ES2555989T3 - Procedimiento para la síntesis del ácido 2,5-furanodicarboxílico - Google Patents

Procedimiento para la síntesis del ácido 2,5-furanodicarboxílico Download PDF

Info

Publication number
ES2555989T3
ES2555989T3 ES11741561.2T ES11741561T ES2555989T3 ES 2555989 T3 ES2555989 T3 ES 2555989T3 ES 11741561 T ES11741561 T ES 11741561T ES 2555989 T3 ES2555989 T3 ES 2555989T3
Authority
ES
Spain
Prior art keywords
carbonate
synthesis
procedure
furanedicarboxylic acid
potassium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES11741561.2T
Other languages
English (en)
Inventor
Giampietro Borsotti
Francesca Digioia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novamont SpA
Original Assignee
Novamont SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novamont SpA filed Critical Novamont SpA
Application granted granted Critical
Publication of ES2555989T3 publication Critical patent/ES2555989T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/24—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Procedimiento para la síntesis del ácido 2,5-furanodicarboxílico mediante la oxidación de 5-hidroximetilfurfural por una corriente de oxígeno, catalizada por un catalizador soportado que contiene un metal del grupo del platino, que se lleva a cabo en una solución acuosa cuyo pH se mantiene superior a 7 e inferior a 12 mediante la adición de una base débil seleccionada de entre el grupo que consiste en bicarbonato de sodio, bicarbonato de potasio, carbonato de sodio, carbonato de potasio, carbonato de calcio, carbonato de magnesio, hidróxido de calcio, hidróxido de magnesio, soluciones tampón de fosfato dibásico y tribásico y sus mezclas.

Description

imagen1
imagen2
imagen3
imagen4
imagen5

Claims (1)

  1. imagen1
ES11741561.2T 2010-08-06 2011-08-04 Procedimiento para la síntesis del ácido 2,5-furanodicarboxílico Active ES2555989T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI2010A001526A IT1401911B1 (it) 2010-08-06 2010-08-06 Processo per la sintesi di acido 2,5-furandicarbossilico
ITMI20101526 2010-08-06
PCT/EP2011/063482 WO2012017052A1 (en) 2010-08-06 2011-08-04 Process for the synthesis of 2,5-furandicarboxylic acid.

Publications (1)

Publication Number Publication Date
ES2555989T3 true ES2555989T3 (es) 2016-01-12

Family

ID=43303893

Family Applications (1)

Application Number Title Priority Date Filing Date
ES11741561.2T Active ES2555989T3 (es) 2010-08-06 2011-08-04 Procedimiento para la síntesis del ácido 2,5-furanodicarboxílico

Country Status (11)

Country Link
US (1) US9359318B2 (es)
EP (1) EP2601182B1 (es)
JP (1) JP6069199B2 (es)
KR (1) KR101936966B1 (es)
CN (1) CN103068809B (es)
BR (1) BR112013002925B1 (es)
CA (1) CA2805574C (es)
ES (1) ES2555989T3 (es)
IT (1) IT1401911B1 (es)
MX (1) MX346052B (es)
WO (1) WO2012017052A1 (es)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103626726B (zh) * 2012-08-23 2016-08-03 中国科学院大连化学物理研究所 一种制备5-羟甲基糠酸和2，5-呋喃二甲酸的方法
FR2995898B1 (fr) 2012-09-27 2019-07-26 Roquette Freres Procede de synthese de l'acide 2,5-furane dicarboxylique a partir d'une composition contenant du furane-2,5-dialdehyde
US9006470B2 (en) * 2012-11-08 2015-04-14 Eastman Chemical Company Method of synthesizing low color furan diesters
US9029579B2 (en) 2012-11-08 2015-05-12 Eastman Chemical Company Method of synthesizing low color furan diesters
WO2015054756A1 (pt) * 2013-10-17 2015-04-23 Petróleo Brasileiro S.A. - Petrobras Processo integrado de produção de ácido 2,5-furânico dicarboxílico
FR3001970B1 (fr) * 2013-02-11 2015-02-27 Centre Nat Rech Scient Procede de preparation d'acide 2,5-furane dicarboxylique
RU2640203C2 (ru) * 2013-03-14 2017-12-27 Арчер Дэниелс Мидлэнд Компани Способ получения 2,5-фурандикарбоновой кислоты
CN105531245B (zh) 2013-08-30 2017-09-19 福兰尼克斯科技公司 用于纯化包含2‑甲酰基‑呋喃‑5‑羧酸和2,5‑呋喃二羧酸的酸组合物的方法
WO2015041013A1 (ja) * 2013-09-19 2015-03-26 花王株式会社 ２，５－フランジカルボン酸の製造方法
WO2015056270A1 (en) 2013-10-17 2015-04-23 Natco Pharma Limited Process for the preparation of 2,5-furandicarboxylic acid
WO2015155784A1 (en) 2014-04-09 2015-10-15 Natco Pharma Limited Process for the preparation of 2,5-furandicarboxylic acid and its ester derivative
KR102498728B1 (ko) * 2014-06-17 2023-02-10 안니키 게엠베하 5-히드록시메틸푸르푸랄의 선택적 산화 방법
WO2015197699A1 (en) * 2014-06-25 2015-12-30 Basf Se Process for preparing furan-2,5-dicarboxylic acid
US9598780B2 (en) * 2015-01-08 2017-03-21 Wisconsin Alumni Research Foundation Electrochemical and photoelectrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and 2,5-diformylfuran
US9885119B2 (en) 2015-02-12 2018-02-06 Wisconsin Alumni Research Foundation Electrochemical and photoelectrochemical reduction of furfurals
US9321744B1 (en) 2015-06-26 2016-04-26 Industrial Technology Research Institute Method for preparing 2,5-furan dicarboxylic acid
BR112018000606B1 (pt) * 2015-07-22 2022-01-18 Basf Se Processo para preparação de ácido furan-2,5- dicarboxílico e uso de um catalisador
RU2721603C2 (ru) * 2015-12-15 2020-05-21 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способы и системы для удаления примеси алкилиодида из возвратного газового потока при получении этиленоксида
EP3391446A4 (en) * 2015-12-18 2019-08-21 Rhodia Operations SELECTIVE OXIDATION OF FURANE ALCOHOLS BY ELECTRO-GENERATING PROCESS
SG11201805514VA (en) 2016-01-13 2018-07-30 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
CN108314667B (zh) * 2017-01-18 2021-10-26 中国科学院过程工程研究所 一种非碱体系生物基2,5-呋喃二甲酸的制备方法
SG11201913469PA (en) 2017-07-12 2020-01-30 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
US10669639B2 (en) 2017-09-05 2020-06-02 Wisconsin Alumni Research Foundation Eletrochemical oxidation of 5-hydroxymethylfurfural using copper-based anodes
US11142833B2 (en) 2017-10-09 2021-10-12 Wisconsin Alumni Research Foundation Electrochemical oxidation of aromatic aldehydes in acidic media
KR102009467B1 (ko) * 2018-01-08 2019-08-09 한국화학연구원 키토산 지지체를 이용한 2,5-퓨란디카복실릭 애시드(2,5-furandicarboxylic acid) 제조용 불균일 촉매 및 그 제조방법
IT201800007204A1 (it) 2018-07-13 2020-01-13 Processo per la produzione e la separazione di 5-idrossimetilfurfurale con sali ammonici quaternari”
CN109046349B (zh) * 2018-08-01 2021-07-23 西华大学 单原子钯催化剂及制备方法以及催化氧化5-hmf制备2,5-fdca的方法
EP3628667A1 (en) 2018-09-28 2020-04-01 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO Process and salts for the preparation of 2,5-furandicarboxylic acid
TWI725347B (zh) * 2018-10-18 2021-04-21 遠東新世紀股份有限公司 2,5-呋喃二甲酸的製備方法
IT201900025096A1 (it) 2019-12-20 2021-06-20 Novamont Spa Processo per la sintesi di acido 2,5-furandicarbossilico
KR102397424B1 (ko) * 2020-03-10 2022-05-11 코오롱인더스트리 주식회사 디카르본산 방향족 헤테로환 화합물 및 제조방법
DE102022201794A1 (de) * 2022-02-21 2023-08-24 Südzucker AG Verfahren zur Oxidation von Hydroxymethylfurfural

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3326944A (en) * 1964-03-09 1967-06-20 Atlas Chem Ind Method of producing dehydromucic acid
DE3826073A1 (de) * 1988-07-30 1990-02-01 Hoechst Ag Verfahren zur oxidation von 5-hydroxymethylfurfural
FR2669634B1 (fr) * 1990-11-22 1994-06-10 Furchim Procede de fabrication d'acide 2-5-furane dicarboxylique.
US7956203B2 (en) * 2000-03-27 2011-06-07 E. I. Du Pont De Nemours And Company Oxidation of 5-(hydroxymethyl) furfural to 2,5-diformylfuran and subsequent decarbonylation to unsubstituted furan
JP5006561B2 (ja) * 2006-03-28 2012-08-22 キヤノン株式会社 フランジカルボン酸の製造方法
JP5217142B2 (ja) * 2006-10-04 2013-06-19 三菱化学株式会社 フラン誘導体の製造法
WO2008054804A2 (en) * 2006-10-31 2008-05-08 Battelle Memorial Institute Hydroxymethyl furfural oxidation methods
JP5072348B2 (ja) * 2006-12-27 2012-11-14 キヤノン株式会社 フラン環化合物の製造方法
JP5207680B2 (ja) * 2007-07-27 2013-06-12 キヤノン株式会社 ２，５−フランジカルボン酸の製造方法
JP5078490B2 (ja) * 2007-07-30 2012-11-21 キヤノン株式会社 カルボン酸の製造方法
CN101386611A (zh) * 2007-09-14 2009-03-18 中国科学院大连化学物理研究所 一种制备5-羟甲基糠醛的方法
CN101456850A (zh) * 2007-12-12 2009-06-17 中国科学院大连化学物理研究所 一种制备5-羟甲基糠醛的方法

Also Published As

Publication number Publication date
EP2601182B1 (en) 2015-09-16
MX346052B (es) 2017-03-02
CN103068809B (zh) 2016-04-06
EP2601182A1 (en) 2013-06-12
IT1401911B1 (it) 2013-08-28
ITMI20101526A1 (it) 2012-02-07
JP6069199B2 (ja) 2017-02-01
CA2805574A1 (en) 2012-02-09
KR20130095748A (ko) 2013-08-28
KR101936966B1 (ko) 2019-01-09
BR112013002925B1 (pt) 2018-04-10
JP2013534219A (ja) 2013-09-02
CN103068809A (zh) 2013-04-24
WO2012017052A1 (en) 2012-02-09
BR112013002925A2 (pt) 2016-06-07
CA2805574C (en) 2018-05-01
US20130137882A1 (en) 2013-05-30
US9359318B2 (en) 2016-06-07
MX2013001432A (es) 2013-03-12

Similar Documents

Publication Publication Date Title
ES2555989T3 (es) Procedimiento para la síntesis del ácido 2,5-furanodicarboxílico
ES2628852T3 (es) Proceso para la producción de bicarbonato de sodio para desulfuración de gases de combustión
ES2492497T3 (es) Perácidos alfa-ceto y métodos para su producción y uso
HN2009000503A (es) Procedimiento para la preparacion de halogenos de n-alquil-naltrexona.
ES2536206T3 (es) Parche medicinal
ES2661081T3 (es) Reactivo de liberación para compuestos de vitamina D
ES2567159T3 (es) Método para la deshidratación de alcoholes grasos
AR077864A1 (es) Microgranulos flotantes
ES2536994T3 (es) Nuevo proceso de preparación de copolímeros de acrilamida por reacción de degradación de Hofmann
BR112012029318A2 (pt) processo para a preparação de polióis de poliéter de carbonato
BR112012022775A2 (pt) composições para a lavagem, do cólon e métodos para a produção e utilização das mesmas
BR112012027444A2 (pt) bloco cáustico altamente concentrado para lavagem de louças
AR092500A1 (es) Solucion de limpieza de colon
CO6290754A2 (es) Método para producir bicarbonato de arginina
ES2532451T3 (es) Composición herbicida
CL2012000374A1 (es) Metodo para la preparacion de una composicion saborizante activa que comprende una primera reaccion entre un compuesto amino y un carbonilo, resultando una primera mezcla de intermediarios, una segunda reaccion con un segundo compuesto amino solo o en combinacion con un compuesto carbinilo, resultando una segunda mezcla de intermediarios, reacciones serparadas adicionales con compuestos de otras clases quimicas, ultima reaccion que comprende una mezcla de todas las mezclas de intermediarios anteriores.
ES2599954T3 (es) Suplemento alimenticio
ATE482727T1 (de) Knochenersatzmaterial
CY1108156T1 (el) Στερεοεκλεκτικη συνθεση αναλογων βιταμινης d
BR112022007620A2 (pt) Métodos para produzir e usar soluções aquosas alcalinas de ferro férrico
MX2013003581A (es) Proceso para producir granulos que comprende una o mas sales de agentes complejas.
ES2496447T3 (es) Procedimiento de preparación de un aminoácido a partir de 2-aminobutirolactona
CL2014000510A1 (es) Proceso para la remineralizacion de agua, que comprende a) proveer agua de alimentacion, b) proveer una solucion acuosa de carbonato de calcio la cual contiene carbonato de calcio disuelto y sus especies de reaccion, y c) combinar el agua de alimentacion del paso a) y la solucion del paso b); y uso de la solucion de carbonato de calcio.
RU2011127602A (ru) Способ синтеза высокодисперсного карбоната кальция
DOP2009000041A (es) Procedimiento de preparacion de halogenuros de n-alquil-naltrexona