FR2354812A1 - Catalyseur pour l'oxydation de la (meth)acroleine en acide (meth)acrylique - Google Patents

Catalyseur pour l'oxydation de la (meth)acroleine en acide (meth)acrylique

Info

Publication number
FR2354812A1
FR2354812A1 FR7718561A FR7718561A FR2354812A1 FR 2354812 A1 FR2354812 A1 FR 2354812A1 FR 7718561 A FR7718561 A FR 7718561A FR 7718561 A FR7718561 A FR 7718561A FR 2354812 A1 FR2354812 A1 FR 2354812A1
Authority
FR
France
Prior art keywords
meth
acrolein
oxidation
catalyst
acrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7718561A
Other languages
English (en)
Other versions
FR2354812B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of FR2354812A1 publication Critical patent/FR2354812A1/fr
Application granted granted Critical
Publication of FR2354812B1 publication Critical patent/FR2354812B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Catalyseur pour l'oxydation, par des gaz contenant de l'oxygène, de l'acroléine ou de la méthacroléine respectivement en acide acrylique ou en acide méthacrylique, constitué par un matériau-support façonné, dont la surface est recouverte d'une matière à activité catalytique, de formule générale Mo12 Aa Bb Cc Dd Ox , dans laquelle A = V et/ou W, B = Cu et/ou Fe et/ou Mn et/ou Ni et/ou Cr, C = Nb et/ou Ta et/ou Bi et/ou Sb et/ou Sn et/ou Th et /ou Ce et/ou U, D = Li et/ou Na et /ou K et/ou Rb et/ou Cs et/ou T1 avec a = 0,1 à 18, b = 0 à 8, c = 0 à 10, d = 0 à 2 et x = 36,25 à 135. La matière catalytique est préparée, avant son application sur le support, à partir de sels des constituants facilement décomposables par voie thermique, en opérant de la manière habituelle par mélange de solutions aqueuses, de suspensions dans l'eau ou de masses humides formées par des sels des constituants, par séchage, par calcination de la matière séchée entre 140 et 600 degrés C, puis la matière est réduite jusqu'à une grosseur des particules inférieure à 150 mu m, et appliquée, après addition d'eau, sous la forme d'une couche d'épaisseur comprise entre 10 et 1500 mm sur le matériau-support préalablement façonné, dont la surface est rugueuse.
FR7718561A 1976-06-16 1977-06-16 Catalyseur pour l'oxydation de la (meth)acroleine en acide (meth)acrylique Granted FR2354812A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2626887A DE2626887B2 (de) 1976-06-16 1976-06-16 Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure

Publications (2)

Publication Number Publication Date
FR2354812A1 true FR2354812A1 (fr) 1978-01-13
FR2354812B1 FR2354812B1 (fr) 1983-09-30

Family

ID=5980631

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7718561A Granted FR2354812A1 (fr) 1976-06-16 1977-06-16 Catalyseur pour l'oxydation de la (meth)acroleine en acide (meth)acrylique

Country Status (8)

Country Link
US (1) US4259211A (fr)
JP (1) JPS598178B2 (fr)
BE (1) BE855741A (fr)
CA (1) CA1095491A (fr)
DE (1) DE2626887B2 (fr)
FR (1) FR2354812A1 (fr)
GB (1) GB1576389A (fr)
NL (1) NL7706647A (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0000564A1 (fr) * 1977-07-28 1979-02-07 The Standard Oil Company Catalyseurs contenant du fer et du molybdène et utilisation de ces catalyseurs pour la préparation d'acrylonitrile ou de méthacrylonitrile
EP0000663A1 (fr) * 1977-07-28 1979-02-07 The Standard Oil Company Procédé d'oxydation d'oléfines avec utilisation de catalyseurs contenant du molybdène et différents éléments promoteurs
EP0024954A1 (fr) * 1979-09-04 1981-03-11 Ube Industries, Ltd. Catalyseur pour la production d'acide carboxylique insaturé, sa préparation, et la production d'acide carboxylique insaturé
FR2481146A1 (fr) * 1980-04-25 1981-10-30 Rhone Poulenc Ind Procede pour la preparation de catalyseurs a base d'oxydes de molybdene et/ou de tungstene et d'oxydes d'autres metaux
FR2519268A1 (fr) * 1982-01-06 1983-07-08 Nippon Catalytic Chem Ind Catalyseur polymetallique a base de molybdene pour l'oxydation du propylene en propenal
EP0267556A2 (fr) * 1986-11-11 1988-05-18 Mitsubishi Rayon Co., Ltd. Procédé pour la préparation de méthanoléine et d'acide méthacrylique
EP0279374A1 (fr) * 1987-02-17 1988-08-24 Nippon Shokubai Kagaku Kogyo Co., Ltd Catalyseur d'oxydation d'oléfines ou d'alcool tertiaire et procédé pour sa préparation
US5208371A (en) * 1986-11-11 1993-05-04 Mitsubishi Rayon Co., Ltd. Process for production of methacrolein and methacrylic acid

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US4272408A (en) * 1978-10-17 1981-06-09 Air Products And Chemicals, Inc. Stable molybdenum catalysts for high conversion of C3 and C4 olefins to corresponding unsaturated aldehydes and acids
DE2849637A1 (de) * 1978-11-16 1980-05-29 Hoechst Ag Traegerkatalysator und verfahren zu seiner herstellung
DE2909670A1 (de) * 1979-03-12 1980-10-02 Basf Ag Verfahren zur herstellung von schalenkatalysatoren
JPS56161841A (en) * 1980-05-19 1981-12-12 Mitsubishi Petrochem Co Ltd Manufacture of composite oxide catalyst
JPS57130548A (en) * 1981-02-05 1982-08-13 Mitsubishi Chem Ind Ltd Catalyst composition
NL8202791A (nl) * 1981-07-17 1983-02-16 Halcon Sd Group Inc Werkwijze voor het bereiden van methacrylzuur.
US4788173A (en) * 1985-12-20 1988-11-29 The Standard Oil Company Catalytic mixtures for ammoxidation of paraffins
US4783545A (en) * 1985-12-20 1988-11-08 The Standard Oil Company Method for ammoxidation of paraffins and catalyst system therefor
US4892856A (en) * 1987-06-05 1990-01-09 Nippon Shokubai Kagaku Kogyo Co., Ltd. Catalyst for oxidation of acrolein and process for preparation thereof
DE3719635A1 (de) * 1987-06-12 1988-12-29 Basf Ag Verfahren zur herstellung von schalenkatalysatoren
JPS6415987U (fr) * 1987-07-13 1989-01-26
JPS6415988U (fr) * 1987-07-13 1989-01-26
NZ228084A (en) * 1988-02-24 1990-11-27 Kawasaki Steel Co Catalysts and their use in catalytic production of pyromellitic dianhydride
EP0415347B2 (fr) * 1989-08-29 2002-06-05 Nippon Shokubai Kagaku Kogyo Co. Ltd. Catalyseur pour la fabrication de l'acide méthacrylique
DE4132263A1 (de) * 1991-09-27 1993-04-01 Basf Ag Verfahren zur katalytischen gasphasenoxidation von acrolein zu acrylsaeure
DE4431949A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure
DE4442346A1 (de) 1994-11-29 1996-05-30 Basf Ag Verfahren zur Herstellung eines Katalysators, bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Oxidmasse
JP3786297B2 (ja) * 1995-03-03 2006-06-14 日本化薬株式会社 触媒の製造方法
DE19622331A1 (de) 1996-06-04 1997-12-11 Basf Ag Verfahren der heterogen katalysierten Gasphasenoxidation von Propan zu Acrolein
KR100204729B1 (ko) 1997-03-17 1999-06-15 성재갑 아크롤레인 부분산화용 촉매의 제조 방법
DE19815278A1 (de) * 1998-04-06 1999-10-07 Basf Ag Multimetalloxidmassen
US6143928A (en) * 1998-08-10 2000-11-07 Saudi Basic Industries Corporation Catalysts for low temperature selective oxidation of propylene, methods of making and using the same
US6384275B2 (en) 1998-09-23 2002-05-07 Lg Chem, Ltd. Method of producing acrylic acid using a catalyst for acrolein oxidation
US6432870B1 (en) * 1999-05-25 2002-08-13 Toagosei Co., Ltd. Process for preparing metal oxide catalyst for acrylic acid production
US6762148B2 (en) * 1999-09-17 2004-07-13 Nippon Kayaku Kabushiki Kaisha Catalyst process of making
US6620968B1 (en) 1999-11-23 2003-09-16 Rohm And Haas Company High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids
JP4318367B2 (ja) * 2000-02-16 2009-08-19 株式会社日本触媒 アクロレインおよびアクリル酸の製造方法
DE10031518A1 (de) * 2000-06-28 2002-01-10 Basf Ag Verfahren zur Herstellung von Hydroformylierungsprodukten des Propylens und von Acrylsäure und/oder Acrolein
DE10046928A1 (de) * 2000-09-21 2002-04-11 Basf Ag Verfahren zur Herstellung von Multimetalloxidmassen
EP1333922B1 (fr) * 2000-10-10 2004-06-02 Basf Aktiengesellschaft Procede de preparation d'un catalyseur a enveloppe annulaire et son utilisation pour produire de l'acroleine
DE10061555A1 (de) * 2000-12-11 2002-06-20 Basf Ag Schalenkatalysator für die Hydrierung von Maleinsäureanhydrid und verwandten Verbindungen zu gamma-Butyrolacton und Tetrahydrofuran und Derivaten davon
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EP1245556B1 (fr) * 2001-03-29 2004-09-15 DSM Fine Chemicals Austria Nfg GmbH & Co KG Procédé de préparation d'acides carboxyliques par oxydation d'aldéhyde et en présence de periodate, dichromate et d'acide dans l'eau
WO2003022819A1 (fr) * 2001-09-07 2003-03-20 Jubilant Organosys Limited Procede de fabrication de nitriles heteroaromatiques, catalyseur ameliore correspondant et procede pour la fabrication dudit catalyseur ameliore
US20030166972A1 (en) * 2002-02-20 2003-09-04 Regents Of The University Of California Office Of Technology Licensing Process for production of formaldehyde from dimethyl ether
ATE493200T1 (de) * 2002-07-12 2011-01-15 Lg Chemical Ltd Verfahren zur herstellung eines katalysators für die partialoxidation von acrolein
US20060205978A1 (en) * 2002-08-20 2006-09-14 Nippon Shokubai Co., Ltd. Production process for catalyst
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US7229945B2 (en) * 2003-12-19 2007-06-12 Saudi Basic Industrics Corporation Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
TWI438187B (zh) * 2005-02-28 2014-05-21 Evonik Degussa Gmbh 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法
DE102005010645A1 (de) 2005-03-08 2005-08-04 Basf Ag Verfahren zum Befüllen eines Reaktors
JP4756890B2 (ja) * 2005-03-29 2011-08-24 日本化薬株式会社 メタクリル酸製造用触媒及びその製造方法
JP2006314923A (ja) * 2005-05-12 2006-11-24 Nippon Kayaku Co Ltd メタクリル酸製造用触媒の製造方法
DE102005062026A1 (de) * 2005-12-22 2007-06-28 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
DE102006039205A1 (de) 2006-08-22 2008-03-20 Stockhausen Gmbh Auf nachwachsenden Rohstoffen basierende Acrylsäure und wasserabsorbierende Polymergebilde sowie Verfahren zu deren Herstellung mittels Dehydratisierung
DE102007010422A1 (de) * 2007-03-01 2008-09-04 Basf Se Verfahren zur Herstellung eines Katalysators bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Masse
DE102007025357A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zum Auftragen einer Washcoatsuspension auf eine Trägerstruktur
DE102007031481A1 (de) 2007-07-06 2009-01-08 BSH Bosch und Siemens Hausgeräte GmbH Waschtrockner
DE102007033494A1 (de) 2007-07-18 2009-01-22 BSH Bosch und Siemens Hausgeräte GmbH Adsorptionstrockner
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MX2008015540A (es) 2007-12-26 2009-06-26 Rohm Ahd Haas Company Un proceso integrado para preparar un acido carboxilico a partir de un alcano.
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TW200948474A (en) 2008-04-09 2009-12-01 Basf Se Coated catalysts comprising a multimetal oxide comprising molybdenum
RU2471554C2 (ru) * 2008-06-02 2013-01-10 Ниппон Каяку Кабусики Кайся Катализатор и способ получения ненасыщенного альдегида и ненасыщенной карбоновой кислоты
EP2143704A1 (fr) 2008-07-10 2010-01-13 Rohm and Haas Company Procédé intégré pour la préparation d'un acide carboxylique à partir d'un alcane
DE102008038273A1 (de) 2008-08-18 2010-03-04 Evonik Stockhausen Gmbh Ein Verfahren zur Herstellung von Acrylsäure und daraus herstellbaren Verbindungen basierend auf Glycerin mit Wechselkatalysator
KR101226522B1 (ko) * 2008-12-22 2013-01-25 제일모직주식회사 솔리드 스피어 구조를 갖는 담지촉매, 그 제조방법 및 이를 이용하여 제조한 탄소나노튜브
TWI478767B (zh) * 2009-04-23 2015-04-01 Treibacher Ind Ag 用於使廢氣進行選擇性催化還原反應之催化劑組成物
CN102770403A (zh) 2009-12-04 2012-11-07 巴斯夫欧洲公司 由生物乙醇制备乙醛和/或乙酸
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
US9399606B2 (en) 2012-12-06 2016-07-26 Basf Se Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene
EA201591040A1 (ru) 2012-12-06 2015-11-30 Басф Се Способ окислительного дегидрирования н-бутенов в бутадиен
WO2014086641A1 (fr) 2012-12-06 2014-06-12 Basf Se Catalyseur et procédé de déshydrogénation oxydative de n-butènes pour obtenir du butadiène
US10144681B2 (en) 2013-01-15 2018-12-04 Basf Se Process for the oxidative dehydrogenation of N-butenes to butadiene
EP3019458B1 (fr) 2013-07-10 2017-04-05 Basf Se Procédé de déshydrogénation oxydative de n-butènes pour donner du butadiène
US20180147561A1 (en) 2015-05-06 2018-05-31 Basf Se Method for producing catalysts containing chrome, for the oxidative dehydrogenation of n-butenes to form butadiene while avoiding cr(vi) intermediates
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0000564A1 (fr) * 1977-07-28 1979-02-07 The Standard Oil Company Catalyseurs contenant du fer et du molybdène et utilisation de ces catalyseurs pour la préparation d'acrylonitrile ou de méthacrylonitrile
EP0000663A1 (fr) * 1977-07-28 1979-02-07 The Standard Oil Company Procédé d'oxydation d'oléfines avec utilisation de catalyseurs contenant du molybdène et différents éléments promoteurs
EP0024954A1 (fr) * 1979-09-04 1981-03-11 Ube Industries, Ltd. Catalyseur pour la production d'acide carboxylique insaturé, sa préparation, et la production d'acide carboxylique insaturé
FR2481146A1 (fr) * 1980-04-25 1981-10-30 Rhone Poulenc Ind Procede pour la preparation de catalyseurs a base d'oxydes de molybdene et/ou de tungstene et d'oxydes d'autres metaux
EP0039267A1 (fr) * 1980-04-25 1981-11-04 Rhone-Poulenc Chimie De Base Procédé pour la préparation de catalyseurs à base d'oxyde de molybdène et/ou de tungstène et d'oxydes d'autres métaux
FR2519268A1 (fr) * 1982-01-06 1983-07-08 Nippon Catalytic Chem Ind Catalyseur polymetallique a base de molybdene pour l'oxydation du propylene en propenal
EP0267556A2 (fr) * 1986-11-11 1988-05-18 Mitsubishi Rayon Co., Ltd. Procédé pour la préparation de méthanoléine et d'acide méthacrylique
EP0267556A3 (en) * 1986-11-11 1989-08-02 Mitsubishi Rayon Co. Ltd. Process for production of methacrolein and methacrylic acid
US5208371A (en) * 1986-11-11 1993-05-04 Mitsubishi Rayon Co., Ltd. Process for production of methacrolein and methacrylic acid
EP0279374A1 (fr) * 1987-02-17 1988-08-24 Nippon Shokubai Kagaku Kogyo Co., Ltd Catalyseur d'oxydation d'oléfines ou d'alcool tertiaire et procédé pour sa préparation

Also Published As

Publication number Publication date
BE855741A (fr) 1977-12-16
JPS52153889A (en) 1977-12-21
US4259211A (en) 1981-03-31
FR2354812B1 (fr) 1983-09-30
DE2626887A1 (de) 1977-12-22
CA1095491A (fr) 1981-02-10
JPS598178B2 (ja) 1984-02-23
DE2626887B2 (de) 1978-06-29
NL7706647A (nl) 1977-12-20
GB1576389A (en) 1980-10-08

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