GB940960A - Process for the catalytic conversion of carbon monoxide with steam to form hydrogen and carbon dioxide - Google Patents

Process for the catalytic conversion of carbon monoxide with steam to form hydrogen and carbon dioxide

Info

Publication number
GB940960A
GB940960A GB4039660A GB4039660A GB940960A GB 940960 A GB940960 A GB 940960A GB 4039660 A GB4039660 A GB 4039660A GB 4039660 A GB4039660 A GB 4039660A GB 940960 A GB940960 A GB 940960A
Authority
GB
United Kingdom
Prior art keywords
sulphide
catalyst
steam
carbon dioxide
cobalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4039660A
Inventor
Ortwin Reitz
Ernst Lorenz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB940960A publication Critical patent/GB940960A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)

Abstract

Hydrogen and carbon dioxide are produced from steam and carbon monoxide using as catalyst a mixture of a sulphide of cobalt and/or nickel together with one or more sulphides of the transition groups VA, VIA, and VIIA of the Periodic System of Leverenz, used either alone or on a carrier. The catalyst may also contain iron or copper sulphide. The reaction may be at superatmospheric pressure, e.g. 7 to 35 atmospheres and in at least two stages, the mean temperature in each successive stage being 50 DEG to 100 DEG C. lower than that in the preceding stage. The gas to be converted may contain hydrogen sulphide and organic sulphur compounds. The catalyst is re-activated by oxidation and re-sulphurization in situ. Catalyst carriers used may be alumina, synthetic and natural silicates, oxides of magnesium, calcium, zirconium, chromium, titanium.ALSO:In the conversion of steam and carbon monoxide to hydrogen and carbon dioxide a catalyst is used comprising a sulphide of cobalt and/or nickel together with a sulphide of a metal of Group VA, VIA, and VIIA of the Leverenz Periodic system. Examples use 9,8% by weight of molybdenum sulphide, and 4,7% by weight of cobalt sulphide using active alumina as carrier, the catalyst used as cylindrical pellets 3 mm. high and 3 mm. diameter.
GB4039660A 1959-11-25 1960-11-24 Process for the catalytic conversion of carbon monoxide with steam to form hydrogen and carbon dioxide Expired GB940960A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DER0055664 1959-11-25

Publications (1)

Publication Number Publication Date
GB940960A true GB940960A (en) 1963-11-06

Family

ID=7410033

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4039660A Expired GB940960A (en) 1959-11-25 1960-11-24 Process for the catalytic conversion of carbon monoxide with steam to form hydrogen and carbon dioxide

Country Status (2)

Country Link
DE (1) DE1250792B (en)
GB (1) GB940960A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011055132A1 (en) 2009-11-05 2011-05-12 Johnson Matthey Plc Water gas shift reaction process
US10099922B2 (en) 2014-01-17 2018-10-16 Johnson Matthey Public Limited Company Method of loading a vessel
US10494255B2 (en) 2015-10-29 2019-12-03 Johnson Matthey Public Limited Company Water gas shift process
US10807866B2 (en) 2015-10-29 2020-10-20 Johnson Matthey Public Limited Company Water-gas shift catalyst
US11014811B2 (en) 2015-10-29 2021-05-25 Johnson Matthey Public Limited Company Water gas shift process

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1281051A (en) * 1968-06-18 1972-07-12 Exxon Research Engineering Co Low temperature shift reaction involving an alkali metal compound and a hydrogenation dehydrogenation component
BE758677A (en) * 1969-11-10 1971-05-10 Exxon Research Engineering Co NEW CATALYST FOR THE PRODUCTION OF HYDROGEN BY DISPLACING GAS TO WATER
US3793081A (en) * 1971-04-28 1974-02-19 Exxon Research Engineering Co Sulfided transition metal fuel cell cathode catalysts
NL175835B (en) * 1973-04-17 1984-08-01 Shell Int Research Process for preparing a hydrogen-rich gas from a carbon monoxide-containing gas using a nickel and / or cobalt and molybdenum-containing catalyst.
US4389335A (en) * 1981-04-14 1983-06-21 United Catalysts Inc. Catalyst for carbon monoxide conversion in sour gas
US4452854A (en) * 1981-04-14 1984-06-05 United Catalysts, Inc. Catalyst and process for carbon monoxide conversion in sour gas

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011055132A1 (en) 2009-11-05 2011-05-12 Johnson Matthey Plc Water gas shift reaction process
US8821833B2 (en) 2009-11-05 2014-09-02 Johnson Matthey Public Limited Company Water gas shift reaction process
US9365421B2 (en) 2009-11-05 2016-06-14 Johnson Matthey Plc Water gas shift reaction process
US10099922B2 (en) 2014-01-17 2018-10-16 Johnson Matthey Public Limited Company Method of loading a vessel
US10494255B2 (en) 2015-10-29 2019-12-03 Johnson Matthey Public Limited Company Water gas shift process
US10807866B2 (en) 2015-10-29 2020-10-20 Johnson Matthey Public Limited Company Water-gas shift catalyst
US11014811B2 (en) 2015-10-29 2021-05-25 Johnson Matthey Public Limited Company Water gas shift process

Also Published As

Publication number Publication date
DE1250792B (en) 1967-09-28

Similar Documents

Publication Publication Date Title
GB940960A (en) Process for the catalytic conversion of carbon monoxide with steam to form hydrogen and carbon dioxide
GB1060547A (en) Improvements relating to the production of hydrogen-or methane-containing gases
GB1087987A (en) Catalysts useful in effecting the shift reaction
KR870002041A (en) Process for producing C1 to C10 aliphatic hydrocarbons or mixed alcohols
GB900945A (en) Treatment of gases
GB907770A (en) A process for the catalytic desulphurisation of hydrocarbon oils
ES8308288A1 (en) Process for the catalytic conversion of carbon monoxide and sulfactive CO conversion catalyst.
GB319396A (en) Improvements relating to the purification of gas containing sulphuretted hydrogen
ES272023A1 (en) Process for the production of ethylene oxide and nitrogen
GB774283A (en) Process for the combined purification and methanisation of gas mixtures containing oxides of carbon and hydrogen
GB938046A (en) Process for producing alcohols from catalytic hydration of olefins
GB851443A (en) Method of treating gases derived from the distillation of coal
GB1140958A (en) Process for suppressing carbon monoxide reversion in iron ore reduction reactions
GB476684A (en) Improvements in or relating to the removal of oxides of nitrogen from combustible gases
GB833551A (en) Production of ammonia synthesis feed gas
GB872256A (en) Improvements in methods for treating fuel gases
GB937260A (en) Process for the catalytic dealkylation of aromatic compounds
SU108260A1 (en) Catalyst Regeneration Method
GB931943A (en) Production of carbon monoxide and hydrogen
GB942029A (en) A method of detoxifying town and trunk gases
GB991884A (en) Improvements in or relating to the conversion of carbon monoxide with steam
GB1009961A (en) Improvements in or relating to a continuous process for the catalytic conversion of hydrocarbons to hydrogen rich gases
GB845558A (en) Process for the hydrogenation of carbon monoxide
GB894451A (en) Process for reducing the carbon monoxide content of industrial combustible gases
GB904940A (en) Process for the thermal-catalytic conversion of gaseous or liquid hydrocarbons into gases consisting mainly of carbon monoxide, hydrogen and possibly methane