GB316399A - Improvements in the hydrogenation of aldehydes - Google Patents
Improvements in the hydrogenation of aldehydesInfo
- Publication number
- GB316399A GB316399A GB1886528A GB1886528A GB316399A GB 316399 A GB316399 A GB 316399A GB 1886528 A GB1886528 A GB 1886528A GB 1886528 A GB1886528 A GB 1886528A GB 316399 A GB316399 A GB 316399A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copper
- silver
- nickel
- iron
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
316,399. Horsley, G. F., and Imperial Chemical Industries, Ltd. June 29, 1928. Catalytic agents, preparation of; hydrogenated organic compounds, catalytic production of.- The catalytic hydrogenation of crotonaldehyde to butanol is effected by passing a mixture of the vapour and hydrogen, with or without steam, over a catalyst comprising copper and/or silver and at least one oxide or hydroxide of the metals iron, cobalt, nickel, zinc, calcium, strontium, barium, magnesium, divalent chromium, manganese., or over a mixture of copper and/or silver with iron and/or nickel containing iron and/or nickel oxide at a temperature below 300‹. The catalyst may be prepared by precipitating the oxides or hydroxides of copper or silver with the oxides or hydroxides of iron, cobalt, nickel, zinc, magnesium, chromium, manganese and reducing the mixture under conditions such that the copper or silver is wholly reduced and the other metal partly or not at all. The presence of mixed salts is avoided by adding the metal salt solution to an alkali solution instead of vice versa. According to an example crotonaldehyde vapour, steam and hydrogen are passed over a catalyst consisting of copper and nickel oxide at a temperature of 120‹. Specifications 2306/14 and 147,118 are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1886528A GB316399A (en) | 1928-06-29 | 1928-06-29 | Improvements in the hydrogenation of aldehydes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1886528A GB316399A (en) | 1928-06-29 | 1928-06-29 | Improvements in the hydrogenation of aldehydes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB316399A true GB316399A (en) | 1929-08-01 |
Family
ID=10119737
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1886528A Expired GB316399A (en) | 1928-06-29 | 1928-06-29 | Improvements in the hydrogenation of aldehydes |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB316399A (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2549416A (en) * | 1948-02-04 | 1951-04-17 | Du Pont | Preparation of alcohols |
US2982789A (en) * | 1957-12-13 | 1961-05-02 | Allied Chem | Manufacture of trifluoroethanol |
US3341610A (en) * | 1961-04-24 | 1967-09-12 | Quaker Oats Co | Hydrogenation of alpha, betaunsaturated aldehydes |
US3431311A (en) * | 1960-06-25 | 1969-03-04 | Distillers Co Yeast Ltd | Production of alkanols |
US3491159A (en) * | 1965-11-26 | 1970-01-20 | Huels Chemische Werke Ag | Process for the preparation of saturated aliphatic alcohols |
US3491158A (en) * | 1965-11-26 | 1970-01-20 | Huels Chemische Werke Ag | Process for the preparation of saturated aliphatic alcohols |
FR2489304A1 (en) * | 1980-09-03 | 1982-03-05 | Alexeeva Klavdia | 2-Ethyl:hexanol prodn. from 2-ethyl-hexenal - by hydrogenation over zinc, copper and chromium contg. catalyst (CS 31.3.81) |
US4762817A (en) * | 1986-11-03 | 1988-08-09 | Union Carbide Corporation | Aldehyde hydrogenation catalyst |
US4876402A (en) * | 1986-11-03 | 1989-10-24 | Union Carbide Chemicals And Plastics Company Inc. | Improved aldehyde hydrogenation process |
US5550302A (en) * | 1994-03-24 | 1996-08-27 | Mitsubishi Chemical Corporation | Method for producing an alcohol and catalyst precursor useful for the method |
GB2482887A (en) * | 2010-08-18 | 2012-02-22 | Johnson Matthey Plc | Catalyst and process for hydrogenation of aldehydes |
-
1928
- 1928-06-29 GB GB1886528A patent/GB316399A/en not_active Expired
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2549416A (en) * | 1948-02-04 | 1951-04-17 | Du Pont | Preparation of alcohols |
US2982789A (en) * | 1957-12-13 | 1961-05-02 | Allied Chem | Manufacture of trifluoroethanol |
US3431311A (en) * | 1960-06-25 | 1969-03-04 | Distillers Co Yeast Ltd | Production of alkanols |
US3341610A (en) * | 1961-04-24 | 1967-09-12 | Quaker Oats Co | Hydrogenation of alpha, betaunsaturated aldehydes |
US3491159A (en) * | 1965-11-26 | 1970-01-20 | Huels Chemische Werke Ag | Process for the preparation of saturated aliphatic alcohols |
US3491158A (en) * | 1965-11-26 | 1970-01-20 | Huels Chemische Werke Ag | Process for the preparation of saturated aliphatic alcohols |
FR2489304A1 (en) * | 1980-09-03 | 1982-03-05 | Alexeeva Klavdia | 2-Ethyl:hexanol prodn. from 2-ethyl-hexenal - by hydrogenation over zinc, copper and chromium contg. catalyst (CS 31.3.81) |
US4762817A (en) * | 1986-11-03 | 1988-08-09 | Union Carbide Corporation | Aldehyde hydrogenation catalyst |
US4876402A (en) * | 1986-11-03 | 1989-10-24 | Union Carbide Chemicals And Plastics Company Inc. | Improved aldehyde hydrogenation process |
US5550302A (en) * | 1994-03-24 | 1996-08-27 | Mitsubishi Chemical Corporation | Method for producing an alcohol and catalyst precursor useful for the method |
GB2482887A (en) * | 2010-08-18 | 2012-02-22 | Johnson Matthey Plc | Catalyst and process for hydrogenation of aldehydes |
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