ES2388714T5 - Procedimiento para la descomposición catalítica de N2O y preparación del catalizador - Google Patents
Procedimiento para la descomposición catalítica de N2O y preparación del catalizador Download PDFInfo
- Publication number
- ES2388714T5 ES2388714T5 ES09788224.5T ES09788224T ES2388714T5 ES 2388714 T5 ES2388714 T5 ES 2388714T5 ES 09788224 T ES09788224 T ES 09788224T ES 2388714 T5 ES2388714 T5 ES 2388714T5
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- catalyst preparation
- catalytic decomposition
- catalytic
- decomposition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003054 catalyst Substances 0.000 title 1
- 238000003421 catalytic decomposition reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/02—Preparation of nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
- B01D53/8646—Simultaneous elimination of the components
- B01D53/865—Simultaneous elimination of the components characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
- B01J29/66—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
- B01J29/67—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
- B01J29/66—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
- B01J29/68—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/7415—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/7615—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/30—Ion-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1026—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
- B01D2255/502—Beta zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/402—Dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/44—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Description
Claims (1)
-
imagen1
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL2001788A NL2001788C2 (nl) | 2008-07-11 | 2008-07-11 | Werkwijze voor de decompositie van N2O, katalysator daarvoor en bereiding van deze katalysator. |
NL2001788 | 2008-07-11 | ||
PCT/NL2009/050420 WO2010005311A1 (en) | 2008-07-11 | 2009-07-10 | Method for the decomposition of n2o, catalyst for it, and the preparation of this catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2388714T3 ES2388714T3 (es) | 2012-10-17 |
ES2388714T5 true ES2388714T5 (es) | 2015-04-24 |
Family
ID=40340483
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES09788224.5T Active ES2388714T5 (es) | 2008-07-11 | 2009-07-10 | Procedimiento para la descomposición catalítica de N2O y preparación del catalizador |
Country Status (18)
Country | Link |
---|---|
US (1) | US8734746B2 (es) |
EP (1) | EP2358465B2 (es) |
JP (1) | JP2011527629A (es) |
KR (1) | KR101634826B1 (es) |
CN (1) | CN102316962B (es) |
AU (1) | AU2009270021B2 (es) |
BR (1) | BRPI0915855B1 (es) |
CA (1) | CA2733355C (es) |
CL (1) | CL2011000066A1 (es) |
CO (1) | CO6331452A2 (es) |
EA (1) | EA019176B1 (es) |
ES (1) | ES2388714T5 (es) |
HR (1) | HRP20120556T4 (es) |
MX (1) | MX2011000381A (es) |
NL (1) | NL2001788C2 (es) |
UA (1) | UA100743C2 (es) |
WO (1) | WO2010005311A1 (es) |
ZA (1) | ZA201100401B (es) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2567779T3 (es) | 2009-08-26 | 2016-04-26 | Jeffrey M. Golini | Composición farmacéutica o nutracéutica |
CN105312081B (zh) * | 2010-05-21 | 2020-09-15 | Pq公司 | 用于NOx还原的新型含金属的沸石β |
CN104245583B (zh) * | 2012-02-06 | 2017-05-03 | 巴斯夫欧洲公司 | 用于处理包含氮氧化物的气流的方法和设备 |
CN102921454B (zh) * | 2012-06-28 | 2015-07-22 | 北京化工大学 | 用于n2o直接催化分解的整体式bea分子筛催化剂的制备方法 |
CN103111322A (zh) * | 2013-02-03 | 2013-05-22 | 北京化工大学 | 一种n2o分解用整体蜂窝状分子筛催化剂制备方法 |
CN105233862B (zh) * | 2014-07-11 | 2018-10-23 | 中国石油化工股份有限公司 | 环己基苯催化剂及其制备方法 |
WO2018095882A1 (en) | 2016-11-22 | 2018-05-31 | Umicore Ag & Co. Kg | Iron containing catalyst |
US10801384B2 (en) * | 2017-03-06 | 2020-10-13 | Umicore Ag & Co. Kg | Diesel oxidation catalyst containing manganese |
CN108435237B (zh) * | 2018-04-08 | 2020-12-18 | 中冶京诚工程技术有限公司 | 一种中低温nh3-scr催化剂及其制备方法与应用 |
US10953366B2 (en) * | 2018-04-20 | 2021-03-23 | GM Global Technology Operations LLC | Nitrogen oxides and hydrocarbon storage catalyst and methods of using the same |
CN110918117B (zh) * | 2019-11-28 | 2023-03-21 | 浙江师范大学 | 一种用于消除含氮有机物的催化剂及其制备方法 |
JP2023509349A (ja) * | 2019-12-13 | 2023-03-08 | ビーエーエスエフ コーポレーション | CuおよびPdを含む、複合材中の共交換されたゼオライト |
KR102425528B1 (ko) * | 2020-10-28 | 2022-07-25 | 한국화학연구원 | 화학 기상 증착법을 이용한 저온활성이 향상된 deNOx 촉매의 제조방법 및 이로부터 제조된 deNOx촉매 |
CN113307239B (zh) * | 2021-06-09 | 2023-06-23 | 东华理工大学 | 一种制备氮氧化磷的方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07106300B2 (ja) † | 1989-12-08 | 1995-11-15 | 財団法人産業創造研究所 | 燃焼排ガス中の窒素酸化物除去法 |
JP3254742B2 (ja) * | 1992-07-03 | 2002-02-12 | 堺化学工業株式会社 | 亜酸化窒素分解用触媒 |
US6248684B1 (en) * | 1992-11-19 | 2001-06-19 | Englehard Corporation | Zeolite-containing oxidation catalyst and method of use |
EP0766992B1 (en) † | 1995-10-06 | 2003-07-30 | ENITECNOLOGIE S.p.a. | Nitrogen oxides reduction catalyst and process for reducing nitrogen oxides in exhaust gas |
JP3550653B2 (ja) | 2000-04-10 | 2004-08-04 | 独立行政法人産業技術総合研究所 | 亜酸化窒素ガス含有ガスの処理方法及びその処理触媒 |
US7438878B2 (en) † | 2001-03-12 | 2008-10-21 | Basf Catalysts Llc | Selective catalytic reduction of N2O |
NL1021116C2 (nl) * | 2002-07-19 | 2004-01-20 | Stichting Energie | Werkwijze voor het verwijderen van NOx en katalysator daarvoor. |
EP1567246A1 (en) † | 2002-11-25 | 2005-08-31 | YARA International ASA | Method for preparation and activation of multimetallic zeolite catalysts, a catalyst composition and application for n2-o abatement |
NL1026207C2 (nl) * | 2004-05-17 | 2005-11-21 | Stichting Energie | Werkwijze voor de decompositie van N2O, katalysator daarvoor en bereiding van deze katalysator. |
JP2006154611A (ja) | 2004-12-01 | 2006-06-15 | Konica Minolta Medical & Graphic Inc | 画像記録装置及び画像記録方法 |
WO2007004774A1 (en) * | 2005-07-06 | 2007-01-11 | Heesung Catalysts Corporation | An oxidation catalyst for nh3 and an apparatus for treating slipped or scrippedd nh3 |
DE102006013234A1 (de) * | 2006-03-22 | 2007-11-29 | Hte Ag The High Throughput Experimentation Company | Oxidationskatalysator |
DE102007063604A1 (de) † | 2007-05-24 | 2008-12-04 | Süd-Chemie AG | Metalldotierter Zeolith und Verfahren zu dessen Herstellung |
-
2008
- 2008-07-11 NL NL2001788A patent/NL2001788C2/nl not_active IP Right Cessation
-
2009
- 2009-07-10 ES ES09788224.5T patent/ES2388714T5/es active Active
- 2009-07-10 AU AU2009270021A patent/AU2009270021B2/en active Active
- 2009-07-10 WO PCT/NL2009/050420 patent/WO2010005311A1/en active Application Filing
- 2009-07-10 KR KR1020117003052A patent/KR101634826B1/ko active IP Right Grant
- 2009-07-10 MX MX2011000381A patent/MX2011000381A/es active IP Right Grant
- 2009-07-10 UA UAA201100291A patent/UA100743C2/ru unknown
- 2009-07-10 US US13/003,396 patent/US8734746B2/en active Active
- 2009-07-10 BR BRPI0915855A patent/BRPI0915855B1/pt active IP Right Grant
- 2009-07-10 CN CN200980127176.0A patent/CN102316962B/zh active Active
- 2009-07-10 CA CA2733355A patent/CA2733355C/en active Active
- 2009-07-10 EA EA201170184A patent/EA019176B1/ru not_active IP Right Cessation
- 2009-07-10 JP JP2011517369A patent/JP2011527629A/ja not_active Ceased
- 2009-07-10 EP EP09788224.5A patent/EP2358465B2/en active Active
-
2011
- 2011-01-11 CL CL2011000066A patent/CL2011000066A1/es unknown
- 2011-01-14 ZA ZA2011/00401A patent/ZA201100401B/en unknown
- 2011-01-18 CO CO11004792A patent/CO6331452A2/es active IP Right Grant
-
2012
- 2012-07-06 HR HRP20120556TT patent/HRP20120556T4/hr unknown
Also Published As
Publication number | Publication date |
---|---|
EA201170184A1 (ru) | 2011-08-30 |
CL2011000066A1 (es) | 2011-06-10 |
HRP20120556T1 (en) | 2012-07-31 |
EP2358465A1 (en) | 2011-08-24 |
EP2358465B1 (en) | 2012-06-20 |
ZA201100401B (en) | 2011-09-28 |
WO2010005311A1 (en) | 2010-01-14 |
ES2388714T3 (es) | 2012-10-17 |
BRPI0915855B1 (pt) | 2019-09-03 |
US8734746B2 (en) | 2014-05-27 |
CA2733355C (en) | 2016-11-29 |
US20110158877A1 (en) | 2011-06-30 |
KR101634826B1 (ko) | 2016-06-29 |
CN102316962A (zh) | 2012-01-11 |
EP2358465B2 (en) | 2015-03-11 |
CN102316962B (zh) | 2015-07-29 |
NL2001788C2 (nl) | 2010-01-12 |
MX2011000381A (es) | 2011-04-05 |
CO6331452A2 (es) | 2011-10-20 |
EA019176B1 (ru) | 2014-01-30 |
BRPI0915855A2 (pt) | 2015-11-03 |
UA100743C2 (ru) | 2013-01-25 |
KR20110041509A (ko) | 2011-04-21 |
CA2733355A1 (en) | 2010-01-14 |
AU2009270021B2 (en) | 2015-09-03 |
JP2011527629A (ja) | 2011-11-04 |
HRP20120556T4 (hr) | 2015-04-24 |
AU2009270021A1 (en) | 2010-01-14 |
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