GB949483A - Improvements in or relating to the recovery of caesium - Google Patents
Improvements in or relating to the recovery of caesiumInfo
- Publication number
- GB949483A GB949483A GB1891061A GB1891061A GB949483A GB 949483 A GB949483 A GB 949483A GB 1891061 A GB1891061 A GB 1891061A GB 1891061 A GB1891061 A GB 1891061A GB 949483 A GB949483 A GB 949483A
- Authority
- GB
- United Kingdom
- Prior art keywords
- caesium
- solvent
- bromine
- polybromides
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D17/00—Rubidium, caesium or francium compounds
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/007—Recovery of isotopes from radioactive waste, e.g. fission products
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Caesium is separated from an aqueous solution by adding a bromide and bromine to the solution, thus forming caesium polybromides, contacting the solution with a water-immiscible solvent for caesium polybromides and removing the caesium from the solvent. The removal of caesium may be effected by first eliminating bromine from the solvent, when the caesium polybromides break down to monobromide which is insoluble in the solvent. The preferred method for the removal of bromine is by steam stripping as this introduces an aqueous phase in which the monobromide is soluble. The bromine is preferably added in the waterimmiscible solvent, e.g. nitrobenzene. To ensure that the solvent is always heavier than the aqueous phase it is convenient to add a dense inactive diluent, e.g. 12% carbon tetrabromide, 15% sym-tetrabromoethane or 15% bromoform.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1891061A GB949483A (en) | 1961-05-25 | 1961-05-25 | Improvements in or relating to the recovery of caesium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1891061A GB949483A (en) | 1961-05-25 | 1961-05-25 | Improvements in or relating to the recovery of caesium |
Publications (1)
Publication Number | Publication Date |
---|---|
GB949483A true GB949483A (en) | 1964-02-12 |
Family
ID=10120525
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1891061A Expired GB949483A (en) | 1961-05-25 | 1961-05-25 | Improvements in or relating to the recovery of caesium |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB949483A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5605669A (en) * | 1993-04-24 | 1997-02-25 | Metallgesellschaft Aktiengesellschaft | Process of preparing cesium salts from cesium aluminum alum |
US9991012B2 (en) | 2010-10-07 | 2018-06-05 | Mallinckrodt Nuclear Medicine Llc | Extraction process |
-
1961
- 1961-05-25 GB GB1891061A patent/GB949483A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5605669A (en) * | 1993-04-24 | 1997-02-25 | Metallgesellschaft Aktiengesellschaft | Process of preparing cesium salts from cesium aluminum alum |
US9991012B2 (en) | 2010-10-07 | 2018-06-05 | Mallinckrodt Nuclear Medicine Llc | Extraction process |
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