GB961860A - Improvements in or relating to the catalytic conversion of carbon monoxide with steam - Google Patents

Improvements in or relating to the catalytic conversion of carbon monoxide with steam

Info

Publication number
GB961860A
GB961860A GB26357/61A GB2635761A GB961860A GB 961860 A GB961860 A GB 961860A GB 26357/61 A GB26357/61 A GB 26357/61A GB 2635761 A GB2635761 A GB 2635761A GB 961860 A GB961860 A GB 961860A
Authority
GB
United Kingdom
Prior art keywords
alkali metal
catalyst
steam
carbon monoxide
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26357/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
Original Assignee
Metallgesellschaft AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallgesellschaft AG filed Critical Metallgesellschaft AG
Publication of GB961860A publication Critical patent/GB961860A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B01J27/0515—Molybdenum with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Carbon monoxide is reacted with steam to form H2 and CO2 at 200-500 DEG C. and above 5 atms. in the presence of a catalyst containing molybdenum, and either nickel or cobalt, all as oxides or sulphides, and also containing an alkali metal compound in amount 0.1-0.6%, calculated as oxide. A catalyst may consist of 15% MoO3 and 3% CoO on an Al2O3 carrier and has alkali metal (e.g. Li, Na, K, Rb, Cs) incorporated therein by impregnating with a carbonate solution and drying. The alkali metal may, however, be present as a compound with other catalyst constituents, e.g. as molybdate or thiomolybdate.ALSO:Carbon monoxide is reacted with steam to form H2 and CO2 at 200-500 DEG C. and above 5 atms. in the presence of a catalyst containing molybdenum, and either nickel or cobalt, all as oxides or sulphides, and also containing an alkali metal compound in amount 0.1-0.6%, calculated as oxide. A catalyst may consist of 15% MoO3 and 3% CoO on an Al2O3 carrier and has alkali metal (e.g. Li, Na, K, Rb, Cs) incorporated therein by impregnating with a carbonate solution and drying. The alkali metal may, however, be present as a compound with other catalyst constituents, e.g. as molybdate or thiomolybdate.
GB26357/61A 1960-07-20 1961-07-20 Improvements in or relating to the catalytic conversion of carbon monoxide with steam Expired GB961860A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEM0045985 1960-07-20

Publications (1)

Publication Number Publication Date
GB961860A true GB961860A (en) 1964-06-24

Family

ID=7305460

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26357/61A Expired GB961860A (en) 1960-07-20 1961-07-20 Improvements in or relating to the catalytic conversion of carbon monoxide with steam

Country Status (1)

Country Link
GB (1) GB961860A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3387942A (en) * 1965-05-10 1968-06-11 Catalysts & Chemicals Inc Production of hydrogen
US3388972A (en) * 1966-12-14 1968-06-18 Catalysts & Chemicals Inc Low temperature shift reaction catalysts and methods for their preparation
FR2011150A1 (en) * 1968-06-18 1970-02-27 Exxon Research Engineering Co
DE2054869A1 (en) * 1969-11-10 1971-05-19 Esso Research and Engineering Co , Linden, NJ (V St A ) Process for the production of hydrogen
US3957962A (en) * 1973-04-17 1976-05-18 Shell Oil Company Process for the preparation of hydrogen-rich gas
US3961037A (en) * 1965-01-05 1976-06-01 Imperial Chemical Industries Limited Process for forming hydrogen and carbon dioxide using a catalyst consisting essentially of oxides of copper, zinc and aluminum or magnesium
US4054644A (en) * 1972-03-16 1977-10-18 Exxon Research & Engineering Co. Water gas shift process
EP0062912A1 (en) * 1981-04-14 1982-10-20 United Catalysts, Inc. Process for the catalytic conversion of carbon monoxide and sulfactive CO conversion catalyst
US4452854A (en) * 1981-04-14 1984-06-05 United Catalysts, Inc. Catalyst and process for carbon monoxide conversion in sour gas
US4540563A (en) * 1981-03-26 1985-09-10 Imperial Chemical Industries Plc Hydrogen production
FR2575453A1 (en) * 1984-12-28 1986-07-04 Pro Catalyse PROCESS FOR THE CONVERSION OF CARBON MONOXIDE BY WATER VAPOR USING A THERAPEUTIC CATALYST
EP0205130A2 (en) * 1985-06-11 1986-12-17 BASF Aktiengesellschaft Copper containing catalysts for the preparation of hydrogen
JP2014519976A (en) * 2011-06-06 2014-08-21 ジョンソン、マッセイ、パブリック、リミテッド、カンパニー Water gas shift catalyst

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3961037A (en) * 1965-01-05 1976-06-01 Imperial Chemical Industries Limited Process for forming hydrogen and carbon dioxide using a catalyst consisting essentially of oxides of copper, zinc and aluminum or magnesium
US3387942A (en) * 1965-05-10 1968-06-11 Catalysts & Chemicals Inc Production of hydrogen
US3388972A (en) * 1966-12-14 1968-06-18 Catalysts & Chemicals Inc Low temperature shift reaction catalysts and methods for their preparation
FR2011150A1 (en) * 1968-06-18 1970-02-27 Exxon Research Engineering Co
DE1928389A1 (en) * 1968-06-18 1970-05-06 Exxon Research Engineering Co Process for the production of hydrogen
DE2054869A1 (en) * 1969-11-10 1971-05-19 Esso Research and Engineering Co , Linden, NJ (V St A ) Process for the production of hydrogen
US4054644A (en) * 1972-03-16 1977-10-18 Exxon Research & Engineering Co. Water gas shift process
US3957962A (en) * 1973-04-17 1976-05-18 Shell Oil Company Process for the preparation of hydrogen-rich gas
US4540563A (en) * 1981-03-26 1985-09-10 Imperial Chemical Industries Plc Hydrogen production
EP0062912A1 (en) * 1981-04-14 1982-10-20 United Catalysts, Inc. Process for the catalytic conversion of carbon monoxide and sulfactive CO conversion catalyst
US4452854A (en) * 1981-04-14 1984-06-05 United Catalysts, Inc. Catalyst and process for carbon monoxide conversion in sour gas
FR2575453A1 (en) * 1984-12-28 1986-07-04 Pro Catalyse PROCESS FOR THE CONVERSION OF CARBON MONOXIDE BY WATER VAPOR USING A THERAPEUTIC CATALYST
EP0189701A1 (en) * 1984-12-28 1986-08-06 Société Française des Produits pour Catalyse "PRO-CATALYSE" Process for the conversion of carbon monoxide by steam using a thioresistant catalyst
AU577434B2 (en) * 1984-12-28 1988-09-22 Societe Francaise Des Produits Pour Catalyse Pro-Catalyse Conversion of carbon monoxide using catalysts
EP0205130A2 (en) * 1985-06-11 1986-12-17 BASF Aktiengesellschaft Copper containing catalysts for the preparation of hydrogen
EP0205130A3 (en) * 1985-06-11 1989-12-27 Basf Aktiengesellschaft Copper containing catalysts for the preparation of hydrogen
JP2014519976A (en) * 2011-06-06 2014-08-21 ジョンソン、マッセイ、パブリック、リミテッド、カンパニー Water gas shift catalyst

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