ES2731815T3 - Proceso para la preparación de un material zeolítico que contiene titanio que tiene una estructura de entramado MWW - Google Patents
Proceso para la preparación de un material zeolítico que contiene titanio que tiene una estructura de entramado MWW Download PDFInfo
- Publication number
- ES2731815T3 ES2731815T3 ES14703328T ES14703328T ES2731815T3 ES 2731815 T3 ES2731815 T3 ES 2731815T3 ES 14703328 T ES14703328 T ES 14703328T ES 14703328 T ES14703328 T ES 14703328T ES 2731815 T3 ES2731815 T3 ES 2731815T3
- Authority
- ES
- Spain
- Prior art keywords
- zeolitic material
- titanium
- mww
- range
- framework structure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 389
- 239000010936 titanium Substances 0.000 title claims abstract description 236
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 230
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 230
- 238000000034 method Methods 0.000 title claims abstract description 192
- 230000008569 process Effects 0.000 title claims abstract description 178
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 148
- 239000000203 mixture Substances 0.000 claims abstract description 116
- 238000001035 drying Methods 0.000 claims abstract description 99
- 238000001694 spray drying Methods 0.000 claims abstract description 81
- 239000012452 mother liquor Substances 0.000 claims abstract description 67
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 58
- 150000001875 compounds Chemical class 0.000 claims abstract description 57
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 40
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 40
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 40
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 40
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 40
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 31
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 31
- 230000002194 synthesizing effect Effects 0.000 claims abstract description 8
- 239000007921 spray Substances 0.000 claims description 191
- 239000000843 powder Substances 0.000 claims description 119
- 239000007789 gas Substances 0.000 claims description 115
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 101
- 239000000725 suspension Substances 0.000 claims description 91
- 229910052757 nitrogen Inorganic materials 0.000 claims description 77
- 239000002243 precursor Substances 0.000 claims description 61
- 229910052710 silicon Inorganic materials 0.000 claims description 59
- 229910052796 boron Inorganic materials 0.000 claims description 58
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 57
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 56
- 239000010703 silicon Substances 0.000 claims description 56
- 238000001354 calcination Methods 0.000 claims description 50
- 239000007788 liquid Substances 0.000 claims description 49
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 48
- 239000007864 aqueous solution Substances 0.000 claims description 46
- 239000002904 solvent Substances 0.000 claims description 43
- 239000003054 catalyst Substances 0.000 claims description 40
- 239000002245 particle Substances 0.000 claims description 38
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 36
- 239000011230 binding agent Substances 0.000 claims description 32
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 23
- 238000005406 washing Methods 0.000 claims description 23
- 229910052799 carbon Inorganic materials 0.000 claims description 21
- 239000007787 solid Substances 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 20
- 229910017604 nitric acid Inorganic materials 0.000 claims description 20
- 238000006735 epoxidation reaction Methods 0.000 claims description 18
- 150000007522 mineralic acids Chemical class 0.000 claims description 17
- 238000002371 ultraviolet--visible spectrum Methods 0.000 claims description 16
- 239000007900 aqueous suspension Substances 0.000 claims description 15
- 239000011148 porous material Substances 0.000 claims description 12
- 239000012018 catalyst precursor Substances 0.000 claims description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 10
- 238000010348 incorporation Methods 0.000 claims description 10
- 238000002459 porosimetry Methods 0.000 claims description 9
- 239000011701 zinc Substances 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 claims description 7
- DRFAYKHQCXTCER-UHFFFAOYSA-M heptyl(trimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCC[N+](C)(C)C DRFAYKHQCXTCER-UHFFFAOYSA-M 0.000 claims description 7
- LYYFCMKDHSQLMB-UHFFFAOYSA-M hexyl(trimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCC[N+](C)(C)C LYYFCMKDHSQLMB-UHFFFAOYSA-M 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- STYCVOUVPXOARC-UHFFFAOYSA-M trimethyl(octyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCC[N+](C)(C)C STYCVOUVPXOARC-UHFFFAOYSA-M 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- SBXORXZXXUXJIE-UHFFFAOYSA-N butane 1-methylpyrrolidine Chemical compound CCCC.CN1CCCC1 SBXORXZXXUXJIE-UHFFFAOYSA-N 0.000 claims description 6
- 125000005842 heteroatom Chemical group 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- 239000010970 precious metal Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 3
- GRWPYGBKJYICOO-UHFFFAOYSA-N 2-methylpropan-2-olate;titanium(4+) Chemical compound [Ti+4].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-] GRWPYGBKJYICOO-UHFFFAOYSA-N 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 102
- 238000003756 stirring Methods 0.000 description 60
- 238000001914 filtration Methods 0.000 description 50
- 239000012065 filter cake Substances 0.000 description 38
- 239000008367 deionised water Substances 0.000 description 35
- 229910021641 deionized water Inorganic materials 0.000 description 35
- 238000001027 hydrothermal synthesis Methods 0.000 description 22
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- 239000002253 acid Substances 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 18
- 238000010306 acid treatment Methods 0.000 description 18
- 239000008119 colloidal silica Substances 0.000 description 15
- 238000002425 crystallisation Methods 0.000 description 15
- 230000008025 crystallization Effects 0.000 description 15
- 238000000926 separation method Methods 0.000 description 15
- 238000012512 characterization method Methods 0.000 description 14
- 238000009826 distribution Methods 0.000 description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 12
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 12
- 238000010992 reflux Methods 0.000 description 12
- 238000000889 atomisation Methods 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- 239000004327 boric acid Substances 0.000 description 10
- 150000007524 organic acids Chemical class 0.000 description 10
- 238000001179 sorption measurement Methods 0.000 description 10
- 239000007858 starting material Substances 0.000 description 10
- 229920000784 Nomex Polymers 0.000 description 9
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 9
- 239000004763 nomex Substances 0.000 description 9
- 235000011007 phosphoric acid Nutrition 0.000 description 9
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 9
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000004146 Propane-1,2-diol Substances 0.000 description 6
- 235000011054 acetic acid Nutrition 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 229960005150 glycerol Drugs 0.000 description 6
- 235000006408 oxalic acid Nutrition 0.000 description 6
- 229960004063 propylene glycol Drugs 0.000 description 6
- 235000013772 propylene glycol Nutrition 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 150000005846 sugar alcohols Polymers 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000011026 diafiltration Methods 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 235000019253 formic acid Nutrition 0.000 description 4
- 229910021485 fumed silica Inorganic materials 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910000510 noble metal Inorganic materials 0.000 description 4
- 235000019260 propionic acid Nutrition 0.000 description 4
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 4
- 239000011975 tartaric acid Substances 0.000 description 4
- 235000002906 tartaric acid Nutrition 0.000 description 4
- 238000000108 ultra-filtration Methods 0.000 description 4
- GNUJKXOGRSTACR-UHFFFAOYSA-M 1-adamantyl(trimethyl)azanium;hydroxide Chemical compound [OH-].C1C(C2)CC3CC2CC1([N+](C)(C)C)C3 GNUJKXOGRSTACR-UHFFFAOYSA-M 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229920000995 Spectralon Polymers 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- -1 boron halide Chemical class 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 230000008030 elimination Effects 0.000 description 3
- 238000003379 elimination reaction Methods 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 101100055113 Caenorhabditis elegans aho-3 gene Proteins 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000007809 chemical reaction catalyst Substances 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229940098779 methanesulfonic acid Drugs 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 229910001680 bayerite Inorganic materials 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 125000005619 boric acid group Chemical group 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000002036 drum drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 229910001679 gibbsite Inorganic materials 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
- C01B39/085—Group IVB- metallosilicates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13154021 | 2013-02-05 | ||
| PCT/EP2014/052205 WO2014122152A1 (en) | 2013-02-05 | 2014-02-05 | Process for preparing a titanium-containing zeolitic material having an mww framework structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2731815T3 true ES2731815T3 (es) | 2019-11-19 |
Family
ID=47665985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES14703328T Active ES2731815T3 (es) | 2013-02-05 | 2014-02-05 | Proceso para la preparación de un material zeolítico que contiene titanio que tiene una estructura de entramado MWW |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US10029244B2 (enExample) |
| EP (1) | EP2953895B1 (enExample) |
| JP (2) | JP6491604B2 (enExample) |
| KR (1) | KR102210984B1 (enExample) |
| CN (2) | CN105408253A (enExample) |
| BR (1) | BR112015018003B1 (enExample) |
| ES (1) | ES2731815T3 (enExample) |
| HU (1) | HUE043845T2 (enExample) |
| MX (1) | MX377403B (enExample) |
| MY (1) | MY182905A (enExample) |
| PL (1) | PL2953895T3 (enExample) |
| RU (1) | RU2650973C2 (enExample) |
| SG (2) | SG10201705892RA (enExample) |
| WO (1) | WO2014122152A1 (enExample) |
| ZA (1) | ZA201506447B (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017533981A (ja) | 2014-10-14 | 2017-11-16 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 香料としてのヘキサデカ−８，１５−ジエナールの使用 |
| US10704794B2 (en) | 2015-04-07 | 2020-07-07 | Brown University | Apparatus and method for passively cooling an interior |
| US20180224137A1 (en) * | 2015-04-07 | 2018-08-09 | Brown University | Apparatus and method for passively cooling an interior |
| WO2017009458A1 (en) | 2015-07-15 | 2017-01-19 | Basf Se | Process for preparing an arylpropene |
| JP2018522007A (ja) | 2015-07-15 | 2018-08-09 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | アリールプロペンの調製方法 |
| ES2907869T3 (es) * | 2016-09-06 | 2022-04-26 | Basf Se | Síntesis térmica de sólidos de una zeolita que contiene boro con una estructura de entramado MWW. |
| US10981796B2 (en) * | 2016-12-13 | 2021-04-20 | Basf Se | Process for the preparation of a titanium-containing zeolite |
| CN110087768B (zh) * | 2016-12-20 | 2023-09-01 | 巴斯夫欧洲公司 | 酸处理以使包含具有mww骨架类型的含钛沸石材料的组合物的可塑性降低的用途 |
| MY199941A (en) * | 2016-12-20 | 2023-11-30 | Basf Se | Process for preparing an extrudable composition comprising a titanium-containing zeolitic material, having framework type mww |
| US10780432B2 (en) | 2017-01-18 | 2020-09-22 | Basf Se | Process for preparing a molding comprising zinc and a titanium-containing zeolite |
| US10053368B1 (en) * | 2017-09-07 | 2018-08-21 | Chevron U.S.A. Inc. | Synthesis of AFX framework type molecular sieves |
| DE102018205122A1 (de) | 2018-04-05 | 2018-10-25 | Basf Se | Verfahren zur Herstellung von Acrylsäurederivaten mittels oxidativer Kondensation aus Essigsäurederivaten |
| WO2020047525A1 (en) | 2018-08-31 | 2020-03-05 | Techstyle Materials, Inc. | Multifunctional system for passive heat and water management |
| KR102244509B1 (ko) * | 2018-12-27 | 2021-04-23 | 고려대학교 산학협력단 | 폐수처리용 촉매, 이의 제조방법 및 이를 이용한 폐수처리 방법 |
| CN110078094A (zh) * | 2019-04-15 | 2019-08-02 | 华东师范大学 | 一种层间扩层的mww结构分子筛的制备方法 |
| US12195755B2 (en) | 2019-05-20 | 2025-01-14 | Brown University | Placental lipid bilayer for cell-free molecular interaction studies |
| CN110420134B (zh) * | 2019-08-28 | 2022-04-15 | 广州骏朗生物科技有限公司 | 一种片状硅石/纳米TiO2复合材料及其制备方法 |
| WO2021087008A1 (en) | 2019-10-28 | 2021-05-06 | Brown University | Bacterial beta-lactamase responsive hydrogels |
| KR102408100B1 (ko) * | 2021-05-31 | 2022-06-15 | 충북대학교 산학협력단 | 메탄의 건식 개질 반응용 2차원 니켈 실리케이트 분자체 촉매의 제조방법 및 이에 따라 제조된 메탄의 건식 개질 반응용 2차원 니켈 실리케이트 분자체 촉매 |
| EP4634142A1 (en) | 2022-12-13 | 2025-10-22 | Basf Se | Process for the production of an alkylstyrene and of an alkylphenyl propionic acid |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1485321A (en) | 1919-05-26 | 1924-02-26 | Elgin Nat Watch Co | Device for lapping gauges |
| JPH0228774A (ja) | 1988-07-18 | 1990-01-30 | Anritsu Corp | 多点測定パタンの入力方法 |
| AU2549295A (en) * | 1995-03-17 | 1996-10-08 | Chevron U.S.A. Inc. | Preparation of zeolites using organic template and amine |
| JP2002102709A (ja) | 2000-09-29 | 2002-04-09 | Showa Denko Kk | 酸化化合物製造用結晶性ｍｗｗ型チタノシリケート触媒、該触媒の製造方法、及び該触媒を用いた酸化化合物の製造方法 |
| US7011802B2 (en) | 2000-12-22 | 2006-03-14 | California Institute Of Technology | Synthesis of molecular sieves by hydrothermal treatment with acid |
| JP4241068B2 (ja) | 2002-03-07 | 2009-03-18 | 昭和電工株式会社 | Ｍｗｗ型ゼオライト物質の製造方法 |
| US7323154B2 (en) * | 2002-03-07 | 2008-01-29 | Showa Denko K.K. | Titanosilicate, process for its production, and its use in producing oxidized compound |
| JP4270901B2 (ja) * | 2002-03-07 | 2009-06-03 | 昭和電工株式会社 | チタノシリケート、その製造方法およびチタノシリケートを用いた酸化化合物の製造方法 |
| DE10232406A1 (de) | 2002-07-17 | 2004-01-29 | Basf Ag | Verfahren zur Herstellung eines zeolithhaltigen Feststoffes |
| US20040054199A1 (en) | 2002-09-17 | 2004-03-18 | Basf Aktiengesellschaft | Process for epoxidation and catalyst to be used therein |
| DE602004009758T2 (de) * | 2003-02-03 | 2008-08-28 | Showa Denko K.K. | Modifiziertes schichtförmiges metallosilicatmaterial und herstellungsverfahren dafür |
| DE10320635A1 (de) | 2003-05-08 | 2004-11-18 | Basf Ag | Verfahren zur Herstellung von Propylenoxid |
| JP2007502828A (ja) | 2003-08-21 | 2007-02-15 | ファイザー・プロダクツ・インク | 神経変性性疾患の治療のための化合物 |
| US7273826B2 (en) * | 2005-07-26 | 2007-09-25 | Lyondell Chemical Technology, L.P. | Epoxidation catalyst |
| JP2008200553A (ja) * | 2007-02-16 | 2008-09-04 | Sumitomo Chemical Co Ltd | チタノシリケート触媒 |
| MX339546B (es) | 2009-11-27 | 2016-05-30 | Basf Se | Proceso para la preparacion de un catalizador de zeolita de titanio. |
| US8124555B2 (en) | 2010-02-01 | 2012-02-28 | Lyondell Chemical Technology L.P. | Process for making titanium-MWW zeolite |
| JP5879339B2 (ja) | 2010-06-18 | 2016-03-08 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Ｌｅｖ型構造ゼオライト系材料の製造用の有機テンプレート不使用合成方法 |
| KR20140057473A (ko) | 2010-11-23 | 2014-05-13 | 릴라이언스 인더스트리즈 리미티드 | Ｍｗｗ형 제올라이트 제조 방법 |
| JP2012236177A (ja) * | 2011-05-13 | 2012-12-06 | Sumitomo Chemical Co Ltd | チタノシリケート含有触媒の製造方法 |
| ES2988632T3 (es) * | 2012-02-07 | 2024-11-21 | Basf Se | Moldura que contiene un material zeolítico tipo mww que contiene ti y zn y su uso como catalizador |
-
2014
- 2014-02-05 SG SG10201705892RA patent/SG10201705892RA/en unknown
- 2014-02-05 MX MX2015010047A patent/MX377403B/es active IP Right Grant
- 2014-02-05 WO PCT/EP2014/052205 patent/WO2014122152A1/en not_active Ceased
- 2014-02-05 MY MYPI2015001945A patent/MY182905A/en unknown
- 2014-02-05 KR KR1020157024156A patent/KR102210984B1/ko active Active
- 2014-02-05 PL PL14703328T patent/PL2953895T3/pl unknown
- 2014-02-05 RU RU2015137732A patent/RU2650973C2/ru active
- 2014-02-05 JP JP2015556478A patent/JP6491604B2/ja active Active
- 2014-02-05 BR BR112015018003-5A patent/BR112015018003B1/pt active IP Right Grant
- 2014-02-05 SG SG11201506135WA patent/SG11201506135WA/en unknown
- 2014-02-05 HU HUE14703328A patent/HUE043845T2/hu unknown
- 2014-02-05 ES ES14703328T patent/ES2731815T3/es active Active
- 2014-02-05 EP EP14703328.6A patent/EP2953895B1/en active Active
- 2014-02-05 CN CN201480020219.6A patent/CN105408253A/zh active Pending
- 2014-02-05 US US14/764,354 patent/US10029244B2/en active Active
- 2014-02-05 CN CN201910169392.7A patent/CN110002463B/zh active Active
-
2015
- 2015-09-03 ZA ZA2015/06447A patent/ZA201506447B/en unknown
-
2019
- 2019-02-27 JP JP2019033624A patent/JP6955815B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| MX377403B (es) | 2025-03-07 |
| MX2015010047A (es) | 2016-03-04 |
| MY182905A (en) | 2021-02-05 |
| BR112015018003B1 (pt) | 2021-12-28 |
| SG11201506135WA (en) | 2015-11-27 |
| KR20150115909A (ko) | 2015-10-14 |
| EP2953895B1 (en) | 2019-03-20 |
| JP2016506904A (ja) | 2016-03-07 |
| JP2019112301A (ja) | 2019-07-11 |
| HUE043845T2 (hu) | 2019-09-30 |
| US10029244B2 (en) | 2018-07-24 |
| ZA201506447B (en) | 2020-01-29 |
| JP6491604B2 (ja) | 2019-03-27 |
| CN110002463A (zh) | 2019-07-12 |
| CN110002463B (zh) | 2022-10-11 |
| PL2953895T3 (pl) | 2019-09-30 |
| WO2014122152A1 (en) | 2014-08-14 |
| BR112015018003A2 (pt) | 2017-07-11 |
| RU2650973C2 (ru) | 2018-04-18 |
| CN105408253A (zh) | 2016-03-16 |
| KR102210984B1 (ko) | 2021-02-02 |
| JP6955815B2 (ja) | 2021-10-27 |
| SG10201705892RA (en) | 2017-08-30 |
| RU2015137732A (ru) | 2017-03-14 |
| US20150368115A1 (en) | 2015-12-24 |
| EP2953895A1 (en) | 2015-12-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2731815T3 (es) | Proceso para la preparación de un material zeolítico que contiene titanio que tiene una estructura de entramado MWW | |
| ES2988632T3 (es) | Moldura que contiene un material zeolítico tipo mww que contiene ti y zn y su uso como catalizador | |
| ES2935820T3 (es) | Un material zeolítico MWW desborado | |
| ES2970242T3 (es) | Regeneración de una zeolita que contiene titanio | |
| KR102469448B1 (ko) | 붕소 및 티타늄을 포함하는 mww 제올라이트 물질의 제조 방법 | |
| ES2907275T3 (es) | Un material zeolítico que contiene estaño y que tiene una estructura de marco de tipo mww | |
| ES2620030T3 (es) | Postratamiento de la zeolita MWW sin boro | |
| ES2894074T3 (es) | Proceso para preparar material zeolítico que contiene boro con estructura marco MWW | |
| ES2621510T3 (es) | Un material zeolítico que contiene estaño que tiene una estructura de marco de tipo MWW | |
| US9296715B2 (en) | Micropowder and molding containing a zeolitic material containing Ti and Zn | |
| ES2641843T3 (es) | Procedimiento de oxidación de compuestos orgánicos de carbonilo |