ES2484367T3 - Método de protección contra el fuego y modificación de propiedades de poliésteres expandidos - Google Patents

Método de protección contra el fuego y modificación de propiedades de poliésteres expandidos Download PDF

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Publication number
ES2484367T3
ES2484367T3 ES10150608.7T ES10150608T ES2484367T3 ES 2484367 T3 ES2484367 T3 ES 2484367T3 ES 10150608 T ES10150608 T ES 10150608T ES 2484367 T3 ES2484367 T3 ES 2484367T3
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Prior art keywords
modification
expanded polyester
fire protection
protection method
recycled
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ES10150608.7T
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English (en)
Inventor
Jürgen WEIDINGER
Mika Meller
Jie Li
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Armacell Enterprise GmbH and Co KG
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Armacell Enterprise GmbH and Co KG
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    • B29C44/22—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length consisting of at least two parts of chemically or physically different materials, e.g. having different densities
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    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987—With nonvoid component of specified composition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987—With nonvoid component of specified composition
    • Y10T428/249988—Of about the same composition as, and adjacent to, the void-containing component
    • Y10T428/249989—Integrally formed skin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987—With nonvoid component of specified composition
    • Y10T428/249991—Synthetic resin or natural rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Structural Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Fireproofing Substances (AREA)

Abstract

Material que consiste en un poliéster expandido como un núcleo cubierto por al menos una capa protectora exterior consistente en poliéster no expandido que contiene entre un 0,5 y un 60 por ciento en peso de aditivos funcionales que son agentes ignífugos y agentes antihidrólisis, estando estos agentes ignífugos y agentes antihidrólisis basados en fósforo.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8
Tabla 1: Ingredientes de mezclas madre en polvo
Mezcla madre
Tipo de PET Aditivo ignífugo y dosificación en mezcla madre Proveedor
1
Virgen 40% Firebrake® 500 (borato) Borax Europe ltd., Guildford, Reino Unido
2
Virgen 40% Melapur® 200 (melamina) Ciba, Grenzach, Alemania
3
Virgen 50% Exolit®OP 1200 (fósforo) Clariant, Muttenz, Suiza
4
Virgen 60% Saytex® 8010 (bromado) Albemarle, Louvain, Bélgica
1A
Reciclado (Armacell) 40% Firebrake® 500 (borato) Borax Europe ltd., Guildford, Reino Unido
2A
Reciclado (Armacell) 40% Melapur® 200 (melamina) Ciba, Grenzach, Alemania
3A
Reciclado (Armacell) 50% Exolit®OP 1200 (fósforo) Clariant, Muttenz, Suiza
4A
Reciclado (Armacell) 60% Saytex® 8010 (bromado) Albemarle, Louvain, Bélgica
1R
Reciclado (mercado libre) 40% Firebrake® 500 (borato) Borax Europe ltd., Guildford, Reino Unido
2R
Reciclado (mercado libre) 40% Melapur® 200 (melamina) Ciba, Grenzach, Alemania
3R
Reciclado (mercado libre) 50% Exolit®OP 1200 (fósforo) Clariant, Muttenz, Suiza
4R
Reciclado (mercado libre) 60% Saytex® 8010 (bromado) Albemarle, Louvain, Bélgica
5R
Reciclado (mercado libre) 30% trihidrato de alúmina, 20% Saytex® 8010 Albemarle; Bergheim, Alemania
Los materiales compuestos producidos se examinaron parcialmente en cuanto al comportamiento ignífugo de acuerdo con EN 13823/EN 13501-1 (ensayo de
10
quemado simple/ensayo de esquinas redondas), DIN 4102, y UL 94 (quemado horizontal/vertical). La Tabla 2 muestra los resultados en comparación con una placa de espuma no tratada del mismo espesor (ejemplo comparativo, marcado con asterisco). Los ejemplos sin asteriscos comprenden el material reivindicado.
Tabla 2: Resultados de los ensayos de inflamabilidad (n.e.: no examinado)
Mezcla madre
EN 13823/ 13501-1 DIN 4102 Revestimiento UL94 en un lado/dos lados Evaluación
ninguna*
E fallo fallo Sumamente inflamable
1
D fallo HB Inflamable
2
C S3 d0 B1 V-2/V-1 Ignífugo
3
B S3 d1 B1 V-1/V-0 Muy ignífugo
4
C S3 d1 B2 V-2/V-1 Ignífugo
1A
D fallo HB Inflamable
2A
C S3 d0 B1 V-2/V-2 Ignífugo
3A
B S3 d1 B1 V-1/V-0 Muy ignífugo
4A
C S3 d1 B2 V-2/V-2 Ignífugo
1R
n.e. fallo HB Inflamable
2R
n.e. n.e. V-2/V-1 Ignífugo
3R
B S3 d1 B1 V-1/V-0 Muy ignífugo
4R
n.e. n.e. HB/V-2 Ignífugo
5R
B S3 d0 B1 V-1/V-0 Muy ignífugo
11

Claims (1)

  1. imagen1
ES10150608.7T 2010-01-13 2010-01-13 Método de protección contra el fuego y modificación de propiedades de poliésteres expandidos Active ES2484367T3 (es)

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KR101825115B1 (ko) 2018-02-02
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MX2011000443A (es) 2011-07-21
EP2345538B8 (en) 2014-07-23
EP2345538A1 (en) 2011-07-20
KR20110083523A (ko) 2011-07-20
TW201134663A (en) 2011-10-16
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