FI71569B - Foerfarande foer polymerisering av 1-olefiner och vid foerfarandet anvaendbar katalysator - Google Patents
Foerfarande foer polymerisering av 1-olefiner och vid foerfarandet anvaendbar katalysator Download PDFInfo
- Publication number
- FI71569B FI71569B FI813745A FI813745A FI71569B FI 71569 B FI71569 B FI 71569B FI 813745 A FI813745 A FI 813745A FI 813745 A FI813745 A FI 813745A FI 71569 B FI71569 B FI 71569B
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- Prior art keywords
- reaction
- transition metal
- halide
- metal
- cocatalyst
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- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 1
- FYYHWMGAXLPEAU-OUBTZVSYSA-N magnesium-25 atom Chemical compound [25Mg] FYYHWMGAXLPEAU-OUBTZVSYSA-N 0.000 description 1
- XKPKPGCRSHFTKM-UHFFFAOYSA-L magnesium;diacetate;tetrahydrate Chemical compound O.O.O.O.[Mg+2].CC([O-])=O.CC([O-])=O XKPKPGCRSHFTKM-UHFFFAOYSA-L 0.000 description 1
- LGLXXNHIGIJYQQ-UHFFFAOYSA-L magnesium;dibromide;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Br-].[Br-] LGLXXNHIGIJYQQ-UHFFFAOYSA-L 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000036316 preload Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012066 reaction slurry Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940087562 sodium acetate trihydrate Drugs 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 1
- WXRGABKACDFXMG-UHFFFAOYSA-N trimethylborane Chemical compound CB(C)C WXRGABKACDFXMG-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- XDSSGQHOYWGIKC-UHFFFAOYSA-N tris(2-methylpropyl)borane Chemical compound CC(C)CB(CC(C)C)CC(C)C XDSSGQHOYWGIKC-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03F—SEWERS; CESSPOOLS
- E03F5/00—Sewerage structures
- E03F5/04—Gullies inlets, road sinks, floor drains with or without odour seals or sediment traps
- E03F5/041—Accessories therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16H—GEARING
- F16H25/00—Gearings comprising primarily only cams, cam-followers and screw-and-nut mechanisms
- F16H25/18—Gearings comprising primarily only cams, cam-followers and screw-and-nut mechanisms for conveying or interconverting oscillating or reciprocating motions
- F16H25/20—Screw mechanisms
- F16H25/2015—Means specially adapted for stopping actuators in the end position; Position sensing means
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- Water Supply & Treatment (AREA)
- Public Health (AREA)
- Hydrology & Water Resources (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Safety Valves (AREA)
- Fluid-Pressure Circuits (AREA)
Claims (10)
1. Förfarande för polymerisering av 1-olefiner en-samma eller med minst en kopolymeriserbar monomer under 5 polymeriseringsbetingelser av temperatur och tryck med ett olefinpolymeriseringskatalysatorsystem, kanne-t e c k n a t därav, att katalysatorsystemet omfattar en blandning, som bestär av en första och en andra kokatalysator, varvid den första kokatalysatorn är en 10 organisk bor- eller organisk aluminiumförening och den andra kokatalysatorn är en med halogenid aktiverad intermetallförening, som erhällits som reaktionsprodukt, när 1) en polymer övergängsmetalloxidalkoxid, i vilken övergängsmetallen är titan eller zirkonium och vilken 15 är framställd genom partiell hydrolys av övergängsmetall-alkoxiden, vilken utförts med ett akvokomplex som vatten-källa, varvid vatten tillförts till reaktionen i form av ett hydratiserat sait säsom i form av ett aluminium-, kobolt-, järn-, magnesium- eller nickelsalthydrat eller i 20 form av en hydratiserad oxid, företrädesvissilikagel, och 2) en reducerande metall av högre oxidationspotential än övergängsmetallen och vilken är magnesium, kalcium, zink, aluminium eller en blandning av dessa, omsatts med varandra. 25 2. Förfarande enligt patentkravet 1, känne tecknat därav, att övergängsmetailens molförhällande tili vatten är cirka 1:0,5-1:1,5.
3. Förfarande enligt patentkravet 1 eller 2, kännetecknat därav, att övergängsmetallen och 30 den reducerande metallen finns närvarande i ett molförhällande av cirka 0,5:1-3:1.
4. Förfarande enligt nägot av patentkraven 1-3, kännetecknat därav, att den första kokatalysatorn beräknad som metall och den andra kokatylysatorn beräknad 35 som metall finns närvarande i ett molförhällande av cirka 3:1-25:1. 61 715 69
5. Förfarande enligt nägot av patentkraven 1-4, kännetecknat därav, att man använder som halogenidaktivator ätminstone en av följande: alkylaluminium-halogenid, kiselhalogenid, alkylkiselhalogenid, titanhalogenid 5 eller alkylborhalogenid.
6. Förfarande enligt nägot av patentkraven 1-5, kännetecknat därav, att kokatalysatoren är en organisk aluminium- eller organisk borförening, företrädesvis trietylaluminium eller trietylboran.
10. Polymeriseringskatalysatorsystem för polymerisering av 1-olefiner ensamma eller med minst en kopolymeriserbar monomer, kännetecknat därav, att det omfattar en blandning, som bestär av en första och en andra kokatalysator, varvid den första kokatalysatorn är en 15 organisk aluminium- eller organisk borförening och den andra kokatalysatorn är en med halogenid aktiverad inter-metallförening, som är en reaktionsprodukt av en polymer övergängsmetalloxidalkoxid och en reducerande metall med högre oxidationspotential än övergängsmetallen, varvid 20 övergängsmetallen är titan eller zirkonium, den recuderande metallen är magnesium, kalcium, zink, aluminium eller blandningar av dessa och varvid den polymera övergängsmetall-oxidalkoxiden är en reaktionsprodukt av en kontrollerad titan- eller zirkoniumalkoxidhydrolys.
8. Katalysatorsystem enligt patentkravet 7, kännetecknat därav, att man använder som halogenidaktivator ätminstone en av följande: alkylaluminium-halogenid, kiselhalogenid, alkylkiselhalogenid, titanhalogenid och alkylborhalogenid.
9. Katalysatorsystem enligt patentkravet 7 eller 8, kännetecknat därav, att övergängsmetallen och den reducerande metallen är närvarande i ett molförhällande av cirka 0,5:1-3:1.
10. Katalysatorsystem enligt nägot av patentkraven 35 7-9, kännetecknat därav, att den första kokata lysatorn beräknad som metall och den andra kokatalysatorn beräknad som metall finns närvarande i ett molförhällande av cirka 3:1-25:1.
Applications Claiming Priority (16)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20922680A | 1980-11-24 | 1980-11-24 | |
| US20922580A | 1980-11-24 | 1980-11-24 | |
| US20922880A | 1980-11-24 | 1980-11-24 | |
| US20922980A | 1980-11-24 | 1980-11-24 | |
| US20922480A | 1980-11-24 | 1980-11-24 | |
| US20922780A | 1980-11-24 | 1980-11-24 | |
| US20922380A | 1980-11-24 | 1980-11-24 | |
| US20922480 | 1980-11-24 | ||
| US20922780 | 1980-11-24 | ||
| US20922980 | 1980-11-24 | ||
| US20922380 | 1980-11-24 | ||
| US20922680 | 1980-11-24 | ||
| US20922880 | 1980-11-24 | ||
| US20922580 | 1980-11-24 | ||
| US22883181A | 1981-01-27 | 1981-01-27 | |
| US22883181 | 1981-01-27 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI813745L FI813745L (fi) | 1982-05-25 |
| FI71569B true FI71569B (fi) | 1986-10-10 |
| FI71569C FI71569C (sv) | 1987-01-19 |
Family
ID=27575178
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI813745A FI71569C (sv) | 1980-11-24 | 1981-11-24 | Förfarande för polymerisering av 1- olefiner och vid förfarandet använ dbar katalysator. |
| FI813744A FI71568C (sv) | 1980-11-24 | 1981-11-24 | Förfarande för framställning av en intermetallförening vilken används som katalytisk ingrediens vid polymerisering av 1-olefiner allena ell er tillsammans med minst en kopolymeriserbar monomer. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI813744A FI71568C (sv) | 1980-11-24 | 1981-11-24 | Förfarande för framställning av en intermetallförening vilken används som katalytisk ingrediens vid polymerisering av 1-olefiner allena ell er tillsammans med minst en kopolymeriserbar monomer. |
Country Status (17)
| Country | Link |
|---|---|
| AT (2) | AT386214B (sv) |
| AU (2) | AU550723B2 (sv) |
| BR (2) | BR8107638A (sv) |
| DE (2) | DE3146524C2 (sv) |
| DK (2) | DK520381A (sv) |
| FI (2) | FI71569C (sv) |
| FR (2) | FR2494700B1 (sv) |
| GB (2) | GB2088862B (sv) |
| IN (2) | IN156133B (sv) |
| IT (1) | IT1139827B (sv) |
| MX (1) | MX6918E (sv) |
| NL (2) | NL189411C (sv) |
| NO (2) | NO160584C (sv) |
| NZ (2) | NZ199047A (sv) |
| SE (2) | SE461100B (sv) |
| TR (2) | TR21347A (sv) |
| YU (2) | YU275581A (sv) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4629714A (en) * | 1985-10-25 | 1986-12-16 | National Distillers And Chemical Corporation | Intermetallic compounds and catalytic use thereof |
| US6458910B1 (en) * | 1992-01-14 | 2002-10-01 | Exxonmobil Oil Corporation | High impact LLDPE films |
| US6043401A (en) * | 1992-05-26 | 2000-03-28 | Bp Amoco Corporation | Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture |
| US5688887A (en) * | 1992-05-26 | 1997-11-18 | Amoco Corporation | Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture |
| DE60037269T2 (de) * | 1999-06-30 | 2008-11-27 | Union Carbide Chemicals & Plastics Technology Corp., Danbury | Gemischte metal-alkoxid-verbindungen und aus diesen hergestellte polymerisationskatalysatoren |
| DE102006031960A1 (de) * | 2006-07-11 | 2008-01-17 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Polymeren aus 3-Methylbut-1-en |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1020055B (it) * | 1973-09-08 | 1977-12-20 | Solvay | Polimerizzazione a bassa pressio ne di olefine |
| DE2906639C2 (de) * | 1979-02-21 | 1982-03-25 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von weitgehend amorphen Ho mo- und/oder Copolymerisaten von α-Olefinen mit 3-3 2 Kohlenstoffatomen |
| IT1113421B (it) * | 1979-03-07 | 1986-01-20 | Anic Spa | Metodo per la riduzione di alcossidi metallici e impiego dei composti cosi' ottenuti |
-
1981
- 1981-11-23 IT IT25230/81A patent/IT1139827B/it active
- 1981-11-24 NZ NZ199047A patent/NZ199047A/en unknown
- 1981-11-24 SE SE8106988A patent/SE461100B/sv not_active IP Right Cessation
- 1981-11-24 DK DK520381A patent/DK520381A/da not_active Application Discontinuation
- 1981-11-24 AU AU77815/81A patent/AU550723B2/en not_active Ceased
- 1981-11-24 NZ NZ199048A patent/NZ199048A/en unknown
- 1981-11-24 DK DK520481A patent/DK520481A/da not_active Application Discontinuation
- 1981-11-24 DE DE3146524A patent/DE3146524C2/de not_active Expired - Fee Related
- 1981-11-24 GB GB8135364A patent/GB2088862B/en not_active Expired
- 1981-11-24 FR FR8122000A patent/FR2494700B1/fr not_active Expired
- 1981-11-24 TR TR21347A patent/TR21347A/xx unknown
- 1981-11-24 IN IN1317/CAL/81A patent/IN156133B/en unknown
- 1981-11-24 AU AU77816/81A patent/AU551320B2/en not_active Ceased
- 1981-11-24 YU YU02755/81A patent/YU275581A/xx unknown
- 1981-11-24 DE DE3146568A patent/DE3146568C2/de not_active Expired - Fee Related
- 1981-11-24 AT AT0506081A patent/AT386214B/de not_active IP Right Cessation
- 1981-11-24 TR TR22074A patent/TR22074A/xx unknown
- 1981-11-24 FR FR8121999A patent/FR2494694B1/fr not_active Expired
- 1981-11-24 NL NLAANVRAGE8105319,A patent/NL189411C/xx not_active IP Right Cessation
- 1981-11-24 FI FI813745A patent/FI71569C/sv not_active IP Right Cessation
- 1981-11-24 YU YU02754/81A patent/YU275481A/xx unknown
- 1981-11-24 FI FI813744A patent/FI71568C/sv not_active IP Right Cessation
- 1981-11-24 BR BR8107638A patent/BR8107638A/pt not_active IP Right Cessation
- 1981-11-24 IN IN1316/CAL/81A patent/IN156404B/en unknown
- 1981-11-24 BR BR8107639A patent/BR8107639A/pt not_active IP Right Cessation
- 1981-11-24 AT AT0505981A patent/AT386212B/de not_active IP Right Cessation
- 1981-11-24 NO NO813991A patent/NO160584C/no unknown
- 1981-11-24 SE SE8106989A patent/SE451587B/sv not_active IP Right Cessation
- 1981-11-24 NO NO813992A patent/NO160583C/no unknown
- 1981-11-24 GB GB8135365A patent/GB2087907B/en not_active Expired
- 1981-11-24 MX MX819778U patent/MX6918E/es unknown
- 1981-11-24 NL NLAANVRAGE8105318,A patent/NL188652C/xx not_active IP Right Cessation
Also Published As
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Legal Events
| Date | Code | Title | Description |
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| MM | Patent lapsed | ||
| MM | Patent lapsed |
Owner name: NATIONAL DISTELLERS AND CHEMICAL |