ES2524692T3 - Polimerización por radicales de etileno cebada por peróxidos orgánicos con alta productividad - Google Patents

Polimerización por radicales de etileno cebada por peróxidos orgánicos con alta productividad Download PDF

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Publication number
ES2524692T3
ES2524692T3 ES12707885.5T ES12707885T ES2524692T3 ES 2524692 T3 ES2524692 T3 ES 2524692T3 ES 12707885 T ES12707885 T ES 12707885T ES 2524692 T3 ES2524692 T3 ES 2524692T3
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ethylene
barley
radical polymerization
high productivity
organic peroxides
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ES12707885.5T
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ES2524692T5 (es
Inventor
Pascal Nicol
Serge Hub
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Arkema France SA
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Arkema France SA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Procedimiento de fabricación de polietileno o de un copolímero de etileno que comprende una etapa de polimerización o copolimerización por radicales de etileno a una temperatura de iniciación que varía de 150 ºC a 200 ºC, a una presión que varía de 500.105 a 3000.105 Pa (500 a 3000 bar), en presencia de un iniciador de polimerización peroxídico seleccionado entre los compuestos peróxidos de fórmula**Fórmula** donde R1 y R8 representan independientemente un grupo alquilo en C2-C6, R2, R3, R6 y R7 representan independientemente un grupo alquilo en C1-C5, R4 y R5 representan independientemente un grupo alquilo en C1-C6.

Description

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Claims (1)

  1. imagen1
ES12707885T 2011-02-10 2012-02-08 Polimerización por radicales de etileno cebada por peróxidos orgánicos con alta productividad Active ES2524692T5 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1151086 2011-02-10
FR1151086A FR2971510B1 (fr) 2011-02-10 2011-02-10 Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite
PCT/FR2012/050270 WO2012107689A1 (fr) 2011-02-10 2012-02-08 Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite

Publications (2)

Publication Number Publication Date
ES2524692T3 true ES2524692T3 (es) 2014-12-11
ES2524692T5 ES2524692T5 (es) 2022-11-02

Family

ID=44140892

Family Applications (1)

Application Number Title Priority Date Filing Date
ES12707885T Active ES2524692T5 (es) 2011-02-10 2012-02-08 Polimerización por radicales de etileno cebada por peróxidos orgánicos con alta productividad

Country Status (13)

Country Link
US (1) US9045571B2 (es)
EP (1) EP2673307B2 (es)
JP (2) JP5859028B2 (es)
KR (1) KR101838771B1 (es)
CN (2) CN103339155B (es)
BR (1) BR112013020243B1 (es)
CA (1) CA2825190C (es)
CO (1) CO6781559A2 (es)
ES (1) ES2524692T5 (es)
FR (1) FR2971510B1 (es)
MX (1) MX2013009207A (es)
MY (1) MY181887A (es)
WO (1) WO2012107689A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2971510B1 (fr) * 2011-02-10 2013-03-22 Arkema France Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite
JP5861824B2 (ja) * 2011-11-17 2016-02-16 スリーボンドファインケミカル株式会社 熱硬化性組成物
FR3041645B1 (fr) * 2015-09-29 2017-09-08 Arkema France Polymerisation radicalaire de l'ethylene amorcee par un couple de peroxydes organiques a haute productivite
KR101699183B1 (ko) * 2015-12-24 2017-01-23 한화토탈 주식회사 에틸렌 비닐아세테이트 공중합체 수지의 제조방법 및 이로부터 제조된 수지와 이를 이용하여 제조된 태양전지 봉지재용 시트
KR101748971B1 (ko) * 2015-12-24 2017-06-20 한화토탈 주식회사 태양전지 봉지재 시트용 에틸렌 비닐아세테이트 공중합체 수지의 제조방법 및 그 제조방법으로 제조된 수지
KR101757565B1 (ko) * 2015-12-29 2017-07-12 한화토탈 주식회사 폴리에틸렌 또는 폴리에틸렌 비닐아세테이트 공중합체의 제조 방법
FR3047485A1 (fr) * 2016-02-10 2017-08-11 Arkema France Compositions de peroxydes organiques et pre- melange polymere
CN109715674B (zh) 2016-10-04 2021-03-16 阿克苏诺贝尔化学品国际有限公司 制备聚乙烯的方法
CN107892728A (zh) * 2017-11-27 2018-04-10 重庆长江造型材料（集团）股份有限公司 纳米填料支撑剂的制备方法

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US3764628A (en) * 1960-01-07 1973-10-09 Grace W R & Co Tertiary-tertiary bisperoxides
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BE756426A (fr) * 1969-09-23 1971-03-22 Basf Ag Procede de preparation d'homo- ou de copolymeres de l'ethylene
US4804775A (en) * 1986-09-09 1989-02-14 Pennwalt Corporation Process for reducing residual monomers in low viscosity polymer-polyols
JPS63168415A (ja) * 1987-01-02 1988-07-12 ペンウオルト・コ−ポレ−シヨン ｔ−アルキルヒドロペルオキシドを用いたアクリル酸誘導体モノマ−の溶液重合方法
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CN1068323C (zh) * 1994-07-21 2001-07-11 阿克佐诺贝尔公司 环酮过氧化物配制剂
DE4431613A1 (de) * 1994-09-05 1996-03-07 Peroxid Chemie Gmbh Verfahren zur Herstellung von Ethylen-Copolymeren
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SG97919A1 (en) * 1999-08-31 2003-08-20 Sumitomo Chemical Co Ethylene-alpha-olefin copolymer and polyethylene composition
WO2001068723A2 (de) * 2000-03-16 2001-09-20 Basell Polyolefine Gmbh Verfahren zur herstellung von polyethylen
DE10030306A1 (de) * 2000-06-27 2002-01-10 Basf Ag Prozeßoptimierung der Peroxid-Einspritzung während der Polyethylenherstellung
DE10102937A1 (de) * 2001-01-23 2002-07-25 Basf Ag Verfahren zur Herstellung von Ethylenpolymerisaten im Hochdruckverfahren
DE10128221A1 (de) * 2001-06-11 2002-12-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von Ethylenhomo-und -copolymeren durch radikalische Hochdruckpolymerisation
JP4774172B2 (ja) * 2001-08-23 2011-09-14 化薬アクゾ株式会社 アクリル樹脂の製造方法
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FR2971510B1 (fr) * 2011-02-10 2013-03-22 Arkema France Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite

Also Published As

Publication number Publication date
CA2825190C (fr) 2018-11-20
JP6161680B2 (ja) 2017-07-12
FR2971510A1 (fr) 2012-08-17
CN103339155A (zh) 2013-10-02
JP5859028B2 (ja) 2016-02-10
MX2013009207A (es) 2013-08-29
US20130310518A1 (en) 2013-11-21
KR101838771B1 (ko) 2018-03-14
FR2971510B1 (fr) 2013-03-22
EP2673307B2 (fr) 2022-06-22
BR112013020243A2 (pt) 2016-10-18
US9045571B2 (en) 2015-06-02
BR112013020243B1 (pt) 2020-04-22
JP2016094617A (ja) 2016-05-26
CO6781559A2 (es) 2013-10-31
CA2825190A1 (fr) 2012-08-16
CN106046213B (zh) 2018-09-18
ES2524692T5 (es) 2022-11-02
EP2673307A1 (fr) 2013-12-18
JP2014505152A (ja) 2014-02-27
WO2012107689A1 (fr) 2012-08-16
EP2673307B1 (fr) 2014-09-17
CN103339155B (zh) 2016-08-10
KR20140048095A (ko) 2014-04-23
CN106046213A (zh) 2016-10-26
MY181887A (en) 2021-01-12

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