ES2905350T3 - Poliamidas a base de furano - Google Patents
Poliamidas a base de furano Download PDFInfo
- Publication number
- ES2905350T3 ES2905350T3 ES13717631T ES13717631T ES2905350T3 ES 2905350 T3 ES2905350 T3 ES 2905350T3 ES 13717631 T ES13717631 T ES 13717631T ES 13717631 T ES13717631 T ES 13717631T ES 2905350 T3 ES2905350 T3 ES 2905350T3
- Authority
- ES
- Spain
- Prior art keywords
- fiber
- polymer
- phenylenediamine
- aromatic
- derivative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 title description 21
- 239000004952 Polyamide Substances 0.000 title description 8
- 229920002647 polyamide Polymers 0.000 title description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 59
- 239000000203 mixture Substances 0.000 claims abstract description 56
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims abstract description 44
- CHTHALBTIRVDBM-UHFFFAOYSA-N furan-2,5-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)O1 CHTHALBTIRVDBM-UHFFFAOYSA-N 0.000 claims abstract description 33
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 30
- 150000004984 aromatic diamines Chemical class 0.000 claims abstract description 23
- 229940018564 m-phenylenediamine Drugs 0.000 claims abstract description 22
- 125000003118 aryl group Chemical group 0.000 claims abstract description 17
- 239000000835 fiber Substances 0.000 claims description 145
- 238000000034 method Methods 0.000 claims description 38
- 238000009987 spinning Methods 0.000 claims description 28
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 18
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 239000000178 monomer Substances 0.000 claims description 13
- 239000011541 reaction mixture Substances 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 11
- 150000004985 diamines Chemical class 0.000 claims description 11
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 10
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 6
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 claims description 6
- NUIURNJTPRWVAP-UHFFFAOYSA-N 3,3'-Dimethylbenzidine Chemical compound C1=C(N)C(C)=CC(C=2C=C(C)C(N)=CC=2)=C1 NUIURNJTPRWVAP-UHFFFAOYSA-N 0.000 claims description 5
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 5
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 claims description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 5
- XZAHJRZBUWYCBM-UHFFFAOYSA-N [1-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1(CN)CCCCC1 XZAHJRZBUWYCBM-UHFFFAOYSA-N 0.000 claims description 5
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 claims description 5
- GOGZBMRXLADNEV-UHFFFAOYSA-N naphthalene-2,6-diamine Chemical compound C1=C(N)C=CC2=CC(N)=CC=C21 GOGZBMRXLADNEV-UHFFFAOYSA-N 0.000 claims description 5
- 239000002798 polar solvent Substances 0.000 claims description 5
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 claims description 4
- 239000012298 atmosphere Substances 0.000 claims description 4
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 claims description 4
- 239000002759 woven fabric Substances 0.000 claims description 4
- 239000004745 nonwoven fabric Substances 0.000 claims description 3
- 229920003235 aromatic polyamide Polymers 0.000 description 16
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 16
- 150000003839 salts Chemical class 0.000 description 15
- 239000004744 fabric Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 10
- -1 poly(trimethylene terephthalate) Polymers 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 239000004760 aramid Substances 0.000 description 7
- DNXDYHALMANNEJ-UHFFFAOYSA-N furan-2,3-dicarboxylic acid Chemical class OC(=O)C=1C=COC=1C(O)=O DNXDYHALMANNEJ-UHFFFAOYSA-N 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- 230000015271 coagulation Effects 0.000 description 6
- 238000005345 coagulation Methods 0.000 description 6
- 238000005227 gel permeation chromatography Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 6
- 239000000292 calcium oxide Substances 0.000 description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000007378 ring spinning Methods 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 230000001112 coagulating effect Effects 0.000 description 4
- 238000000113 differential scanning calorimetry Methods 0.000 description 4
- 238000000578 dry spinning Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000002166 wet spinning Methods 0.000 description 4
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000007383 open-end spinning Methods 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 241000219146 Gossypium Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000010042 air jet spinning Methods 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000009960 carding Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000000701 coagulant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- YMWUJEATGCHHMB-DICFDUPASA-N dichloromethane-d2 Chemical compound [2H]C([2H])(Cl)Cl YMWUJEATGCHHMB-DICFDUPASA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- CTSLXHKWHWQRSH-UHFFFAOYSA-N oxalyl chloride Chemical compound ClC(=O)C(Cl)=O CTSLXHKWHWQRSH-UHFFFAOYSA-N 0.000 description 2
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XBTRYWRVOBZSGM-UHFFFAOYSA-N (4-methylphenyl)methanediamine Chemical compound CC1=CC=C(C(N)N)C=C1 XBTRYWRVOBZSGM-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- NYHNVHGFPZAZGA-UHFFFAOYSA-N 2-hydroxyhexanoic acid Chemical compound CCCCC(O)C(O)=O NYHNVHGFPZAZGA-UHFFFAOYSA-N 0.000 description 1
- JRHWHSJDIILJAT-UHFFFAOYSA-N 2-hydroxypentanoic acid Chemical compound CCCC(O)C(O)=O JRHWHSJDIILJAT-UHFFFAOYSA-N 0.000 description 1
- ULKFLOVGORAZDI-UHFFFAOYSA-N 3,3-dimethyloxetan-2-one Chemical class CC1(C)COC1=O ULKFLOVGORAZDI-UHFFFAOYSA-N 0.000 description 1
- SJZRECIVHVDYJC-UHFFFAOYSA-N 4-hydroxybutyric acid Chemical compound OCCCC(O)=O SJZRECIVHVDYJC-UHFFFAOYSA-N 0.000 description 1
- VLGDSNWNOFYURG-UHFFFAOYSA-N 4-propyloxetan-2-one Chemical compound CCCC1CC(=O)O1 VLGDSNWNOFYURG-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000009967 Erodium cicutarium Nutrition 0.000 description 1
- 240000002024 Gossypium herbaceum Species 0.000 description 1
- 235000004341 Gossypium herbaceum Nutrition 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910006124 SOCl2 Inorganic materials 0.000 description 1
- 229920013627 Sorona Polymers 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- UGUYQBMBIJFNRM-OQFOIZHKSA-N [(z)-but-2-en-2-yl]benzene Chemical compound C\C=C(\C)C1=CC=CC=C1 UGUYQBMBIJFNRM-OQFOIZHKSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000011903 deuterated solvents Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000013305 flexible fiber Substances 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 238000004895 liquid chromatography mass spectrometry Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000026676 system process Effects 0.000 description 1
- 230000010512 thermal transition Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/40—Polyamides containing oxygen in the form of ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/28—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/32—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/18—Formation of filaments, threads, or the like by means of rotating spinnerets
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
- D01F6/605—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides from aromatic polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Polyamides (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261618456P | 2012-03-30 | 2012-03-30 | |
| PCT/US2013/034666 WO2013149180A1 (en) | 2012-03-30 | 2013-03-29 | Furan based polyamides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2905350T3 true ES2905350T3 (es) | 2022-04-08 |
Family
ID=48142952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13717631T Active ES2905350T3 (es) | 2012-03-30 | 2013-03-29 | Poliamidas a base de furano |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20150044927A1 (enExample) |
| EP (2) | EP4032935A1 (enExample) |
| JP (1) | JP6185981B2 (enExample) |
| KR (1) | KR20150002703A (enExample) |
| CN (2) | CN110229512A (enExample) |
| CA (1) | CA2868286C (enExample) |
| ES (1) | ES2905350T3 (enExample) |
| HK (1) | HK1205168A1 (enExample) |
| IN (1) | IN2014DN07041A (enExample) |
| MY (1) | MY171277A (enExample) |
| SG (1) | SG11201405172UA (enExample) |
| WO (1) | WO2013149180A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3060598A1 (en) * | 2013-10-21 | 2016-08-31 | Furanix Technologies B.V. | Polyamides containing the bio-based 2,5-furandicarboxylic acid |
| US9938376B2 (en) | 2013-10-21 | 2018-04-10 | Synvina C.V. | Process for preparing a furan-based polyamide, a furan-based oligomer and compositions and articles comprising the furan-based polyamide |
| JP7278709B2 (ja) * | 2014-07-31 | 2023-05-22 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | フラン系ポリアミドおよびそれらから作製される物品 |
| KR101692987B1 (ko) * | 2015-04-01 | 2017-01-05 | 한국과학기술연구원 | 점도가 향상된 퓨란계 코폴리아미드 화합물 및 이의 제조방법 |
| PL3283470T3 (pl) | 2015-04-14 | 2024-05-06 | E I Du Pont De Nemours | Sposoby wytwarzania kwasu 2,5-furanodikarboksylowego i jego pochodnych |
| JP6723005B2 (ja) * | 2015-12-03 | 2020-07-15 | ユニチカ株式会社 | ポリアミドおよびその成形体 |
| WO2017106405A1 (en) * | 2015-12-15 | 2017-06-22 | E. I. Du Pont De Nemours And Company | A solvent-free melt polycondensation process of making furan-based polyamides |
| CN105801843A (zh) * | 2016-04-19 | 2016-07-27 | 东华大学 | 一种半生物质呋喃基可溶性芳香聚酰胺及其制备方法和应用 |
| CN106011192B (zh) * | 2016-07-22 | 2019-09-20 | 南京工业大学 | 一种基于呋喃二甲酸的生物基芳纶及其制备方法 |
| WO2018105649A1 (ja) * | 2016-12-07 | 2018-06-14 | ユニチカ株式会社 | ポリアミド |
| CN107857746B (zh) * | 2017-11-10 | 2021-04-02 | 东华大学 | 一种呋喃基二酸单体及可溶性芳香聚酰胺与可重复加工的交联聚酰胺及其制备方法和应用 |
| BR112020013857A2 (pt) | 2018-07-09 | 2020-12-01 | Hkg Epitherapeutics Limited | método de uso de uma assinatura de metilação de dna de "binário-categórica" de câncer para detectar câncer e kit para detectar pelo menos um dentre câncer, carcinoma hepatocelular (chc), câncer de pulmão, câncer de próstata, câncer de mama, câncer colorretal, câncer de pâncreas, câncer de cérebro glioblastoma, câncer gástrico (estômago), câncer de ovário, câncer cervical, carcinoma de célula escamosa de cabeça e pescoço (hnsc), carcinoma de esôfago, câncer de bexiga, câncer de rim renal, câncer testicular, tumores sólidos comuns, leucemia mielóide aguda (lma) e melanoma |
| CN110229329A (zh) * | 2019-05-13 | 2019-09-13 | 中国科学技术大学 | 一种高聚合度半生物质基呋喃聚酰胺树脂连续生产装置及连续生产方法 |
| CN110256668B (zh) * | 2019-06-04 | 2021-12-10 | 中国科学技术大学 | 高分子量呋喃基芳香聚酰胺及其制备方法和应用 |
| IL324962A (en) | 2019-11-27 | 2026-01-01 | Gi Innovation Inc | Pharmaceutical preparation for the treatment of cancer containing a fusion protein containing 2-il protein and 80cd protein and an immune checkpoint inhibitor |
| JP7626612B2 (ja) * | 2020-12-24 | 2025-02-04 | 旭化成株式会社 | ポリアミド組成物及び成形体 |
| CN113896886B (zh) * | 2021-09-24 | 2023-07-25 | 珠海万通特种工程塑料有限公司 | 一种呋喃二酸基聚酰胺及其制备方法和一种呋喃二酸基聚酰胺组合物 |
| CN114249890B (zh) * | 2021-12-02 | 2023-02-21 | 南京工业大学 | 一种生物基聚酯酰胺及其制备方法 |
| JP7432252B2 (ja) * | 2022-02-08 | 2024-02-16 | 平岡織染株式会社 | 軟質塩化ビニル系樹脂複合シート |
| CN114891206A (zh) * | 2022-05-06 | 2022-08-12 | 中国科学技术大学先进技术研究院 | 生物基耐热包装膜原液的制备方法及生物基耐热包装膜原液的应用 |
| CN115160561A (zh) * | 2022-06-29 | 2022-10-11 | 浙江中科玖源新材料有限公司 | 一种呋喃基芳香族聚酰胺和其聚酰胺膜 |
| JP2024078923A (ja) * | 2022-11-30 | 2024-06-11 | 大阪瓦斯株式会社 | 芳香族ポリアミド系樹脂およびその製造方法 |
| CN116217920A (zh) * | 2023-03-22 | 2023-06-06 | 中国科学院宁波材料技术与工程研究所 | 基于呋喃环的芳香族聚酰胺及其制备方法与应用 |
| CN116284756B (zh) * | 2023-04-18 | 2024-05-31 | 南京工业大学 | 一种基于微反应装置制备生物基半芳香族聚酰胺的方法 |
| CN116575138B (zh) * | 2023-04-20 | 2025-08-19 | 中科国生(杭州)科技有限公司 | 一种生物基芳香聚酰胺纤维的制备方法 |
| CN116462838B (zh) * | 2023-06-15 | 2023-09-05 | 烟台泰和新材高分子新材料研究院有限公司 | 一种聚合物及其制备方法和用途 |
| CN117604676B (zh) * | 2023-11-30 | 2024-09-10 | 江苏欣鑫纺织科技有限公司 | 一种抗拉锦纶纤维及其制备方法 |
| CN120842841B (zh) * | 2025-07-08 | 2026-05-26 | 深圳市嘉凯勒实业有限公司 | 一种耐高温的生物基尼龙及其制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3063966A (en) | 1958-02-05 | 1962-11-13 | Du Pont | Process of making wholly aromatic polyamides |
| US4973442A (en) | 1985-09-26 | 1990-11-27 | Foster Miller Inc. | Forming biaxially oriented ordered polymer films |
| US4939235A (en) | 1985-09-26 | 1990-07-03 | Foster-Miller, Inc. | Biaxially oriented ordered polybenzothiazole film |
| US4898924A (en) | 1989-01-11 | 1990-02-06 | Hoechst Celanese Corporation | Process for the production of biaxially oriented rigid rod heterocyclic liquid crystalline polymer films |
| DE59207726D1 (de) * | 1991-02-26 | 1997-01-30 | Hoechst Ag | Aromatische copolyamide, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von geformten gebilden |
| DE59206996D1 (de) * | 1991-10-26 | 1996-10-02 | Hoechst Ag | Hydrophile, asymmetrische, chemikalienbeständige Polyaramidmembran |
| US5367042A (en) | 1992-08-27 | 1994-11-22 | The Dow Chemical Company | Process for fabricating oriented polybenzazole films |
| US5667743A (en) | 1996-05-21 | 1997-09-16 | E. I. Du Pont De Nemours And Company | Wet spinning process for aramid polymer containing salts |
| CN101311396A (zh) | 1999-06-14 | 2008-11-26 | 纳幕尔杜邦公司 | 拉断法和产品 |
| JP2009001630A (ja) * | 2007-06-20 | 2009-01-08 | Canon Inc | 高分子化合物、その製造方法、及び成形品用組成物 |
-
2013
- 2013-03-29 SG SG11201405172UA patent/SG11201405172UA/en unknown
- 2013-03-29 CN CN201910479463.3A patent/CN110229512A/zh active Pending
- 2013-03-29 IN IN7041DEN2014 patent/IN2014DN07041A/en unknown
- 2013-03-29 WO PCT/US2013/034666 patent/WO2013149180A1/en not_active Ceased
- 2013-03-29 ES ES13717631T patent/ES2905350T3/es active Active
- 2013-03-29 MY MYPI2014002413A patent/MY171277A/en unknown
- 2013-03-29 EP EP21209673.9A patent/EP4032935A1/en not_active Withdrawn
- 2013-03-29 CA CA2868286A patent/CA2868286C/en active Active
- 2013-03-29 EP EP13717631.9A patent/EP2831145B1/en not_active Not-in-force
- 2013-03-29 US US14/385,915 patent/US20150044927A1/en not_active Abandoned
- 2013-03-29 CN CN201380017343.2A patent/CN104245793A/zh active Pending
- 2013-03-29 JP JP2015503656A patent/JP6185981B2/ja not_active Expired - Fee Related
- 2013-03-29 HK HK15105903.8A patent/HK1205168A1/xx unknown
- 2013-03-29 KR KR1020147030082A patent/KR20150002703A/ko not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013149180A1 (en) | 2013-10-03 |
| CA2868286C (en) | 2024-01-09 |
| EP4032935A1 (en) | 2022-07-27 |
| CN110229512A (zh) | 2019-09-13 |
| IN2014DN07041A (enExample) | 2015-04-10 |
| JP6185981B2 (ja) | 2017-08-23 |
| HK1205168A1 (en) | 2015-12-11 |
| SG11201405172UA (en) | 2014-09-26 |
| EP2831145A1 (en) | 2015-02-04 |
| MY171277A (en) | 2019-10-07 |
| CN104245793A (zh) | 2014-12-24 |
| US20150044927A1 (en) | 2015-02-12 |
| CA2868286A1 (en) | 2013-10-03 |
| KR20150002703A (ko) | 2015-01-07 |
| EP2831145B1 (en) | 2022-01-05 |
| JP2015514150A (ja) | 2015-05-18 |
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