FI92409B - Förfarande för samtidig avlägsning av arsen och karbonylsulfid ur en omättad fraktion av kolväten i vätskefas - Google Patents

Förfarande för samtidig avlägsning av arsen och karbonylsulfid ur en omättad fraktion av kolväten i vätskefas Download PDF

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Publication number
FI92409B
FI92409B FI883681A FI883681A FI92409B FI 92409 B FI92409 B FI 92409B FI 883681 A FI883681 A FI 883681A FI 883681 A FI883681 A FI 883681A FI 92409 B FI92409 B FI 92409B
Authority
FI
Finland
Prior art keywords
arsenic
mass
lead
liquid phase
weight
Prior art date
Application number
FI883681A
Other languages
English (en)
Finnish (fi)
Other versions
FI883681A (sv
FI92409C (sv
FI883681A0 (sv
Inventor
Jean-Paul Boitiaux
Jean Cosyns
Original Assignee
Inst Francais Du Petrole
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Francais Du Petrole filed Critical Inst Francais Du Petrole
Publication of FI883681A0 publication Critical patent/FI883681A0/sv
Publication of FI883681A publication Critical patent/FI883681A/sv
Publication of FI92409B publication Critical patent/FI92409B/sv
Application granted granted Critical
Publication of FI92409C publication Critical patent/FI92409C/sv

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/16—Metal oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Catalysts (AREA)

Claims (5)

1. Förfarande for samtidig eliminering av arsenik och kar-bonylsulfid frän en kolvätefraktion, enligt vilket förfarande 5 kolvätefraktionen bringas i kontakt med en absorberande massa, som omfattar en bärare och blyoxid, kanne -tecknad av att kolvätefraktionen bringas i vätskefas i kontakt med massan. 10
2. Förfarande enligt krav 1, kännetecknat av att sagda massa uppstär genom att man (a) blandar en lösning av en löslig blyförening med en aluminiumoxidbärare, vars yta uppgär till 10...300 m2/g och vars porvolym uppgär till 0,2...1,2 cm3/g, varvid volymen hos 15 de makroporer som är over 100 nm Stora uppgär till 0,1...0,5 cm3/g och surheten mätt med adsorptionsvärmet för ammoniak vid 40 kPa och 320 °C är under 40 J per gram av bäraren, och därefter (b) upphettar blandningen vid 300...900 °C i en atmosfär som 20 innehäller syre.
3. Förfarande enligt krav 1 eller 2, kännetecknat av att man använder en aluminiumoxidbärare, vars yta uppgär till 50...200 m2/g och porernas totalvolym till 0,5...1,2 2. cm3/g.
4. Förfarande enligt krav 2 eller 3, kännetecknat av att säsom löslig blyförening används blyacetat. 30
5. Förfarande enligt nägot av kraven 1-4, känne tecknat av att man använder en massa, som innehäller 5 - 50 vikt-% bly beräknat säsom PbO.
FI883681A 1987-08-07 1988-08-05 Förfarande för samtidig avlägsning av arsen och karbonylsulfid ur en omättad fraktion av kolväten i vätskefas FI92409C (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8711347 1987-08-07
FR8711347A FR2619120B1 (fr) 1987-08-07 1987-08-07 Procede pour l'elimination conjointe d'arsenic et d'oxysulfure de carbone d'une coupe d'hydrocarbures insatures en phase liquide

Publications (4)

Publication Number Publication Date
FI883681A0 FI883681A0 (sv) 1988-08-05
FI883681A FI883681A (sv) 1989-02-08
FI92409B true FI92409B (sv) 1994-07-29
FI92409C FI92409C (sv) 1994-11-10

Family

ID=9354053

Family Applications (1)

Application Number Title Priority Date Filing Date
FI883681A FI92409C (sv) 1987-08-07 1988-08-05 Förfarande för samtidig avlägsning av arsen och karbonylsulfid ur en omättad fraktion av kolväten i vätskefas

Country Status (9)

Country Link
US (1) US4849577A (sv)
EP (1) EP0302771B1 (sv)
JP (1) JP2591663B2 (sv)
KR (1) KR930006815B1 (sv)
CN (1) CN1012964B (sv)
AT (1) ATE68457T1 (sv)
DE (1) DE3865578D1 (sv)
FI (1) FI92409C (sv)
FR (1) FR2619120B1 (sv)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4962272A (en) * 1989-05-30 1990-10-09 Aristech Chemical Corporation Treatment of arsine removal catalysts
US5169516A (en) * 1991-07-30 1992-12-08 Carr Norman L Removal of arsenic compounds from light hydrocarbon streams
CN1045199C (zh) * 1993-04-23 1999-09-22 武汉大学 工业规模制备富勒烯c60/c70的方法
DE19710762A1 (de) * 1997-03-14 1998-09-17 Basf Ag Verfahren zur Reinigung von Stoffströmen
GB9920871D0 (en) * 1999-09-06 1999-11-10 Ici Plc Catalysts
FR2806092B1 (fr) 2000-03-08 2002-05-03 Inst Francais Du Petrole Procede d'elimination d'arsenic en presence d'une masse d'absorption comprenant de l'oxyde de plomb partiellement presulfure
GB0104096D0 (en) * 2001-02-20 2001-04-04 Synetix Intellectual Property Catalysts
GB0218785D0 (en) * 2002-08-13 2002-09-18 Ici Plc Catalyst bed combination
CN101591552B (zh) * 2008-05-30 2013-09-11 北京三聚环保新材料股份有限公司 一种常温复合脱硫脱砷剂的制备方法
CN101591553B (zh) * 2008-05-30 2013-10-16 北京三聚环保新材料股份有限公司 一种常温复合脱硫脱砷剂
CN101659877B (zh) * 2008-08-29 2013-06-26 中国石油化工股份有限公司 烃类气体中所含h2s的吸收剂及应用
US8241491B1 (en) 2011-10-01 2012-08-14 Jacam Chemicals, Llc Method of removing arsenic from hydrocarbons
US8211294B1 (en) 2011-10-01 2012-07-03 Jacam Chemicals, Llc Method of removing arsenic from hydrocarbons
CN106756112B (zh) * 2016-12-29 2018-09-07 湖南工业大学 一种沉砷渣还原固硫焙烧直接生产金属砷的方法
CN110639466B (zh) 2019-09-30 2020-12-01 四川润和催化新材料股份有限公司 一种脱砷吸附剂及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1581369A (en) * 1925-05-14 1926-04-20 James W Weir Method of refining lubricating-oil stocks
US3782076A (en) * 1972-04-27 1974-01-01 Gulf Research Development Co Process for reducing the arsenic content of gaseous hydrocarbon streams by use of supported lead oxide
US4009009A (en) * 1974-07-26 1977-02-22 Gulf Research & Development Company Process for reducing the COS content of gaseous hydrocarbon streams by use of supported lead oxide
LU85487A1 (fr) * 1984-07-27 1986-02-12 Labofina Sa Procede de purification de charges d'hydrocarbures liquides

Also Published As

Publication number Publication date
KR930006815B1 (ko) 1993-07-24
KR890003924A (ko) 1989-04-18
EP0302771A1 (fr) 1989-02-08
CN1031557A (zh) 1989-03-08
ATE68457T1 (de) 1991-11-15
JP2591663B2 (ja) 1997-03-19
US4849577A (en) 1989-07-18
EP0302771B1 (fr) 1991-10-16
JPS6466291A (en) 1989-03-13
FI883681A (sv) 1989-02-08
FI92409C (sv) 1994-11-10
FR2619120A1 (fr) 1989-02-10
CN1012964B (zh) 1991-06-26
DE3865578D1 (de) 1991-11-21
FR2619120B1 (fr) 1989-12-29
FI883681A0 (sv) 1988-08-05

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