HU189266B (en) * 1983-04-19 1986-06-30 Taurus Gumiipari Vallalat,Hu Process for production of thermoplastic elastomers and elastomer-compositions
US5086121A (en) * 1984-07-11 1992-02-04 Advanced Elastomer Systems, L. P. Dynamically cured thermoplastic olefin polymers
US4960830A (en) * 1984-07-11 1990-10-02 Exxon Research And Engineering Company Dynamically cured thermoplastic olefin polymers
US4607074A (en) * 1984-07-11 1986-08-19 Exxon Research & Engineering Co. Dynamically cured thermoplastic olefin polymers
US4851468A (en) * 1984-12-10 1989-07-25 Exxon Research & Engineering Company Dynamically cured thermoplastic olefin polymers
US4593062A (en) * 1984-12-10 1986-06-03 Exxon Research & Engineering Co. Dynamically cured thermoplastic olefin polymers
BR8606735A (pt) * 1985-06-19 1987-08-11 Exxon Chemical Patents Inc Composicao de elastomero termoplastico
US4833206A (en) * 1986-02-27 1989-05-23 Kabushiki Kaisha Toritsu Industry Sanitary rubber composition or article
US4802155A (en) * 1986-03-03 1989-01-31 Matsushita Electric Industrial Co., Ltd. Recording disc playback apparatus
WO1987007625A1 (fr) * 1986-06-03 1987-12-17 Exxon Research And Engineering Company Polymeres d'olefines thermoplastiques e-76 a vulcanisation dynamique
US4675349A (en) * 1986-09-02 1987-06-23 Gencorp Inc. Method of preparing composition for tire tread cap
US4874447A (en) * 1987-01-27 1989-10-17 Exxon Chemical Patents, Inc. Melt blown nonwoven web from fiber comprising an elastomer
US4804577A (en) * 1987-01-27 1989-02-14 Exxon Chemical Patents Inc. Melt blown nonwoven web from fiber comprising an elastomer
US4810752A (en) * 1987-09-24 1989-03-07 The West Company Halobutyl thermoplastic elastomer
US6013727A (en) * 1988-05-27 2000-01-11 Exxon Chemical Patents, Inc. Thermoplastic blend containing engineering resin
US5013793A (en) * 1990-07-26 1991-05-07 Exxon Chemical Patents Inc. Dynamically cured thermoplastic olefin polymers and process for producing the same
GB8818880D0 (en) * 1988-08-09 1988-09-14 Research Corp Ltd Modified polymers
US5021500A (en) * 1988-10-28 1991-06-04 Exxon Chemical Company Dynamically vulcanized alloys of crystalline polyolefin resin and halobutyl rubber material
US5247015A (en) * 1988-12-22 1993-09-21 The West Company, Incorporated Molded thermoplastic elastomer
US4975308A (en) * 1988-12-22 1990-12-04 The West Company Molded pharmaceutical primary closure
US4916180A (en) * 1988-12-29 1990-04-10 Polysar Limited Butyl rubber/polypropylene elastoplastic
US4978714A (en) * 1989-03-01 1990-12-18 The West Company Incorporated Modified halobutyl thermoplastic elastomer
US4978717A (en) * 1989-04-19 1990-12-18 Exxon Chemical Patents Inc. Thermoelastic composition of ethylene-1-olefin copolymer and rubber
US5157081A (en) * 1989-05-26 1992-10-20 Advanced Elastomer Systems, L.P. Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix
US5075387A (en) * 1989-12-22 1991-12-24 Exxon Chemical Patents Inc. Partially crosslinked elastomeric polymers and process for producing the same
US5102958A (en) * 1989-12-22 1992-04-07 Exxon Chemical Patents Inc. Partially crosslinked elastomeric polymers and process for producing the same
US5023301A (en) * 1990-03-05 1991-06-11 The Goodyear Tire & Rubber Company Polypropylene reinforced rubber
US5051477A (en) * 1990-05-04 1991-09-24 Advanced Elastomer Systems, L. P. Dynamically cured thermoplastic olefin polymers and process for producing the same
US5051478A (en) * 1990-07-26 1991-09-24 Advanced Elastomer Systems, L. P. Ethylene copolymer - modified dynamically vulcanized alloys
JPH0517943U (ja) * 1991-08-14 1993-03-05 第二しなのポリマー株式会社 低圧縮、低抵抗型コネクタ
US5290886A (en) * 1993-04-20 1994-03-01 Advanced Elastomer Systems, L.P. Thermoplastic elastomers having improved low temperature properties
JP3548619B2 (ja) 1994-03-04 2004-07-28 アドバンスド エラストマー システムズ，エル．ピー． 半透明熱可塑性エラストマー
US6079465A (en) 1995-01-23 2000-06-27 The Yokohama Rubber Co., Ltd. Polymer composition for tire and pneumatic tire using same
US5907004A (en) * 1995-02-07 1999-05-25 Dsm N.V. Thermoplastic elastomer
DE69622505T2 (de) * 1995-05-02 2002-12-12 Yokohama Rubber Co Ltd Verfahren zum herstellen von luftreifen
US5621045A (en) 1995-11-13 1997-04-15 Patel; Raman Thermoplastic vulcanizates from isobutylene rubber and either EPDM or a conjugated diene rubber
US5672660A (en) 1995-12-01 1997-09-30 Advanced Elastomer Systems, L.P. Hydrosilylation crosslinking
US6150464A (en) * 1995-12-01 2000-11-21 Advanced Elastomer Systems, L.P. Preferred process for silicon hydride addition and preferred degree of polymerization for silicon hydride for thermoplastic vulcanizates
US6235356B1 (en) * 1995-12-26 2001-05-22 Asahi Glass Company Ltd. Resin composition for building materials and insulating glass
US5952425A (en) * 1996-12-31 1999-09-14 Advanced Elastomer Systems, L.P. Preferred structure of phenolic resin curative for thermoplastic vulcanizate
JP3601569B2 (ja) * 1997-03-26 2004-12-15 株式会社ブリヂストン 樹脂強化エラストマー、その製造方法、及びそれを用いた空気入りタイヤ
US5939464A (en) * 1997-05-02 1999-08-17 Advanced Elastomer Systems, L.P. High elasticity foams
US5750625A (en) * 1997-06-09 1998-05-12 Advanced Elastomer Systems, L.P. Phenolic resin curatives which form nonstaining thermoplastic elastomers
US5889119A (en) * 1997-07-17 1999-03-30 The University Of Akron Thermoplastic rubbery compositions
ES2213297T3 (es) 1997-11-20 2004-08-16 Advanced Elastomer Systems, L.P. Modificacion de vulcanizados termoplasticos con un copolimero termoplastico al azar de etileno.
US6255389B1 (en) 1998-08-27 2001-07-03 Advanced Elastomer Systems, L.P. Star-branched rubber thermoplastic elastomer vulcanizates
US6084031A (en) * 1998-11-30 2000-07-04 Advanced Elastomer Systems, L.P. TPV from hydrosilylation crosslinking of acrylic modified bromo XP-50 butyl rubber
US6503984B2 (en) 1998-12-22 2003-01-07 Advanced Elastomer Systems, L.P. TPE composition that exhibits excellent adhesion to textile fibers
US6100334A (en) * 1999-01-05 2000-08-08 Advanced Elastomer Systems, L.P. Thermoplastic vulcanizates from a cyclic olefin rubber, a polyolefin, and a compatiblizer
US6303694B1 (en) * 2000-02-18 2001-10-16 Bridgestone Corporation Compounding process for achieving uniform, fine particle size dispersion of curing agents in the substantial absence of solvents and a sealant produced thereby
US6617383B2 (en) 2000-04-11 2003-09-09 The Yokohama Rubber Co., Ltd. Thermoplastic elastomer composition having improved processability and tire using the same
US6440492B1 (en) * 2000-05-10 2002-08-27 Gencorp, Inc. Methods of coating rubber with solventless crystalline polyolefin coatings
US7019058B2 (en) * 2000-10-11 2006-03-28 Exxonmobil Chemical Patents, Inc. Halogenated elastomeric compositions having enhanced viscosity
CZ2003999A3 (cs) * 2000-10-11 2003-11-12 Exxonmobil Chemical Patents Inc. Halogenované elastomerní kompozice se zlepšenou viskozitou
US6552108B1 (en) * 2000-10-11 2003-04-22 Exxonmobil Chemical Patents Inc. Rubber blends having improved stability and green strength
DE10125045A1 (de) * 2001-05-23 2002-12-05 Bosch Gmbh Robert Wischerblatt
CN1524109A (zh) * 2001-06-07 2004-08-25 ����ɭ���ڻ�ѧר����˾ 粘度增加的卤化异丁烯基共聚物和其热塑性组合物
TWI300425B (en) * 2001-06-28 2008-09-01 Kaneka Corp Thermoplastic elastomer composition
JP3969329B2 (ja) * 2002-04-26 2007-09-05 豊田合成株式会社 ゴム製品の成形方法
IL156870A0 (en) 2003-07-10 2004-02-08 Carmel Olefines Ltd Process for making thermoplastic vulcanizates
EP1674530A1 (fr) 2004-12-24 2006-06-28 Kraton Polymers Research B.V. Composition élastomère thermoplastique présentant une résistance a l'état de fusion élevée
JP4122033B2 (ja) * 2005-10-21 2008-07-23 横浜ゴム株式会社 変性ブチルゴム組成物
US7585914B2 (en) * 2005-11-09 2009-09-08 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer compositions and methods for making the same
US7645832B2 (en) * 2006-03-08 2010-01-12 Exxonmobil Chemical Patents Inc. Use of metal oxides and salts to enhance adhesion to steels
US8207270B2 (en) * 2006-09-29 2012-06-26 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer compositions, methods of making and articles made from the same
US9546266B2 (en) 2013-03-13 2017-01-17 Basf Se Inner liner for a pneumatic tire assembly
US10035383B2 (en) 2015-08-13 2018-07-31 The Goodyear Tire & Rubber Company Pneumatic tire with post cure sealant layer
EP3438184A1 (fr) 2017-08-03 2019-02-06 Sika Technology Ag Composition polymère présentant des propriétés mécaniques améliorées
US11725098B2 (en) 2017-12-18 2023-08-15 Celanese International Corporation Thermoplastic vulcanizate conduits for transporting hydrocarbon fluids
US20220042625A1 (en) 2018-09-14 2022-02-10 Exxonmobil Chemical Patents Inc. Thermoplastic Vulcanizate Compositions in Polymeric Inner / Pressure Sheaths of Flexible Pipes for Oil & Gas Applications
US11413800B2 (en) 2019-05-20 2022-08-16 Kraton Polymers Llc Molding compositions and articles made thereof
EP4021718A1 (fr) 2019-08-26 2022-07-06 Celanese International Corporation Compositions de vulcanisat thermoplastique et compositions oléfiniques thermoplastiques en tant que couches isolantes dans des tuyaux non flexibles
CN111484684A (zh) * 2020-06-04 2020-08-04 青岛科技大学 一种高阻尼、低气味环保丁基橡胶/聚丙烯热塑性硫化胶及其制备方法

Citations (4)

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FR1219247A (fr) * 1957-12-16 1960-05-16 Exxon Research Engineering Co Mélanges de polymères élastomères et plastomères, tels que de caoutchouc butyle et de polyalkène
GB844958A (en) * 1957-08-30 1960-08-17 Ici Ltd Rubber compositions
FR2149719A5 (fr) * 1971-08-12 1973-03-30 Uniroyal Inc
FR2310379A1 (fr) * 1975-05-06 1976-12-03 Huels Chemische Werke Ag Vulcanisats thermosoudables a base de caoutchoucs de polyolefine

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GB955235A (en) * 1961-05-18 1964-04-15 Albert Ag Chem Werke Vulcanisation process
BE623902A (fr) * 1961-10-26
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GB844958A (en) * 1957-08-30 1960-08-17 Ici Ltd Rubber compositions
FR1219247A (fr) * 1957-12-16 1960-05-16 Exxon Research Engineering Co Mélanges de polymères élastomères et plastomères, tels que de caoutchouc butyle et de polyalkène
FR2149719A5 (fr) * 1971-08-12 1973-03-30 Uniroyal Inc
FR2310379A1 (fr) * 1975-05-06 1976-12-03 Huels Chemische Werke Ag Vulcanisats thermosoudables a base de caoutchoucs de polyolefine

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0172645A2 (fr) * 1984-07-11 1986-02-26 Advanced Elastomer Systems, L.P. Composition polyoléfinique, thermoplastique rétrécissant à la chaleur
EP0172645A3 (en) * 1984-07-11 1987-09-02 Exxon Research And Engineering Company Heat-shrinkable thermoplastic polyolefin composition
EP0287282A1 (fr) * 1987-04-07 1988-10-19 Tonen Chemical Corporation Composition élastomère thermoplastique
WO1988008015A1 (fr) * 1987-04-07 1988-10-20 Exxon Chemical Patents, Inc. Composition elastomere thermoplastique
EP0363208A2 (fr) * 1988-10-06 1990-04-11 Exxon Chemical Patents Inc. Caoutchouc butyl halogéné
EP0363208A3 (fr) * 1988-10-06 1991-09-04 Exxon Chemical Patents Inc. Caoutchouc butyl halogéné
WO1990014389A2 (fr) * 1989-05-26 1990-11-29 Advanced Elastomer Systems, L.P. Alliages dynamiquement vulcanises comportant deux copolymeres dans la phase reticulee ainsi qu'une matrice cristalline
WO1990014389A3 (fr) * 1989-05-26 1991-10-31 Exxon Chemical Patents Inc Alliages dynamiquement vulcanises comportant deux copolymeres dans la phase reticulee ainsi qu'une matrice cristalline
EP0754726A2 (fr) * 1989-05-26 1997-01-22 Advanced Elastomer Systems, L.P. Alliages dynamiquement vulcanisés comportant deux copolymères dans la phase réticulée ainsi qu'une matrice cristalline
EP0754726A3 (fr) * 1989-05-26 1999-01-07 Advanced Elastomer Systems, L.P. Alliages dynamiquement vulcanisés comportant deux copolymères dans la phase réticulée ainsi qu'une matrice cristalline

Also Published As

Publication number Publication date
ES465202A1 (es) 1978-09-01
DE2757430C2 (fr) 1988-12-22
JPS6118581B2 (fr) 1986-05-13
NL183523B (nl) 1988-06-16
SE422072B (sv) 1982-02-15
DE2757430A1 (de) 1978-07-06
FR2375284B1 (fr) 1984-09-07
AU3187877A (en) 1979-06-28
US4130534A (en) 1978-12-19
JPS5382846A (en) 1978-07-21
BE862160A (fr) 1978-06-22
NL183523C (nl) 1992-06-16
AU514444B2 (en) 1981-02-12
BR7708591A (pt) 1978-08-22
CA1096986A (fr) 1981-03-03
IT1089349B (it) 1985-06-18
GB1556631A (en) 1979-11-28
NL7714041A (nl) 1978-06-29
SE7714649L (sv) 1978-06-28

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