GB275345A - Improvements in or relating to the production of methanol and other oxygenated organic compounds - Google Patents
Improvements in or relating to the production of methanol and other oxygenated organic compoundsInfo
- Publication number
- GB275345A GB275345A GB1222826A GB1222826A GB275345A GB 275345 A GB275345 A GB 275345A GB 1222826 A GB1222826 A GB 1222826A GB 1222826 A GB1222826 A GB 1222826A GB 275345 A GB275345 A GB 275345A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methanol
- catalyst
- zinc
- chromate
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/04—Methanol
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
275,345. Synthetic Ammonia & Nitrates, Ltd., and Smith, H. G. May 12,1926. Methanol, higher alcohols, and other oxygenated organic compounds are produced by interaction of carbon oxides and hydrogen at elevated temperature and pressure in the presence of a catalyst comprising a basic zinc chromate of the composition 4ZnO.CrO3. This catalyst, which becomes reduced during the operation or may be reduced beforehand, effects the synthesis at low temperatures (300-400‹ C.), and is not poisoned by sulphur, though volatile compounds of iron, nickel and cobalt should be excluded. The basic zinc chromate is made by adding a slight excess of chromic acid to an aqueous suspension of zinc oxide or hydroxide, or by double decomposition of say zinc sulphate with sodium chromate. Except for the production of methanol, soluble alkali salts may be present in the material. Comparative experiments using a catalyst of varying composition of zinc and chromium oxides under standard reaction conditions are described. Specification 227,147 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1222826A GB275345A (en) | 1926-05-12 | 1926-05-12 | Improvements in or relating to the production of methanol and other oxygenated organic compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1222826A GB275345A (en) | 1926-05-12 | 1926-05-12 | Improvements in or relating to the production of methanol and other oxygenated organic compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB275345A true GB275345A (en) | 1927-08-11 |
Family
ID=10000692
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1222826A Expired GB275345A (en) | 1926-05-12 | 1926-05-12 | Improvements in or relating to the production of methanol and other oxygenated organic compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB275345A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3136088A1 (en) * | 1980-09-15 | 1982-04-15 | Snamprogetti S.p.A., Milano | METHOD FOR PRODUCING MIXTURES FROM METHANOL AND HIGHER ALCOHOLS |
US4762858A (en) * | 1985-09-16 | 1988-08-09 | The Dow Chemical Company | Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst |
-
1926
- 1926-05-12 GB GB1222826A patent/GB275345A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3136088A1 (en) * | 1980-09-15 | 1982-04-15 | Snamprogetti S.p.A., Milano | METHOD FOR PRODUCING MIXTURES FROM METHANOL AND HIGHER ALCOHOLS |
US4762858A (en) * | 1985-09-16 | 1988-08-09 | The Dow Chemical Company | Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst |
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