FI112204B - Menetelmä cesiumsuolojen valmistamiseksi aluminiumcesiumsulfaatista - Google Patents
Menetelmä cesiumsuolojen valmistamiseksi aluminiumcesiumsulfaatista Download PDFInfo
- Publication number
- FI112204B FI112204B FI955049A FI955049A FI112204B FI 112204 B FI112204 B FI 112204B FI 955049 A FI955049 A FI 955049A FI 955049 A FI955049 A FI 955049A FI 112204 B FI112204 B FI 112204B
- Authority
- FI
- Finland
- Prior art keywords
- cesium
- aluminum
- preparation
- amount
- calcium
- Prior art date
Links
- YRAMACNQEYDINL-UHFFFAOYSA-J aluminum;cesium;disulfate Chemical compound [Al+3].[Cs+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O YRAMACNQEYDINL-UHFFFAOYSA-J 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 159000000006 cesium salts Chemical class 0.000 title claims abstract description 7
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 9
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 7
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 7
- 159000000007 calcium salts Chemical class 0.000 claims abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
- 238000005119 centrifugation Methods 0.000 claims abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000006243 chemical reaction Methods 0.000 claims description 9
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 3
- 229940044172 calcium formate Drugs 0.000 claims description 3
- 239000004281 calcium formate Substances 0.000 claims description 3
- 235000019255 calcium formate Nutrition 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- -1 cesium halide Chemical class 0.000 description 5
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 4
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 3
- 229910001863 barium hydroxide Inorganic materials 0.000 description 3
- ATZQZZAXOPPAAQ-UHFFFAOYSA-M caesium formate Chemical compound [Cs+].[O-]C=O ATZQZZAXOPPAAQ-UHFFFAOYSA-M 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000001639 calcium acetate Substances 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000001553 barium compounds Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 150000001674 calcium compounds Chemical class 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D17/00—Rubidium, caesium or francium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Processing Of Solid Wastes (AREA)
- Inorganic Insulating Materials (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4313480 | 1993-04-24 | ||
DE4313480A DE4313480C1 (de) | 1993-04-24 | 1993-04-24 | Verfahren zur Herstellung von Cäsiumsalzen aus Cäsium-Aluminium-Alaun |
PCT/EP1994/001202 WO1994025422A1 (fr) | 1993-04-24 | 1994-04-19 | Procede de fabrication de sels de cesium a partir d'alun de cesium-aluminium |
EP9401202 | 1994-04-19 |
Publications (3)
Publication Number | Publication Date |
---|---|
FI955049A FI955049A (fi) | 1995-10-23 |
FI955049A0 FI955049A0 (fi) | 1995-10-23 |
FI112204B true FI112204B (fi) | 2003-11-14 |
Family
ID=6486296
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI955049A FI112204B (fi) | 1993-04-24 | 1995-10-23 | Menetelmä cesiumsuolojen valmistamiseksi aluminiumcesiumsulfaatista |
Country Status (22)
Country | Link |
---|---|
US (1) | US5605669A (fr) |
EP (1) | EP0695286B1 (fr) |
JP (1) | JP4079991B2 (fr) |
KR (1) | KR100303251B1 (fr) |
CN (1) | CN1055677C (fr) |
AT (1) | ATE161818T1 (fr) |
AU (1) | AU679528B2 (fr) |
BR (1) | BR9406214A (fr) |
CA (1) | CA2161245C (fr) |
CZ (1) | CZ287380B6 (fr) |
DE (2) | DE4313480C1 (fr) |
DK (1) | DK0695286T3 (fr) |
FI (1) | FI112204B (fr) |
HU (1) | HU214206B (fr) |
LV (1) | LV11540B (fr) |
NO (1) | NO303984B1 (fr) |
PL (1) | PL177619B1 (fr) |
RO (1) | RO113983B1 (fr) |
SK (1) | SK280404B6 (fr) |
WO (1) | WO1994025422A1 (fr) |
ZA (1) | ZA942813B (fr) |
ZW (1) | ZW4994A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SK285016B6 (sk) * | 1995-04-06 | 2006-04-06 | Cabot Corporation | Spôsob výroby céznej soli |
US6015535A (en) * | 1995-04-06 | 2000-01-18 | Cabot Corporation | Process for producing purified cesium compound from cesium alum |
US6652820B2 (en) | 2001-04-02 | 2003-11-25 | Cabot Corporation | Methods of making cesium salts and other alkali metal salts |
RU2408534C2 (ru) * | 2005-01-27 | 2011-01-10 | Шеметалл Гмбх | Способ получения растворов гидроксида цезия |
US7759273B2 (en) * | 2005-04-20 | 2010-07-20 | Cabot Corporation | Methods of forming an alkali metal salt |
CN110256232B (zh) * | 2019-06-28 | 2022-05-03 | 百杰瑞(荆门)新材料有限公司 | 一种甲酸铯生产方法 |
CN110172575B (zh) * | 2019-07-05 | 2021-03-05 | 新疆有色金属研究所 | 一种铯矾原料的处理方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2481455A (en) * | 1948-06-01 | 1949-09-06 | Dow Chemical Co | Cesium bromide separation |
GB949483A (en) * | 1961-05-25 | 1964-02-12 | Atomic Energy Authority Uk | Improvements in or relating to the recovery of caesium |
US3207571A (en) * | 1962-04-09 | 1965-09-21 | San Antonio Chemicals Inc | Process for preparing cesium compounds from cesium alum |
US3130010A (en) * | 1962-12-04 | 1964-04-21 | Dow Chemical Co | Process for production of high purity cesium metal and cesium compounds |
DE1253252B (de) * | 1963-03-01 | 1967-11-02 | Atomic Energy Commission | Verfahren zum Abtrennen von radioaktivem Caesium aus waessrigen Loesungen |
US3489509A (en) * | 1967-05-18 | 1970-01-13 | Kewanee Oil Co | Process for recovery of cesium compounds of high purity |
-
1993
- 1993-04-24 DE DE4313480A patent/DE4313480C1/de not_active Expired - Lifetime
-
1994
- 1994-04-19 WO PCT/EP1994/001202 patent/WO1994025422A1/fr active IP Right Grant
- 1994-04-19 AU AU66792/94A patent/AU679528B2/en not_active Expired
- 1994-04-19 ZW ZW4994A patent/ZW4994A1/xx unknown
- 1994-04-19 CA CA002161245A patent/CA2161245C/fr not_active Expired - Lifetime
- 1994-04-19 KR KR1019950704634A patent/KR100303251B1/ko not_active IP Right Cessation
- 1994-04-19 EP EP94914402A patent/EP0695286B1/fr not_active Expired - Lifetime
- 1994-04-19 HU HU9503041A patent/HU214206B/hu not_active IP Right Cessation
- 1994-04-19 RO RO95-01847A patent/RO113983B1/ro unknown
- 1994-04-19 DE DE59404963T patent/DE59404963D1/de not_active Expired - Lifetime
- 1994-04-19 BR BR9406214A patent/BR9406214A/pt not_active IP Right Cessation
- 1994-04-19 JP JP52382394A patent/JP4079991B2/ja not_active Expired - Lifetime
- 1994-04-19 AT AT94914402T patent/ATE161818T1/de not_active IP Right Cessation
- 1994-04-19 SK SK1311-95A patent/SK280404B6/sk unknown
- 1994-04-19 CN CN94191890A patent/CN1055677C/zh not_active Expired - Lifetime
- 1994-04-19 PL PL94311231A patent/PL177619B1/pl unknown
- 1994-04-19 DK DK94914402.6T patent/DK0695286T3/da active
- 1994-04-19 CZ CZ19952737A patent/CZ287380B6/cs not_active IP Right Cessation
- 1994-04-19 US US08/537,927 patent/US5605669A/en not_active Expired - Lifetime
- 1994-04-22 ZA ZA942813A patent/ZA942813B/xx unknown
-
1995
- 1995-10-17 NO NO954134A patent/NO303984B1/no not_active IP Right Cessation
- 1995-10-23 FI FI955049A patent/FI112204B/fi not_active IP Right Cessation
- 1995-10-24 LV LVP-95-321A patent/LV11540B/lv unknown
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
FI112204B (fi) | Menetelmä cesiumsuolojen valmistamiseksi aluminiumcesiumsulfaatista | |
US5182094A (en) | Process for the preparation of polyaluminum compounds | |
EP0069961B1 (fr) | Chaux éteinte, procédé pour la préparer et utilisation de celle-ci | |
NO140897B (no) | Fremgangsmaate for kontinuerlig farvning av aromatiske polyester/cellulosetekstilblandinger | |
ES2399913T3 (es) | Método para la producción de 2,4,6-trimercapto-1,3,5-triazina | |
US5099049A (en) | Chelate compositions and their production | |
US5258168A (en) | Production of alunites | |
JP3532500B2 (ja) | 船底塗料用防汚剤およびそれに用いる高純度銅ピリチオンの製造方法 | |
CA1272464A (fr) | Methode d'extraction du gallium de rebuts qui le renferment | |
US3347863A (en) | Process for basic aluminum salt of pyridinethione | |
US4670594A (en) | Continuous process for the preparation of dimethyldiallylammonium chloride | |
EP0055707A1 (fr) | Preparation de carbonate de sodium dihydroxyaluminium. | |
CA2720885A1 (fr) | Procede de production du sel trisodique de la trimercapto-s-triazine 2,4,6 | |
CS276111B6 (en) | Process for separating barium from strontium salts being dissolved in water | |
JP3444876B2 (ja) | 塩基性次亜塩素酸マグネシウムの製造方法 | |
US4950819A (en) | Process for the preparation of alkali metal salts of phosphonic acid monoalkyl esters | |
JPS5921510A (ja) | リン酸一水素カルシウム二水化物の製法 | |
JPH04261189A (ja) | トリフルオロメタンスルホン酸スズの製造法 | |
JPS61286219A (ja) | ポリ塩化アルミニウムの製造方法 | |
US1881430A (en) | Process for the manufacture of solutions containing alpha compound of fluorine and aluminium | |
US5097030A (en) | Process for the preparation of 2-(methylthio)barbituric acid | |
US4166909A (en) | Process for preparation of a substituted triazine | |
RU2224763C2 (ru) | Способ получения бис (1-гидроксиэтан-1,1-дифосфоната(1-)) меди (II) | |
CA1126756A (fr) | Methode pour l'obtention de sels d'acide carboxymethyloxysuccinique | |
JP3263428B2 (ja) | グアニジン化合物のアルミン酸塩の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MA | Patent expired |