FI83531B - Fluorerade kopolymerer och anvaendning av dem foer behandling av olika substrat foer att goera dem vatten- och oljeavstoetande. - Google Patents

Fluorerade kopolymerer och anvaendning av dem foer behandling av olika substrat foer att goera dem vatten- och oljeavstoetande. Download PDF

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Publication number
FI83531B
FI83531B FI861157A FI861157A FI83531B FI 83531 B FI83531 B FI 83531B FI 861157 A FI861157 A FI 861157A FI 861157 A FI861157 A FI 861157A FI 83531 B FI83531 B FI 83531B
Authority
FI
Finland
Prior art keywords
denotes
monomers
carbon atoms
dem
hydrogen atom
Prior art date
Application number
FI861157A
Other languages
English (en)
Finnish (fi)
Other versions
FI861157A0 (fi
FI83531C (sv
FI861157A (fi
Inventor
Andre Dessaint
Marie-Jose Lina
Original Assignee
Atochem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atochem filed Critical Atochem
Publication of FI861157A0 publication Critical patent/FI861157A0/fi
Publication of FI861157A publication Critical patent/FI861157A/fi
Application granted granted Critical
Publication of FI83531B publication Critical patent/FI83531B/fi
Publication of FI83531C publication Critical patent/FI83531C/sv

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C04B41/4838—Halogenated polymers
    • C04B41/4842—Fluorine-containing polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/282—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing two or more oxygen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Paper (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polyethers (AREA)
  • Water Treatment By Sorption (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (6)

1. Kopolymerer, kännetecknade av att de uttryckt i vikt-procent innehäller: (a) mellan 50 ooh 65 % av en eller flera polyfluormonomerer med den allmänna formeln: 20 83531 O II Rf-B-Q-C-C=CH2 (I) ch3 där Rf är en rak eller förgrenad perfluorerad radikal inne-hällande mellan 2 och 20 kolatomer, företrädesvis mellan 4 och 16 kolatomer, Q är en syre- eller svavelatom, B är en tvävärd ked, som är bunden vid Q med en kolatom och kan innehälla en eller flera syra-, svavel- och/eller kväveato-mer; (b) mellan 32,5 och 50 % av en eller flera monomerer, med den allmänna formeln: 0 II H2C=C-C-0[CnH2n0] -R2 (II) I 3 R1 där R^ är en väteatom eller en metylradikal, R2 är en alkyl-radikal med mellan 1 och 4 kolatomer, n är 2 eller 3; och eventuellt (c) högst 10 % av en eller flera monomerer valda bland följande: vinylacetat, akryl- eller metakrylsyra, maleinan-hydrid, alkylakrylater eller -metakrylater, etylenglykol-eller trietylenglykoldiakrylater eller -dimetakrylater, N-vinyl-2-pyrrolidon, etylenglykol- eller propylenglykol-monoakrylater eller -metakrylater, akrylamid, metakryl-amid, N-metylolakrylamid eller -metakrylamid, N,N-dimetyl-aminoetyl- eller N-tertiärbutylaminoetylmetakrylat.
2. Kopolymerer enligt patentkravet 1, kännetecknade av att polyfluormonomeren eller -monomererna motsvaras av formeln: 0 Rf-(CH2)p-0-C-C=CH2 (III) ch3 21 83531 där Rf betecknar detsamma som i patentkravet 1 och p är ett heltal mellan 1 och 20, företrädesvis 2 eller 4.
3. Kopolymerer enligt patentkravet 2, kännetecknade av att de framställts genom användning av monomerer enligt forraeln (III), där Rf-radikalerna är olika.
4. Kopolymerer enligt nägot av patentkraven 1-3, kännetecknade av att R2 är en metyl- eller etylradikal.
5. Användning av kopolymerer enligt nägot av patentkraven 1-4 för behandling av olika substrat, företrädesvis skin, för att göra dem olje- och vattenavvisande.
6. Material och produkter behandlade med en kopolymer enligt nägot av patentkraven 1-4.
FI861157A 1985-03-20 1986-03-19 Fluorerade kopolymerer och användning av dem för behandling av olika s ubstrat för att göra dem vatten- och oljeavstötande FI83531C (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8504102A FR2579211B1 (fr) 1985-03-20 1985-03-20 Copolymeres fluores et leur application au traitement hydrophobe et oleophobe de substrats divers
FR8504102 1985-03-20

Publications (4)

Publication Number Publication Date
FI861157A0 FI861157A0 (fi) 1986-03-19
FI861157A FI861157A (fi) 1986-09-21
FI83531B true FI83531B (fi) 1991-04-15
FI83531C FI83531C (sv) 1991-07-25

Family

ID=9317380

Family Applications (1)

Application Number Title Priority Date Filing Date
FI861157A FI83531C (sv) 1985-03-20 1986-03-19 Fluorerade kopolymerer och användning av dem för behandling av olika s ubstrat för att göra dem vatten- och oljeavstötande

Country Status (13)

Country Link
EP (1) EP0195714B1 (sv)
JP (1) JPS61236806A (sv)
KR (1) KR910009380B1 (sv)
AT (1) ATE39260T1 (sv)
AU (1) AU588024B2 (sv)
CA (1) CA1282544C (sv)
DE (1) DE3661421D1 (sv)
DK (1) DK171717B1 (sv)
ES (1) ES8705477A1 (sv)
FI (1) FI83531C (sv)
FR (1) FR2579211B1 (sv)
NO (1) NO165806C (sv)
ZA (1) ZA862037B (sv)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1314353C (en) * 1987-05-14 1993-03-09 Donald L. Schmidt Fluorocarbon containing, reactive polymeric surfactants and coating compositions therefrom
JP2508760B2 (ja) * 1987-10-20 1996-06-19 旭硝子株式会社 汚れ離脱性を有する撥水撥油剤
US5143991A (en) * 1989-06-21 1992-09-01 Daikin Industries, Ltd. Copolymer desoiling agent
US5194542A (en) * 1989-09-30 1993-03-16 Hoya Corporation Contact lens
JPH03281509A (ja) * 1990-03-29 1991-12-12 Mitsubishi Rayon Co Ltd 滑性効果を有するフッ化アクリル系重合体およびそれを含む熱可塑性樹脂組成物
US5288825A (en) * 1990-03-29 1994-02-22 Mitsubishi Rayon Company Ltd. Fluoroacrylic polymer having lubricating effect and thermoplastic resin composition comprising same
AU648100B2 (en) * 1990-09-03 1994-04-14 Unilever Plc Hair treatment composition
FR2683535B1 (fr) * 1991-11-12 1994-10-28 Atochem Nouveaux copolymeres fluores et leur utilisation pour le revetement et l'impregnation de substrats divers.
DE4201603A1 (de) * 1992-01-22 1993-07-29 Bayer Ag Mischungen fluorhaltiger copolymerisate
DE4201604A1 (de) * 1992-01-22 1993-07-29 Bayer Ag Fluorhaltige copolymerisate und daraus hergestellte waessrige dispersionen
GB9204509D0 (en) * 1992-03-02 1992-04-15 Unilever Plc Hair care composition
US6113925A (en) * 1993-12-15 2000-09-05 L'oreal Method of forming a film using a composition containing a fluoroalkyl copolymer
FR2713649B1 (fr) * 1993-12-15 1996-08-02 Oreal Composition filmogène contenant un copolymère d'alkyle perfluoré, utilisable comme vernis à ongles.
EP0714870A1 (fr) 1994-11-29 1996-06-05 Elf Atochem S.A. Procédé et composition pour le traitement oléophobe et hydrophobe des matériaux de construction
US6037429A (en) * 1995-06-16 2000-03-14 3M Innovative Properties Company Water-soluble fluorochemical polymers for use in water and oil repellent masonry treatments
JPH11158037A (ja) * 1997-11-27 1999-06-15 Mitsubishi Chemical Corp 化粧料
US6353051B1 (en) * 1999-03-10 2002-03-05 E. I. Du Pont De Nemours And Company Top coating for synthetic leathers
KR100477743B1 (ko) * 2001-07-05 2005-03-18 삼성에스디아이 주식회사 불소계 코폴리머, 이를 이용한 겔형 고분자 전해질 및상기 고분자 전해질을 채용하고 있는 리튬 전지
KR101153762B1 (ko) * 2004-03-23 2012-06-13 아사히 가라스 가부시키가이샤 내수 내유제 조성물
EP1739143B1 (en) * 2004-03-26 2012-01-11 Daikin Industries, Ltd. Surface treating agent, fluorine-containing monomer and fluorine-containing polymer
CA2561890A1 (en) 2004-04-05 2005-10-20 Daikin Industries, Ltd. Stain remover containing fluoropolymer
CN101218269A (zh) * 2005-07-14 2008-07-09 大金工业株式会社 含氟聚合物和去污剂
DE602007003186D1 (de) 2007-03-21 2009-12-24 Du Pont Fluorobetain-copolymer und Löschschaumkonzentrate daraus
EP2045276A1 (en) * 2007-10-05 2009-04-08 E.I. Du Pont De Nemours And Company Fluoropolymer
JP5459212B2 (ja) 2007-12-13 2014-04-02 ダイキン工業株式会社 含フッ素重合体および水性処理剤
JP6331026B2 (ja) * 2012-08-30 2018-05-30 日産化学工業株式会社 含フッ素高分岐ポリマー及びそれを含む不飽和ポリエステル樹脂組成物
WO2017002847A1 (ja) * 2015-06-30 2017-01-05 富士フイルム株式会社 含フッ素共重合体、組成物、光学フィルム、ハードコートフィルム、偏光板、及びタッチパネルディスプレイ、並びに含フッ素共重合体の製造方法

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Publication number Priority date Publication date Assignee Title
GB1123829A (en) * 1964-12-01 1968-08-14 Minnesota Mining & Mfg Fluorine containing copolymers
US3654244A (en) * 1970-03-16 1972-04-04 Us Agriculture Polymers for soil-release textile finishes
JPS5235033B2 (sv) * 1972-11-24 1977-09-07
US3944527A (en) * 1974-07-11 1976-03-16 Minnesota Mining And Manufacturing Company Fluoroaliphatic copolymers
JPS5235033A (en) * 1976-09-27 1977-03-17 Toyota Motor Corp Construction for mounting an oil reservoir tank on a vehicle
US4127711A (en) * 1977-03-31 1978-11-28 E. I. Du Pont De Nemours And Company Fluorine-containing terpolymers

Also Published As

Publication number Publication date
FI861157A0 (fi) 1986-03-19
ES8705477A1 (es) 1987-05-01
FI83531C (sv) 1991-07-25
JPS61236806A (ja) 1986-10-22
EP0195714B1 (fr) 1988-12-14
DK126186D0 (da) 1986-03-19
DK126186A (da) 1986-09-21
CA1282544C (fr) 1991-04-02
DK171717B1 (da) 1997-04-07
KR860007296A (ko) 1986-10-10
EP0195714A1 (fr) 1986-09-24
ZA862037B (en) 1986-11-26
AU588024B2 (en) 1989-09-07
AU5488486A (en) 1986-09-25
NO861062L (no) 1986-09-22
KR910009380B1 (ko) 1991-11-14
FR2579211B1 (fr) 1987-09-18
FI861157A (fi) 1986-09-21
ATE39260T1 (de) 1988-12-15
NO165806B (no) 1991-01-02
DE3661421D1 (en) 1989-01-19
FR2579211A1 (fr) 1986-09-26
ES553198A0 (es) 1987-05-01
NO165806C (no) 1991-04-10

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Owner name: ATOCHEM