GB2087907B - Olefin polymerisation process and catalyst - Google Patents

Olefin polymerisation process and catalyst

Info

Publication number
GB2087907B
GB2087907B GB8135365A GB8135365A GB2087907B GB 2087907 B GB2087907 B GB 2087907B GB 8135365 A GB8135365 A GB 8135365A GB 8135365 A GB8135365 A GB 8135365A GB 2087907 B GB2087907 B GB 2087907B
Authority
GB
United Kingdom
Prior art keywords
transition metal
catalyst
polymerisation process
olefin polymerisation
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8135365A
Other versions
GB2087907A (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Millennium Petrochemicals Inc
Original Assignee
National Destillers and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Destillers and Chemical Corp filed Critical National Destillers and Chemical Corp
Publication of GB2087907A publication Critical patent/GB2087907A/en
Application granted granted Critical
Publication of GB2087907B publication Critical patent/GB2087907B/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00Compounds of zirconium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • EFIXED CONSTRUCTIONS
    • E03WATER SUPPLY; SEWERAGE
    • E03FSEWERS; CESSPOOLS
    • E03F5/00Sewerage structures
    • E03F5/04Gullies inlets, road sinks, floor drains with or without odour seals or sediment traps
    • E03F5/041Accessories therefor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16HGEARING
    • F16H25/00Gearings comprising primarily only cams, cam-followers and screw-and-nut mechanisms
    • F16H25/18Gearings comprising primarily only cams, cam-followers and screw-and-nut mechanisms for conveying or interconverting oscillating or reciprocating motions
    • F16H25/20Screw mechanisms
    • F16H25/2015Means specially adapted for stopping actuators in the end position; Position sensing means

Abstract

A 1-olefin is polymerised or copolymerised using a catalyst system comprising a mixture of cocatalysts, one of which is a halide activated intermetallic compd. comprising the reaction product of a polymeric transition metal oxide alkoxide a reducing metal of higher oxidation potential than the transition metal. Low density polyethylene for blown or cast film, wire and cable coating, coextrusion and injection or rotational moulding is produced having a broader molecular wt. distribution and higher melt index.
GB8135365A 1980-11-24 1981-11-24 Olefin polymerisation process and catalyst Expired GB2087907B (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US20922580A 1980-11-24 1980-11-24
US20922480A 1980-11-24 1980-11-24
US20922380A 1980-11-24 1980-11-24
US20922780A 1980-11-24 1980-11-24
US20922980A 1980-11-24 1980-11-24
US20922680A 1980-11-24 1980-11-24
US20922880A 1980-11-24 1980-11-24
US22883181A 1981-01-27 1981-01-27

Publications (2)

Publication Number Publication Date
GB2087907A GB2087907A (en) 1982-06-03
GB2087907B true GB2087907B (en) 1985-05-09

Family

ID=27575178

Family Applications (2)

Application Number Title Priority Date Filing Date
GB8135364A Expired GB2088862B (en) 1980-11-24 1981-11-24 Intermetallic compounds and their production
GB8135365A Expired GB2087907B (en) 1980-11-24 1981-11-24 Olefin polymerisation process and catalyst

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB8135364A Expired GB2088862B (en) 1980-11-24 1981-11-24 Intermetallic compounds and their production

Country Status (17)

Country Link
AT (2) AT386214B (en)
AU (2) AU550723B2 (en)
BR (2) BR8107639A (en)
DE (2) DE3146524C2 (en)
DK (2) DK520381A (en)
FI (2) FI71569C (en)
FR (2) FR2494694B1 (en)
GB (2) GB2088862B (en)
IN (2) IN156133B (en)
IT (1) IT1139827B (en)
MX (1) MX6918E (en)
NL (2) NL189411C (en)
NO (2) NO160584C (en)
NZ (2) NZ199047A (en)
SE (2) SE451587B (en)
TR (2) TR22074A (en)
YU (2) YU275481A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4629714A (en) * 1985-10-25 1986-12-16 National Distillers And Chemical Corporation Intermetallic compounds and catalytic use thereof
US6458910B1 (en) * 1992-01-14 2002-10-01 Exxonmobil Oil Corporation High impact LLDPE films
US6043401A (en) * 1992-05-26 2000-03-28 Bp Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
US5688887A (en) * 1992-05-26 1997-11-18 Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
CN1238359C (en) * 1999-06-30 2006-01-25 联合碳化物化学和塑料技术公司 Mixed metal alkoxide complexes and polymerization catalysts made therefrom
DE102006031960A1 (en) 2006-07-11 2008-01-17 Oxeno Olefinchemie Gmbh Process for the preparation of polymers of 3-methylbut-1-ene

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1020055B (en) * 1973-09-08 1977-12-20 Solvay LOW PRESSURE POLYMERIZATION OF OLEFINS
DE2906639C2 (en) * 1979-02-21 1982-03-25 Chemische Werke Hüls AG, 4370 Marl Process for the production of largely amorphous homo- and / or copolymers of α-olefins having 3-3 2 carbon atoms
IT1113421B (en) * 1979-03-07 1986-01-20 Anic Spa METHOD FOR THE REDUCTION OF METALLIC ALCOXIDS AND USE OF THE COMPOUNDS SO OBTAINED

Also Published As

Publication number Publication date
FR2494700B1 (en) 1987-06-19
BR8107638A (en) 1982-08-24
NO813991L (en) 1982-05-25
ATA505981A (en) 1987-12-15
GB2088862B (en) 1985-03-20
BR8107639A (en) 1982-08-24
NL8105319A (en) 1982-06-16
AU7781581A (en) 1982-06-03
IN156404B (en) 1985-07-20
FI71568B (en) 1986-10-10
DK520481A (en) 1982-05-25
SE451587B (en) 1987-10-19
NL189411C (en) 1993-04-01
NO160584C (en) 1989-05-03
TR22074A (en) 1986-04-18
FI813744L (en) 1982-05-25
FI71569C (en) 1987-01-19
YU275481A (en) 1983-10-31
DE3146524A1 (en) 1982-06-24
SE8106988L (en) 1982-05-25
FR2494694A1 (en) 1982-05-28
NO813992L (en) 1982-05-25
FI71569B (en) 1986-10-10
IN156133B (en) 1985-05-18
DE3146568A1 (en) 1982-07-08
MX6918E (en) 1986-11-11
AU7781681A (en) 1982-06-03
FI813745L (en) 1982-05-25
TR21347A (en) 1984-04-18
DK520381A (en) 1982-05-25
SE8106989L (en) 1982-05-25
NZ199047A (en) 1984-12-14
DE3146524C2 (en) 1994-09-22
GB2088862A (en) 1982-06-16
NZ199048A (en) 1985-01-31
AU550723B2 (en) 1986-04-10
SE461100B (en) 1990-01-08
FR2494700A1 (en) 1982-05-28
GB2087907A (en) 1982-06-03
ATA506081A (en) 1987-12-15
IT1139827B (en) 1986-09-24
NO160583B (en) 1989-01-23
YU275581A (en) 1983-12-31
DE3146568C2 (en) 1994-12-08
NL189411B (en) 1992-11-02
NO160584B (en) 1989-01-23
AT386214B (en) 1988-07-25
NL8105318A (en) 1982-06-16
FR2494694B1 (en) 1986-12-19
AU551320B2 (en) 1986-04-24
AT386212B (en) 1988-07-25
NL188652C (en) 1992-08-17
FI71568C (en) 1987-01-19
NO160583C (en) 1989-05-03
IT8125230A0 (en) 1981-11-23

Similar Documents

Publication Publication Date Title
MY108973A (en) Polyethylene copolymer and polymerization process
HUT74314A (en) Components and catalysts for the polymerization of olefins, process for polymerizing olefins thereby, the produced polymers and products
AU2194683A (en) Extruding, thermoforming and injection moulding olefin/ styrene/butadiene polymer alloy
DE69633569D1 (en) TRANSITION METAL COMPLEX CONTAINING POLYMERIZATION CATALYST AND METHOD FOR PRODUCING OLEFIN POLYMERS
PL338979A1 (en) Polymerisation of olefins
ZA87519B (en) Catalyst composition for polymerizing alpha-olefins
DE69429771D1 (en) Process for olefin polymerization using a Ziegler-Natta catalyst
HUT69750A (en) Chromium catalyst compositions and process of polymerizing of olefin
GB2087907B (en) Olefin polymerisation process and catalyst
ATE168700T1 (en) CHROME-BASED ALPHA-OLEFIN POLYMERIZATION CATALYSTS CONTAINING CYCLOPENTADIENYL GROUP AND METHOD FOR POLYMERIZING ALPHA-OLEFINS
AU521746B2 (en) Anionic polymerization catalyst
ES8206590A1 (en) Process of making products consisting of foamed and/or cross-linked synthetic polymers.
IT1139828B (en) Olefin polymerisation catalyst contg. halide activated cpd.
FR2442261A1 (en) TWO-LAYER COMPLEX, ESPECIALLY FOR CLOSING PLASTIC PACKAGING
FR2676063B1 (en) PHOSPHONITRILE HALIDE CATALYST, PROCESS FOR THE PREPARATION THEREOF, COMPOSITION CONTAINING THE SAME AND USE THEREOF FOR THE POLYMERIZATION OF ORGANOSILOXANES.
EP0210498A3 (en) Process for the polymerization of acetylene in the presence of polymers, and polymer products containing polyacetylene
AU600440B2 (en) Novel vanadium containing polymerization catalyst and method for producing relatively narrow molecular weight distribution olefin polymers
GB2090157B (en) Phosphated alumina or aluminum phosphate chromium-containing olefin polymerisation catalyst process for the preparation and use thereof
DE69333963D1 (en) Ethylene-olefin copolymers, process for their preparation with catalyst
JPS57159806A (en) Polymerization of olefin
PL291092A1 (en) Method of preventing formation of polymer precipitate, agent therefor and polymerization reactor
AU535396B2 (en) Catalytic polymerisation process
JPS57198708A (en) Catalyst for polyolefin production
EP0172021A3 (en) Polymerization catalyst
GB2121065B (en) Polymers of ethylenic monomers containing sulphonyl and carboxylic ester groups, and filaments, fibres and films produced from them

Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19951124