ES8206410A1 - Methanol/higher alcohol mixtures - Google Patents

Methanol/higher alcohol mixtures

Info

Publication number
ES8206410A1
ES8206410A1 ES506040A ES506040A ES8206410A1 ES 8206410 A1 ES8206410 A1 ES 8206410A1 ES 506040 A ES506040 A ES 506040A ES 506040 A ES506040 A ES 506040A ES 8206410 A1 ES8206410 A1 ES 8206410A1
Authority
ES
Spain
Prior art keywords
methanol
oxides
higher alcohol
alcohol mixtures
alkali metals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES506040A
Other languages
Spanish (es)
Other versions
ES506040A0 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SnamProgetti SpA
Original Assignee
SnamProgetti SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SnamProgetti SpA filed Critical SnamProgetti SpA
Publication of ES506040A0 publication Critical patent/ES506040A0/en
Publication of ES8206410A1 publication Critical patent/ES8206410A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Mixtures of methanol and higher alcohols to be used in particular as fuels, either alone or in admixture with petrol, are produced by reacting H2 and CO, possibly in the presence of CO2, in a molar ratio H2:CO of from 0.1:1 to 20:1, preferably from 0.5:1 to 5:1, at a temperature of from 300 to 500 DEG C, preferably from 350 to 450 DEG C, and at a pressure of from 2000 to 16000 KPa, in the presence of a catalyst based on chromium, zinc and at least one alkali metal. The Zn:Cr weight ratio of the catalyst, considered as oxides thereof, is from 5:1 to 1:1 and the alkali metals or the alkali metals as oxides are present in an amount of 0.5 to 5% by weight relative to the total of the elements considered as oxides.
ES506040A 1980-09-15 1981-09-15 Methanol/higher alcohol mixtures Expired ES8206410A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT24659/80A IT1193555B (en) 1980-09-15 1980-09-15 PROCEDURE FOR THE PRODUCTION OF METHANOL MIXTURES AND HIGHER ALCOHOLS AND MIXTURES OBTAINED BY THAT PROCEDURE

Publications (2)

Publication Number Publication Date
ES506040A0 ES506040A0 (en) 1982-08-16
ES8206410A1 true ES8206410A1 (en) 1982-08-16

Family

ID=11214288

Family Applications (1)

Application Number Title Priority Date Filing Date
ES506040A Expired ES8206410A1 (en) 1980-09-15 1981-09-15 Methanol/higher alcohol mixtures

Country Status (32)

Country Link
JP (1) JPS5780486A (en)
KR (1) KR860000422B1 (en)
AT (1) AT375062B (en)
AU (1) AU546859B2 (en)
BE (1) BE890341A (en)
BR (1) BR8105777A (en)
CA (1) CA1187109A (en)
CH (1) CH651852A5 (en)
CS (1) CS221987B2 (en)
CU (1) CU35516A (en)
DD (1) DD201671A5 (en)
DE (1) DE3136088A1 (en)
DK (1) DK396981A (en)
ES (1) ES8206410A1 (en)
FI (1) FI812866L (en)
FR (1) FR2490215B1 (en)
GB (1) GB2083469B (en)
GR (1) GR74675B (en)
IE (1) IE51556B1 (en)
IN (1) IN154478B (en)
IT (1) IT1193555B (en)
LU (1) LU83631A1 (en)
NL (1) NL8104257A (en)
NO (1) NO156007C (en)
NZ (1) NZ198082A (en)
PH (1) PH17030A (en)
PL (1) PL136284B1 (en)
RO (1) RO83096B (en)
SE (1) SE8105470L (en)
TR (1) TR22083A (en)
YU (1) YU202481A (en)
ZA (1) ZA816258B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3524317A1 (en) * 1985-07-08 1987-01-15 Union Rheinische Braunkohlen METHOD FOR THE CATALYTIC PRODUCTION OF AN ALCOHOL MIXTURE WITH INCREASED ISOBUTANOL CONTENT
US4705532A (en) * 1985-07-15 1987-11-10 The Standard Oil Company Alcohol compositions for blending with gasoline
IT1276931B1 (en) * 1995-10-13 1997-11-03 Snam Progetti PROCEDURE FOR PRODUCING MIXTURES OF METHANOL AND HIGHER ALCOHOLS
AU2008347306B2 (en) * 2008-01-04 2012-08-30 University Of Southern California Environmentally friendly ternary transportation flex-fuel of gasoline, methanol and bioethanol
CN106390978B (en) * 2016-09-14 2019-04-09 中国科学院大连化学物理研究所 A kind of high temperature resistant synthesizing methanol by hydrogenating carbon dioxide catalyst and its preparation and application

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB275345A (en) * 1926-05-12 1927-08-11 Synthetic Ammonia & Nitrates Improvements in or relating to the production of methanol and other oxygenated organic compounds
GB323240A (en) * 1928-06-22 1929-12-23 Du Pont Improvements in and relating to the catalytic synthesis of aliphatic alcohols
DE868146C (en) * 1944-01-04 1953-02-23 Basf Ag Process for the production of catalysts from chromium oxide and excess zinc oxide for the synthesis of alcohols from carbon oxide-hydrogen mixtures

Also Published As

Publication number Publication date
IN154478B (en) 1984-11-03
PL233029A1 (en) 1982-04-13
SE8105470L (en) 1982-03-16
DE3136088C2 (en) 1987-03-26
GB2083469B (en) 1984-05-31
NO156007C (en) 1987-07-08
ES506040A0 (en) 1982-08-16
AU7439181A (en) 1982-03-25
NL8104257A (en) 1982-04-01
PL136284B1 (en) 1986-02-28
CU35516A (en) 1982-12-22
FR2490215B1 (en) 1985-06-14
FR2490215A1 (en) 1982-03-19
NO156007B (en) 1987-03-30
KR860000422B1 (en) 1986-04-19
PH17030A (en) 1984-05-17
BR8105777A (en) 1982-05-25
AT375062B (en) 1984-06-25
DK396981A (en) 1982-03-16
RO83096B (en) 1984-02-28
IE812127L (en) 1982-03-05
YU202481A (en) 1983-06-30
DD201671A5 (en) 1983-08-03
IT8024659A0 (en) 1980-09-15
CS221987B2 (en) 1983-04-29
LU83631A1 (en) 1982-04-14
TR22083A (en) 1986-03-21
NZ198082A (en) 1984-11-09
ATA396981A (en) 1983-11-15
IT1193555B (en) 1988-07-08
DE3136088A1 (en) 1982-04-15
RO83096A (en) 1984-02-21
AU546859B2 (en) 1985-09-26
CA1187109A (en) 1985-05-14
GB2083469A (en) 1982-03-24
JPS5780486A (en) 1982-05-20
CH651852A5 (en) 1985-10-15
NO813093L (en) 1982-03-16
BE890341A (en) 1982-03-15
KR830007800A (en) 1983-11-07
IE51556B1 (en) 1987-01-07
FI812866L (en) 1982-03-16
GR74675B (en) 1984-07-02
ZA816258B (en) 1982-11-24

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