ES2655195T3 - Eliminación sinérgica de manchas mediante una combinación de quelantes nuevos - Google Patents
Eliminación sinérgica de manchas mediante una combinación de quelantes nuevos Download PDFInfo
- Publication number
- ES2655195T3 ES2655195T3 ES13762438.3T ES13762438T ES2655195T3 ES 2655195 T3 ES2655195 T3 ES 2655195T3 ES 13762438 T ES13762438 T ES 13762438T ES 2655195 T3 ES2655195 T3 ES 2655195T3
- Authority
- ES
- Spain
- Prior art keywords
- detergent composition
- ppm
- concentrated detergent
- combination
- stain removal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002738 chelating agent Substances 0.000 title 1
- 230000002195 synergetic effect Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract description 39
- 239000003599 detergent Substances 0.000 abstract description 28
- 235000019832 sodium triphosphate Nutrition 0.000 abstract description 9
- VUABPTIDJBJIPI-ZETCQYMHSA-N (2S)-2-(diacetylamino)pentanedioic acid Chemical compound C(C)(=O)N([C@@H](CCC(=O)O)C(=O)O)C(C)=O VUABPTIDJBJIPI-ZETCQYMHSA-N 0.000 abstract description 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- -1 alkali metal tripolyphosphate Chemical class 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 18
- 239000008139 complexing agent Substances 0.000 description 14
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 11
- 108090001060 Lipase Proteins 0.000 description 11
- 102000004882 Lipase Human genes 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 239000004367 Lipase Substances 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 235000010216 calcium carbonate Nutrition 0.000 description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 description 9
- 235000019421 lipase Nutrition 0.000 description 9
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 108010065511 Amylases Proteins 0.000 description 7
- 102000013142 Amylases Human genes 0.000 description 7
- 108010059892 Cellulase Proteins 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 7
- 108090000790 Enzymes Proteins 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 7
- 229940088598 enzyme Drugs 0.000 description 7
- 239000008233 hard water Substances 0.000 description 7
- 244000269722 Thea sinensis Species 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 235000019418 amylase Nutrition 0.000 description 5
- 229940106157 cellulase Drugs 0.000 description 5
- 244000005700 microbiome Species 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 241000233866 Fungi Species 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 239000004382 Amylase Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- 108091005804 Peptidases Proteins 0.000 description 3
- 102000003992 Peroxidases Human genes 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 108010084185 Cellulases Proteins 0.000 description 2
- 102000005575 Cellulases Human genes 0.000 description 2
- 241000223198 Humicola Species 0.000 description 2
- 108700020962 Peroxidase Proteins 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- 241000223258 Thermomyces lanuginosus Species 0.000 description 2
- 229940025131 amylases Drugs 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 description 2
- 235000012241 calcium silicate Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- 108010005400 cutinase Proteins 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- CQPFMGBJSMSXLP-ZAGWXBKKSA-M Acid orange 7 Chemical compound OC1=C(C2=CC=CC=C2C=C1)/N=N/C1=CC=C(C=C1)S(=O)(=O)[O-].[Na+] CQPFMGBJSMSXLP-ZAGWXBKKSA-M 0.000 description 1
- 241000607534 Aeromonas Species 0.000 description 1
- 240000006439 Aspergillus oryzae Species 0.000 description 1
- 235000002247 Aspergillus oryzae Nutrition 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000193744 Bacillus amyloliquefaciens Species 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 108010073997 Bromide peroxidase Proteins 0.000 description 1
- 108010035722 Chloride peroxidase Proteins 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 108010000238 Deterzyme Proteins 0.000 description 1
- 241000237379 Dolabella Species 0.000 description 1
- 241000193385 Geobacillus stearothermophilus Species 0.000 description 1
- 108010001336 Horseradish Peroxidase Proteins 0.000 description 1
- 241001480714 Humicola insolens Species 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- ZQISRDCJNBUVMM-YFKPBYRVSA-N L-histidinol Chemical compound OC[C@@H](N)CC1=CNC=N1 ZQISRDCJNBUVMM-YFKPBYRVSA-N 0.000 description 1
- 241000237852 Mollusca Species 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 241000145542 Pseudomonas marginata Species 0.000 description 1
- 101000968491 Pseudomonas sp. (strain 109) Triacylglycerol lipase Proteins 0.000 description 1
- 241000589614 Pseudomonas stutzeri Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 239000004161 brilliant blue FCF Substances 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 238000011496 digital image analysis Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- FTZLWXQKVFFWLY-UHFFFAOYSA-L disodium;2,5-dichloro-4-[3-methyl-5-oxo-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazol-1-yl]benzenesulfonate Chemical compound [Na+].[Na+].CC1=NN(C=2C(=CC(=C(Cl)C=2)S([O-])(=O)=O)Cl)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FTZLWXQKVFFWLY-UHFFFAOYSA-L 0.000 description 1
- ZOESAMNEZGSOPU-UHFFFAOYSA-L disodium;4-[4-[acetyl(methyl)amino]-2-sulfonatoanilino]-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(N(C(C)=O)C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O ZOESAMNEZGSOPU-UHFFFAOYSA-L 0.000 description 1
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 210000000514 hepatopancreas Anatomy 0.000 description 1
- 108010062085 ligninase Proteins 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000008402 moderately hard water Substances 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N pentanal Chemical compound CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 235000012756 tartrazine Nutrition 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 239000008403 very hard water Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/16—Phosphates including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2013/068625 WO2015032451A1 (en) | 2013-09-09 | 2013-09-09 | Synergistic stain removal through novel chelator combination |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2655195T3 true ES2655195T3 (es) | 2018-02-19 |
Family
ID=49170674
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13762438.3T Active ES2655195T3 (es) | 2013-09-09 | 2013-09-09 | Eliminación sinérgica de manchas mediante una combinación de quelantes nuevos |
| ES17187391T Active ES2905972T3 (es) | 2013-09-09 | 2013-09-09 | Eliminación sinérgica de manchas a través de una nueva combinación de quelantes |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES17187391T Active ES2905972T3 (es) | 2013-09-09 | 2013-09-09 | Eliminación sinérgica de manchas a través de una nueva combinación de quelantes |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9796950B2 (https=) |
| EP (2) | EP3044301B1 (https=) |
| JP (1) | JP6317449B2 (https=) |
| CN (1) | CN105555930B (https=) |
| AU (1) | AU2013399899B2 (https=) |
| BR (1) | BR112016005143B1 (https=) |
| CA (1) | CA2921811A1 (https=) |
| ES (2) | ES2655195T3 (https=) |
| MX (1) | MX394036B (https=) |
| WO (1) | WO2015032451A1 (https=) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2982202T3 (es) | 2013-09-09 | 2024-10-15 | Ecolab Usa Inc | Método de lavado de vajilla basado en la eliminación sinérgica de manchas mediante una nueva combinación de quelantes |
| KR20170127493A (ko) * | 2015-03-11 | 2017-11-21 | 바스프 에스이 | 킬레이트제의 혼합물, 및 이러한 혼합물의 제조 방법 |
| ES2881309T3 (es) * | 2015-03-12 | 2021-11-29 | Basf Se | Proceso para preparación de mezclas de enantiómeros, y mezclas de enantiómeros |
| PT3156475T (pt) | 2015-10-16 | 2018-10-19 | Georg Hagleitner Hans | Concentrado de limpeza líquido |
| CA3068058C (en) | 2017-06-27 | 2023-08-22 | Ecolab Usa Inc. | Non-phosphorous transition metal control in laundry applications |
| JP6514288B2 (ja) * | 2017-09-14 | 2019-05-15 | エコラボ ユーエスエー インコーポレイティド | 新規なキレート化剤の組合せによる相乗的汚れ除去 |
| EP3546557B1 (en) * | 2018-03-28 | 2020-10-07 | The Procter & Gamble Company | Catalase inhibition during a laundering process |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1234445A (https=) | 1967-10-03 | 1971-06-03 | ||
| IE81141B1 (en) | 1983-06-24 | 2000-04-05 | Genencor Int | Procaryotic carbonyl hydrolases |
| EP0322429B1 (en) | 1987-05-29 | 1994-10-19 | Genencor International, Inc. | Cutinase cleaning composition |
| DE3727740A1 (de) | 1987-08-20 | 1989-03-02 | Rheinmetall Gmbh | Vorrichtung fuer einen nach vorn gerichteten huelsenauswurf aus einer fremdgetriebenen maschinenkanone |
| DK212388D0 (da) | 1988-04-15 | 1988-04-15 | Novo Industri As | Detergent additiv |
| DK204290D0 (da) | 1990-08-24 | 1990-08-24 | Novo Nordisk As | Enzymatisk detergentkomposition og fremgangsmaade til enzymstabilisering |
| DK28792D0 (da) | 1992-03-04 | 1992-03-04 | Novo Nordisk As | Nyt enzym |
| DK52393D0 (https=) | 1993-05-05 | 1993-05-05 | Novo Nordisk As | |
| USRE37484E1 (en) | 1993-09-14 | 2001-12-25 | Rego-Fix Ag | Clamping device for machine tools |
| US6436690B1 (en) | 1993-09-15 | 2002-08-20 | The Procter & Gamble Company | BPN′ variants having decreased adsorption and increased hydrolysis wherein one or more loop regions are substituted |
| MA23346A1 (fr) | 1993-10-14 | 1995-04-01 | Genencor Int | Variantes de la subtilisine |
| HU219851B (hu) | 1993-10-14 | 2001-08-28 | The Procter And Gamble Company | Proteáz tartalmú tisztítókészítmények |
| ZA952220B (en) | 1994-05-02 | 1995-12-14 | Procter & Gamble | Bpn' variants having decreased adsorption and increased hydrolysis wherein one or more loop regions are substituted |
| US6599730B1 (en) | 1994-05-02 | 2003-07-29 | Procter & Gamble Company | Subtilisin 309 variants having decreased adsorption and increased hydrolysis |
| GB2311541A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Oxygen-releasing bleach composition |
| GB2311538A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Detergent compositions |
| US6165970A (en) * | 1996-03-29 | 2000-12-26 | The Procter & Gamble Company | Detergent composition comprising acrylic acid-based polymer and amino tricarboxylic acid-based compound |
| US20040147426A1 (en) * | 1998-07-10 | 2004-07-29 | The Procter & Gamble Company | Laundry and cleaning compositions |
| JP5025097B2 (ja) * | 2005-06-02 | 2012-09-12 | ディバーシー・アイピー・インターナショナル・ビー・ヴイ | 自動洗浄機用液体洗浄剤組成物 |
| DE102007042857A1 (de) * | 2007-09-10 | 2009-03-12 | Henkel Ag & Co. Kgaa | Verfahren zum maschinellen Reinigen von Geschirr |
| US8198228B2 (en) * | 2008-01-04 | 2012-06-12 | Ecolab Usa Inc. | Solidification matrix using an aminocarboxylate |
| JP5324207B2 (ja) * | 2008-12-19 | 2013-10-23 | ディバーシー株式会社 | 自動食器洗浄機用固形洗浄剤の製法およびそれによって得られる自動食器洗浄機用固形洗浄剤 |
| WO2011076897A1 (en) * | 2009-12-22 | 2011-06-30 | Novozymes A/S | Use of amylase variants at low temperature |
| MX2012009162A (es) * | 2010-02-09 | 2012-10-03 | Basf Se | Composicion detergente. |
| DE102010029348A1 (de) * | 2010-05-27 | 2011-12-08 | Henkel Ag & Co. Kgaa | Maschinelles Geschirrspülmittel |
| ES2551227T3 (es) * | 2010-10-29 | 2015-11-17 | The Procter & Gamble Company | Composición limpiadora líquida espesada para superficies duras |
| CN104379737B (zh) * | 2012-06-08 | 2018-10-23 | 丹尼斯科美国公司 | 对淀粉聚合物具有增强的活性的变体α淀粉酶 |
| ES2982202T3 (es) * | 2013-09-09 | 2024-10-15 | Ecolab Usa Inc | Método de lavado de vajilla basado en la eliminación sinérgica de manchas mediante una nueva combinación de quelantes |
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2013
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- 2013-09-09 MX MX2016002935A patent/MX394036B/es unknown
- 2013-09-09 EP EP13762438.3A patent/EP3044301B1/en active Active
- 2013-09-09 ES ES13762438.3T patent/ES2655195T3/es active Active
- 2013-09-09 CA CA2921811A patent/CA2921811A1/en not_active Abandoned
- 2013-09-09 BR BR112016005143-2A patent/BR112016005143B1/pt active IP Right Grant
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- 2013-09-09 CN CN201380079436.8A patent/CN105555930B/zh active Active
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|---|---|
| AU2013399899A1 (en) | 2016-03-10 |
| MX394036B (es) | 2025-03-24 |
| US20160222320A1 (en) | 2016-08-04 |
| EP3044301B1 (en) | 2017-10-25 |
| EP3272847A1 (en) | 2018-01-24 |
| JP2016534207A (ja) | 2016-11-04 |
| AU2013399899B2 (en) | 2016-10-13 |
| EP3272847B1 (en) | 2022-01-19 |
| EP3044301A1 (en) | 2016-07-20 |
| CA2921811A1 (en) | 2015-03-12 |
| ES2905972T3 (es) | 2022-04-12 |
| BR112016005143A2 (https=) | 2017-08-01 |
| WO2015032451A1 (en) | 2015-03-12 |
| CN105555930A (zh) | 2016-05-04 |
| JP6317449B2 (ja) | 2018-04-25 |
| BR112016005143B1 (pt) | 2021-10-19 |
| US9796950B2 (en) | 2017-10-24 |
| MX2016002935A (es) | 2016-06-06 |
| CN105555930B (zh) | 2018-09-28 |
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