FI60020C - Som herbicid anvaendbart 2-karboxietyl-n-fosfonometylglycinat och dess salter - Google Patents
Som herbicid anvaendbart 2-karboxietyl-n-fosfonometylglycinat och dess salter Download PDFInfo
- Publication number
- FI60020C FI60020C FI3227/74A FI322774A FI60020C FI 60020 C FI60020 C FI 60020C FI 3227/74 A FI3227/74 A FI 3227/74A FI 322774 A FI322774 A FI 322774A FI 60020 C FI60020 C FI 60020C
- Authority
- FI
- Finland
- Prior art keywords
- phosphonomethylglycinate
- carboxythyl
- anvaendbart
- herbicid
- som
- Prior art date
Links
- 230000002363 herbicidal effect Effects 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- VLTQCAKAICGHKR-UHFFFAOYSA-N 3-[2-(phosphonomethylamino)acetyl]oxypropanoic acid Chemical compound C(=O)(O)CCOC(CNCP(=O)(O)O)=O VLTQCAKAICGHKR-UHFFFAOYSA-N 0.000 claims description 9
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 7
- 239000004009 herbicide Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- JJWLVOIRVHMVIS-UHFFFAOYSA-O isopropylaminium Chemical compound CC(C)[NH3+] JJWLVOIRVHMVIS-UHFFFAOYSA-O 0.000 claims description 3
- 229960000380 propiolactone Drugs 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 description 11
- 239000004480 active ingredient Substances 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 125000000143 2-carboxyethyl group Chemical group [H]OC(=O)C([H])([H])C([H])([H])* 0.000 description 3
- 244000062793 Sorghum vulgare Species 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 235000019713 millet Nutrition 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 description 2
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 240000008620 Fagopyrum esculentum Species 0.000 description 2
- 235000009419 Fagopyrum esculentum Nutrition 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 235000021536 Sugar beet Nutrition 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 239000000546 pharmaceutical excipient Substances 0.000 description 2
- -1 propiolactone Chemical class 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 description 1
- 101100246550 Caenorhabditis elegans pyr-1 gene Proteins 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- FKLJPTJMIBLJAV-UHFFFAOYSA-N Compound IV Chemical compound O1N=C(C)C=C1CCCCCCCOC1=CC=C(C=2OCCN=2)C=C1 FKLJPTJMIBLJAV-UHFFFAOYSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 244000248416 Fagopyrum cymosum Species 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 244000278243 Limnocharis flava Species 0.000 description 1
- 235000003403 Limnocharis flava Nutrition 0.000 description 1
- 241000533293 Sesbania emerus Species 0.000 description 1
- 240000006394 Sorghum bicolor Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- 239000005862 Whey Substances 0.000 description 1
- 102000007544 Whey Proteins Human genes 0.000 description 1
- 108010046377 Whey Proteins Proteins 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 210000000941 bile Anatomy 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- RMBGSBIZBRZJPK-UHFFFAOYSA-N butan-1-amine;2-dodecylbenzenesulfonic acid Chemical compound CCCCN.CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O RMBGSBIZBRZJPK-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- SIQGBUJXKSJZAV-UHFFFAOYSA-L disodium;2-(phosphonomethylamino)acetate Chemical compound [Na+].[Na+].OP(O)(=O)CNCC([O-])=O.OP(O)(=O)CNCC([O-])=O SIQGBUJXKSJZAV-UHFFFAOYSA-L 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- BPGBAEXPBQHBSV-UHFFFAOYSA-N pyr1 Chemical compound C1=C2C3=C(C)C(C(NC=C4)=O)=C4C(C)=C3NC2=CC=C1OC(=O)C1=CC=CC=C1 BPGBAEXPBQHBSV-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 244000045561 useful plants Species 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cosmetics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41785873 | 1973-11-21 | ||
| US417858A US3868407A (en) | 1973-11-21 | 1973-11-21 | Carboxyalkyl esters of n-phosphonomethyl glycine |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI322774A FI322774A (xx) | 1975-05-22 |
| FI60020B FI60020B (fi) | 1981-07-31 |
| FI60020C true FI60020C (fi) | 1981-11-10 |
Family
ID=23655654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI3227/74A FI60020C (fi) | 1973-11-21 | 1974-11-05 | Som herbicid anvaendbart 2-karboxietyl-n-fosfonometylglycinat och dess salter |
Country Status (31)
| Country | Link |
|---|---|
| US (1) | US3868407A (xx) |
| JP (1) | JPS5242854B2 (xx) |
| AR (1) | AR219688A1 (xx) |
| AT (1) | AT341267B (xx) |
| BE (1) | BE821879A (xx) |
| BG (1) | BG26183A3 (xx) |
| BR (1) | BR7409238A (xx) |
| CA (1) | CA1048053A (xx) |
| CH (1) | CH593013A5 (xx) |
| CS (1) | CS178935B2 (xx) |
| DD (2) | DD121596A5 (xx) |
| DE (1) | DE2452460C3 (xx) |
| DK (1) | DK139360B (xx) |
| EG (1) | EG11241A (xx) |
| ES (1) | ES431614A1 (xx) |
| FI (1) | FI60020C (xx) |
| FR (1) | FR2251569B1 (xx) |
| GB (1) | GB1440847A (xx) |
| HU (1) | HU171312B (xx) |
| IL (1) | IL45989A (xx) |
| IN (1) | IN140421B (xx) |
| IT (1) | IT1049325B (xx) |
| NL (1) | NL172065C (xx) |
| NO (1) | NO143747C (xx) |
| PH (1) | PH10683A (xx) |
| PL (2) | PL93298B1 (xx) |
| RO (1) | RO72710A (xx) |
| SE (1) | SE421625B (xx) |
| SU (1) | SU682097A3 (xx) |
| YU (1) | YU40107B (xx) |
| ZA (1) | ZA747107B (xx) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3988142A (en) * | 1972-02-03 | 1976-10-26 | Monsanto Company | Increasing carbohydrate deposition in plants with N-phosphono-methylglycine and derivatives thereof |
| US3948975A (en) * | 1974-08-05 | 1976-04-06 | Monsanto Company | Hydroxyalkyl esters of N-phosphonomethyl glycine |
| US4197254A (en) * | 1976-05-03 | 1980-04-08 | Monsanto Company | Derivatives of N-phosphonomethylglycine |
| US4159901A (en) * | 1977-05-16 | 1979-07-03 | Monsanto Company | Corrosion inhibited agricultural compositions |
| JPS5839127B2 (ja) * | 1978-03-09 | 1983-08-27 | 明治製菓株式会社 | 除草剤組成物 |
| US4226610A (en) * | 1978-04-15 | 1980-10-07 | Meiji Selka Kaisha, Ltd. | Herbicidal compounds, preparation thereof and herbicides containing the same |
| WO1984003607A1 (en) * | 1983-03-16 | 1984-09-27 | Chevron Res | Glyphosate-type herbicidal compositions |
| ES534413A0 (es) * | 1983-07-27 | 1986-01-01 | Rhone Poulenc Agrochimie | Procedimiento de preparacion de sulfonamidas con grupo ansinometilfosfonico |
| JPS60185443U (ja) * | 1984-05-21 | 1985-12-09 | 温泉青果農業協同組合 | 収穫用鋏 |
| US5580841A (en) * | 1985-05-29 | 1996-12-03 | Zeneca Limited | Solid, phytoactive compositions and method for their preparation |
| US5468718A (en) * | 1985-10-21 | 1995-11-21 | Ici Americas Inc. | Liquid, phytoactive compositions and method for their preparation |
| US5047079A (en) * | 1986-08-18 | 1991-09-10 | Ici Americas Inc. | Method of preparation and use of solid, phytoactive compositions |
| FR2635522B1 (fr) * | 1988-08-18 | 1990-11-16 | Rhone Poulenc Agrochimie | N-sulfonomethylglycinate procede de preparation, utilisation dans la preparation d'herbicides de type glyphosate |
| US5187292A (en) * | 1988-08-18 | 1993-02-16 | Rhone-Poulenc Agrochimie | N-sulfomethylglycinate, use in the preparation of herbicides of the glyphosate type |
| US6930075B1 (en) | 1990-11-02 | 2005-08-16 | Monsanto Technology, Llc | Fatty acid-based herbicidal composition |
| IL101539A (en) | 1991-04-16 | 1998-09-24 | Monsanto Europe Sa | Mono-ammonium salts of the history of N phosphonomethyl glycyl which are not hygroscopes, their preparations and pesticides containing |
| HU212802B (en) | 1991-07-19 | 1996-11-28 | Monsanto Europe Sa | Phytoactive sack-like composition containing glyphosate-izopropylamine salt |
| AU1790697A (en) * | 1996-02-28 | 1997-09-16 | Bayer Aktiengesellschaft | Use of n-phosphonomethylglycine esters in aqueous solution as herbicides, and new n-phosphonomethylglycine esters |
| ITTO980048A1 (it) * | 1998-01-20 | 1999-07-20 | Ipici Spa | Composizioni erbicide, procedimenti per la loro preparazione ed impieghi |
| US6921834B2 (en) | 2002-05-22 | 2005-07-26 | Dow Agrosciences Llc | Continuous process for preparing N-phosphonomethyl glycine |
| AR037559A1 (es) * | 2002-11-19 | 2004-11-17 | Atanor S A | Una formulacion herbicida solida de n-fosfonometilglicina, bajo la forma de polvo, granulos o escamas, soluble o dispersable en agua, y el procedimiento para preparar dicha composicion |
| US8470741B2 (en) * | 2003-05-07 | 2013-06-25 | Croda Americas Llc | Homogeneous liquid saccharide and oil systems |
| ATE542425T1 (de) * | 2004-09-17 | 2012-02-15 | Monsanto Technology Llc | Glyphosate-formulierungen mit früh auftretenden verbrennungssymptomen |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3799758A (en) * | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
-
1973
- 1973-11-21 US US417858A patent/US3868407A/en not_active Expired - Lifetime
-
1974
- 1974-11-04 ES ES431614A patent/ES431614A1/es not_active Expired
- 1974-11-04 NL NLAANVRAGE7414338,A patent/NL172065C/xx not_active IP Right Cessation
- 1974-11-04 SU SU742076318A patent/SU682097A3/ru active
- 1974-11-04 IL IL45989A patent/IL45989A/en unknown
- 1974-11-05 FI FI3227/74A patent/FI60020C/fi active
- 1974-11-05 BG BG7428118A patent/BG26183A3/xx unknown
- 1974-11-05 PL PL1974187852A patent/PL93298B1/pl unknown
- 1974-11-05 CA CA212,996A patent/CA1048053A/en not_active Expired
- 1974-11-05 DD DD189587A patent/DD121596A5/xx unknown
- 1974-11-05 RO RO7480433A patent/RO72710A/ro unknown
- 1974-11-05 JP JP49126653A patent/JPS5242854B2/ja not_active Expired
- 1974-11-05 FR FR7436746A patent/FR2251569B1/fr not_active Expired
- 1974-11-05 IT IT29129/74A patent/IT1049325B/it active
- 1974-11-05 HU HU74MO00000919A patent/HU171312B/hu unknown
- 1974-11-05 IN IN2419/CAL/1974A patent/IN140421B/en unknown
- 1974-11-05 BR BR9238/74A patent/BR7409238A/pt unknown
- 1974-11-05 DK DK575274AA patent/DK139360B/da not_active IP Right Cessation
- 1974-11-05 PL PL1974175344A patent/PL92403B1/pl unknown
- 1974-11-05 DE DE2452460A patent/DE2452460C3/de not_active Expired
- 1974-11-05 YU YU2949/74A patent/YU40107B/xx unknown
- 1974-11-05 DD DD182166A patent/DD115686A5/xx unknown
- 1974-11-05 ZA ZA00747107A patent/ZA747107B/xx unknown
- 1974-11-05 SE SE7413853A patent/SE421625B/xx not_active IP Right Cessation
- 1974-11-05 CH CH1476974A patent/CH593013A5/xx not_active IP Right Cessation
- 1974-11-05 NO NO743973A patent/NO143747C/no unknown
- 1974-11-05 GB GB4783174A patent/GB1440847A/en not_active Expired
- 1974-11-05 AR AR256392A patent/AR219688A1/es active
- 1974-11-05 CS CS7400007541A patent/CS178935B2/cs unknown
- 1974-11-05 BE BE150233A patent/BE821879A/xx not_active IP Right Cessation
- 1974-11-05 AT AT884674A patent/AT341267B/de not_active IP Right Cessation
- 1974-11-08 PH PH16494A patent/PH10683A/en unknown
- 1974-11-20 EG EG515/74A patent/EG11241A/xx active
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