FI107809B - Förfarande för tillvaratagning av kobolt och volfram ur reaktionsvätskor samt för deras återanvändning - Google Patents
Förfarande för tillvaratagning av kobolt och volfram ur reaktionsvätskor samt för deras återanvändning Download PDFInfo
- Publication number
- FI107809B FI107809B FI950505A FI950505A FI107809B FI 107809 B FI107809 B FI 107809B FI 950505 A FI950505 A FI 950505A FI 950505 A FI950505 A FI 950505A FI 107809 B FI107809 B FI 107809B
- Authority
- FI
- Finland
- Prior art keywords
- tungsten
- cobalt
- hydroxide
- alkaline earth
- earth metal
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 68
- 229910052721 tungsten Inorganic materials 0.000 title claims abstract description 38
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000010937 tungsten Substances 0.000 title claims abstract description 37
- 239000010941 cobalt Substances 0.000 title claims abstract description 33
- 229910017052 cobalt Inorganic materials 0.000 title claims abstract description 33
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000011084 recovery Methods 0.000 title claims description 12
- 239000012295 chemical reaction liquid Substances 0.000 title claims description 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 19
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 14
- 239000011707 mineral Substances 0.000 claims abstract description 14
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 12
- 239000002244 precipitate Substances 0.000 claims abstract description 11
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 claims abstract description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 6
- 150000001868 cobalt Chemical class 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 9
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 9
- 239000000920 calcium hydroxide Substances 0.000 claims description 9
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 6
- 150000003658 tungsten compounds Chemical class 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 150000001341 alkaline earth metal compounds Chemical class 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 1
- 235000011613 Pinus brutia Nutrition 0.000 claims 1
- 241000018646 Pinus brutia Species 0.000 claims 1
- 230000000717 retained effect Effects 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 abstract description 27
- 229910003893 H2WO4 Inorganic materials 0.000 abstract 2
- 150000005325 alkali earth metal hydroxides Chemical class 0.000 abstract 1
- 239000012670 alkaline solution Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000012530 fluid Substances 0.000 description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 11
- 238000007248 oxidative elimination reaction Methods 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 6
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 6
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000003929 acidic solution Substances 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- -1 alkaline earth metal tungstate Chemical class 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- 229940011182 cobalt acetate Drugs 0.000 description 3
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000001639 calcium acetate Substances 0.000 description 2
- 235000011092 calcium acetate Nutrition 0.000 description 2
- 229960005147 calcium acetate Drugs 0.000 description 2
- XQKKWWCELHKGKB-UHFFFAOYSA-L calcium acetate monohydrate Chemical compound O.[Ca+2].CC([O-])=O.CC([O-])=O XQKKWWCELHKGKB-UHFFFAOYSA-L 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 150000003657 tungsten Chemical class 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- 238000004876 x-ray fluorescence Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910004829 CaWO4 Inorganic materials 0.000 description 1
- 101100494773 Caenorhabditis elegans ctl-2 gene Proteins 0.000 description 1
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 1
- 235000003115 Diospyros discolor Nutrition 0.000 description 1
- 240000000902 Diospyros discolor Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 101100112369 Fasciola hepatica Cat-1 gene Proteins 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 101100005271 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) cat-1 gene Proteins 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001536 azelaic acids Chemical class 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- GDUDPOLSCZNKMK-UHFFFAOYSA-L cobalt(2+);diacetate;hydrate Chemical compound O.[Co+2].CC([O-])=O.CC([O-])=O GDUDPOLSCZNKMK-UHFFFAOYSA-L 0.000 description 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 1
- 229910021515 thallium hydroxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
- C22B23/026—Obtaining nickel or cobalt by dry processes from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/30—Obtaining chromium, molybdenum or tungsten
- C22B34/36—Obtaining tungsten
- C22B34/365—Obtaining tungsten from spent catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Claims (15)
1. Förfarande för tillvaratagande av kobolt och volfrara ur reaktionsvatten (vätskor) och för äteranvänd- 5 ning av dem, kännetecknat av att nämnda vätskor be-handlas: (a) med en jordalkalimetallhydroxid för utfällning av kobolt och volfram och utfällningen behandlas sedan med en stark mineralsyra för upplösning av koboltsaltet och 10 separering av det frän utfälld volframsyra; eller (b) med en alkalimetallhydroxid för utfällning och separering av koboltoxid/-hydroxid och den erhällna alka-limetallösningen behandlas sedan med en lösning av en jor-dalkalimetall för utfällning av jordalkalimetallvolframat, 15 som filtreras bort och som behandlas med en stark mineralsyra för att erhälla volframsyra.
2. Förfarande enligt patentkrav 1, kännetecknat av att reaktionsvätskornas pH-värde förmänligt är mellan 9-14 och förmänligare mellan 10-13. 20 3 . Förfarande enligt patentkrav 1, känneteck- . nat av att molförhällandet mellan nämnda jordalkalime- ··· · .**·. tallhydroxid och Co2+-jon i utföringsform (a) av förfaran- ··· : .·. det är mellan 4-30 och förmänligare 5-20. • · · ”1/ 4. Förfarande enligt patentkrav 1, känneteck- • · .*** 25 nat av att molf örhällandet mellan nämnda jordalkalime- • · · ·“/ tallhydroxid och volfram i utföringsform (a) av förfaran- • · · *·* * det är mellan 5-20 och förmänligare 8-15.
5. Förfarande enligt patentkrav 1, känneteck- *:‘*5 nat av att i utföringsform (a) av förfarandet är mängden • · · 30 stark mineralsyra som ekvivalenter minst tvä gänger sä .·* stor som mängden jordalkalimetallhydroxid i form av moler. • · · *... 6. Förfarande enligt patentkrav 1, känneteck- ♦ · *;* nat av att molf örhällandet mellan nämnda jordalkalime- • tallhydroxid och Co -jon i utföringsform (b) av förfaran- *:**: 35 det förmänligt är mellan 4-20 och förmänligare 5-15. 107809
7. Förfarande enligt patentkrav 1, känneteck-nat av att molförhällandet mellan nämnda jordalkalime-tallhydroxid och volframförening i utföringsform (b) av förfarandet förmänligt är mellan 5-20 och förmänligare 8- 5 15.
8. Förfarande enligt patentkrav 1, känneteck-nat av att molförhällandet mellan nämnda jordalkalime-tallförening och volframförening i utföringsform (b) av förfarandet förmänligt är mellan 1-20 och förmänligare 2- 10 15.
9. Förfarande enligt patentkrav 1, känneteck-nat av att i utföringsform (b) av förfarandet skall mängden stark mineralsyra som ekvivalenter vara minst tvä ganger sä stor som mängden volf ramf örening i form av mo- 15 ler.
10. Förfarande enligt patentkrav 1, känne- tecknat av att nämnda jordalkalimetallhydroxid i utföringsform (a) av förfarandet är kalciumhydroxid.
11. Förfarande enligt patentkrav 1, känne- 20 tecknat av att nämnda alkalimetallhydroxid i utfö- ringsform (b) av förfarandet är natriumhydroxid. • · · · .···, 12. Förfarande enligt patentkrav 1, känne- 107809
17. Förfarande enligt patentkrav 16, kanne -tecknat av att den starka mineralsyrans koncentration är mellan 0,5-12 N och förmänligare 1-6 N. • · • · « ·1« · • · · • · « · • · · • · • · · » · 1 • · · · • 1 1 • · • · ·»· « · « · · t » t • · · · ··· • · · * » · « »·»·« • · • · · • · *· · • « • · • · · • · · • t • · • · · • ^ • · · • 1 • · · · · · • ·
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI940211 | 1994-02-07 | ||
| ITMI940211 IT1276314B1 (it) | 1994-02-07 | 1994-02-07 | Procedimento per il recupero ed il riutilizzo del cobalto e del tungsteno dalle acque di reazione |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI950505A0 FI950505A0 (sv) | 1995-02-06 |
| FI950505A FI950505A (sv) | 1995-08-08 |
| FI107809B true FI107809B (sv) | 2001-10-15 |
Family
ID=11367776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI950505A FI107809B (sv) | 1994-02-07 | 1995-02-06 | Förfarande för tillvaratagning av kobolt och volfram ur reaktionsvätskor samt för deras återanvändning |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5599514A (sv) |
| EP (1) | EP0666108B1 (sv) |
| JP (1) | JPH07300316A (sv) |
| AT (1) | ATE172888T1 (sv) |
| AU (1) | AU685888B2 (sv) |
| BR (1) | BR9500545A (sv) |
| CA (1) | CA2141892A1 (sv) |
| DE (1) | DE69505701T2 (sv) |
| FI (1) | FI107809B (sv) |
| IT (1) | IT1276314B1 (sv) |
| NO (1) | NO307549B1 (sv) |
| RU (1) | RU2139361C1 (sv) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5728197A (en) * | 1996-07-17 | 1998-03-17 | Nanodyne Incorporated | Reclamation process for tungsten carbide/cobalt using acid digestion |
| US6264904B1 (en) | 2000-04-11 | 2001-07-24 | Sherritt International Corporation | Process for recovery of cobalt by selective precipitation of cobalt-calcium double salt |
| US6267800B1 (en) | 2000-04-11 | 2001-07-31 | Sherritt International Corporation | Process for producing cobalt metal powder from nickel-cobalt sulphides |
| WO2006108195A2 (en) * | 2005-04-04 | 2006-10-12 | The Petroleum Oil And Gas Corporation Of South Africa (Pty) Ltd | Process for the removal of cobalt from fischer-tropsch process water |
| EP2064358B1 (en) * | 2006-09-14 | 2012-08-22 | Albemarle Netherlands BV | Process for recovering group vi-b metals from spent catalysts |
| US20130001167A1 (en) * | 2010-03-08 | 2013-01-03 | The Board Of Regents For Oklahoma State University | Process for water softening |
| KR101452179B1 (ko) * | 2014-03-11 | 2014-10-24 | 한국지질자원연구원 | 탈질 폐촉매의 침출용액으로부터 바나듐 및 텅스텐의 회수방법 |
| TR201819677T4 (tr) | 2015-01-22 | 2019-01-21 | Novamont Spa | Sulu çözeltilerden kobaltın ve tungstik asidin ve veya bunların türevlerinin geri kazanımına yönelik proses. |
| CN108164075B (zh) * | 2018-01-30 | 2021-03-12 | 昆山三一环保科技有限公司 | 一种四钴废水的资源化处理系统及其方法 |
| CN111115704A (zh) * | 2018-10-31 | 2020-05-08 | 格林美（江苏）钴业股份有限公司 | 一种四氧化三钴的制备方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA503615A (en) * | 1954-06-08 | C. Carosella Michael | Treating tungstate solutions | |
| US1293403A (en) * | 1918-02-11 | 1919-02-04 | David John Giles | Process of extracting tungsten and similar metals from their ores. |
| GB839838A (en) * | 1955-12-05 | 1960-06-29 | Rhoanglo Mine Services Ltd | Improvements in or relating to the preparation of cobalt compounds |
| US3887680A (en) * | 1973-10-23 | 1975-06-03 | Gte Sylvania Inc | Process for recovering tungsten from tungsten carbides containing an iron group of metals |
| JPS5320245B2 (sv) * | 1974-03-22 | 1978-06-26 | ||
| US3953194A (en) * | 1975-06-20 | 1976-04-27 | Allegheny Ludlum Industries, Inc. | Process for reclaiming cemented metal carbide |
| JPS601369B2 (ja) * | 1977-09-06 | 1985-01-14 | 堺化学工業株式会社 | 分離方法 |
| US4256708A (en) * | 1979-12-26 | 1981-03-17 | Gte Products Corporation | Process for recovering tungsten from cemented tungsten carbide |
| US4629503A (en) * | 1985-04-17 | 1986-12-16 | Ramot - University Authority For Applied Research And Industrial Development | Process for the recovery of tungsten in a pure form from tungsten-containing materials |
| US4668483A (en) * | 1986-05-12 | 1987-05-26 | Gte Products Corporation | Process for recovery of chromium |
| US4910175A (en) * | 1988-12-12 | 1990-03-20 | E. I. Du Pont De Nemours And Company | Catalyst recovery |
| JPH02217321A (ja) * | 1989-02-14 | 1990-08-30 | Nisso Maruzen Chem Kk | タングステン酸類の回収方法 |
| US4954466A (en) * | 1989-11-30 | 1990-09-04 | Monsanto Company | Recovery of cobalt catalyst values |
| EP0477450B1 (en) * | 1990-09-24 | 1996-03-13 | Gte Products Corporation | Method for recovery of tungsten from spent catalysts |
| IT1256989B (it) * | 1992-10-29 | 1995-12-27 | Novamont Spa | Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri. |
-
1994
- 1994-02-07 IT ITMI940211 patent/IT1276314B1/it active IP Right Grant
-
1995
- 1995-01-26 DE DE69505701T patent/DE69505701T2/de not_active Expired - Fee Related
- 1995-01-26 AT AT95101019T patent/ATE172888T1/de active
- 1995-01-26 EP EP19950101019 patent/EP0666108B1/en not_active Expired - Lifetime
- 1995-02-03 JP JP1700995A patent/JPH07300316A/ja not_active Ceased
- 1995-02-03 NO NO950407A patent/NO307549B1/no not_active IP Right Cessation
- 1995-02-06 CA CA 2141892 patent/CA2141892A1/en not_active Abandoned
- 1995-02-06 BR BR9500545A patent/BR9500545A/pt not_active IP Right Cessation
- 1995-02-06 FI FI950505A patent/FI107809B/sv active
- 1995-02-06 US US08/384,427 patent/US5599514A/en not_active Expired - Fee Related
- 1995-02-06 RU RU95101837A patent/RU2139361C1/ru active
- 1995-02-07 AU AU11631/95A patent/AU685888B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP0666108B1 (en) | 1998-11-04 |
| EP0666108A1 (en) | 1995-08-09 |
| NO950407D0 (no) | 1995-02-03 |
| US5599514A (en) | 1997-02-04 |
| ITMI940211A1 (it) | 1995-08-07 |
| NO307549B1 (no) | 2000-04-25 |
| ATE172888T1 (de) | 1998-11-15 |
| JPH07300316A (ja) | 1995-11-14 |
| NO950407L (no) | 1995-08-08 |
| DE69505701T2 (de) | 1999-03-25 |
| AU1163195A (en) | 1995-08-17 |
| BR9500545A (pt) | 1995-09-26 |
| IT1276314B1 (it) | 1997-10-28 |
| AU685888B2 (en) | 1998-01-29 |
| ITMI940211A0 (it) | 1994-02-07 |
| CA2141892A1 (en) | 1995-08-08 |
| RU2139361C1 (ru) | 1999-10-10 |
| RU95101837A (ru) | 1996-12-27 |
| FI950505A0 (sv) | 1995-02-06 |
| DE69505701D1 (de) | 1998-12-10 |
| FI950505A (sv) | 1995-08-08 |
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