ES2813575T3 - Impresión 3D de materiales compuestos de grafeno (óxido) - Google Patents
Impresión 3D de materiales compuestos de grafeno (óxido) Download PDFInfo
- Publication number
- ES2813575T3 ES2813575T3 ES16710677T ES16710677T ES2813575T3 ES 2813575 T3 ES2813575 T3 ES 2813575T3 ES 16710677 T ES16710677 T ES 16710677T ES 16710677 T ES16710677 T ES 16710677T ES 2813575 T3 ES2813575 T3 ES 2813575T3
- Authority
- ES
- Spain
- Prior art keywords
- printed
- printable
- electrically conductive
- graphene
- printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 166
- 229910021389 graphene Inorganic materials 0.000 title claims description 102
- 238000010146 3D printing Methods 0.000 title description 19
- 239000002131 composite material Substances 0.000 title description 11
- 239000000463 material Substances 0.000 claims abstract description 374
- 238000000034 method Methods 0.000 claims abstract description 60
- 238000007639 printing Methods 0.000 claims abstract description 45
- 230000008021 deposition Effects 0.000 claims abstract description 18
- 238000010292 electrical insulation Methods 0.000 claims abstract description 12
- 229910002804 graphite Inorganic materials 0.000 claims description 63
- 239000010439 graphite Substances 0.000 claims description 63
- 230000005855 radiation Effects 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 9
- 230000005611 electricity Effects 0.000 claims description 7
- 230000001678 irradiating effect Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 description 52
- 239000004020 conductor Substances 0.000 description 40
- 238000005325 percolation Methods 0.000 description 33
- 238000006243 chemical reaction Methods 0.000 description 19
- 238000000151 deposition Methods 0.000 description 17
- 239000002243 precursor Substances 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 14
- 239000000654 additive Substances 0.000 description 11
- 230000000996 additive effect Effects 0.000 description 11
- 239000010410 layer Substances 0.000 description 11
- 238000002844 melting Methods 0.000 description 11
- 230000008018 melting Effects 0.000 description 11
- 230000008569 process Effects 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 7
- 230000009471 action Effects 0.000 description 6
- 239000012777 electrically insulating material Substances 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 239000011810 insulating material Substances 0.000 description 4
- 239000012212 insulator Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 238000002679 ablation Methods 0.000 description 3
- 238000005253 cladding Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 230000014509 gene expression Effects 0.000 description 3
- 238000007641 inkjet printing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000012811 non-conductive material Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000010793 electronic waste Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- -1 for example Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 238000003913 materials processing Methods 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/118—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/141—Processes of additive manufacturing using only solid materials
- B29C64/153—Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2507/00—Use of elements other than metals as filler
- B29K2507/04—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0003—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular electrical or magnetic properties, e.g. piezoelectric
- B29K2995/0005—Conductive
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Mechanical Engineering (AREA)
- Conductive Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Manufacturing Of Printed Wiring (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15157997 | 2015-03-06 | ||
| PCT/EP2016/053507 WO2016142147A1 (en) | 2015-03-06 | 2016-02-19 | 3d printing of graphene (oxide) composites |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2813575T3 true ES2813575T3 (es) | 2021-03-24 |
Family
ID=52627092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES16710677T Active ES2813575T3 (es) | 2015-03-06 | 2016-02-19 | Impresión 3D de materiales compuestos de grafeno (óxido) |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11090860B2 (OSRAM) |
| EP (1) | EP3265293B1 (OSRAM) |
| JP (1) | JP6783784B2 (OSRAM) |
| CN (1) | CN107428085B (OSRAM) |
| ES (1) | ES2813575T3 (OSRAM) |
| WO (1) | WO2016142147A1 (OSRAM) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160099116A1 (en) * | 2014-10-05 | 2016-04-07 | Yongzhi Yang | Methods and apparatus for the production of capacitor with electrodes made of interconnected corrugated carbon-based network |
| US11376785B2 (en) | 2017-08-11 | 2022-07-05 | Signify Holding B.V. | Method for manufacturing a 3D item having an electrically conductive coil |
| GB2566053A (en) * | 2017-08-31 | 2019-03-06 | Weston Aerospace Ltd | Sensor and method of manufacturing same |
| ES3049653T3 (en) * | 2017-11-15 | 2025-12-17 | Airbus Operations Slu | Driling template |
| CN111801050B (zh) * | 2018-03-08 | 2024-03-08 | 美国西门子医疗系统股份有限公司 | 使用增添方法的准直器的三维打印的系统和方法 |
| EP3552806A1 (en) | 2018-04-09 | 2019-10-16 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Method of apparatus for forming an object by means of additive manufacturing |
| CN108516730A (zh) * | 2018-04-19 | 2018-09-11 | 中国科学院福建物质结构研究所 | 一种基于粘结剂喷射3d打印的组合物、制备及其应用 |
| US10987857B2 (en) * | 2018-05-14 | 2021-04-27 | Rolls-Royce Corporation | Additively manufactured polymeric components |
| WO2020007877A1 (en) | 2018-07-02 | 2020-01-09 | Dassi Limited | Movable items and wearable items worn by users of the same, and systems and methods for monitoring or controlling operation of movable items |
| CN110044972A (zh) * | 2019-04-18 | 2019-07-23 | 厦门理工学院 | 一种石墨烯基气敏传感器及其制备方法 |
| US11799183B2 (en) * | 2019-07-17 | 2023-10-24 | Xerox Corporation | System, apparatus, and method for producing printed electrically conductive lines |
| US11584086B2 (en) * | 2019-12-20 | 2023-02-21 | Xerox Corporation | Particles comprising marking additives for selective laser sintering-based manufacturing systems |
| US11433605B2 (en) * | 2019-12-20 | 2022-09-06 | Xerox Corporation | Filament materials comprising marking additives for extrusion-based additive manufacturing systems |
| US11812561B2 (en) * | 2020-04-08 | 2023-11-07 | Schlumberger Technology Corporation | Thermally induced graphene sensing circuitry on intelligent valves, actuators, and pressure sealing applications |
| US12365152B2 (en) * | 2020-05-04 | 2025-07-22 | The United States Of America As Represented By The Secretary Of The Army | Photonic annealing of electrically-conductive thermoplastics |
| DE102021000576A1 (de) | 2021-02-04 | 2022-08-04 | Bundesrepublik Deutschland, vertr. durch das Bundesministerium der Verteidigung, vertr. durch das Bundesamt für Ausrüstung, Informationstechnik und Nutzung der Bundeswehr | Verfahren zur Herstellung eines Bauteils mit elektrisch leitenden Schichten |
| US11554537B2 (en) | 2021-02-09 | 2023-01-17 | Xerox Corporation | Polymer filaments comprising a metal precursor for additive manufacturing and methods associated therewith |
| US20230395913A1 (en) * | 2022-06-07 | 2023-12-07 | Xerox Corporation | Filament sealing layer for biodegradable electrochemical device and methods thereof |
| DE102022004141B3 (de) | 2022-11-08 | 2023-11-02 | Bundesrepublik Deutschland (Bundesamt für Ausrüstung, Informationstechnik und Nutzung der Bundeswehr) | Verfahren zur Herstellung eines Bauteils mit gezielt eingebrachten Rußpartikeln |
| DE102023100450A1 (de) * | 2023-01-10 | 2024-07-11 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Verfahren und Herstellungssystem zur additiven Herstellung einer Schaltungseinheit sowie Schaltungseinheit |
| SE547774C2 (en) * | 2023-03-30 | 2025-11-25 | Northvolt Ab | Method for manufacturing an electrode for a secondary cell |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5622216A (en) * | 1994-11-22 | 1997-04-22 | Brown; Stuart B. | Method and apparatus for metal solid freeform fabrication utilizing partially solidified metal slurry |
| JPH10303061A (ja) * | 1997-04-25 | 1998-11-13 | Matsushita Electric Ind Co Ltd | 加熱導電性絶縁材料およびその加熱方法 |
| CN1167300A (zh) * | 1997-05-27 | 1997-12-10 | 中国航天工业总公司第一研究院第十三研究所 | 用能量场进行三维物体制造成型的方法和系统 |
| DE10221100C1 (de) * | 2002-05-03 | 2003-06-05 | Neuhaus Elektronik Gmbh | Elektrisch leitfähige Dichtung sowie Verfahren und Vorrichtung zu deren Herstellung |
| US9518188B2 (en) | 2010-11-15 | 2016-12-13 | John S. Lettow | Method of printing a conductive article and articles made thereby |
| US8810996B2 (en) | 2010-11-22 | 2014-08-19 | The Trustees Of The Stevens Institute Of Technology | Inkjet-printed flexible electronic components from graphene oxide |
| EP2457719A1 (en) | 2010-11-24 | 2012-05-30 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Interconnect structure and method for producing same |
| CN108058373B (zh) * | 2011-04-17 | 2021-03-16 | 斯特拉塔西斯有限公司 | 用于对象的增材制造的系统和方法 |
| WO2013040636A1 (en) | 2011-09-19 | 2013-03-28 | University Of Wollongong | Reduced graphene oxide and method of producing same |
| US20140265035A1 (en) * | 2013-03-13 | 2014-09-18 | Makerbot Industries, Llc | Three-dimensional printing with control of thermoalterable build materials |
| WO2014168979A1 (en) | 2013-04-08 | 2014-10-16 | Vorbeck Materials | Use of graphene-containing polymer composites |
| US10166751B2 (en) | 2013-06-14 | 2019-01-01 | Lawrence Livermore National Security, Llc | Method for enhanced additive manufacturing |
| CA2915409A1 (en) * | 2013-06-24 | 2014-12-31 | President And Fellows Of Harvard College | Printed three-dimensional (3d) functional part and method of making |
| US20150197063A1 (en) * | 2014-01-12 | 2015-07-16 | Zohar SHINAR | Device, method, and system of three-dimensional printing |
| CN103980705B (zh) * | 2014-04-30 | 2016-02-24 | 中国科学院化学研究所 | 一种适合3d打印的高性能聚酰亚胺模塑粉材料及其3d打印成型方法 |
| CN103980489B (zh) * | 2014-04-30 | 2018-08-31 | 中国科学院化学研究所 | 一种低熔体黏度热塑性聚酰亚胺材料及其3d打印成型方法 |
-
2016
- 2016-02-19 WO PCT/EP2016/053507 patent/WO2016142147A1/en not_active Ceased
- 2016-02-19 EP EP16710677.2A patent/EP3265293B1/en active Active
- 2016-02-19 CN CN201680013999.0A patent/CN107428085B/zh active Active
- 2016-02-19 US US15/554,175 patent/US11090860B2/en active Active
- 2016-02-19 JP JP2017546139A patent/JP6783784B2/ja active Active
- 2016-02-19 ES ES16710677T patent/ES2813575T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20180079132A1 (en) | 2018-03-22 |
| CN107428085A (zh) | 2017-12-01 |
| WO2016142147A1 (en) | 2016-09-15 |
| CN107428085B (zh) | 2020-04-17 |
| EP3265293B1 (en) | 2020-06-24 |
| EP3265293A1 (en) | 2018-01-10 |
| US11090860B2 (en) | 2021-08-17 |
| JP2018512302A (ja) | 2018-05-17 |
| JP6783784B2 (ja) | 2020-11-11 |
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