FI57118C - Sampolymerer av akrylsyra vilka aer anvaendbara saosom komplexbildare och/eller sekvestreringsaemne foer flervaerda metalljoner och foerfarande foer deras framstaellning - Google Patents
Sampolymerer av akrylsyra vilka aer anvaendbara saosom komplexbildare och/eller sekvestreringsaemne foer flervaerda metalljoner och foerfarande foer deras framstaellning Download PDFInfo
- Publication number
- FI57118C FI57118C FI1553/74A FI155374A FI57118C FI 57118 C FI57118 C FI 57118C FI 1553/74 A FI1553/74 A FI 1553/74A FI 155374 A FI155374 A FI 155374A FI 57118 C FI57118 C FI 57118C
- Authority
- FI
- Finland
- Prior art keywords
- och
- acrylic acid
- polymer
- acid
- solution
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title description 4
- 239000002184 metal Substances 0.000 title description 4
- 229920001577 copolymer Polymers 0.000 claims description 35
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 28
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 28
- 229920000642 polymer Polymers 0.000 claims description 22
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 150000003863 ammonium salts Chemical class 0.000 claims description 11
- 230000007062 hydrolysis Effects 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 229910021645 metal ion Inorganic materials 0.000 claims description 8
- 239000003352 sequestering agent Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 239000008139 complexing agent Substances 0.000 claims description 5
- 230000000536 complexating effect Effects 0.000 claims description 4
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 16
- 239000002253 acid Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 9
- 101100399296 Mus musculus Lime1 gene Proteins 0.000 description 9
- 235000011941 Tilia x europaea Nutrition 0.000 description 9
- 239000000460 chlorine Substances 0.000 description 9
- 229910052801 chlorine Inorganic materials 0.000 description 9
- 239000004571 lime Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 8
- 150000001447 alkali salts Chemical class 0.000 description 8
- 239000004342 Benzoyl peroxide Substances 0.000 description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 description 7
- 238000009835 boiling Methods 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 229910001424 calcium ion Inorganic materials 0.000 description 5
- 239000004584 polyacrylic acid Substances 0.000 description 5
- 230000009919 sequestration Effects 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 4
- SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical compound OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- RIZUCYSQUWMQLX-UHFFFAOYSA-N 2,3-dimethylbenzoic acid Chemical compound CC1=CC=CC(C(O)=O)=C1C RIZUCYSQUWMQLX-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000010836 blood and blood product Substances 0.000 description 1
- 229940125691 blood product Drugs 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229940070721 polyacrylate Drugs 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000013558 reference substance Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960001790 sodium citrate Drugs 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/12—Hydrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2327097 | 1973-05-28 | ||
| DE19732327097 DE2327097B2 (de) | 1973-05-28 | 1973-05-28 | Copolymerisate der acrylsaeure, bzw. ihre alkali- oder ammoniumsalze |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI155374A FI155374A (fr) | 1974-11-29 |
| FI57118B FI57118B (fi) | 1980-02-29 |
| FI57118C true FI57118C (fi) | 1980-06-10 |
Family
ID=5882341
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI1553/74A FI57118C (fi) | 1973-05-28 | 1974-05-21 | Sampolymerer av akrylsyra vilka aer anvaendbara saosom komplexbildare och/eller sekvestreringsaemne foer flervaerda metalljoner och foerfarande foer deras framstaellning |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US3890291A (fr) |
| JP (1) | JPS5749561B2 (fr) |
| AT (1) | AT329268B (fr) |
| BE (1) | BE815558A (fr) |
| CA (1) | CA1017491A (fr) |
| CH (1) | CH596243A5 (fr) |
| DD (1) | DD111916A5 (fr) |
| DE (1) | DE2327097B2 (fr) |
| DK (1) | DK286974A (fr) |
| FI (1) | FI57118C (fr) |
| FR (1) | FR2231686B1 (fr) |
| GB (1) | GB1444864A (fr) |
| IT (1) | IT1013227B (fr) |
| NL (1) | NL7406528A (fr) |
| SE (1) | SE402781B (fr) |
| SU (1) | SU534186A3 (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE793422A (fr) * | 1971-12-28 | 1973-06-28 | Knapsack Ag | Oligomeres et/ou polymeres contenant des groupes hydroxyliques et carboxyliques et leur procede de preparation |
| US4031022A (en) * | 1973-05-28 | 1977-06-21 | Hoechst Aktiengesellschaft | Builders for detergent and cleaning compositions |
| US4107411A (en) * | 1973-07-18 | 1978-08-15 | Solvay & Cie. | Method of preparing salts of poly-alpha-hydroxyacrylic acid |
| LU71867A1 (fr) * | 1975-02-17 | 1977-01-05 | ||
| JPH0651754B2 (ja) * | 1987-06-17 | 1994-07-06 | 日本パ−オキサイド株式会社 | ポリ−α−ヒドロキシアクリル酸あるいはその塩の水溶液の製造方法 |
| GB8928320D0 (en) * | 1989-12-14 | 1990-02-21 | Unilever Plc | Polymers and detergent compositions containing them |
| MX9204788A (es) * | 1991-08-22 | 1993-04-01 | Sandoz Ag | Proceso para la produccion de curtido o recurtido mineral de cuero o piel |
| JPH108092A (ja) * | 1996-06-21 | 1998-01-13 | Mitsubishi Paper Mills Ltd | 過酸化物漂白用安定化剤及びそれを用いた繊維系物質の漂白方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2754291A (en) * | 1951-08-09 | 1956-07-10 | Maxwell A Pollack | Polyamino acids |
| DE1795312C3 (de) * | 1968-09-11 | 1980-08-14 | Basf Ag, 6700 Ludwigshafen | Hydroxylgruppen enthaltende Copolymerisate |
-
1973
- 1973-05-28 DE DE19732327097 patent/DE2327097B2/de not_active Withdrawn
-
1974
- 1974-04-29 SE SE7405747A patent/SE402781B/xx unknown
- 1974-05-15 NL NL7406528A patent/NL7406528A/xx not_active Application Discontinuation
- 1974-05-21 FI FI1553/74A patent/FI57118C/fi active
- 1974-05-22 US US472277A patent/US3890291A/en not_active Expired - Lifetime
- 1974-05-24 CA CA200,768A patent/CA1017491A/fr not_active Expired
- 1974-05-24 GB GB2332774A patent/GB1444864A/en not_active Expired
- 1974-05-24 IT IT51190/74A patent/IT1013227B/it active
- 1974-05-24 JP JP49058661A patent/JPS5749561B2/ja not_active Expired
- 1974-05-27 CH CH718574A patent/CH596243A5/xx not_active IP Right Cessation
- 1974-05-27 AT AT434074A patent/AT329268B/de not_active IP Right Cessation
- 1974-05-27 DD DD178783A patent/DD111916A5/xx unknown
- 1974-05-27 DK DK286974A patent/DK286974A/da unknown
- 1974-05-27 BE BE144767A patent/BE815558A/fr not_active IP Right Cessation
- 1974-05-28 FR FR7418476A patent/FR2231686B1/fr not_active Expired
- 1974-05-28 SU SU2029565A patent/SU534186A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| GB1444864A (en) | 1976-08-04 |
| CA1017491A (fr) | 1977-09-13 |
| FR2231686A1 (fr) | 1974-12-27 |
| DK286974A (fr) | 1975-01-20 |
| FI155374A (fr) | 1974-11-29 |
| BE815558A (fr) | 1974-09-16 |
| JPS5027887A (fr) | 1975-03-22 |
| FI57118B (fi) | 1980-02-29 |
| DE2327097B2 (de) | 1976-09-02 |
| AT329268B (de) | 1976-05-10 |
| IT1013227B (it) | 1977-03-30 |
| NL7406528A (fr) | 1974-12-02 |
| ATA434074A (de) | 1975-07-15 |
| SE402781B (sv) | 1978-07-17 |
| FR2231686B1 (fr) | 1977-10-14 |
| DE2327097A1 (de) | 1974-12-19 |
| US3890291A (en) | 1975-06-17 |
| CH596243A5 (fr) | 1978-03-15 |
| JPS5749561B2 (fr) | 1982-10-22 |
| SU534186A3 (ru) | 1976-10-30 |
| DD111916A5 (fr) | 1975-03-12 |
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