FR2115594A5 - - Google Patents

Info

Publication number
FR2115594A5
FR2115594A5 FR7042410A FR7042410A FR2115594A5 FR 2115594 A5 FR2115594 A5 FR 2115594A5 FR 7042410 A FR7042410 A FR 7042410A FR 7042410 A FR7042410 A FR 7042410A FR 2115594 A5 FR2115594 A5 FR 2115594A5
Authority
FR
France
Prior art keywords
impregnated
grafted
solution
solvent
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7042410A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institut Textile de France
Original Assignee
Institut Textile de France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institut Textile de France filed Critical Institut Textile de France
Priority to FR7042410A priority Critical patent/FR2115594A5/fr
Priority to DE19712157902 priority patent/DE2157902C3/en
Priority to BE775761A priority patent/BE775761A/en
Priority to GB5486271A priority patent/GB1360665A/en
Application granted granted Critical
Publication of FR2115594A5 publication Critical patent/FR2115594A5/fr
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12Chemical modification
    • C08J7/16Chemical modification with polymerisable compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275Heterogeneous membranes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers

Abstract

1360665 Graft polymerization process INSTITUT TEXTILE DE FRANCE 25 Nov 1971 [25 Nov 1970] 54862/71 Heading C3G A graft polymerization process comprises (a) impregnating the polymer to be grafted with a solution in a first solvent of an activating agent capable of producing free radicals on the polymer chain and, after separating the impregnated polymer from the solution of the activating agent, (b) grafting the impregnated polymer by contacting it with a solution in a second solvent of a monomer of low volatility having a limited solubility in the first solvent. Preferably the first solvent is water, the second solvent is an organic solvent immiscible in all proportions with water, or aqueous acetic acid, and the activating agent is a ceric salt. In the examples, (a) cotton fabric or ground cellulose linters are impregnated with a ceric ammonium sulphate/sulphuric acid solution and grafted with acrylic acid in benzene; (b) formalized polyvinyl alcohol fabric is impregnated as in (a) and grafted with acrylic acid in benzene saturated with water; (c) cotton poplin is impregnated as in (a) and grafted with methyl acrylate in hexane containing acetic acid or in carbon disulphide, or with acrylamide in benzene/acetonitrile/acetic acid; (d) polyvinyl alcohol film is impregnated with a solution of ceric ammonium sulphate and sodium sulphate in sulphuric acid and grafted as in (a); (e) nylon is swollen in formic acid/water, impregnated and grafted as in (a); and (f) cotton poplin is impregnated with a ceric ammonium nitrate/nitric acid solution and grafted in an aqueous acetic acid solution with 2-ethylhexyl acrylate or a mixture thereof with acrylamide or acrylonitrile.
FR7042410A 1970-11-25 1970-11-25 Expired FR2115594A5 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR7042410A FR2115594A5 (en) 1970-11-25 1970-11-25
DE19712157902 DE2157902C3 (en) 1970-11-25 1971-11-23 Process for grafting a polymerizable compound onto a base polymer
BE775761A BE775761A (en) 1970-11-25 1971-11-24 NEW POLYMER GRAFTING PROCESS, ESPECIALLY FOR THE MANUFACTURE OF GRAFT TISSUES AND ION EXCHANGE MEMBRANES
GB5486271A GB1360665A (en) 1970-11-25 1971-11-25 Process for grafting polymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7042410A FR2115594A5 (en) 1970-11-25 1970-11-25

Publications (1)

Publication Number Publication Date
FR2115594A5 true FR2115594A5 (en) 1972-07-07

Family

ID=9064723

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7042410A Expired FR2115594A5 (en) 1970-11-25 1970-11-25

Country Status (4)

Country Link
BE (1) BE775761A (en)
DE (1) DE2157902C3 (en)
FR (1) FR2115594A5 (en)
GB (1) GB1360665A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1501239A (en) * 1975-04-07 1978-02-15 Personal Products Co Cellulose graft copolymer
US4774093A (en) * 1985-06-25 1988-09-27 Fmc Corporation Polysaccharide compositions, preparation and uses
DE19528029B4 (en) 1995-07-31 2008-01-10 Chemagen Biopolymer-Technologie Aktiengesellschaft Magnetic polymer particles based on polyvinyl alcohol, process for their preparation and use
US10910651B2 (en) * 2016-03-10 2021-02-02 Zeon Corporation Binder for non-aqueous secondary battery electrode, slurry for non-aqueous secondary battery electrode, electrode for non-aqueous secondary battery, and non-aqueous secondary battery

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL222108A (en) * 1956-11-03
FR1405642A (en) * 1963-08-08 1965-07-09 Hoechst Ag Textile finishing process

Also Published As

Publication number Publication date
DE2157902B2 (en) 1980-08-21
DE2157902A1 (en) 1972-05-31
BE775761A (en) 1972-03-16
DE2157902C3 (en) 1981-05-07
GB1360665A (en) 1974-07-17

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