ES2639807T3 - Cuerpo moldeado celulósico tridimensional, procedimiento para su fabricación y su uso - Google Patents
Cuerpo moldeado celulósico tridimensional, procedimiento para su fabricación y su uso Download PDFInfo
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- ES2639807T3 ES2639807T3 ES14838769.9T ES14838769T ES2639807T3 ES 2639807 T3 ES2639807 T3 ES 2639807T3 ES 14838769 T ES14838769 T ES 14838769T ES 2639807 T3 ES2639807 T3 ES 2639807T3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B1/00—Preparatory treatment of cellulose for making derivatives thereof, e.g. pre-treatment, pre-soaking, activation
- C08B1/003—Preparation of cellulose solutions, i.e. dopes, with different possible solvents, e.g. ionic liquids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0279—Porous; Hollow
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/16—Amides, e.g. hydroxamic acids
- A61K31/165—Amides, e.g. hydroxamic acids having aromatic rings, e.g. colchicine, atenolol, progabide
- A61K31/167—Amides, e.g. hydroxamic acids having aromatic rings, e.g. colchicine, atenolol, progabide having the nitrogen of a carboxamide group directly attached to the aromatic ring, e.g. lidocaine, paracetamol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/0002—Galenical forms characterised by the drug release technique; Application systems commanded by energy
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/14—Particulate form, e.g. powders, Processes for size reducing of pure drugs or the resulting products, Pure drug nanoparticles
- A61K9/16—Agglomerates; Granulates; Microbeadlets ; Microspheres; Pellets; Solid products obtained by spray drying, spray freeze drying, spray congealing,(multiple) emulsion solvent evaporation or extraction
- A61K9/1605—Excipients; Inactive ingredients
- A61K9/1629—Organic macromolecular compounds
- A61K9/1652—Polysaccharides, e.g. alginate, cellulose derivatives; Cyclodextrin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/14—Particulate form, e.g. powders, Processes for size reducing of pure drugs or the resulting products, Pure drug nanoparticles
- A61K9/16—Agglomerates; Granulates; Microbeadlets ; Microspheres; Pellets; Solid products obtained by spray drying, spray freeze drying, spray congealing,(multiple) emulsion solvent evaporation or extraction
- A61K9/1682—Processes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/02—Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B16/00—Regeneration of cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/126—Polymer particles coated by polymer, e.g. core shell structures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/65—Characterized by the composition of the particulate/core
- A61K2800/654—The particulate/core comprising macromolecular material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2301/02—Cellulose; Modified cellulose
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
Abstract
Cuerpo moldeado celulósico tridimensional, que presenta una estructura de núcleo-envolvente ópticamente detectable, en donde la envolvente presenta una mayor densidad y una menor cristalinidad que el núcleo y el núcleo presenta una estructura similar a una esponja, caracterizado por que la envolvente presenta una densidad relativa del 65% al 85%y el núcleo presenta una densidad relativa del 20% al 60%-referido a la celulosa compacta-, el espesor de la envolvente oscila entre 50 μ 200 μa relación de espesor de la envolvente y el diámetro total del cuerpo moldeado oscila entre 1:5 y 1:50 y la relación de los semiejes del cuerpo moldeado no supera 3:1.
Description
5
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30
Tabla 1
- V1
- V2 V3 V4 V5 V6
- Diámetro de orificio [mm]
- 1,0 1,5 1,5 1,5 1,5 1,5
- Número de revoluciones de la cuchilla [rpm]
- 4500 3000 3000 3000 3000 3000
- Temperatura del baño de precipitación [°C]
- 30 50 50 50 50 10
- Baño de presentación de NMMO concentrado [% en peso]
- 20 34,5 38,9 42 44,6 0
- Espesor de la piel [μm] – valor medio
- 114,7 89,0 85,0 75,2 53,6 182,2
- Espesor de la piel [μm] – desviación estándar
- 20,1 14,7 4,2 7,7 8,0 35,3
Las perlas celulósicas fabricadas mediante la granuladora sumergida fueron precipitadas en agua completamente desalinizada (agua VE) y seguidamente sometidas a lavado en una columna con agua VE caliente a una temperatura de 80°C. El lavado fino tuvo lugar con lejía de sosa (pH 11). Después del lavado con lejía de sosa se lavaron las pequeñas esferas con agua a una temperatura de 80°C bajo pH neutro y se sometieron a centrifugación hasta una humedad residual de aproximadamente el 70% en peso.
La estructura de las partículas nunca secadas de los ensayos V1 a V6 fue examinada bajo un microscopio óptico ( tipo Zeiss Discovery.V12, Olympus DP71). En este caso se comprobó que todas las partículas presentan una destacada estructura de núcleo y envuelta. La Figura 1 muestra como ejemplo partícula de V6.
Mediante el software AnalySIS 5.0 de Olympus se midió el espesor de la envuelta, efectuándose y promediándose cinco mediciones. Los resultados se han recopilado también en la Tabla 1. Se encontró una manifiesta dependencia del espesor de la envolvente con respecto a las condiciones de regeneración. Al aumentar la concentración de NMMO en el baño de precipitación, junto con una elevación de la temperatura, disminuye el espesor de la capa externa.
Además, se puede reconocer que la piel exterior es transparente, mientras que el interior de las pequeñas esferas es blanco. Esto demuestra de manera unívoca la diferente estructuración del material. La capa transparente es muy densa, mientras que, en cambio, la capa interior de las perlas celulósicas presenta una estructura de tipo esponja. En el ejemplo 5 puede encontrarse una caracterización detallada de la estructura del núcleo-envuelta.
Ejemplo 2 -Carga con sustancia activa
20 g de perlas celulósicas nunca secadas V1 del Ejemplo 1 (68,3% en peso de humedad residual) fueron añadidos a 40 ml de un paracetamol (Merck) al 5% en peso regulado a una temperatura de 30°C en solución p.A. de etanol. Esta suspensión fue sometida a agitación a 100 rpm durante 120 min. Se filtraron las perlas celulósicas cargadas y se lavaron subsiguientemente con 10 ml de agua VE completamente desalinizada y a continuación se secaron en un gabinete de secado al vacío a 40°C, 150 mbar durante aproximadamente 8 h. El peso total de las perlas celulósicas secadas era de 5,6915 g. La carga de las perlas celulósicas con paracetamol era del 8,48% en peso (aumento de peso).
Como sustancias comparativas se utilizaron los siguientes materiales: Tencel® CP 4 (Polvo de celulosa esférico, fabricante: Lenzing AG), Tencel® Gel (suspensión de celulosa, Lenzing AG) y Vivapur 105 (MCC, Fabricante, J. R & Söhne). A partir de ellos también se prepararon suspensiones con paracetamol en etanol de manera análoga a las perlas celulósicas de acuerdo con la invención, manteniéndose siempre constante la relación entre la celulosa y el paracetamol. Sin embargo, los materiales comparativos no fueron secados en el gabinete de secado en vacío, por cuanto que, debido a las partículas finas, esto habría conducido a la formación de grumos, sino mediante la secadora de rociado Büchi B290. En la Tabla 2 se han resumido las propiedades de las partículas cargadas.
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Claims (1)
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Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATA794/2013A AT515180B1 (de) | 2013-10-15 | 2013-10-15 | Dreidimensionaler cellulosischer Formkörper, Verfahren zu seiner Herstellung und seine Verwendung |
AT7942013 | 2013-10-15 | ||
PCT/AT2014/000202 WO2015054711A2 (de) | 2013-10-15 | 2014-11-14 | Dreidimensionaler cellulosischer formkörper, verfahren zu seiner herstellung und seine verwendung |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2639807T3 true ES2639807T3 (es) | 2017-10-30 |
Family
ID=52544214
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES14838769.9T Active ES2639807T3 (es) | 2013-10-15 | 2014-11-14 | Cuerpo moldeado celulósico tridimensional, procedimiento para su fabricación y su uso |
Country Status (10)
Country | Link |
---|---|
US (1) | US10093790B2 (es) |
EP (1) | EP3058022B1 (es) |
JP (1) | JP6511441B2 (es) |
KR (1) | KR20170071444A (es) |
CN (1) | CN105829351B (es) |
AT (1) | AT515180B1 (es) |
DK (1) | DK3058022T3 (es) |
ES (1) | ES2639807T3 (es) |
PL (1) | PL3058022T3 (es) |
WO (1) | WO2015054711A2 (es) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT515174B1 (de) | 2013-10-15 | 2019-05-15 | Chemiefaser Lenzing Ag | Cellulosesuspension, Verfahren zu ihrer Herstellung und Verwendung |
AT517020B1 (de) | 2015-02-06 | 2020-02-15 | Chemiefaser Lenzing Ag | Recycling von cellulosischen Kunstfasern |
WO2020022524A1 (ja) * | 2018-07-26 | 2020-01-30 | 株式会社日本触媒 | セルロースモノリスの製法および該方法によって得られるセルロースモノリス |
Family Cites Families (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT101779B (de) | 1923-07-07 | 1925-11-25 | Bleichert & Co Adolf | Verfahren zum Befördern und Verlegen von Rohrleitungen auf stark geneigten Geländeteilen. |
US2543928A (en) * | 1946-06-08 | 1951-03-06 | Olin Ind Inc | Method of producing cellulose pellets |
US2593786A (en) * | 1947-06-19 | 1952-04-22 | Olin Ind Inc | Regenerated cellulose pellets |
DE907051C (de) | 1949-11-01 | 1954-02-11 | Rayonier Inc | Verfahren zur Herstellung von Viskose aus Baumwolle, insbesondere Linters |
AT287905B (de) | 1968-09-20 | 1971-02-10 | Chemiefaser Lenzing Ag | Verfahren zur Herstellung von Faden aus regenerierter Cellulose |
US4946953A (en) | 1986-10-16 | 1990-08-07 | Kanebo, Ltd. | Fine cellulose particles and process for production thereof employing coagulated viscose |
JP2627642B2 (ja) | 1988-06-11 | 1997-07-09 | チッソ株式会社 | 粉末化粧料 |
AT392972B (de) | 1988-08-16 | 1991-07-25 | Chemiefaser Lenzing Ag | Verfahren zur herstellung von loesungen von cellulose sowie einrichtung zur durchfuehrung des verfahrens |
US5328603A (en) * | 1990-03-20 | 1994-07-12 | The Center For Innovative Technology | Lignocellulosic and cellulosic beads for use in affinity and immunoaffinity chromatography of high molecular weight proteins |
US5331801A (en) | 1992-01-24 | 1994-07-26 | Eco Fibre Canada Inc. | Recycled yarns from textile waste and the manufacturing process therefor |
ATA53792A (de) | 1992-03-17 | 1995-02-15 | Chemiefaser Lenzing Ag | Verfahren zur herstellung cellulosischer formkörper, vorrichtung zur durchführung des verfahrens sowie verwendung einer spinnvorrichtung |
US6010594A (en) | 1993-03-03 | 2000-01-04 | Ahlstrom Machinery Corporation | Method of bleaching pulp with chlorine-free chemicals wherein a complexing agent is added immediately after an ozone bleach stage |
US5447603A (en) | 1993-07-09 | 1995-09-05 | The Dow Chemical Company | Process for removing metal ions from liquids |
US5369861A (en) | 1994-01-21 | 1994-12-06 | Burlington Industries, Inc. | Process for recycling denim waste |
US5481864A (en) | 1994-07-11 | 1996-01-09 | Wright; Herbert J. | Cloth scrap recycling method |
AT401392B (de) | 1994-09-05 | 1996-08-26 | Chemiefaser Lenzing Ag | Verfahren zur herstellung eines cellulosischen formkörpers |
DE4444245C1 (de) | 1994-12-13 | 1996-07-04 | Hoechst Ag | Verfahren zum Recycling von gefärbten, cellulosischen Abfallprodukten zu Fasern |
AT401779B (de) * | 1995-02-02 | 1996-11-25 | Chemiefaser Lenzing Ag | Verfahren zur herstellung cellulosischer formkörper und regenerierte lösung |
AT408547B (de) | 1995-09-26 | 2001-12-27 | Chemiefaser Lenzing Ag | Verfahren zum transportieren einer lösung von cellulose in einem wässrigen tertiären aminoxid |
US6471727B2 (en) | 1996-08-23 | 2002-10-29 | Weyerhaeuser Company | Lyocell fibers, and compositions for making the same |
US6306334B1 (en) | 1996-08-23 | 2001-10-23 | The Weyerhaeuser Company | Process for melt blowing continuous lyocell fibers |
CN1080779C (zh) | 1996-11-21 | 2002-03-13 | 东洋纺织株式会社 | 再生纤维素纤维及其制造方法 |
DE19755352C1 (de) * | 1997-12-14 | 1999-06-24 | Thueringisches Inst Textil | Verfahren zur Herstellung von regulären, porösen Perlcellulosen aus Celluloselösungen und die Verwendung der Perlcellulosen |
DE19755353C1 (de) * | 1997-12-14 | 1999-04-29 | Thueringisches Inst Textil | Verfahren zur Herstellung regulärer, poröser Perlcellulosen und ihre Verwendung |
AT407997B (de) * | 1999-08-10 | 2001-07-25 | Chemiefaser Lenzing Ag | Gefärbte cellulosische formkörper |
US6458162B1 (en) * | 1999-08-13 | 2002-10-01 | Vita Special Purpose Corporation | Composite shaped bodies and methods for their production and use |
US7052578B2 (en) | 2000-01-28 | 2006-05-30 | Martin Marietta Magnesia Specialties, Inc. | Process employing magnesium hydroxide in peroxide bleaching of mechanical pulp |
US6378179B1 (en) | 2001-01-05 | 2002-04-30 | Gary F. Hirsch | System and method for reconstituting fibers from recyclable waste material |
DE10102334C2 (de) | 2001-01-19 | 2003-12-04 | Thueringisches Inst Textil | Verfahren zur Herstellung von regulären, monodispersen Celluloseperlen und ihre Verwendung |
US7132469B2 (en) | 2002-06-28 | 2006-11-07 | Reinforced Polymers, Inc. | Molding compositions with solid thermoplastic elastomer thickeners and products obtained therefrom |
US20040131690A1 (en) | 2002-09-20 | 2004-07-08 | Lynch Maurice Gerard | Beads and methods of preparation |
WO2004043329A2 (en) | 2002-11-12 | 2004-05-27 | L'oreal | Use of cellulose microbeads to make the skin matt |
FI117393B (fi) | 2003-01-10 | 2006-09-29 | Kemira Oyj | Menetelmä selluloosakuitumateriaalin valkaisemiseksi |
FI119375B (fi) | 2007-02-02 | 2008-10-31 | Kemira Oyj | Uusi koostumus ja menetelmä kuitumateriaalin käsittelemiseksi |
US20100209708A1 (en) | 2007-09-17 | 2010-08-19 | Basf Se | Crosslinked cellulose beads |
AT505905B1 (de) * | 2007-09-21 | 2009-05-15 | Chemiefaser Lenzing Ag | Cellulosepulver und verfahren zu seiner herstellung |
US20100297445A1 (en) | 2007-11-22 | 2010-11-25 | Basf Se | Production of spherical particles from solutions comprising a water-miscible solvent by the method of underwater pelletization |
WO2009103680A1 (de) * | 2008-02-22 | 2009-08-27 | Basf Se | Feste, poröse materialien mit kern-schale-struktur auf der basis von synthetischen polymeren und biopolymeren, verfahren zu ihrer herstellung und ihre verwendung |
AT507758A1 (de) | 2008-12-23 | 2010-07-15 | Chemiefaser Lenzing Ag | Yarn and threads from blends of fibres and articles therefrom |
US10099192B2 (en) * | 2009-02-09 | 2018-10-16 | Cellutech Ab | Polymer shells |
CN101906214A (zh) * | 2009-06-05 | 2010-12-08 | 华东理工大学 | 一种制备交联球形纤维素颗粒的方法 |
WO2011077446A1 (en) | 2009-12-23 | 2011-06-30 | Varun Gambhir | Process for recycling cotton fabrics |
WO2011130276A2 (en) | 2010-04-12 | 2011-10-20 | Enova Textile And Apparel, Llc | Processes for using recycled waste cotton material in producing a textile product and textile products produced form waste cotton material |
CN103025931B (zh) | 2010-06-30 | 2015-07-08 | 可隆工业株式会社 | 溶解性纤维纺纱用涂料、利用该涂料的溶解性长丝纤维及溶解性短丝纤维的制造方法 |
PL2683858T3 (pl) | 2011-03-08 | 2018-03-30 | Sappi Netherlands Services B.V. | Sposób suchego przędzenia obojętnej i modyfikowanej anionowo celulozy |
CN102677230A (zh) | 2011-03-12 | 2012-09-19 | 咸立强 | 一种环境无害化生产再生棉的方法 |
CN102199310B (zh) | 2011-05-17 | 2013-01-02 | 东华大学 | 一种废旧涤棉混纺织物中含棉成分的回收方法 |
AT511624B1 (de) | 2011-07-13 | 2014-02-15 | Chemiefaser Lenzing Ag | Cellulose ii suspension, deren herstellung und daraus gebildete strukturen |
AR088787A1 (es) | 2011-08-30 | 2014-07-10 | Cargill Inc | Composicion de pulpa |
CN102660791A (zh) | 2012-04-15 | 2012-09-12 | 广东巨洋环保科技有限公司 | 一种旧衣服回收利用方法 |
BR112014029701B8 (pt) | 2012-05-28 | 2022-02-08 | Chemiefaser Lenzing Ag | Processo para fabricação de polpa de dissolução, licor, e, polpa |
EP2891747B1 (en) | 2012-07-06 | 2018-08-08 | Nippon Paper Industries Co., Ltd. | Recycled fiber and process for preparing the recycled fiber |
US20160369456A1 (en) | 2014-04-17 | 2016-12-22 | Evrnu, Spc | Methods and systems for processing cellulose-containing materials and isolating cellulose molecules; methods for regenerating cellulosic fibers |
AT515152B1 (de) | 2013-11-26 | 2015-12-15 | Chemiefaser Lenzing Ag | Verfahren zum Vorbehandeln von rückgewonnenen Baumwollfasern zur Verwendung bei der Herstellung von Formkörpern aus regenerierter Cellulose |
TWI667378B (zh) | 2014-01-03 | 2019-08-01 | 奧地利商蘭精股份有限公司 | 纖維素纖維 |
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2013
- 2013-10-15 AT ATA794/2013A patent/AT515180B1/de not_active IP Right Cessation
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2014
- 2014-11-14 KR KR1020167012437A patent/KR20170071444A/ko not_active Application Discontinuation
- 2014-11-14 PL PL14838769T patent/PL3058022T3/pl unknown
- 2014-11-14 WO PCT/AT2014/000202 patent/WO2015054711A2/de active Application Filing
- 2014-11-14 CN CN201480056149.XA patent/CN105829351B/zh not_active Expired - Fee Related
- 2014-11-14 EP EP14838769.9A patent/EP3058022B1/de not_active Not-in-force
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JP6511441B2 (ja) | 2019-05-15 |
DK3058022T3 (da) | 2017-10-02 |
CN105829351B (zh) | 2019-05-10 |
AT515180B1 (de) | 2016-06-15 |
WO2015054711A3 (de) | 2015-07-16 |
AT515180A1 (de) | 2015-06-15 |
KR20170071444A (ko) | 2017-06-23 |
US10093790B2 (en) | 2018-10-09 |
PL3058022T3 (pl) | 2017-11-30 |
US20160257806A1 (en) | 2016-09-08 |
EP3058022B1 (de) | 2017-06-14 |
CN105829351A (zh) | 2016-08-03 |
JP2016538367A (ja) | 2016-12-08 |
WO2015054711A2 (de) | 2015-04-23 |
EP3058022A2 (de) | 2016-08-24 |
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