ES2546756T3 - Dispersión de un polímero preformado en un poliol - Google Patents
Dispersión de un polímero preformado en un poliol Download PDFInfo
- Publication number
- ES2546756T3 ES2546756T3 ES08153126.1T ES08153126T ES2546756T3 ES 2546756 T3 ES2546756 T3 ES 2546756T3 ES 08153126 T ES08153126 T ES 08153126T ES 2546756 T3 ES2546756 T3 ES 2546756T3
- Authority
- ES
- Spain
- Prior art keywords
- dispersion
- polyol
- preformed polymer
- polymer
- polymer resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0871—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic
- C08G18/0876—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic the dispersing or dispersed phase being a polyol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
Un procedimiento para hacer una dispersión estable que comprende las etapas: (a) poner en contacto, en un mezclador sencillo, una resina de polímero preformado, un poliol de poliéter y un estabilizador bajo condiciones de suficiente calor para fundir el polímero preformado, formando así un fundido de polímero, y suficiente cizalla para formar una dispersión inicial de la resina de polímero en el poliol; y (b) mientras está bajo cizalla, enfriar la dispersión inicial suficientemente para formar una dispersión estable; en donde la resina de polímero preformado es un polímero de polietileno, caracterizándose el procedimiento por el poliol de poliéter que tiene un peso molecular promediado en peso de entre 500 y 8000, una funcionalidad de 2 a 8, y un número de hidroxilo de 70 a 5,61 y la dispersión que comprende un estabilizador que es un producto de reacción imida de una cera de polietileno funcionalizada con anhídrido maleico y un poliol de monoamina.
Description
Claims (1)
-
imagen1
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US23814000P | 2000-10-05 | 2000-10-05 | |
US238140P | 2000-10-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2546756T3 true ES2546756T3 (es) | 2015-09-28 |
Family
ID=22896675
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES08153126.1T Expired - Lifetime ES2546756T3 (es) | 2000-10-05 | 2001-09-10 | Dispersión de un polímero preformado en un poliol |
Country Status (14)
Country | Link |
---|---|
US (1) | US6613827B2 (es) |
EP (1) | EP1326923B1 (es) |
JP (2) | JP5037777B2 (es) |
KR (1) | KR100835550B1 (es) |
CN (1) | CN1249164C (es) |
AU (1) | AU2001290759A1 (es) |
BR (1) | BR0114521B1 (es) |
DE (1) | DE60135670D1 (es) |
ES (1) | ES2546756T3 (es) |
MX (1) | MXPA03002982A (es) |
PL (1) | PL217904B1 (es) |
TW (2) | TWI300787B (es) |
WO (1) | WO2002028937A2 (es) |
ZA (1) | ZA200301784B (es) |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2002215338A1 (en) * | 2000-11-07 | 2002-05-21 | Basf Corporation | Coating compositions for adhesion to olefinic substrates |
US20040081780A1 (en) * | 2002-10-29 | 2004-04-29 | Anatoliy Goldman | Container closure with a multi-layer oxygen barrier liner |
AU2005267399A1 (en) | 2004-06-24 | 2006-02-02 | Century-Board Usa, Llc | Continuous forming apparatus for three-dimensional foamed products |
US20070112099A1 (en) | 2005-11-15 | 2007-05-17 | Wade Bruce E | Methods and devices for continuous production of polymeric dispersions |
US20070222105A1 (en) | 2006-03-24 | 2007-09-27 | Century-Board Usa, Llc | Extrusion of polyurethane composite materials |
ES2410555T3 (es) * | 2006-11-09 | 2013-07-02 | Basf Se | Proceso para la producción de dispersiones de poliol |
US7601761B2 (en) * | 2007-02-26 | 2009-10-13 | Bayer Materialscience Llc | Rigid polyurethane foams with increased heat performance |
US7601762B2 (en) * | 2007-02-26 | 2009-10-13 | Bayer Materialscience Llc | Polyvinylchloride/polyurethane hybrid foams with improved burn properties and reduced after-glow |
BRPI0819366A2 (pt) | 2007-11-14 | 2015-04-22 | Univ Northern Iowa Res Foundation | Sistema para uso na preparação de uma composição polimérica, processo de preparação de uma composição polimérica, kit, artigo, artigo preenchido e molde de fundição |
EP2242793B1 (en) * | 2008-02-08 | 2017-08-16 | Dow Global Technologies LLC | Polyurethane foam comprising a water-redispersible polymer powder |
WO2009138379A2 (de) * | 2008-05-13 | 2009-11-19 | Basf Se | Verfahren zur herstellung von polyoldispersionen |
EP2297219B1 (en) * | 2008-06-19 | 2012-04-04 | Dow Global Technologies LLC | Melt dispersion process for making polymer polyols |
JP2010235903A (ja) * | 2009-03-31 | 2010-10-21 | Sanyo Chem Ind Ltd | ポリマーポリオールの製造方法 |
GB2471303A (en) | 2009-06-24 | 2010-12-29 | Bell Flavors & Fragrances Duft Und Aroma Gmbh | Microparticles and method of making microparticles |
US9481759B2 (en) | 2009-08-14 | 2016-11-01 | Boral Ip Holdings Llc | Polyurethanes derived from highly reactive reactants and coal ash |
US8846776B2 (en) | 2009-08-14 | 2014-09-30 | Boral Ip Holdings Llc | Filled polyurethane composites and methods of making same |
US8309620B2 (en) | 2009-10-06 | 2012-11-13 | Amcol International Corp. | Lignite-based urethane resins with enhanced suspension properties and foundry sand binder performance |
US8853299B2 (en) | 2009-10-06 | 2014-10-07 | Amcol International Corp. | Lignite-based urethane resins with enhanced suspension properties and foundry sand binder performance |
US8623959B2 (en) | 2009-10-06 | 2014-01-07 | Joseph M. Fuqua | Non-veining urethane resins for foundry sand casting |
US8426494B2 (en) | 2009-10-06 | 2013-04-23 | Amcol International Corp. | Lignite urethane based resins for enhanced foundry sand performance |
US8436073B2 (en) | 2009-10-06 | 2013-05-07 | Amcol International | Lignite-based foundry resins |
US9115246B2 (en) | 2010-04-30 | 2015-08-25 | Basf Se | Polyether polyols, process for preparing polyether polyols and their use for producing polyurethanes |
CN102958977A (zh) | 2010-04-30 | 2013-03-06 | 巴斯夫欧洲公司 | 聚醚多元醇、制备聚醚多元醇的方法及其用于生产聚氨酯的用途 |
BR112013028982B1 (pt) | 2011-05-12 | 2020-10-27 | Dow Global Technologies Llc. | processo para fazer um poliol polimérico estabilizante e poliol polimérico estabilizante |
WO2013052732A1 (en) | 2011-10-07 | 2013-04-11 | Boral Industries Inc. | Inorganic polymer/organic polymer composites and methods of making same |
EP2841502B1 (en) * | 2012-03-30 | 2023-07-12 | Dow Global Technologies LLC | Dispersion of a functionalized polyolefin in a polyol |
CN104781298B (zh) | 2012-10-05 | 2019-04-19 | 陶氏环球技术有限公司 | 用于制造聚合物多元醇的大分子单体和方法 |
US10053597B2 (en) | 2013-01-18 | 2018-08-21 | Basf Se | Acrylic dispersion-based coating compositions |
WO2014168633A1 (en) | 2013-04-12 | 2014-10-16 | Boral Ip Holdings (Australia) Pty Limited | Composites formed from an absorptive filler and a polyurethane |
AU2014342768B2 (en) | 2013-10-30 | 2018-01-18 | Dow Global Technologies Llc | Syntactic polyurethane elastomers for use in subsea pipeline insulation |
EP2868686B1 (de) * | 2013-11-05 | 2018-12-26 | Coperion GmbH | Verfahren und vorrichtung zur herstellung einer additiv- und treibmittelhaltigen polymerschmelze |
CN106255711A (zh) | 2014-04-30 | 2016-12-21 | 巴斯夫欧洲公司 | 用于聚合物多元醇制备方法的稳定剂 |
MX2016014296A (es) | 2014-04-30 | 2017-02-06 | Basf Se | Proceso para preparar un poliol polimerico. |
US10138341B2 (en) | 2014-07-28 | 2018-11-27 | Boral Ip Holdings (Australia) Pty Limited | Use of evaporative coolants to manufacture filled polyurethane composites |
WO2016022103A1 (en) | 2014-08-05 | 2016-02-11 | Amitabha Kumar | Filled polymeric composites including short length fibers |
ES2742165T3 (es) * | 2014-11-27 | 2020-02-13 | Basf Se | Síntesis de polioles poliméricos en polioles insaturados, polioles poliméricos y su uso |
US10266703B2 (en) * | 2014-12-01 | 2019-04-23 | Dow Global Technologies Llc | Polyolefin polyols as surface modifying agents |
WO2016118141A1 (en) | 2015-01-22 | 2016-07-28 | Boral Ip Holdings (Australia) Pty Limited | Highly filled polyurethane composites |
WO2016195717A1 (en) | 2015-06-05 | 2016-12-08 | Boral Ip Holdings (Australia) Pty Limited | Filled polyurethane composites with lightweight fillers |
ES2784724T3 (es) | 2015-09-25 | 2020-09-30 | Dow Global Technologies Llc | Copolímero de poliol con aditivo funcional en fase dispersa |
US20170267585A1 (en) | 2015-11-12 | 2017-09-21 | Amitabha Kumar | Filled polyurethane composites with size-graded fillers |
PL3436496T3 (pl) | 2016-03-31 | 2021-08-16 | Dow Global Technologies, Llc | Sposób wytwarzania polimeropoliolu z monodyspersją zdyspergowanych cząstek polimeru |
AU2018388869B2 (en) | 2017-12-20 | 2023-11-23 | Dow Global Technologies Llc | Polyurethane foams for comfort applications |
JP7324764B2 (ja) | 2018-03-13 | 2023-08-10 | ダウ グローバル テクノロジーズ エルエルシー | 粘弾性フォーム |
CN113454135B (zh) | 2019-02-07 | 2023-12-15 | 陶氏环球技术有限责任公司 | 单体回收过程 |
US20220089814A1 (en) | 2019-02-07 | 2022-03-24 | Dow Global Technologies Llc | Process for preparing a copolymer polyol |
US20220275156A1 (en) * | 2019-08-29 | 2022-09-01 | Dow Global Technologies Llc | Method of making a homogeneous mixture of polyolefin solids and solid additive |
MX2022008252A (es) | 2020-01-06 | 2022-07-21 | Dow Global Technologies Llc | Macromero y proceso para elaborar polioles de polimero. |
JP2023513041A (ja) | 2020-01-31 | 2023-03-30 | ダウ グローバル テクノロジーズ エルエルシー | 快適性用途のためのポリウレタン発泡体 |
CN115989250A (zh) | 2020-07-08 | 2023-04-18 | 陶氏环球技术有限责任公司 | 用于制备聚合物多元醇的熔融分散方法 |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE629136A (es) | 1962-03-02 | |||
US3558531A (en) * | 1968-03-28 | 1971-01-26 | Atomic Energy Commission | Process for closed-cell rigid polyurethane foams |
US3660339A (en) | 1969-06-03 | 1972-05-02 | Nalco Chemical Co | Latex thickener |
US4014846A (en) * | 1974-04-29 | 1977-03-29 | Basf Wyandotte Corporation | Low-viscous, stable polymer dispersions and polyurethanes prepared therefrom |
US4575529A (en) | 1978-09-15 | 1986-03-11 | The Dow Chemical Company | Dispersible vinylidene chloride polymer powders as additives for polymers |
DE3112123A1 (de) * | 1981-03-27 | 1982-10-07 | Basf Ag, 6700 Ludwigshafen | Lagerstabile dispersionen von aromatischen polyestern in polyhydroxylverbindungen, verfahren zu deren herstellung und deren verwendung zur herstellung von gegebenenfalls zelligen polyurethan- und/oder polyisocyanurat-kunststoffen |
US4452920A (en) | 1981-05-20 | 1984-06-05 | Joubert & Joubert Proprietary Limited | Flexible polyurethane foams having junction modifying particulate additives |
US4454254A (en) | 1982-12-01 | 1984-06-12 | Basf Wyandotte Corporation | Aminoplast resins, dispersions, and low flammability cellular and non-cellular polyurethane products prepared therefrom |
GB2164339A (en) | 1984-09-11 | 1986-03-19 | Ciba Geigy Ag | Polymaleic anhydride derivatives |
ES2024644B3 (es) * | 1987-06-16 | 1992-03-01 | Exxon Chemical Patents Inc | Aditivo de copolimero de etileno injertado estabilizado util en composiciones de aceite. |
US5262075A (en) | 1989-05-30 | 1993-11-16 | Exxon Chemical Patents Inc. | Multifunctional viscosity index improver exhibitng improved low temperature viscometric properties |
US5086084A (en) | 1989-08-29 | 1992-02-04 | Lee H. Ambrose | Polyvinyl chloride/polyurethane hybrid foams |
GB9006315D0 (en) * | 1990-03-21 | 1990-05-16 | Shell Int Research | Polymer compositions |
JPH04205936A (ja) | 1990-11-30 | 1992-07-28 | Hitachi Ltd | 転写用成形媒体およびその製造方法 |
CA2080174A1 (en) | 1991-10-11 | 1993-04-12 | John E. Hayes | Polymer polyol dispersants from polymers containing anhydride groups |
WO1993009179A1 (fr) * | 1991-11-05 | 1993-05-13 | Showa Denko K.K. | Composition de resine et piece moulee produite avec ladite resine |
US5641829A (en) * | 1991-12-30 | 1997-06-24 | Ppg Industries, Inc. | Coating compositions prepared from base neutralized, stable aqueous dispersion of hydroxyl functional acrylic polymers |
US5298568A (en) | 1992-01-31 | 1994-03-29 | Toyo Ink Manufacturing Co., Ltd. | Modified olefin resin and resin composition |
US5270399A (en) | 1992-09-22 | 1993-12-14 | Basf Corporation | Urea-modified copolymers as dispersants for pigments in coating compositions |
US5851594A (en) * | 1992-10-20 | 1998-12-22 | Rhone Poulenc Chimie | Aqueous dispersions based on viscous silicone oils capable of cross-linking on removal of water |
JPH06199973A (ja) * | 1992-12-18 | 1994-07-19 | Sanyo Chem Ind Ltd | ポリウレタンフォームの製造方法 |
US5959032A (en) | 1993-07-13 | 1999-09-28 | Huntsman Petrochemical Corporation | Polyether amine modification of polypropylene |
US5364906A (en) * | 1993-08-20 | 1994-11-15 | Arco Chemical Technology, L.P. | Low viscosity polymer polyols with improved dispersion stability |
FR2740777B1 (fr) * | 1995-11-02 | 1998-01-02 | Hutchinson | Films d'elastomere contenant au moins une substance chimique active, leur procede de preparation et leurs applications |
GB9611118D0 (en) | 1996-05-29 | 1996-07-31 | Ici Plc | Dispersions |
US6179458B1 (en) * | 1996-11-01 | 2001-01-30 | E. I. Du Pont De Nemours And Company | Forming a solution of fluids having low miscibility and large-scale differences in viscosity |
US5859111A (en) * | 1996-12-18 | 1999-01-12 | National Starch And Chemical Investment Holding Corporation | Processes for making nonionic aqueous polyurethane dispersions |
JP3933790B2 (ja) * | 1998-05-01 | 2007-06-20 | 三井化学株式会社 | ポリオキシアルキレンポリオール及びポリマー分散ポリオール |
US6329440B2 (en) | 1998-05-09 | 2001-12-11 | Basf Aktiengesellschaft | Preparation of polyisocyanate polyaddition products |
US6265457B1 (en) | 1998-12-11 | 2001-07-24 | Woodbridge Foam Corporation | Isocyanate-based polymer foam and process for production thereof |
US6512024B1 (en) | 1999-05-20 | 2003-01-28 | Dow Global Technologies Inc. | Continuous process of extruding and mechanically dispersing a polymeric resin in an aqueous or non-aqueous medium |
-
2001
- 2001-09-10 US US09/950,327 patent/US6613827B2/en not_active Expired - Lifetime
- 2001-09-10 CN CNB018168736A patent/CN1249164C/zh not_active Expired - Lifetime
- 2001-09-10 BR BRPI0114521-5A patent/BR0114521B1/pt not_active IP Right Cessation
- 2001-09-10 EP EP01970792A patent/EP1326923B1/en not_active Expired - Lifetime
- 2001-09-10 WO PCT/US2001/028372 patent/WO2002028937A2/en active Application Filing
- 2001-09-10 ES ES08153126.1T patent/ES2546756T3/es not_active Expired - Lifetime
- 2001-09-10 PL PL360732A patent/PL217904B1/pl unknown
- 2001-09-10 MX MXPA03002982A patent/MXPA03002982A/es active IP Right Grant
- 2001-09-10 AU AU2001290759A patent/AU2001290759A1/en not_active Abandoned
- 2001-09-10 JP JP2002532516A patent/JP5037777B2/ja not_active Expired - Fee Related
- 2001-09-10 DE DE60135670T patent/DE60135670D1/de not_active Expired - Lifetime
- 2001-09-10 KR KR1020037004762A patent/KR100835550B1/ko active IP Right Grant
- 2001-10-04 TW TW090124535A patent/TWI300787B/zh active
- 2001-10-04 TW TW097117834A patent/TWI333497B/zh not_active IP Right Cessation
-
2003
- 2003-03-04 ZA ZA200301784A patent/ZA200301784B/en unknown
-
2012
- 2012-03-13 JP JP2012056283A patent/JP5421416B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP5421416B2 (ja) | 2014-02-19 |
MXPA03002982A (es) | 2004-02-12 |
TW200904846A (en) | 2009-02-01 |
US6613827B2 (en) | 2003-09-02 |
CN1468285A (zh) | 2004-01-14 |
DE60135670D1 (de) | 2008-10-16 |
WO2002028937B1 (en) | 2002-12-05 |
PL217904B1 (pl) | 2014-09-30 |
KR20030051697A (ko) | 2003-06-25 |
PL360732A1 (en) | 2004-09-20 |
JP2004510855A (ja) | 2004-04-08 |
CN1249164C (zh) | 2006-04-05 |
AU2001290759A1 (en) | 2002-04-15 |
TWI300787B (en) | 2008-09-11 |
EP1326923A2 (en) | 2003-07-16 |
BR0114521A (pt) | 2003-07-29 |
TWI333497B (en) | 2010-11-21 |
EP1326923B1 (en) | 2008-09-03 |
WO2002028937A2 (en) | 2002-04-11 |
JP5037777B2 (ja) | 2012-10-03 |
JP2012136707A (ja) | 2012-07-19 |
WO2002028937A3 (en) | 2002-06-27 |
US20020042463A1 (en) | 2002-04-11 |
ZA200301784B (en) | 2004-03-04 |
BR0114521B1 (pt) | 2011-09-20 |
KR100835550B1 (ko) | 2008-06-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2546756T3 (es) | Dispersión de un polímero preformado en un poliol | |
Tai et al. | Organic–inorganic networks in foams from high internal phase emulsion polymerizations | |
Lluch et al. | “Click” Synthesis of Fatty Acid Derivatives as Fast‐Degrading Polyanhydride Precursors | |
JP2003507516A5 (es) | ||
BRPI0508173A (pt) | copolìmero, processo para preparar um copolìmero em multibloco contendo propileno, processo para preparar um copolìmero em multibloco contendo 4-metil-1-penteno, copolìmero em multibloco, derivado funcionalizado, mistura homogênea de polìmero e derivado reticulado | |
Yin et al. | Synthesis, characterization, mechanical properties and biocompatibility of interpenetrating polymer network–super‐porous hydrogel containing sodium alginate | |
DE60228833D1 (de) | Ester-terminierte poly(esteramide) nützlich zur erzeugung transparenter gele in niedrig-polar-flüssigkeiten | |
BR9812386A (pt) | Processo para preparação de polìmeros estabilizados por colóides de proteção | |
Jia et al. | Mechanical properties and thermal stability of porous polyimide/hollow mesoporous silica nanoparticles composite films prepared by using polystyrene microspheres as the pore‐forming template | |
Muir et al. | Influence of microgel and interstitial matrix compositions on granular hydrogel composite properties | |
Han et al. | Poly (methyl methacrylate)–epoxy vitrimer composites | |
Zhang et al. | Preparation and thermomechanical properties of nanocrystalline cellulose reinforced poly (lactic acid) nanocomposites | |
Jiang et al. | Multi‐Crosslinked Hydrogels with Instant Self‐Healing and Tissue Adhesive Properties for Biomedical Applications | |
Yuan et al. | Phenolic foams toughened with crosslinked poly (n‐butyl acrylate)/silica core‐shell nanocomposite particles | |
Galanopoulo et al. | RAFT‐Mediated Emulsion Polymerization‐Induced Self‐Assembly for the Synthesis of Core‐Degradable Waterborne Particles | |
Chen et al. | Preparation and characterization of poly (vinyl alcohol)/halloysite nanotubes composite sponges with improved mechanical properties | |
Javadi et al. | Microcellular poly (hydroxybutyrate‐co‐hydroxyvalerate)‐hyperbranched polymer–nanoclay nanocomposites | |
Ji et al. | Physically entangled antiswelling hydrogels with high stiffness | |
Ray et al. | Static and dynamic mechanical properties of vinylester resin matrix composites filled with fly ash | |
Zhang et al. | Supramolecular hydrogel of poly (vinyl alcohol)/chitosan: A dual cross‐link design | |
US7884151B2 (en) | Material of nanocomposites of the resin and its manufacturing process | |
Liu et al. | Preparation of poly (methyl methacrylate‐co‐butyl methacrylate) nanoparticles and their reinforcing effect on natural rubber | |
Okubo et al. | Production of hollow polymer particles by suspension polymerizations for ethylene glycol dimethacrylate/toluene droplets dissolving styrene–methyl methacrylate copolymers | |
Chiriac et al. | Copolymerization of 2‐hydroxyethyl methacrylate with a comonomer with spiroacetal moiety | |
Dabrowski et al. | Methacrylate‐based polymer foams with controllable pore sizes and controllable polydispersities via foamed emulsion templating |