FI93540B - Förfarande för producering av en självbärande keramisk sammansatt struktur samt en självbärande keramisk sammansatt struktur - Google Patents

Förfarande för producering av en självbärande keramisk sammansatt struktur samt en självbärande keramisk sammansatt struktur Download PDF

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Publication number
FI93540B
FI93540B FI880121A FI880121A FI93540B FI 93540 B FI93540 B FI 93540B FI 880121 A FI880121 A FI 880121A FI 880121 A FI880121 A FI 880121A FI 93540 B FI93540 B FI 93540B
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Finland
Prior art keywords
carbide
metal
filler
parent metal
carbon
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FI880121A
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English (en)
Finnish (fi)
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FI880121A (sv
FI880121A0 (sv
FI93540C (sv
Inventor
Adam Jan Gesing
Edward Stanley Luce
Narashimha Srinivaka Raghavan
Danny Ray White
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Lanxide Technology Co Ltd
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Publication of FI880121A0 publication Critical patent/FI880121A0/sv
Publication of FI880121A publication Critical patent/FI880121A/sv
Publication of FI93540B publication Critical patent/FI93540B/sv
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Publication of FI93540C publication Critical patent/FI93540C/sv

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/10Isostatic pressing, i.e. using non-rigid pressure-exerting members against rigid parts or dies
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/5607Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on refractory metal carbides
    • C04B35/5611Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on refractory metal carbides based on titanium carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/5607Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on refractory metal carbides
    • C04B35/5622Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on refractory metal carbides based on zirconium or hafnium carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • C04B35/65Reaction sintering of free metal- or free silicon-containing compositions
    • C04B35/652Directional oxidation or solidification, e.g. Lanxide process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • B29C43/361Moulds for making articles of definite length, i.e. discrete articles with pressing members independently movable of the parts for opening or closing the mould, e.g. movable pistons
    • B29C2043/3615Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices
    • B29C2043/3628Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices moving inside a barrel or container like sleeve
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Products (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Powder Metallurgy (AREA)
  • Inorganic Fibers (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Materials For Medical Uses (AREA)
  • Catalysts (AREA)

Claims (17)

1. Förfarande för producering av en självbärande keramisk sammansatt struktur som innefattar en metallkarbid, kanne tecknat 5 därav, att förfarandet innefattar: (a) att man hiller en massa av smält grundmetall i en väsentligen inert atmosfär vilken metall väljs frän en grupp som bestär av titan, hafnium och zirkonium, i ytkontakt med en permeabel massa som innefattar (i) 10 ett fyllnadsämne, och (ii) en kolkalla för reaktion med nämnda smälta metall för att bilda en karbid av den smälta metallen, varvid kolande-len av kolkällan inte är närvarande i mera än en stökiömetriskt mängd; (b) att man upprätthäller ytkontakten för en tid som räcker tili för 15 att ästadkoma infiltrering av smält grundmetall innanför den permeabla massan och för att tilläta reaktion av den smälta grundmetallen med kolkällan för att bilda en grundmetallkarbid; och (c) att man lätar infiltreringen och reaktionen fortsätta för en tid 20 som är tillräcklig för att ätminstone väsentligen läta nämnda reaktion gä till slut och därvid producera önskade självbärande keramiska sam-mansatta struktur.
2. Förfarande enligt patentkrav 1, kännetecknat därav, att 25 fyllnadsämnet innefattar en karbid av titan, hafnium eller zirkonium.
3. Förfarande enligt patentkrav 1, kännetecknat därav, att fyllnadsämnet innefattar ett väsentligen inert fyllnadsämne. 30
4. Förfarande enligt patentkrav 1,2 eller 3, kännetecknat därav, att kolkällan är elementärt koi.
5. Förfarande enligt patentkrav 4, kännetecknat därav, att kolkällan innefattar petroleumkoks. 35 93540
6. Förfarande enligt patentkrav 1,2 eller 3, kännetecknat därav, att kolkällan innefattar metallkarbid som kan reduceras av den smälta grundmetallen. 5
7. Förfarande enligt patentkrav 6, kännetecknat därav, att den reducerbara metallkarbiden väljes frän en grupp som bestär av mo-lybdenkarbid, kromkarbid, koboltkarbid, järnkarbid, nickelkarbid och vanadinkarbid. 10
8. Förfarande enligt patentkrav 1,2 eller 3, kännetecknat därav, att fyllnadsämnena innefattar ett material som väljes frän en grupp som bestär av fibrer, här, partiklar, pulver, stavar, viratyger, eldfasta tyger, nätformiga skum, skivor, skivstycken, fasta sfärer och ihäliga sfärer. 15
9. Förfarande enligt patentkrav 1,2 eller 3, kännetecknat därav, att den permeabla massan är en förform av pä förhand bestämd form, och infiltreringen och reaktionen inträffar genom ätminstone en del av volymen av förformen varvid nämnda självbärande kropp som er- 20 hällits i steg (c) har en konfiguration som svarar mot en del av förformen.
10. Förfarande enligt patentkrav 1,2 eller 3, kännetecknat därav, att den genomträngliga massan innefattar mindre än den stökiö- 25 metriska mängden av kolkällan för att den skall reagera med den smälta grundmetallen, vid vilket förfarande inte ali smält grundmetall som infiltrerar massan reagerar, genom att därvid producera en självbärande kropp som ocksä innehäller icke-reagerad grundmetall. 30
11. Förfarande enligt patentkrav 2, kännetecknat därav, att karbiden är en metallkarbid där metallen motsvarar grundmetallen.
12. Förfarande enligt patentkrav 2, kännetecknat därav, att fyllnadsämneskarbiden innefattar en metall som skiljer sig frän 35 grundmetallen, och att fyllnadsämneskarbiden blandas med grundmetallen II 93540 för att därvid bilda en tertiär fast lösning av grundmetallen, nämnda avvikande metall och koi.
13. Förfarande enligt patentkrav 1, kännetecknat därav, 5 att fyllnadsämnet vidare innefattar ett väsentligen inert fyllnadsäm- nesmaterial.
14. En självbärande keramisk sammansatt struktur, känneteck-n a d därav, att den innefattar (a) ett fyllnadsämne som är (i) en 10 karbid av titan, hafnium och/eller zirkonium; eller (ii) ett material som är väsentligen inert för smält grundmetall och för reaktionspro-dukten som bildas; och (b) en keramisk matris som bäddar in fyllnadsämnet, varvid den keramiska matrisen innefattar en karbid av titan, hafnium och/eller zirkonium och som karakteriseras som reaktionsprodukten 15 mellan en av nämnda metaller och en kolinnehällande förening i stökiö-metrisk mängd sä att väsentligen inget icke-reagerat koi blivit kvar.
15. Sammansatt struktur enligt patentkrav 14, kännetecknad därav, att fyllnadsämnet innefattar en metallkarbid som skiljer sig 20 frän metallkarbiden av den keramiska matrisen, varvid nämnda samman-satta struktur innefattar tertiär fast lösning.
16. Sammansatt struktur enligt patentkrav 14, kännetecknad därav, att den innefattar ett extra fyllnadsämne som är väsentligen 25 inert.
17. Sammansatt struktur enligt patentkrav 14, kännetecknad därav, att fyllnadsämnet innefattar en metallkarbid som awiker frän karbiden i den keramiska matrisen. 30
FI880121A 1987-01-13 1988-01-12 Förfarande för producering av en självbärande keramisk sammansatt struktur samt en självbärande keramisk sammansatt struktur FI93540C (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/002,823 US4891338A (en) 1987-01-13 1987-01-13 Production of metal carbide articles
US282387 1988-12-09

Publications (4)

Publication Number Publication Date
FI880121A0 FI880121A0 (sv) 1988-01-12
FI880121A FI880121A (sv) 1988-07-14
FI93540B true FI93540B (sv) 1995-01-13
FI93540C FI93540C (sv) 1995-04-25

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FI880121A FI93540C (sv) 1987-01-13 1988-01-12 Förfarande för producering av en självbärande keramisk sammansatt struktur samt en självbärande keramisk sammansatt struktur

Country Status (32)

Country Link
US (1) US4891338A (sv)
EP (1) EP0277085B1 (sv)
JP (2) JPH06665B2 (sv)
KR (1) KR950014719B1 (sv)
CN (1) CN88100073A (sv)
AT (1) ATE70038T1 (sv)
AU (1) AU601539B2 (sv)
BG (1) BG60293B2 (sv)
BR (1) BR8800082A (sv)
CA (1) CA1327492C (sv)
CS (1) CS276459B6 (sv)
DD (1) DD284699A5 (sv)
DE (1) DE3866550D1 (sv)
DK (1) DK11188A (sv)
ES (1) ES2038782T3 (sv)
FI (1) FI93540C (sv)
GR (1) GR3003821T3 (sv)
HU (1) HU205335B (sv)
IE (1) IE61458B1 (sv)
IL (1) IL85071A (sv)
IN (1) IN169041B (sv)
MX (1) MX166268B (sv)
NO (1) NO880096L (sv)
NZ (1) NZ223094A (sv)
PH (1) PH26252A (sv)
PL (1) PL157986B1 (sv)
PT (1) PT86537B (sv)
RO (1) RO100373B1 (sv)
RU (1) RU1838279C (sv)
TR (1) TR24678A (sv)
YU (1) YU46856B (sv)
ZA (1) ZA88177B (sv)

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YU46856B (sh) 1994-06-24
YU3588A (en) 1990-06-30
FI880121A (sv) 1988-07-14
FI880121A0 (sv) 1988-01-12
GR3003821T3 (sv) 1993-03-16
DK11188A (da) 1988-07-14
TR24678A (tr) 1992-01-10
BR8800082A (pt) 1988-08-16
IL85071A (en) 1991-08-16
AU601539B2 (en) 1990-09-13
NO880096D0 (no) 1988-01-12
PT86537B (pt) 1991-12-31
DE3866550D1 (de) 1992-01-16
PL157986B1 (pl) 1992-07-31
IL85071A0 (en) 1988-06-30
IE880042L (en) 1988-07-13
RU1838279C (ru) 1993-08-30
JPH06665B2 (ja) 1994-01-05
JP2645180B2 (ja) 1997-08-25
JPS63176361A (ja) 1988-07-20
DK11188D0 (da) 1988-01-12
CS276459B6 (en) 1992-06-17
CN88100073A (zh) 1988-08-24
PT86537A (en) 1988-02-01
CA1327492C (en) 1994-03-08
FI93540C (sv) 1995-04-25
MX166268B (es) 1992-12-28
JPH0692732A (ja) 1994-04-05
KR880008961A (ko) 1988-09-13
IE61458B1 (en) 1994-11-02
NO880096L (no) 1988-07-14
CS8800117A2 (en) 1991-09-15
PL270099A1 (en) 1988-11-24
BG60293B2 (en) 1994-04-29
DD284699A5 (de) 1990-11-21
RO100373B1 (en) 1992-05-05
ATE70038T1 (de) 1991-12-15
HU205335B (en) 1992-04-28
KR950014719B1 (ko) 1995-12-13
ES2038782T3 (es) 1993-08-01
EP0277085B1 (en) 1991-12-04
PH26252A (en) 1992-04-01
ZA88177B (en) 1988-06-30
EP0277085A1 (en) 1988-08-03
US4891338A (en) 1990-01-02
HUT47063A (en) 1989-01-30
NZ223094A (en) 1991-01-29
AU1001888A (en) 1988-07-14
IN169041B (sv) 1991-08-24

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