ES466207A1 - Mejoras en el metodo para la polimerizacion catalitica de etileno solamente o la copolimerizacion de etileno con alfa-olefinas - Google Patents

Mejoras en el metodo para la polimerizacion catalitica de etileno solamente o la copolimerizacion de etileno con alfa-olefinas

Info

Publication number
ES466207A1
ES466207A1 ES466207A ES466207A ES466207A1 ES 466207 A1 ES466207 A1 ES 466207A1 ES 466207 A ES466207 A ES 466207A ES 466207 A ES466207 A ES 466207A ES 466207 A1 ES466207 A1 ES 466207A1
Authority
ES
Spain
Prior art keywords
titanium
ethylene polymerization
silyl chromate
modified silyl
chromate catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES466207A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES466207A1 publication Critical patent/ES466207A1/es
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Mejora en el método para la polimerización catalítica de etileno solamente o la copolimerización de etileno con alfa-olefinas que contienen de 3 a 6 átomos de carbono, caracterizada porque la polimerización se lleva a cabo en presencia de un catalizador constituido por un cromato de sililo con la fórmula: **(Fórmula)** en la cual cada R es un radical hidrocarbilo que contiene de 1 a aproximadamente 14 átomos de carbono, depositado sobre un soporte de sílice de elevada área superficial, conteniendo dicho soporte, tratado por calor previamente a una temperatura de 500-100ºC, aluminio y titanio.
ES466207A 1977-01-21 1978-01-20 Mejoras en el metodo para la polimerizacion catalitica de etileno solamente o la copolimerizacion de etileno con alfa-olefinas Expired ES466207A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/761,213 US4100105A (en) 1977-01-21 1977-01-21 Titanium-modified silyl chromate catalysts for ethylene polymerization

Publications (1)

Publication Number Publication Date
ES466207A1 true ES466207A1 (es) 1979-01-16

Family

ID=25061518

Family Applications (2)

Application Number Title Priority Date Filing Date
ES466207A Expired ES466207A1 (es) 1977-01-21 1978-01-20 Mejoras en el metodo para la polimerizacion catalitica de etileno solamente o la copolimerizacion de etileno con alfa-olefinas
ES467604A Expired ES467604A1 (es) 1977-01-21 1978-03-07 Un metodo de preparacion de un catalizador de polimerizacionde etileno.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES467604A Expired ES467604A1 (es) 1977-01-21 1978-03-07 Un metodo de preparacion de un catalizador de polimerizacionde etileno.

Country Status (26)

Country Link
US (2) US4100105A (es)
JP (1) JPS5391092A (es)
AR (1) AR223142A1 (es)
AU (1) AU524400B2 (es)
BE (1) BE863121A (es)
BR (1) BR7800318A (es)
CA (1) CA1111408A (es)
CS (1) CS203181B2 (es)
DE (1) DE2802517A1 (es)
DK (1) DK152216C (es)
EG (1) EG13129A (es)
ES (2) ES466207A1 (es)
FI (1) FI63950C (es)
FR (1) FR2378048A1 (es)
GB (1) GB1551596A (es)
HK (1) HK37483A (es)
IN (1) IN147022B (es)
IT (1) IT1093202B (es)
MX (1) MX4482E (es)
NL (1) NL177315C (es)
NO (1) NO155140C (es)
NZ (1) NZ186280A (es)
PH (1) PH13673A (es)
SE (1) SE441273B (es)
SU (1) SU1025322A3 (es)
ZA (1) ZA777666B (es)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4263422A (en) * 1979-12-31 1981-04-21 The Dow Chemical Company Polymerization of olefins with dual, independently supported catalysts
US4532311A (en) * 1981-03-26 1985-07-30 Union Carbide Corporation Process for reducing sheeting during polymerization of alpha-olefins
US4792592A (en) * 1981-03-26 1988-12-20 Union Carbide Corporation Process for reducing sheeting during polymerization of alpha-olefins
JPS58170957A (ja) * 1982-03-31 1983-10-07 Aisin Warner Ltd 車両用自動変速機のアキユムレ−タ
JPH0725817B2 (ja) * 1986-04-23 1995-03-22 日本石油株式会社 オレフイン重合用触媒
JPH072798B2 (ja) * 1987-10-28 1995-01-18 住友化学工業株式会社 オレフィン重合用固体触媒成分
EP0594914A1 (en) * 1992-10-26 1994-05-04 Bp Chemicals S.N.C. Preparation of a catalyst for the manufacture of polyethylene
US6720396B2 (en) * 2000-11-30 2004-04-13 Univation Technologies, Llc Polymerization process
FR2825357B1 (fr) * 2001-05-31 2004-04-30 Cit Alcatel Procede de dopage de la silice par du fluor
US6989344B2 (en) * 2002-12-27 2006-01-24 Univation Technologies, Llc Supported chromium oxide catalyst for the production of broad molecular weight polyethylene
CA2517269A1 (en) * 2003-03-28 2004-11-04 Union Carbide Chemicals & Plastics Technology Corporation Chromium-based catalysts in mineral oil for production of polyethylene
US6982304B2 (en) * 2003-12-22 2006-01-03 Union Carbide Chemicals & Plastics Technology Corporation Blow molding resins with improved ESCR
US7790826B2 (en) * 2004-05-06 2010-09-07 DowGlobal Technologies Inc. Polymer molding compositions
DE602005020688D1 (de) 2004-12-17 2010-05-27 Dow Global Technologies Inc Rheologiemodifizierte polyethylenzusammensetzungen
US7629422B2 (en) 2004-12-21 2009-12-08 Univation Technologies, Llc Process for transitioning between Ziegler-Natta-based and chromium-based catalysts
CN100436316C (zh) * 2005-12-16 2008-11-26 厦门大学 一种硅胶载体的制备方法
CA2605044C (en) * 2007-10-01 2014-12-02 Nova Chemicals Corporation Polymerization process using a mixed catalyst system
CA2740755C (en) 2011-05-25 2019-01-15 Nova Chemicals Corporation Chromium catalysts for olefin polymerization
CA2783494C (en) 2012-07-23 2019-07-30 Nova Chemicals Corporation Adjusting polymer composition
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
SG10201906006QA (en) 2013-11-21 2019-08-27 Univation Tech Llc Method for controlling polyolefin properties during polymerisation
CA2837591A1 (en) 2013-12-19 2015-06-19 Nova Chemicals Corporation Polyethylene composition for extrusion coating
WO2015181151A1 (en) 2014-05-27 2015-12-03 Sabic Global Technologies B.V. Process for transitioning between incompatible catalysts
JP6674911B2 (ja) 2014-06-24 2020-04-01 ノヴァ ケミカルズ(アンテルナショナル)ソシエテ アノニム 攪拌反応器内の局所流体齢の制御
CA2857456C (en) 2014-07-22 2022-05-03 Nova Chemicals Corporation Improved control over particulate feed
EP3188834B1 (en) 2014-09-02 2021-02-17 Univation Technologies, LLC Polyolefin production with chromium-based catalysts
SG11201701451UA (en) 2014-09-02 2017-03-30 Univation Tech Llc Polyolefin production with chromium-based catalysts
SG11201701437PA (en) 2014-09-02 2017-03-30 Univation Tech Llc Polyolefin production with chromium-based catalysts
CA2870027C (en) 2014-11-07 2022-04-26 Matthew Zaki Botros Blow molding composition and process
US10266618B2 (en) 2014-11-24 2019-04-23 Univation Technologies, Llc Chromium-based catalyst compositions for olefin polymerization
EP3223943B1 (en) 2014-11-24 2023-09-27 Univation Technologies, LLC Composition comprising particles
CA2891002C (en) 2015-05-13 2022-09-06 Veronica Rose Zimmerman Modeling a bed plate and its use
PL3377421T3 (pl) 2015-11-19 2021-06-14 Dow Global Technologies Llc Kompozycje polietylenowe mające właściwości żywego zawiasu
ES2765241T3 (es) 2015-12-10 2020-06-08 Dow Global Technologies Llc Cintas, fibras o monofilamentos de polietileno que comprenden un polímero de etileno/alfa-olefina
MX2018007480A (es) 2015-12-21 2018-08-01 Dow Global Technologies Llc Formulaciones de polietileno con barrera mejorada y dureza para aplicaciones de moldeo.
US11492467B2 (en) 2015-12-21 2022-11-08 Dow Global Technologies Llc Polyethylene formulations with improved barrier and environmental stress crack resistance
EP3408314B1 (en) 2016-01-29 2020-12-23 Univation Technologies, LLC Polyolefin film with improved toughness
JP6971252B2 (ja) 2016-04-20 2021-11-24 ユニベーション・テクノロジーズ・エルエルシー ポリマーフローインデックス調整剤
CN109983035B (zh) 2016-12-15 2022-02-11 尤尼威蒂恩技术有限责任公司 对聚合工艺进行评定
US11161924B2 (en) 2017-10-27 2021-11-02 Univation Technologies, Llc Polyethylene copolymer resins and films
CA3079202A1 (en) 2017-10-27 2019-05-02 Univation Technologies, Llc Selectively transitioning polymerization processes
US10738182B2 (en) 2018-04-23 2020-08-11 Dow Global Technologies Llc Molded articles and methods thereof
US20210070902A1 (en) 2018-05-24 2021-03-11 Univation Technologies, Llc Unimodal polyethylene copolymer and film thereof
EP3830145A1 (en) 2018-07-31 2021-06-09 Univation Technologies, LLC Unimodal polyethylene copolymer and film thereof
CN112585177A (zh) 2018-07-31 2021-03-30 尤尼威蒂恩技术有限责任公司 单峰聚乙烯共聚物和其膜
CN112673032B (zh) 2018-09-24 2024-03-15 切弗朗菲利浦化学公司 制备具有增强的聚合活性的负载型铬催化剂的方法
CA3142138A1 (en) 2019-06-10 2020-12-17 Univation Technologies, Llc Polyethylene blend
WO2021205333A1 (en) 2020-04-07 2021-10-14 Nova Chemicals (International) S.A. High density polyethylene for rigid articles

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1545098C3 (de) * 1963-09-05 1980-11-06 Union Carbide Corp., New York, N.Y. (V.St.A.) Verfahren zur Polymerisation von Äthylen
NL128841C (es) 1963-06-21
NL135065C (es) * 1965-05-14
US3445367A (en) * 1965-11-22 1969-05-20 Phillips Petroleum Co Catalyst and process for making olefin polymers of narrow molecular weight distribution
US3622521A (en) * 1967-08-21 1971-11-23 Phillips Petroleum Co Olefin polymerization with chromium and titanium-containing compounds
US3704287A (en) * 1970-09-17 1972-11-28 Union Carbide Corp High temperature reduced catalyst and process
US3974101A (en) * 1970-10-08 1976-08-10 Phillips Petroleum Company Olefin polymerization catalyst
US3887494A (en) * 1970-11-12 1975-06-03 Phillips Petroleum Co Olefin polymerization catalyst
US3798202A (en) * 1971-10-12 1974-03-19 Phillips Petroleum Co Polyolefin production
US3870656A (en) * 1972-05-25 1975-03-11 Phillips Petroleum Co Preparation of silica-containing compositions
GB1429174A (en) * 1972-06-12 1976-03-24 Bp Chem Int Ltd Polymerisation process and catalyst
US3884832A (en) * 1974-02-04 1975-05-20 Chemplex Co Organotin chromate polymerization catalyst
US3941761A (en) * 1974-02-04 1976-03-02 Chemplex Company Method of polymerizing olefins
GB1495547A (en) * 1974-03-22 1977-12-21 British Petroleum Co Polymerisation catalyst
US3959178A (en) * 1974-03-28 1976-05-25 Phillips Petroleum Company Mixed hydrocarbyloxide treated catalyst activated at different temperatures
US3950316A (en) * 1974-05-03 1976-04-13 Phillips Petroleum Company Catalyst support formed by adding acidic material to silica containing titanium
GB1447605A (en) 1974-05-08 1976-08-25 Phillips Petroleum Co Olefin polymerization catalyst peparation
GB1505994A (en) * 1974-06-11 1978-04-05 British Petroleum Co Polymerisation process
US3976632A (en) * 1974-12-04 1976-08-24 Phillips Petroleum Company Reactivation of organochromium olefin polymerization catalyst in presence of oxygen
US4001196A (en) * 1974-12-04 1977-01-04 Phillips Petroleum Company Reactivation of organochromium olefin polymerization catalyst in presence of oxygen
US4011382A (en) * 1975-03-10 1977-03-08 Union Carbide Corporation Preparation of low and medium density ethylene polymer in fluid bed reactor
US4049896A (en) * 1975-03-14 1977-09-20 National Petro Chemicals Corporation Olefin polymerization catalyst
US3984351A (en) * 1975-03-14 1976-10-05 National Petro Chemicals Corporation Olefin polymerization catalyst
US4016343A (en) * 1975-08-22 1977-04-05 Chemplex Company Tetravalent chromium alkoxide polymerization catalyst and method
US4053437A (en) * 1976-03-04 1977-10-11 Chemplex Company Polyolefin catalyst and method for its preparation
US4065612A (en) * 1976-03-30 1977-12-27 Union Carbide Corporation Phenol modified polymerization catalyst and polymerization process

Also Published As

Publication number Publication date
US4100105A (en) 1978-07-11
FR2378048A1 (fr) 1978-08-18
DE2802517A1 (de) 1978-07-27
PH13673A (en) 1980-08-26
HK37483A (en) 1983-10-07
SU1025322A3 (ru) 1983-06-23
MX4482E (es) 1982-05-19
BE863121A (fr) 1978-07-20
FR2378048B1 (es) 1984-10-19
EG13129A (en) 1981-06-30
NZ186280A (en) 1980-05-08
NO780227L (no) 1978-07-24
SE7800738L (sv) 1978-07-22
CS203181B2 (en) 1981-02-27
NL7800749A (nl) 1978-07-25
NL177315C (nl) 1985-09-02
NL177315B (nl) 1985-04-01
CA1111408A (en) 1981-10-27
IN147022B (es) 1979-10-20
US4152502A (en) 1979-05-01
AU524400B2 (en) 1982-09-16
IT7819503A0 (it) 1978-01-20
BR7800318A (pt) 1978-10-10
FI63950C (fi) 1983-09-12
JPS5541683B2 (es) 1980-10-25
DK29778A (da) 1978-07-22
SE441273B (sv) 1985-09-23
IT1093202B (it) 1985-07-19
AU3251478A (en) 1979-07-26
FI63950B (fi) 1983-05-31
DK152216C (da) 1988-07-11
DE2802517C2 (es) 1987-08-06
FI780140A (fi) 1978-07-22
NO155140B (no) 1986-11-10
GB1551596A (en) 1979-08-30
DK152216B (da) 1988-02-08
AR223142A1 (es) 1981-07-31
ES467604A1 (es) 1978-10-16
NO155140C (no) 1987-02-18
ZA777666B (en) 1978-10-25
JPS5391092A (en) 1978-08-10

Similar Documents

Publication Publication Date Title
ES467604A1 (es) Un metodo de preparacion de un catalizador de polimerizacionde etileno.
AU522013B2 (en) Catalyst for olefin polymerization
AU5935280A (en) Catalyst for producing olefin polymers
AU545468B2 (en) Olefin polymerization catalyst
YU39287B (en) Process for the preparation of stereospecific catalysts for the polymerization of alpha-olefines
NZ185222A (en) Supported chromium catalysts for ethylene polymerization
EP0002673A3 (en) Chromium-containing catalyst, process for its preparation and use thereof for olefin polymerization
AU541964B2 (en) Olefin polymerisation catalyst
JPS56125409A (en) Chromium-containing polymerization catalyst
AU529414B2 (en) Catalysts for polymerizing olefins
AU538862B2 (en) Olefin polymerisation catalyst support
NZ189729A (en) Catalytic polymerisation of ethylene using a chromium catalyst in the presence of a phenolic antioxidant
ES8106915A1 (es) Procedimiento para la preparacion de un catalizador de poli-merizacion
AU515644B2 (en) Olefin polymerisation catalyst
BE852976A (fr) Support perfectionne en silice pour catalyseur de polymerisation de l'ethylene
AU4871279A (en) Olefin polymerization catalyst including stereoregulator
JPS5426985A (en) Manufacture of chromium oxide carrier catalyst for olefin polymerization
GB2067206B (en) Olefin polymerization using supported ziegler catalysts
AU525555B2 (en) Olefin polymerization catalysts
GB2090238B (en) Preparing aluminium phosphate gel and use thereof as a support for olefin polymerisation catalysts
AU542379B2 (en) Olefin polymerisation catalyst
AU514019B2 (en) Chromium-containing olefin polymerization catalysts
AU546319B2 (en) Catalyst for producing copolymers of ethylene
AU497619B2 (en) Catalyst for preparing highly stereoregular 2- olefin polymers
AU525413B2 (en) Preparation of ci03 catalyst for olefin polymerization