ES8601860A1 - Un procedimiento para preparar un alcohol s-alfa-ciano-3-fenoxibencilico opcionalmente sustituido - Google Patents

Un procedimiento para preparar un alcohol s-alfa-ciano-3-fenoxibencilico opcionalmente sustituido

Info

Publication number
ES8601860A1
ES8601860A1 ES527417A ES527417A ES8601860A1 ES 8601860 A1 ES8601860 A1 ES 8601860A1 ES 527417 A ES527417 A ES 527417A ES 527417 A ES527417 A ES 527417A ES 8601860 A1 ES8601860 A1 ES 8601860A1
Authority
ES
Spain
Prior art keywords
optically
active
preparation
cyanomethyl esters
treating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES527417A
Other languages
English (en)
Other versions
ES527417A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell USA Inc
Original Assignee
Shell Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Oil Co filed Critical Shell Oil Co
Publication of ES8601860A1 publication Critical patent/ES8601860A1/es
Publication of ES527417A0 publication Critical patent/ES527417A0/es
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/08Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/32Separation; Purification; Stabilisation; Use of additives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/23Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and carboxyl groups, other than cyano groups, bound to the same unsaturated acyclic carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/38Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by esterified hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/87Preparation of ketenes or dimeric ketenes
    • C07C45/89Preparation of ketenes or dimeric ketenes from carboxylic acids, their anhydrides, esters or halides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/88Ketenes; Dimeric ketenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07KPEPTIDES
    • C07K5/00Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof
    • C07K5/04Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing only normal peptide links
    • C07K5/06Dipeptides
    • C07K5/06008Dipeptides with the first amino acid being neutral
    • C07K5/06017Dipeptides with the first amino acid being neutral and aliphatic
    • C07K5/06034Dipeptides with the first amino acid being neutral and aliphatic the side chain containing 2 to 4 carbon atoms
    • C07K5/06043Leu-amino acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07KPEPTIDES
    • C07K5/00Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof
    • C07K5/04Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing only normal peptide links
    • C07K5/06Dipeptides
    • C07K5/06139Dipeptides with the first amino acid being heterocyclic
    • C07K5/06147Dipeptides with the first amino acid being heterocyclic and His-amino acid; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07KPEPTIDES
    • C07K5/00Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof
    • C07K5/04Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing only normal peptide links
    • C07K5/12Cyclic peptides with only normal peptide bonds in the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biophysics (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Medicinal Chemistry (AREA)
  • Biochemistry (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Peptides Or Proteins (AREA)
  • Catalysts (AREA)

Abstract

PROCEDIMIENTO PARA PREPARAR UN ALCOHOL S-ALFA-CIANO-3-FENOXIBENCILICO OPCIONALMENTE SUSTITUIDO. CONSISTE EN TRATAR UN 3-FENOXIBENZOLDEHIDO, OPCIONALMENTE SUSTITUIDO CON CIANURO DE HIDROGENO EN UNA RELACION DE MOLES DE 1 A 3 RESPECTIVAMENTE, EN PRESENCIA DE UN DISOLVENTE APROTICO INMISCIBLE CON AGUA, COMO UN HIDROCARBURO AROMATICO, TIPO TOLUENO, O UN ETER, COMO DIETIL-ETER, O BIEN UNA MEZCLA DE LOS MIMOS, Y UN CATALIZADOR, DEL TIPO DE DEPEPTIDO CICLO (D-FENILALANIL-D-HISTIDINA), PARA OBTENER UN ALCOHOL S-ALFA-CIANO-3-FENOXIBENCILICO OPCIONALMENTE SUSTITUIDO O UNA MEZCLA ENRIQUECIDA DEL MISMO. SE UTILIZA EN PROCEDIMIENTOS DE PREPARACION DE ESTERES CIANOMETILICOS QUE TIENEN CENTROS QUIRALES EN EL RADICAL ACIDO Y EN EL RADICAL ALCOHOLICO.
ES527417A 1982-11-22 1983-11-21 Un procedimiento para preparar un alcohol s-alfa-ciano-3-fenoxibencilico opcionalmente sustituido Granted ES527417A0 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US44376482A 1982-11-22 1982-11-22
US44351382A 1982-11-22 1982-11-22
US44376382A 1982-11-22 1982-11-22

Publications (2)

Publication Number Publication Date
ES8601860A1 true ES8601860A1 (es) 1985-11-01
ES527417A0 ES527417A0 (es) 1985-11-01

Family

ID=27412181

Family Applications (1)

Application Number Title Priority Date Filing Date
ES527417A Granted ES527417A0 (es) 1982-11-22 1983-11-21 Un procedimiento para preparar un alcohol s-alfa-ciano-3-fenoxibencilico opcionalmente sustituido

Country Status (24)

Country Link
EP (2) EP0109681B1 (es)
JP (2) JPH02270852A (es)
KR (1) KR890003660B1 (es)
AU (1) AU577032B2 (es)
BG (1) BG40805A3 (es)
BR (1) BR8306312A (es)
CA (1) CA1263800A (es)
DD (1) DD216453A5 (es)
DE (1) DE3382524D1 (es)
DK (1) DK532383A (es)
ES (1) ES527417A0 (es)
FI (1) FI834259A (es)
GR (1) GR79041B (es)
HU (1) HU200584B (es)
IL (1) IL70155A (es)
IN (1) IN161692B (es)
MX (1) MX167266B (es)
NO (1) NO834257L (es)
NZ (1) NZ206106A (es)
OA (1) OA07593A (es)
PL (1) PL244585A1 (es)
PT (1) PT77685B (es)
SU (1) SU1542412A3 (es)
YU (2) YU43197B (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU576322B2 (en) * 1983-07-22 1988-08-25 Ici Australia Limited Alpha-substituted-alpha-cyanomethyl alcohols
US4554102A (en) * 1983-09-26 1985-11-19 Shell Oil Company Cyanohydrination catalyst comprising non-crystalline or amorphous dipeptide
EP0172380A3 (en) * 1984-08-20 1987-06-16 E.I. Du Pont De Nemours And Company Preparation of cyanomethyl esters
US4611077A (en) * 1985-06-26 1986-09-09 Shell Oil Company Increasing enantiomeric selectivity in chiral cyanohydrination
US4611076A (en) * 1985-06-26 1986-09-09 Shell Oil Company Chiral cyanohydrination process
JPH064578B2 (ja) * 1986-12-15 1994-01-19 鐘淵化学工業株式会社 光学活性シアノ化合物の製造方法
JP2924000B2 (ja) * 1989-09-29 1999-07-26 住友化学工業株式会社 不斉誘起触媒
CA2062233A1 (en) * 1991-03-12 1992-09-13 Atsunori Mori Catalyst for asymmetric induction
GB0304132D0 (en) * 2003-02-24 2003-03-26 Syngenta Ltd Chemical process
KR101279327B1 (ko) * 2009-12-25 2013-06-26 세레보스퍼시픽리미티드 학습 의욕 개선제

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2383137A (en) * 1939-12-05 1945-08-21 American Cyanamid Co Acetylation of cyanohydrins
BE635217A (es) * 1963-07-22
ZA7911B (en) * 1978-01-31 1980-01-30 Roussel Uclaf Optically-active substituted benzyl alcohol and process for preparing it
FR2458542A1 (fr) * 1979-06-12 1981-01-02 Roussel Uclaf Procede de preparation d'alcools a-cyanes optiquement actifs
DE3116474A1 (de) * 1981-04-25 1982-11-11 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von optisch aktiven carbonsaeuren
JPS5829757A (ja) * 1981-08-17 1983-02-22 Nippon Kayaku Co Ltd 光学活性マンデロニトリルの製造法
AU527142B2 (en) * 1981-12-16 1983-02-17 Bayer Aktiengesellschaft Phenoxy benzyl alcohols
ZA837994B (en) * 1982-11-22 1984-06-27 Shell Oil Co Process for the preparation of optically-active cyanomethyl esters
AU576322B2 (en) * 1983-07-22 1988-08-25 Ici Australia Limited Alpha-substituted-alpha-cyanomethyl alcohols

Also Published As

Publication number Publication date
HUT37915A (en) 1986-03-28
GR79041B (es) 1984-10-02
AU2155583A (en) 1984-05-31
EP0109681A3 (en) 1986-01-15
YU222783A (en) 1986-12-31
KR890003660B1 (ko) 1989-09-29
YU36986A (en) 1986-12-31
AU577032B2 (en) 1988-09-15
BR8306312A (pt) 1984-07-03
HU200584B (en) 1990-07-28
EP0109681B1 (en) 1992-03-11
JPH03238053A (ja) 1991-10-23
EP0451927A1 (en) 1991-10-16
FI834259A0 (fi) 1983-11-21
IL70155A (en) 1989-09-10
IN161692B (es) 1988-01-16
NZ206106A (en) 1987-10-30
FI834259A (fi) 1984-05-23
CA1263800A (en) 1989-12-05
EP0109681A2 (en) 1984-05-30
DD216453A5 (de) 1984-12-12
MX167266B (es) 1993-03-12
PL244585A1 (en) 1985-11-05
PT77685A (en) 1983-12-01
ES527417A0 (es) 1985-11-01
DK532383D0 (da) 1983-11-21
JPH02270852A (ja) 1990-11-05
OA07593A (en) 1985-03-31
NO834257L (no) 1984-05-23
BG40805A3 (en) 1987-02-16
SU1542412A3 (ru) 1990-02-07
DE3382524D1 (de) 1992-04-16
DK532383A (da) 1984-05-23
PT77685B (en) 1986-03-27
YU43197B (en) 1989-04-30
IL70155A0 (en) 1984-02-29
YU43429B (en) 1989-06-30
KR840007715A (ko) 1984-12-20

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19980706