FI74983B - Krotonesterhaltiga kopolymerisat, foerfarande foer deras framstaellning och deras anvaendning som foertjockningsmedel i vattenhaltiga system och som klisteraemne. - Google Patents

Krotonesterhaltiga kopolymerisat, foerfarande foer deras framstaellning och deras anvaendning som foertjockningsmedel i vattenhaltiga system och som klisteraemne. Download PDF

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Publication number
FI74983B
FI74983B FI841261A FI841261A FI74983B FI 74983 B FI74983 B FI 74983B FI 841261 A FI841261 A FI 841261A FI 841261 A FI841261 A FI 841261A FI 74983 B FI74983 B FI 74983B
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FI
Finland
Prior art keywords
copolymer
acid
weight
ethylenically unsaturated
water
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FI841261A
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English (en)
Finnish (fi)
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FI74983C (sv
FI841261A (fi
FI841261A0 (fi
Inventor
Dieter Engel
Helmut Rinno
Klaus Zimmerschied
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Hoechst Ag
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Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of FI841261A0 publication Critical patent/FI841261A0/fi
Publication of FI841261A publication Critical patent/FI841261A/fi
Application granted granted Critical
Publication of FI74983B publication Critical patent/FI74983B/fi
Publication of FI74983C publication Critical patent/FI74983C/sv

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)
  • Polymerisation Methods In General (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paper (AREA)

Claims (10)

1. Kopolymerisat sorti framställts genom radikaliskt initierad emulsions- eller lösningskopolymerisation av 5 omättade kopolymeriserbara monomerer och eventuellt efter-följande delvis eller fullständig neutralisation av de fria syragrupperna av kopolymerisaten genom tillsats av baser, kännetecknade därav, att kopolymerisaten bestär av 10 a) 1 - 45 vikt-% av etyleniskt omättade (C^-C^)- monokarboxylsyror, etyleniskt omättade (C^-C^)-dikarbosyl- syror eller deras halvestrar med alifatiska (C^-Cg)-alko- holer eller blandningar av dessa monomerer, företrädesvis metakrylsyra, akrylsyra, krotonsyra, maleinsyra, maleinsyra- 15 monoalkylestrar eller deras blandningar och b) 0,5-30 vikt-% av en ytaktiv krotonsyraester med den allmänna formeln I: 0 CH_-CH=CH-C-0-(CH„-CH_-0) -R (I) 3 2 2 n 20 där n är ett tai frän 2 tili 100 och R star för en ali- fatisk (C2“Cgg)-rest som kan vara lineär eller grenad, en mono-, di- eller trialkylfenylrest med alkylgrupper av 4-12 C-atomer, en rest av en blockkopolymer med formlerna Ha eller Hb: 25 - (CH-CH„-0) - (CH--CH„-0) -R1 (Ha) i 2 m 2 2 p CH3 - (CH_-CH-0) - (CH -CH0-0) -R1 ( Hb) 2. m 2 2 p CH3
30 J i vilka m är ett tai frän 10 tili 100, p är ett tai frän 0 tili 100 och R^ är H, krotyl, (C^- C2q) -alkyl, fenyl, alkylfenyl med (C1-C2Q)-alkylgrupper, eller är en per- fluorerad eller delvis fluorerad (C.-C.c)-alkylrest, och 1 ib 25 c) 30 - 85 vikt-% metakrylsyraestrar eller akryl- syraestrar av alifatiska (C1-C1g)-alkoholer eller en blandning av dessa estrar, och 28 74983 d) 0-40 vikt-% av andra etyleniskt omättade komonomerer, företrädesvis vinylestrar, aromatiska vinyl-föreningar, etyleniskt omättade nitriler, estrar av etyleniskt omättade mono- och dikarboxylsyror, sävida de 5 inte redan anförts ovan under (c), etyleniskt omättade sulfonsyror eller etyleniskt omättade sulfonsyraderivat, och e) 0 - 3 vikt-% av mangfalldigt etyleniskt omättade föreningar, företrädesvis divinylbensen, diallylftaiat, 10 butandioldiakrylat eller -dimetakrylat, och f) 0 - 5 vikt-% molekylviktsreglerare, företrädesvis dodekylmerkaptan, tetrakismerkaptoacetylpentaerytritol, koltetraklorid eller bromtriklormetan.
2. Kopolymerisat enligt patetkravet 1, k ä n n e - 15 tecknade därav, att de föreligger i delvis eller fullständigt med baser neutraliserad vattenlöslig eller i vatten kolloidalt dispergerbar form.
3. Användning av kopolymerisaten enligt patent-kravet 1 eller 2 till förtjockning av vattenhaltiga system, 20 speciellt vattenhaltiga dispersioner.
4. Användning av kopolymerisaten i delvis eller fullständigt med baser neutraliserad, vattenlöslig eller i vatten kolloidalt dispergerbar form enligt patentkravet 1 eller 2 till förtjockning av vattenhaltiga system, 25 speciellt vattenhaltiga dispersioner.
5. Avnändning av kopolymerisaten enligt patentkravet 1 eller 2 till förtjockning av dispersionsfärger, dispersionsglanslacker, textiltryckpastor eller pappers-tryckpastor.
6. Användning av kopolymerisaten i delvis eller fullständigt med baser neutraliserad, vattenlöslig eller i vatten kolloidalt dispergerbar form enligt patentkravet 1 eller 2 till förtjockning av dispersionsfärger, dispersionsglanslacker, textiltryckpastor eller papperstryck- 35 pastor. II 29 74983
7. Användning av kopolymerisaten enligt patent-kravet 1 eller 2 tili förtjockning av vattenhaltiga system, speciellt vattenhaltiga dispersioner, genom att kopolymerisaten i sin syraform som lösningar eller dis- 5 persioner i den erforderliga mängden blandas med det vattenhaltiga systemet som skall förtjockas, speciellt med dispersionen som skall förtjockas och den resulteran-de blandningen därefter genom tillsats av baser delvis eller fullständigt neutraliseras eller görs svagt alka-10 lisk sä att kopolymerisaten föreligger som i vattenlösliga eller kolloidalt dispergerbara kopolymerisatsalter.
8. Användning av kopolymerisaten enligt patent-kravet 1 eller 2 som klister i textilindustrin.
9. Förfarande för framställning av kopolymerisat 15 genom radikaliskt initierad emulsions- eller lösningskopo- lymerisation av omättade, kopolymeriserbara monomerer och eventuellt efterföljande delvis eller fullständig neutralisation av de fria syragrupperna av kopolymerisaten genom tillsats av baser, kännetecknat därav, att som 20 monomerer kopolymeriseras a) 1-45 vikt-% av etyleniskt omättade (Cg-Cg)-monokarboxylsyror, etyleniskt omättade (C^-C^)-dikarboxyl-syror eller deras halvestrar med alifatiska (C^-Cg)-alkoholer eller blandningar av dessa monomerer, föret- 25 rädesvis metakrylsyra, akrylsyra, krotonsyra, maleinsyra, maleinsyramonoalkylestrar eller deras blandningar och b) 0,5-30 vikt-% av en ytaktiv krotonsyraester med den allmännä formeln I: O 30 ch3-ch=ch-c-o-(ch2-ch2-o)-R (I) där n är ett tai frän 2 tili 100 och R star för en ali-fatisk (C2~C3q)-rest som kan vara lineär eller grenad, en mono-, di- eller trialkylfenylrest med alkylgrupper 35 av 4 - 12 C-atomer, en rest av en blockkopolymer med formlerna Ha eller Hb:
FI841261A 1983-03-31 1984-03-29 Krotonesterhaltiga kopolymerisat, förfarande för deras framställning o ch deras användning som förtjockningsmedel i vattenhaltiga system och som klisterämne. FI74983C (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3311752 1983-03-31
DE19833311752 DE3311752A1 (de) 1983-03-31 1983-03-31 Crotonesterhaltige copolymerisate, verfahren zu ihrer herstellung und ihre verwendung als verdicker in waessrigen systemen sowie als schlichtemittel

Publications (4)

Publication Number Publication Date
FI841261A0 FI841261A0 (fi) 1984-03-29
FI841261A FI841261A (fi) 1984-10-01
FI74983B true FI74983B (fi) 1987-12-31
FI74983C FI74983C (sv) 1988-04-11

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Family Applications (1)

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FI841261A FI74983C (sv) 1983-03-31 1984-03-29 Krotonesterhaltiga kopolymerisat, förfarande för deras framställning o ch deras användning som förtjockningsmedel i vattenhaltiga system och som klisterämne.

Country Status (17)

Country Link
US (1) US4569965A (sv)
EP (1) EP0121230B1 (sv)
JP (2) JPH0639501B2 (sv)
AR (1) AR241598A1 (sv)
AT (1) ATE24732T1 (sv)
AU (1) AU568352B2 (sv)
BR (1) BR8401449A (sv)
CA (1) CA1225791A (sv)
DE (2) DE3311752A1 (sv)
DK (1) DK169682B1 (sv)
ES (1) ES531116A0 (sv)
FI (1) FI74983C (sv)
IE (1) IE57180B1 (sv)
MX (1) MX164249B (sv)
NO (1) NO163015C (sv)
PT (1) PT78348B (sv)
ZA (1) ZA842382B (sv)

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Also Published As

Publication number Publication date
PT78348A (en) 1984-04-01
IE840800L (en) 1984-09-30
AU2634784A (en) 1984-10-04
AU568352B2 (en) 1987-12-24
MX164249B (es) 1992-07-27
FI74983C (sv) 1988-04-11
CA1225791A (en) 1987-08-18
JPH0639501B2 (ja) 1994-05-25
JPS59184214A (ja) 1984-10-19
JPH0649153A (ja) 1994-02-22
AR241598A1 (es) 1992-09-30
NO163015B (no) 1989-12-11
EP0121230B1 (de) 1987-01-07
NO841271L (no) 1984-10-01
FI841261A (fi) 1984-10-01
US4569965A (en) 1986-02-11
ATE24732T1 (de) 1987-01-15
BR8401449A (pt) 1984-11-06
JPH0830101B2 (ja) 1996-03-27
DK143584D0 (da) 1984-02-29
NO163015C (no) 1990-03-21
FI841261A0 (fi) 1984-03-29
IE57180B1 (en) 1992-05-20
DK143584A (da) 1984-10-01
DE3311752A1 (de) 1984-10-04
ZA842382B (en) 1984-11-28
ES8501420A1 (es) 1984-12-01
PT78348B (en) 1986-07-14
ES531116A0 (es) 1984-12-01
EP0121230A1 (de) 1984-10-10
DK169682B1 (da) 1995-01-09
DE3461929D1 (en) 1987-02-12

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