ES2242754T3 - Membrana de poliamida con estabilidad reforzada frente a la hidrolisis y procedimiento para su preparacion. - Google Patents
Membrana de poliamida con estabilidad reforzada frente a la hidrolisis y procedimiento para su preparacion.Info
- Publication number
- ES2242754T3 ES2242754T3 ES01947310T ES01947310T ES2242754T3 ES 2242754 T3 ES2242754 T3 ES 2242754T3 ES 01947310 T ES01947310 T ES 01947310T ES 01947310 T ES01947310 T ES 01947310T ES 2242754 T3 ES2242754 T3 ES 2242754T3
- Authority
- ES
- Spain
- Prior art keywords
- polyamide
- temperature
- membrane
- polymer
- solvent system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002647 polyamide Polymers 0.000 title claims abstract description 162
- 239000004952 Polyamide Substances 0.000 title claims abstract description 161
- 239000012528 membrane Substances 0.000 title claims abstract description 158
- 238000000034 method Methods 0.000 title claims abstract description 72
- 230000007062 hydrolysis Effects 0.000 title claims abstract description 22
- 238000006460 hydrolysis reaction Methods 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 97
- 229920000642 polymer Polymers 0.000 claims abstract description 61
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 41
- 239000000203 mixture Substances 0.000 claims abstract description 29
- 239000003381 stabilizer Substances 0.000 claims abstract description 28
- 238000005191 phase separation Methods 0.000 claims abstract description 27
- 238000001816 cooling Methods 0.000 claims abstract description 24
- 239000007788 liquid Substances 0.000 claims abstract description 21
- 239000002826 coolant Substances 0.000 claims abstract description 19
- 239000012071 phase Substances 0.000 claims abstract description 18
- 238000007711 solidification Methods 0.000 claims abstract description 18
- 230000008023 solidification Effects 0.000 claims abstract description 18
- 239000012456 homogeneous solution Substances 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 238000000465 moulding Methods 0.000 claims abstract description 10
- 239000007791 liquid phase Substances 0.000 claims abstract description 9
- 238000000926 separation method Methods 0.000 claims abstract description 7
- 239000004953 Aliphatic polyamide Substances 0.000 claims abstract description 5
- 229920003231 aliphatic polyamide Polymers 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 150000001875 compounds Chemical class 0.000 claims description 32
- 230000001954 sterilising effect Effects 0.000 claims description 32
- 238000004659 sterilization and disinfection Methods 0.000 claims description 32
- 239000000126 substance Substances 0.000 claims description 32
- 229940126062 Compound A Drugs 0.000 claims description 20
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 20
- 239000011148 porous material Substances 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 229920002292 Nylon 6 Polymers 0.000 claims description 12
- 230000003078 antioxidant effect Effects 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 238000004090 dissolution Methods 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 230000006641 stabilisation Effects 0.000 claims description 4
- 238000011105 stabilization Methods 0.000 claims description 4
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 claims description 3
- 239000011241 protective layer Substances 0.000 claims description 3
- DMHHYBUEZRZGDK-UHFFFAOYSA-N 2-(3,5-ditert-butyl-4-hydroxyphenyl)propanamide Chemical compound NC(=O)C(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 DMHHYBUEZRZGDK-UHFFFAOYSA-N 0.000 claims description 2
- WPMYUUITDBHVQZ-UHFFFAOYSA-M 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-M 0.000 claims 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 2
- 239000000155 melt Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 47
- 238000012360 testing method Methods 0.000 description 18
- 230000015556 catabolic process Effects 0.000 description 17
- 238000006731 degradation reaction Methods 0.000 description 17
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000012510 hollow fiber Substances 0.000 description 10
- 229920006045 Akulon® Polymers 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 229920001223 polyethylene glycol Polymers 0.000 description 7
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 229940105990 diglycerin Drugs 0.000 description 5
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
- 229920000572 Nylon 6/12 Polymers 0.000 description 4
- 239000012736 aqueous medium Substances 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 235000019253 formic acid Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229930188620 butyrolactone Natural products 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- -1 for For example Substances 0.000 description 3
- 238000005057 refrigeration Methods 0.000 description 3
- 238000002145 thermally induced phase separation Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920003620 Grilon® Polymers 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 229910002056 binary alloy Inorganic materials 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 238000001471 micro-filtration Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000000108 ultra-filtration Methods 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 229920002556 Polyethylene Glycol 300 Polymers 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 229920006097 Ultramide® Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001891 gel spinning Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 238000001631 haemodialysis Methods 0.000 description 1
- 230000000322 hemodialysis Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000409 membrane extraction Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
- B01D67/0018—Thermally induced processes [TIPS]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/003—Organic membrane manufacture by inducing porosity into non porous precursor membranes by selective elimination of components, e.g. by leaching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/56—Polyamides, e.g. polyester-amides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/22—Thermal or heat-resistance properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/30—Chemical resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/34—Molecular weight or degree of polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Dispersion Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Moulding By Coating Moulds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10027701 | 2000-06-03 | ||
| DE10027701 | 2000-06-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2242754T3 true ES2242754T3 (es) | 2005-11-16 |
Family
ID=7644688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES01947310T Expired - Lifetime ES2242754T3 (es) | 2000-06-03 | 2001-05-23 | Membrana de poliamida con estabilidad reforzada frente a la hidrolisis y procedimiento para su preparacion. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7201860B2 (enExample) |
| EP (1) | EP1289636B1 (enExample) |
| JP (2) | JP4808902B2 (enExample) |
| KR (1) | KR100802348B1 (enExample) |
| CN (1) | CN1214854C (enExample) |
| AT (1) | ATE297799T1 (enExample) |
| AU (1) | AU2001269034A1 (enExample) |
| DE (1) | DE50106526D1 (enExample) |
| ES (1) | ES2242754T3 (enExample) |
| WO (1) | WO2001093994A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6261589A (ja) * | 1985-09-10 | 1987-03-18 | Fuji Oil Co Ltd | グリセリド油脂の加工法 |
| US7229665B2 (en) | 2001-05-22 | 2007-06-12 | Millipore Corporation | Process of forming multilayered structures |
| US7942274B2 (en) * | 2000-05-24 | 2011-05-17 | Millipore Corporation | High-throughput asymmetric membrane |
| WO2010038414A1 (ja) | 2008-09-30 | 2010-04-08 | ユニチカ株式会社 | ポリアミド中空糸膜及びその製造方法 |
| KR101495210B1 (ko) * | 2010-03-26 | 2015-02-24 | 코오롱플라스틱 주식회사 | 폴리아미드 수지 조성물 |
| US20130098830A1 (en) * | 2010-06-30 | 2013-04-25 | Nitto Denko Corporation | Method for producing porous thermosetting resin sheet and composite separation membrane using same |
| CN103127845A (zh) * | 2011-12-05 | 2013-06-05 | 杭州费尔过滤技术有限公司 | 一种无支撑聚酰胺微孔膜及其制备方法 |
| WO2014196835A1 (ko) | 2013-06-07 | 2014-12-11 | 주식회사 엘지화학 | 내산화성 및 내염소성이 우수한 폴리아미드계 수처리 분리막 및 그 제조방법 |
| JP2015116539A (ja) * | 2013-12-19 | 2015-06-25 | 東レ株式会社 | 複合半透膜およびその製造方法 |
| EP3106139A1 (de) | 2015-06-17 | 2016-12-21 | 3M Innovative Properties Company | Brandwundauflage mit polyamidmembran |
| KR102225919B1 (ko) | 2016-06-27 | 2021-03-11 | 엔테그리스, 아이엔씨. | 제어된 수축을 거쳐 제조된 고도의 보유성 폴리아미드 중공 섬유 멤브레인 |
| EP3421117A1 (en) | 2017-06-28 | 2019-01-02 | 3M Innovative Properties Company | Polyamide flat sheet membranes with microporous surface structure for nanoparticle retention |
| US20210001278A1 (en) * | 2017-12-04 | 2021-01-07 | King Abdullah University Of Science And Technology | Methods of making porous membranes |
| WO2022229748A1 (en) | 2021-04-29 | 2022-11-03 | 3M Innovative Properties Company | Surface-modified polymeric membranes and method of making thereof |
| WO2024122564A1 (ja) * | 2022-12-07 | 2024-06-13 | 旭化成株式会社 | 半透膜の再生方法 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2630421A (en) * | 1951-01-24 | 1953-03-03 | Du Pont | Stabilization of polyamides |
| US3644482A (en) * | 1961-10-30 | 1972-02-22 | Geigy Ag J R | (4-hydroxy-5-alkylphenyl) alkanoic acid esters of polyols |
| US3285855A (en) * | 1965-03-11 | 1966-11-15 | Geigy Chem Corp | Stabilization of organic material with esters containing an alkylhydroxy-phenyl group |
| DE1694067A1 (de) * | 1966-04-28 | 1971-06-09 | Bayer Ag | Stabilisierte Polyamide |
| US3454412A (en) * | 1966-10-19 | 1969-07-08 | Gen Mills Inc | Stabilized synthetic polyamides |
| US4247498A (en) * | 1976-08-30 | 1981-01-27 | Akzona Incorporated | Methods for making microporous products |
| US4519909A (en) * | 1977-07-11 | 1985-05-28 | Akzona Incorporated | Microporous products |
| JPS6388004A (ja) * | 1978-05-15 | 1988-04-19 | ポール・コーポレーション | ポリアミド微孔質膜 |
| US4340480A (en) | 1978-05-15 | 1982-07-20 | Pall Corporation | Process for preparing liquophilic polyamide membrane filter media and product |
| NO153836C (no) * | 1978-05-15 | 1986-06-04 | Pall Corp | Hydrofile, alkoholuopploeslige polyamidmembraner og fremgangsmaate for deres fremstilling. |
| US4181606A (en) * | 1978-06-06 | 1980-01-01 | Monsanto Company | Lactam terpolymer membranes |
| US4274965A (en) | 1978-06-06 | 1981-06-23 | Monsanto Company | Lactam terpolymer membranes |
| US4711793A (en) * | 1980-10-27 | 1987-12-08 | Cuno Incorporated | Process for charge modifying a microphorous membrane |
| DE3205289C2 (de) | 1982-02-15 | 1984-10-31 | Akzo Gmbh, 5600 Wuppertal | Verfahren zur Herstellung von porösen Körpern mit einstellbarem Gesamtporenvolumen, einstellbarer Porengröße und einstellbarer Porenwandung |
| JPS60500406A (ja) * | 1983-02-02 | 1985-03-28 | メムテツク リミテツド | 架橋した多孔質膜 |
| IL78169A0 (en) * | 1986-03-17 | 1986-07-31 | Weizmann Kiryat Membrane Prod | Novel membranes and process for making them |
| JPH0286819A (ja) * | 1988-09-21 | 1990-03-27 | Nippon Steel Corp | シート状多孔質分離膜およびその製造方法 |
| IE62001B1 (en) * | 1988-11-10 | 1994-12-14 | Memtec Ltd | Extrusion of hollow fibre membranes |
| JP2917401B2 (ja) * | 1990-04-20 | 1999-07-12 | 三菱化学株式会社 | 耐熱水性の優れた二軸延伸ポリアミドフィルム |
| US5698101A (en) * | 1990-07-09 | 1997-12-16 | Memtec Limited | Hollow fiber membranes |
| US5458782A (en) * | 1994-01-07 | 1995-10-17 | Cuno Incorporated | Hydrolytically stable nylon membrane |
| JPH07268209A (ja) * | 1994-03-30 | 1995-10-17 | Mitsubishi Chem Corp | フィルム成形用ポリアミド樹脂組成物及びそれよりなる二軸延伸ポリアミドフィルム |
| KR0183370B1 (ko) * | 1995-07-07 | 1999-04-15 | 김은영 | 방향족 폴리에스테르 또는 방향족 폴리에스테르와 폴리아미드 공중합체의 활성층을 갖는 역삼투용 복합막 |
| US6413070B1 (en) * | 1997-04-11 | 2002-07-02 | Cuno Incorporated | System for manufacturing reinforced three-zone microporous membrane |
| JPH1112372A (ja) * | 1997-06-25 | 1999-01-19 | Toyobo Co Ltd | 金属板被覆用フィルム、成形加工用フィルム被覆金属板及びその製造法 |
| SG68701A1 (en) * | 1997-12-05 | 1999-11-16 | Ciba Sc Holding Ag | Stabilisation of polyamide polyester and polyacetal |
| US6146757A (en) * | 1998-06-29 | 2000-11-14 | Techmer Pm | Wettable polymer fibers, compositions for preparaing same and articles made therefrom |
| US6723759B2 (en) * | 1999-05-07 | 2004-04-20 | Mitsubishi Engineering-Plastics Corporation | Recycled resin composition and method for producing the same |
| DE60043333D1 (de) * | 1999-12-28 | 2009-12-31 | Kao Corp | Tinte auf Wasserbasis |
| EP1247560B1 (de) * | 2001-04-03 | 2004-06-23 | Sympatex Technologies GmbH | Porenfreie atmungsaktive Membran enthaltend Polyamid 4.6 |
-
2001
- 2001-05-23 CN CNB01810634XA patent/CN1214854C/zh not_active Expired - Lifetime
- 2001-05-23 DE DE50106526T patent/DE50106526D1/de not_active Expired - Lifetime
- 2001-05-23 ES ES01947310T patent/ES2242754T3/es not_active Expired - Lifetime
- 2001-05-23 US US10/297,179 patent/US7201860B2/en not_active Expired - Lifetime
- 2001-05-23 AU AU2001269034A patent/AU2001269034A1/en not_active Abandoned
- 2001-05-23 WO PCT/EP2001/005918 patent/WO2001093994A1/de not_active Ceased
- 2001-05-23 AT AT01947310T patent/ATE297799T1/de not_active IP Right Cessation
- 2001-05-23 JP JP2002501560A patent/JP4808902B2/ja not_active Expired - Lifetime
- 2001-05-23 KR KR1020027016453A patent/KR100802348B1/ko not_active Expired - Lifetime
- 2001-05-23 EP EP01947310A patent/EP1289636B1/de not_active Expired - Lifetime
-
2011
- 2011-05-09 JP JP2011104526A patent/JP2011200863A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011200863A (ja) | 2011-10-13 |
| WO2001093994A8 (de) | 2004-03-04 |
| WO2001093994A1 (de) | 2001-12-13 |
| AU2001269034A1 (en) | 2001-12-17 |
| DE50106526D1 (de) | 2005-07-21 |
| EP1289636B1 (de) | 2005-06-15 |
| US7201860B2 (en) | 2007-04-10 |
| KR100802348B1 (ko) | 2008-02-13 |
| CN1214854C (zh) | 2005-08-17 |
| EP1289636A1 (de) | 2003-03-12 |
| JP2003534908A (ja) | 2003-11-25 |
| ATE297799T1 (de) | 2005-07-15 |
| US20030159984A1 (en) | 2003-08-28 |
| KR20030038551A (ko) | 2003-05-16 |
| CN1431926A (zh) | 2003-07-23 |
| JP4808902B2 (ja) | 2011-11-02 |
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