ES2311210T3 - Copolimeros sobre la base de derivados de acidos mono- o di-carboxilicos insaturados y de oxialquilenglicol-alquenil-eteres, procedimientos para su preparacion, y su utilizacion. - Google Patents
Copolimeros sobre la base de derivados de acidos mono- o di-carboxilicos insaturados y de oxialquilenglicol-alquenil-eteres, procedimientos para su preparacion, y su utilizacion. Download PDFInfo
- Publication number
- ES2311210T3 ES2311210T3 ES05707171T ES05707171T ES2311210T3 ES 2311210 T3 ES2311210 T3 ES 2311210T3 ES 05707171 T ES05707171 T ES 05707171T ES 05707171 T ES05707171 T ES 05707171T ES 2311210 T3 ES2311210 T3 ES 2311210T3
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- Prior art keywords
- mol
- acid
- radical
- vinyl
- copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229920001577 copolymer Polymers 0.000 title claims abstract description 49
- 239000002253 acid Substances 0.000 title claims description 29
- 238000000034 method Methods 0.000 title claims description 17
- 238000002360 preparation method Methods 0.000 title claims description 9
- 150000007513 acids Chemical class 0.000 title description 6
- -1 ester compounds Chemical class 0.000 claims abstract description 48
- 239000011230 binding agent Substances 0.000 claims abstract description 15
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 9
- 239000000654 additive Substances 0.000 claims abstract description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 6
- 239000011707 mineral Substances 0.000 claims abstract description 6
- 239000007900 aqueous suspension Substances 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 36
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 11
- 150000003254 radicals Chemical class 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 230000000977 initiatory effect Effects 0.000 claims description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 8
- 150000005840 aryl radicals Chemical class 0.000 claims description 7
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- 229910052925 anhydrite Inorganic materials 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 2
- 239000011505 plaster Substances 0.000 claims description 2
- 229910001415 sodium ion Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 3
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims 1
- ATMLPEJAVWINOF-UHFFFAOYSA-N acrylic acid acrylic acid Chemical compound OC(=O)C=C.OC(=O)C=C ATMLPEJAVWINOF-UHFFFAOYSA-N 0.000 claims 1
- 229910001424 calcium ion Inorganic materials 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 1
- 229910001425 magnesium ion Inorganic materials 0.000 claims 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical group [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 claims 1
- 229910001414 potassium ion Inorganic materials 0.000 claims 1
- 230000000392 somatic effect Effects 0.000 claims 1
- 125000000542 sulfonic acid group Chemical group 0.000 claims 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 claims 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 21
- 239000004567 concrete Substances 0.000 abstract description 18
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 abstract description 6
- 239000000725 suspension Substances 0.000 abstract description 4
- 229920001515 polyalkylene glycol Polymers 0.000 abstract description 3
- 238000012545 processing Methods 0.000 abstract description 3
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 22
- 239000000203 mixture Substances 0.000 description 21
- 229920001223 polyethylene glycol Polymers 0.000 description 17
- 239000000243 solution Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 239000004566 building material Substances 0.000 description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
- 238000010276 construction Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 5
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 4
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 150000003460 sulfonic acids Chemical class 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000009415 formwork Methods 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 230000036316 preload Effects 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000012935 ammoniumperoxodisulfate Substances 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 229940035422 diphenylamine Drugs 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical compound C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- IOTXOXUMAGBQJL-UHFFFAOYSA-N iron(2+);heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2] IOTXOXUMAGBQJL-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- GNVRJGIVDSQCOP-UHFFFAOYSA-N n-ethyl-n-methylethanamine Chemical compound CCN(C)CC GNVRJGIVDSQCOP-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000005076 polymer ester Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011178 precast concrete Substances 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2641—Polyacrylates; Polymethacrylates
- C04B24/2647—Polyacrylates; Polymethacrylates containing polyether side chains
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2664—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of ethylenically unsaturated dicarboxylic acid polymers, e.g. maleic anhydride copolymers
- C04B24/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of ethylenically unsaturated dicarboxylic acid polymers, e.g. maleic anhydride copolymers containing polyether side chains
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/302—Water reducers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/1416—Monomers containing oxygen in addition to the ether oxygen, e.g. allyl glycidyl ether
- C08F216/1425—Monomers containing side chains of polyether groups
- C08F216/145—Monomers containing side chains of polyethylene-co-propylene oxide groups
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004005434A DE102004005434A1 (de) | 2004-02-04 | 2004-02-04 | Copolymere auf Basis von ungesättigten Mono- oder Dicarbonsäure-Derivaten und Oxyalkylenglykol-Alkenylethern, Verfahren zu deren Herstellung und ihre Verwendung |
| DE102004005434 | 2004-02-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2311210T3 true ES2311210T3 (es) | 2009-02-01 |
Family
ID=34801545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES05707171T Expired - Lifetime ES2311210T3 (es) | 2004-02-04 | 2005-02-03 | Copolimeros sobre la base de derivados de acidos mono- o di-carboxilicos insaturados y de oxialquilenglicol-alquenil-eteres, procedimientos para su preparacion, y su utilizacion. |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US20070161724A1 (enExample) |
| EP (1) | EP1711544B1 (enExample) |
| JP (1) | JP4942032B2 (enExample) |
| KR (1) | KR101159042B1 (enExample) |
| CN (1) | CN100575375C (enExample) |
| AT (1) | ATE411344T1 (enExample) |
| AU (1) | AU2005209997B2 (enExample) |
| BR (1) | BRPI0507444B1 (enExample) |
| CA (1) | CA2554763C (enExample) |
| DE (2) | DE102004005434A1 (enExample) |
| ES (1) | ES2311210T3 (enExample) |
| MX (1) | MXPA06008842A (enExample) |
| WO (1) | WO2005075529A2 (enExample) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005061153A1 (de) * | 2005-12-21 | 2007-06-28 | Construction Research & Technology Gmbh | Copolymere auf Basis von ungesättigten Mono- oder Dicarbonsäure-Derivaten und Oxyalkylenglykol-Alkenylethern, Verfahren zu deren Herstellung und ihre Verwendung |
| DE102006049381A1 (de) * | 2006-10-19 | 2008-04-24 | Süd-Chemie AG | Amphiphile Pfropfpolymere |
| EP2090599A1 (de) * | 2008-02-13 | 2009-08-19 | Construction Research and Technology GmbH | Copolymer mit Polyetherseitenketten und Dicarbonsäurederivatbausteinen |
| EP2090597A1 (de) | 2008-02-13 | 2009-08-19 | Construction Research and Technology GmbH | Wässrige Lösung enthaltend Copolymer mit Polyetherseitenketten |
| EP2090596A1 (de) | 2008-02-13 | 2009-08-19 | Construction Research and Technology GmbH | Copolymer mit Polyetherseitenketten und Hydroxyalkyl- und Säurebausteinen |
| EP2257578B1 (de) | 2008-03-19 | 2014-08-13 | Construction Research & Technology GmbH | Semikontinuierlich betriebenes verfahren zur herstellung von copolymeren |
| US7973110B2 (en) | 2008-06-16 | 2011-07-05 | Construction Research & Technology Gmbh | Copolymer synthesis process |
| DE102008040329A1 (de) * | 2008-07-10 | 2010-01-14 | Construction Research & Technology Gmbh | Verfahren zur Herstellung von Copolymeren mit einem reduzierten Acetaldehyd-Gehalt |
| EP2310157B1 (de) * | 2008-07-23 | 2013-04-10 | Construction Research & Technology GmbH | Verfahren zur herstellung von metallnanopartikeln in polyolen |
| US20110144288A1 (en) * | 2008-08-08 | 2011-06-16 | Simone Klapdohr | Production of Silylated Polyurethane and/or Polyurea |
| WO2010029117A2 (en) * | 2008-09-11 | 2010-03-18 | Construction Research & Technology Gmbh | Dynamic copolymers for workability retention of cementitious composition |
| SA109300600B1 (ar) * | 2008-10-09 | 2013-01-02 | كونستروكشن ريسيرتش آند تكنولوجي جي ام بي اتش | مواد إعاقة امتزاز لركام في خلطات مادة بناء تحتوي على مادة تلدين |
| WO2010040794A1 (de) * | 2008-10-10 | 2010-04-15 | Construction Research & Technology Gmbh | KONTINUIERLICHE HERSTELLUNG VON SICH ALS FLIEßMITTEL EIGNENDEN COPOLYMEREN |
| WO2010066577A1 (de) * | 2008-12-08 | 2010-06-17 | Construction Research & Technology Gmbh | Semikontinuierlich betriebenes verfahren zur herstellung von copolymeren |
| EP2194077A1 (de) * | 2008-12-08 | 2010-06-09 | Construction Research and Technology GmbH | Verfahren zur Herstellung von wässrigen Copolymerzubereitungen |
| EP2194078B1 (de) | 2008-12-08 | 2013-03-13 | Construction Research & Technology GmbH | Verfahren zur Herstellung von Copolymeren |
| CA2745417C (en) | 2008-12-08 | 2016-12-20 | Silke Flakus | Copolymer containing acid building blocks and various types of polyether building blocks |
| EP2194076A1 (de) | 2008-12-08 | 2010-06-09 | Construction Research and Technology GmbH | Semikontinuierlich betriebenes Verfahren zur Herstellung von Copolymeren |
| WO2010066576A1 (de) * | 2008-12-08 | 2010-06-17 | Construction Research & Technology Gmbh | Semikontinuierlich betriebenes verfahren zur herstellung von copolymeren |
| EP2194079A1 (de) | 2008-12-08 | 2010-06-09 | Construction Research and Technology GmbH | Semikontinuierlich betriebenes Verfahren zur Herstellung von Copolymeren |
| ES2467671T3 (es) * | 2008-12-08 | 2014-06-12 | Construction Research & Technology Gmbh | Agente dispersante que contiene mezcla de copolímeros |
| EP2373737B1 (de) * | 2008-12-08 | 2014-05-14 | Construction Research & Technology GmbH | Copolymermischung enthaltendes dispergiermittel |
| EP2193838B1 (de) * | 2008-12-08 | 2011-03-02 | Construction Research & Technology GmbH | Semikontinuierlich betriebenes Verfahren zur Herstellung von Copolymeren |
| EP2373706B1 (de) | 2008-12-08 | 2016-06-08 | Construction Research & Technology GmbH | Wasserfrei herstellbare polymerisationsmischung |
| EP2373736B1 (de) * | 2008-12-08 | 2014-05-14 | Construction Research & Technology GmbH | Copolymermischung enthaltendes dispergiermittel |
| TWI471370B (zh) * | 2008-12-15 | 2015-02-01 | Teijin Ltd | Method of using cyclic carbodiimide |
| EP2443923A1 (de) | 2010-10-25 | 2012-04-25 | Basf Se | Zusammensetzung umfassend ein Pestizid und ein Polycarboxylatether |
| CN103179853A (zh) * | 2010-10-11 | 2013-06-26 | 巴斯夫欧洲公司 | 包含农药和聚羧酸化物醚的组合物 |
| EP2463317A1 (de) | 2010-12-09 | 2012-06-13 | BASF Construction Polymers GmbH | Additiv für fließmittel enthaltende Baustoffmischungen |
| EP2522680B1 (de) * | 2011-05-10 | 2013-08-07 | Sika Technology AG | Polymer aus Maleinsäure, Allylether und (Meth-)Acrylsäureverbindungen, dessen Herstellung und Verwendung |
| WO2012156148A1 (en) * | 2011-05-16 | 2012-11-22 | Basf Se | Use of polyether-containing copolymers in the cementing of boreholes |
| EP2742995A1 (de) | 2012-12-11 | 2014-06-18 | Construction Research & Technology GmbH | Kontinuierliches Verfahren zur Herstellung von Copolymeren |
| CN103059231B (zh) * | 2013-01-16 | 2014-10-08 | 山西大学 | 一种梳型高分子固沙保水剂及其制备方法 |
| US9126866B2 (en) | 2013-03-06 | 2015-09-08 | Construction Research & Technology Gmbh | Polycarboxylate ethers with branched side chains |
| EP2774899A1 (de) | 2013-03-06 | 2014-09-10 | Construction Research & Technology GmbH | Polycarboxylatether mit verzweigten Seitenketten |
| RU2624818C2 (ru) * | 2013-05-29 | 2017-07-07 | Силкроуд К Энд Т | Макромономер для получения добавки к цементу, способ его получения, добавка к цементу, включающая поликарбоксильный сополимер, полученный из макромономера и слоистого двойного гидроксида, и способ получения добавки к цементу |
| KR101572122B1 (ko) * | 2014-03-06 | 2015-11-26 | 한국산노프코 주식회사 | 시멘트 분산제 및 제조방법과 이를 이용한 모르타르·콘크리트 혼화제 |
| JP6386282B2 (ja) * | 2014-07-17 | 2018-09-05 | 株式会社日本触媒 | セメント分散剤およびセメント組成物 |
| JP6747962B2 (ja) * | 2016-01-04 | 2020-08-26 | 株式会社日本触媒 | セメント用添加剤およびセメント組成物 |
| WO2019100372A1 (zh) * | 2017-11-27 | 2019-05-31 | 科之杰新材料集团有限公司 | 一种掺量低敏感型聚羧酸的快速低温制备方法 |
| CN111995717A (zh) * | 2020-08-20 | 2020-11-27 | 安徽海螺新材料科技有限公司 | 一种高性能聚羧酸减水剂及其制备方法、一种混凝土 |
| WO2024056497A1 (en) * | 2022-09-16 | 2024-03-21 | Basf Se | Water-soluble polymer comprising hydroxamic acid groups |
| WO2025035453A1 (en) * | 2023-08-17 | 2025-02-20 | Sika Technology Ag | Polycarboxylate based dispesant |
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| DE3671913D1 (de) * | 1985-08-12 | 1990-07-19 | Allied Colloids Ltd | Waessrige klebstoffe und deren verwendung. |
| EP0537870A1 (en) * | 1991-10-18 | 1993-04-21 | W.R. Grace & Co.-Conn. | Copolymers of ethylenically unsaturated ethers useful as hydraulic cement superplasticizers |
| AU664812B2 (en) * | 1992-02-14 | 1995-11-30 | Nof Corporation | Cement admixture composition |
| JP3420274B2 (ja) * | 1993-04-05 | 2003-06-23 | ダブリュー・アール・グレース・アンド・カンパニー−コーン | 流動性低下防止に優れた新規なセメント分散剤組成物 |
| DE4328817A1 (de) * | 1993-08-27 | 1995-03-02 | Basf Ag | Wasserlösliche, Carboxylgruppen enthaltende Copolymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung als Scaleinhibitor |
| DE19513126A1 (de) * | 1995-04-07 | 1996-10-10 | Sueddeutsche Kalkstickstoff | Copolymere auf Basis von Oxyalkylenglykol-Alkenylethern und ungesättigten Dicarbonsäure-Derivaten |
| DE19529348C2 (de) * | 1995-08-09 | 1997-11-20 | Stockhausen Chem Fab Gmbh | Absorptionsmittel für Wasser und wäßrige Flüssigkeiten auf Polyacrylatbasis sowie Verfahren zu ihrer Herstellung und Verwendung |
| WO1998025735A1 (en) * | 1996-12-13 | 1998-06-18 | Koninklijke Philips Electronics N.V. | Hair-cutting system including a hair-cutting apparatus having an adjustment button and an on/off button |
| US5912284A (en) | 1996-12-26 | 1999-06-15 | Nippon Shokubai Co., Ltd. | Cement additive, its production process and use |
| DE19834173A1 (de) * | 1997-08-01 | 1999-02-04 | Sueddeutsche Kalkstickstoff | Copolymere auf Basis von ungesättigten Dicarbonsäure-Derivaten und Oxyalkylenglykol-Alkenylethern |
| EP0985691A1 (en) * | 1998-09-10 | 2000-03-15 | Dow Deutschland Inc., Zweigniederlassung Stade | Process for preparing hydrophobically modified low foaming copolymers, hydrophobically modified low foaming copolymers and their use as cement additives |
| DE19926611A1 (de) * | 1999-06-11 | 2000-12-14 | Sueddeutsche Kalkstickstoff | Copolymere auf Basis von ungesättigten Mono- oder Dicarbonsäure-Derivaten und Oxyalkylenglykol-Alkenylethern, Verfahren zu deren Herstellung und ihre Verwendung |
| CA2325972A1 (en) * | 1999-11-24 | 2001-05-24 | Dainippon Ink And Chemicals, Inc. | Compatibilizing agent, radical copolymerizable unsaturated resin composition, molding material, and molded article |
| JP3583343B2 (ja) | 1999-11-29 | 2004-11-04 | 松下電器産業株式会社 | 通信端末装置、基地局装置および送信電力制御方法 |
| US6875801B2 (en) * | 1999-12-10 | 2005-04-05 | Construction Research & Technology Gmbh | Solubilized defoamers for cementitious compositions |
| CN1109004C (zh) * | 2000-04-04 | 2003-05-21 | 北京市建筑材料科学研究院 | 聚羧酸系引气高效混凝土减水剂 |
| JP2002348161A (ja) * | 2001-05-28 | 2002-12-04 | Nippon Shokubai Co Ltd | セメント分散剤、その製造方法およびその用途 |
| DE10136447A1 (de) * | 2001-07-26 | 2003-02-06 | Bayer Ag | Pfropfpolymerisate auf Basis von Polyalkylenoxiden |
| CN1120136C (zh) * | 2001-09-29 | 2003-09-03 | 华南理工大学 | 氨基磺酸系高效减水剂及其制备方法 |
| JP2003221266A (ja) * | 2002-01-30 | 2003-08-05 | Nippon Shokubai Co Ltd | セメント混和剤 |
-
2004
- 2004-02-04 DE DE102004005434A patent/DE102004005434A1/de not_active Withdrawn
-
2005
- 2005-02-03 KR KR1020067015642A patent/KR101159042B1/ko not_active Expired - Fee Related
- 2005-02-03 BR BRPI0507444-4A patent/BRPI0507444B1/pt not_active IP Right Cessation
- 2005-02-03 AU AU2005209997A patent/AU2005209997B2/en not_active Ceased
- 2005-02-03 EP EP05707171A patent/EP1711544B1/de not_active Expired - Lifetime
- 2005-02-03 ES ES05707171T patent/ES2311210T3/es not_active Expired - Lifetime
- 2005-02-03 DE DE502005005688T patent/DE502005005688D1/de not_active Expired - Lifetime
- 2005-02-03 CA CA2554763A patent/CA2554763C/en not_active Expired - Fee Related
- 2005-02-03 MX MXPA06008842A patent/MXPA06008842A/es active IP Right Grant
- 2005-02-03 JP JP2006551803A patent/JP4942032B2/ja not_active Expired - Fee Related
- 2005-02-03 AT AT05707171T patent/ATE411344T1/de not_active IP Right Cessation
- 2005-02-03 US US10/588,041 patent/US20070161724A1/en not_active Abandoned
- 2005-02-03 CN CN200580004031A patent/CN100575375C/zh not_active Expired - Fee Related
- 2005-02-03 WO PCT/EP2005/001087 patent/WO2005075529A2/de not_active Ceased
-
2011
- 2011-02-11 US US13/025,423 patent/US20110136944A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| KR101159042B1 (ko) | 2012-07-06 |
| EP1711544B1 (de) | 2008-10-15 |
| MXPA06008842A (es) | 2007-02-16 |
| CN100575375C (zh) | 2009-12-30 |
| BRPI0507444B1 (pt) | 2014-12-02 |
| US20070161724A1 (en) | 2007-07-12 |
| US20110136944A1 (en) | 2011-06-09 |
| DE102004005434A1 (de) | 2005-08-25 |
| JP4942032B2 (ja) | 2012-05-30 |
| WO2005075529A3 (de) | 2006-11-30 |
| EP1711544A2 (de) | 2006-10-18 |
| CA2554763C (en) | 2012-12-18 |
| AU2005209997B2 (en) | 2010-09-16 |
| ATE411344T1 (de) | 2008-10-15 |
| BRPI0507444A (pt) | 2007-07-10 |
| WO2005075529A2 (de) | 2005-08-18 |
| JP2007523235A (ja) | 2007-08-16 |
| DE502005005688D1 (de) | 2008-11-27 |
| AU2005209997A1 (en) | 2005-08-18 |
| CN1997679A (zh) | 2007-07-11 |
| KR20070028310A (ko) | 2007-03-12 |
| CA2554763A1 (en) | 2005-08-18 |
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