ES2216031T3 - Copolimeros de elevado peso molecular. - Google Patents
Copolimeros de elevado peso molecular.Info
- Publication number
- ES2216031T3 ES2216031T3 ES96118856T ES96118856T ES2216031T3 ES 2216031 T3 ES2216031 T3 ES 2216031T3 ES 96118856 T ES96118856 T ES 96118856T ES 96118856 T ES96118856 T ES 96118856T ES 2216031 T3 ES2216031 T3 ES 2216031T3
- Authority
- ES
- Spain
- Prior art keywords
- carbon atoms
- group
- methyl
- mol
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241001282138 Antigonia capros Species 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 53
- 229920001577 copolymer Polymers 0.000 claims abstract description 47
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 19
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 55
- 239000003054 catalyst Substances 0.000 claims description 51
- -1 8 to 12 carbon atoms Chemical compound 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 26
- 125000004429 atom Chemical group 0.000 claims description 24
- 239000001257 hydrogen Substances 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 23
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 22
- 229910052726 zirconium Inorganic materials 0.000 claims description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 15
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
- 150000002431 hydrogen Chemical class 0.000 claims description 8
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 125000005018 aryl alkenyl group Chemical group 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 229910052732 germanium Inorganic materials 0.000 claims description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052729 chemical element Inorganic materials 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 125000004407 fluoroaryl group Chemical group 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 abstract description 34
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 33
- 150000001336 alkenes Chemical class 0.000 abstract description 15
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 8
- 101150068479 chrb gene Proteins 0.000 abstract 1
- 229920002959 polymer blend Polymers 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 147
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 87
- 239000000243 solution Substances 0.000 description 56
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 54
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 48
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 45
- 239000000047 product Substances 0.000 description 37
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 36
- 239000002904 solvent Substances 0.000 description 35
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 27
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 26
- 230000000052 comparative effect Effects 0.000 description 26
- 229920000642 polymer Polymers 0.000 description 26
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 238000005160 1H NMR spectroscopy Methods 0.000 description 23
- 239000000725 suspension Substances 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 21
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 21
- 238000010992 reflux Methods 0.000 description 21
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 20
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 20
- 239000002253 acid Substances 0.000 description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 18
- 239000011541 reaction mixture Substances 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- 239000000203 mixture Substances 0.000 description 16
- 239000012074 organic phase Substances 0.000 description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 14
- 239000007789 gas Substances 0.000 description 14
- 229910000077 silane Inorganic materials 0.000 description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 13
- 229910007928 ZrCl2 Inorganic materials 0.000 description 13
- 229920006395 saturated elastomer Polymers 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 12
- 239000000741 silica gel Substances 0.000 description 12
- 229910002027 silica gel Inorganic materials 0.000 description 12
- 238000001914 filtration Methods 0.000 description 11
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 11
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 229910052786 argon Inorganic materials 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 229920001400 block copolymer Polymers 0.000 description 9
- 239000013078 crystal Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 239000011780 sodium chloride Substances 0.000 description 9
- 239000012265 solid product Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000001953 recrystallisation Methods 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 8
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 8
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 7
- 229920001519 homopolymer Polymers 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 235000017557 sodium bicarbonate Nutrition 0.000 description 7
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 7
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 239000012230 colorless oil Substances 0.000 description 6
- 239000012442 inert solvent Substances 0.000 description 6
- 238000001819 mass spectrum Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000007334 copolymerization reaction Methods 0.000 description 5
- 239000012043 crude product Substances 0.000 description 5
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
- 239000003446 ligand Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 229920006301 statistical copolymer Polymers 0.000 description 5
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
- RGDQEELGYQIORT-UHFFFAOYSA-N 1-(2-methyl-6-propan-2-yl-3h-inden-4-yl)naphthalene Chemical compound C1=CC=C2C(C=3C=4CC(C)=CC=4C=C(C=3)C(C)C)=CC=CC2=C1 RGDQEELGYQIORT-UHFFFAOYSA-N 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- AGEZXYOZHKGVCM-UHFFFAOYSA-N benzyl bromide Chemical compound BrCC1=CC=CC=C1 AGEZXYOZHKGVCM-UHFFFAOYSA-N 0.000 description 4
- 238000004587 chromatography analysis Methods 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 4
- 239000000375 suspending agent Substances 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- JQCCMEDYANGBOG-UHFFFAOYSA-N 2-methyl-7-phenyl-1h-indene Chemical compound C=12CC(C)=CC2=CC=CC=1C1=CC=CC=C1 JQCCMEDYANGBOG-UHFFFAOYSA-N 0.000 description 3
- MPCBCIIAQIDKTH-UHFFFAOYSA-N 7-[3,5-di(propan-2-yl)phenyl]-2-methyl-1h-indene Chemical compound CC(C)C1=CC(C(C)C)=CC(C=2C=3CC(C)=CC=3C=CC=2)=C1 MPCBCIIAQIDKTH-UHFFFAOYSA-N 0.000 description 3
- QSBPXEDWBXHWKP-UHFFFAOYSA-N CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 QSBPXEDWBXHWKP-UHFFFAOYSA-N 0.000 description 3
- YQMLGDDBGRGBAW-UHFFFAOYSA-L CC1=Cc2c(cccc2-c2cc3ccccc3c3ccccc23)C1[Zr](Cl)(Cl)(C1C(C)=Cc2c1cccc2-c1cc2ccccc2c2ccccc12)=[Si](C)C Chemical compound CC1=Cc2c(cccc2-c2cc3ccccc3c3ccccc23)C1[Zr](Cl)(Cl)(C1C(C)=Cc2c1cccc2-c1cc2ccccc2c2ccccc12)=[Si](C)C YQMLGDDBGRGBAW-UHFFFAOYSA-L 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000001464 adherent effect Effects 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 150000004702 methyl esters Chemical class 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 3
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical class ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- VQSMDEGMFQYKRS-UHFFFAOYSA-N 1-(2-methyl-3h-inden-4-yl)naphthalene Chemical compound C1=CC=C2C(C=3C=CC=C4C=C(CC4=3)C)=CC=CC2=C1 VQSMDEGMFQYKRS-UHFFFAOYSA-N 0.000 description 2
- DRFPSPRQWNZEMK-UHFFFAOYSA-N 1-(2-methylphenyl)naphthalene Chemical compound CC1=CC=CC=C1C1=CC=CC2=CC=CC=C12 DRFPSPRQWNZEMK-UHFFFAOYSA-N 0.000 description 2
- QSSXJPIWXQTSIX-UHFFFAOYSA-N 1-bromo-2-methylbenzene Chemical compound CC1=CC=CC=C1Br QSSXJPIWXQTSIX-UHFFFAOYSA-N 0.000 description 2
- CMHWKURALISWAN-UHFFFAOYSA-N 2-(2-methyl-3h-inden-4-yl)naphthalene Chemical compound C1=CC=CC2=CC(C=3C=CC=C4C=C(CC4=3)C)=CC=C21 CMHWKURALISWAN-UHFFFAOYSA-N 0.000 description 2
- FCVQDADWCGVNDK-UHFFFAOYSA-N 2-(2-methylphenyl)naphthalene Chemical compound CC1=CC=CC=C1C1=CC=C(C=CC=C2)C2=C1 FCVQDADWCGVNDK-UHFFFAOYSA-N 0.000 description 2
- GJVSHKYHUSYPAG-UHFFFAOYSA-N 2-[2-(bromomethyl)phenyl]naphthalene Chemical compound BrCC1=CC=CC=C1C1=CC=C(C=CC=C2)C2=C1 GJVSHKYHUSYPAG-UHFFFAOYSA-N 0.000 description 2
- GCBUNTNONFEZPX-UHFFFAOYSA-N 2-methyl-4-naphthalen-1-yl-2,3-dihydroinden-1-one Chemical compound C1=CC=C2C(C3=CC=CC4=C3CC(C4=O)C)=CC=CC2=C1 GCBUNTNONFEZPX-UHFFFAOYSA-N 0.000 description 2
- LPQUJIFWQOFRMH-UHFFFAOYSA-N 2-methyl-4-naphthalen-2-yl-2,3-dihydroinden-1-one Chemical compound C1=CC=CC2=CC(C3=CC=CC4=C3CC(C4=O)C)=CC=C21 LPQUJIFWQOFRMH-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- QDIICDTVUXGQOE-UHFFFAOYSA-N CC=1C(C2=CC=CC(=C2C=1)C1=CC2=CC=CC=C2C=C1)[Zr] Chemical compound CC=1C(C2=CC=CC(=C2C=1)C1=CC2=CC=CC=C2C=C1)[Zr] QDIICDTVUXGQOE-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910006124 SOCl2 Inorganic materials 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19544828A DE19544828A1 (de) | 1995-12-01 | 1995-12-01 | Hochmolekulare Copolymere |
| DE19544828 | 1995-12-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2216031T3 true ES2216031T3 (es) | 2004-10-16 |
Family
ID=7778922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96118856T Expired - Lifetime ES2216031T3 (es) | 1995-12-01 | 1996-11-26 | Copolimeros de elevado peso molecular. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6057408A (enExample) |
| EP (2) | EP0776913B1 (enExample) |
| JP (1) | JP4519952B2 (enExample) |
| AT (2) | ATE456589T1 (enExample) |
| BR (1) | BR9605779A (enExample) |
| CA (1) | CA2191661A1 (enExample) |
| DE (3) | DE19544828A1 (enExample) |
| ES (1) | ES2216031T3 (enExample) |
| NO (1) | NO310877B1 (enExample) |
| TW (1) | TW454021B (enExample) |
| ZA (1) | ZA9610051B (enExample) |
Families Citing this family (96)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE222936T1 (de) | 1995-10-18 | 2002-09-15 | Chisso Corp | Olefin(co)polymerzusammensetzung, verfahren zu dessen herstellung, katalysator for olefin(co)polymerisation und verfahren zu dessen herstellung |
| SG67392A1 (en) * | 1996-05-27 | 1999-09-21 | Sumitomo Chemical Co | Propylene/ethylene-alpha-olefin block copolymer and process for producing the same |
| US6303696B1 (en) * | 1997-04-11 | 2001-10-16 | Chisso Corporation | Propylene (co)polymer composition using metallocene catalyst |
| US6818585B2 (en) * | 1998-12-30 | 2004-11-16 | Univation Technologies, Llc | Catalyst compounds, catalyst systems thereof and their use in a polymerization process |
| JP2003522194A (ja) | 2000-02-08 | 2003-07-22 | エクソンモービル・ケミカル・パテンツ・インク | 第１４族架橋ビスシクロペンタジエニル・リガンドの調製方法 |
| US6376412B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6399723B1 (en) | 2000-06-30 | 2002-06-04 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380124B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380122B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376410B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376408B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6414095B1 (en) | 2000-06-30 | 2002-07-02 | Exxon Mobil Chemical Patents Inc. | Metallocene compositions |
| US6380330B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376627B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380121B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376411B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376409B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380331B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US7122498B2 (en) | 2000-06-30 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| US6376413B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380120B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| DE60112307T8 (de) * | 2000-06-30 | 2007-02-15 | Exxonmobil Chemical Patents Inc., Baytown | Metallocenverbindungen mit einem verbrückten 4-phenylindenyl-ligandsystem zur polymerisation von olefinen |
| US6380334B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6870016B1 (en) | 2000-06-30 | 2005-03-22 | Exxonmobil Chemical Patents Inc. | Polymerization process and polymer composition |
| US6380123B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376407B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| JP2003128720A (ja) | 2001-10-19 | 2003-05-08 | Sunallomer Ltd | オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物 |
| US20050182266A1 (en) * | 2002-06-12 | 2005-08-18 | Schulte Jorg L. | Transition metal componds their preparation and their use in catalyst systems for the polymerization and copolymerization of olefins |
| US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
| US8008412B2 (en) * | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| KR100579843B1 (ko) * | 2003-04-01 | 2006-05-12 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법 |
| JP2007505947A (ja) * | 2003-05-28 | 2007-03-15 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 特定の置換パターンを有する有機遷移金属化合物、ビスシクロペンタジエニル配位子組成物、触媒組成物、及ポリオレフィンの製造法 |
| SA04250253B1 (ar) | 2003-08-21 | 2009-11-10 | استرازينيكا ايه بي | احماض فينوكسي اسيتيك مستبدلة باعتبارها مركبات صيدلانية لعلاج الامراض التنفسية مثل الربو ومرض الانسداد الرئوي المزمن |
| DE10358082A1 (de) * | 2003-12-10 | 2005-07-14 | Basell Polyolefine Gmbh | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
| US8178636B2 (en) * | 2004-05-04 | 2012-05-15 | Basell Polyolefine Gmbh | Process for the preparation of atactic 1-butene polymers |
| CN101124235B (zh) * | 2004-07-08 | 2010-12-15 | 埃克森美孚化学专利公司 | 烯烃聚合催化剂体系及其使用方法 |
| GB0418830D0 (en) | 2004-08-24 | 2004-09-22 | Astrazeneca Ab | Novel compounds |
| GB0422057D0 (en) * | 2004-10-05 | 2004-11-03 | Astrazeneca Ab | Novel compounds |
| US7169864B2 (en) * | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| US7232869B2 (en) * | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
| WO2007024447A1 (en) * | 2005-08-19 | 2007-03-01 | Dow Global Technologies, Inc. | Propylene based meltblown nonwoven layers and composite structures |
| TW200745003A (en) | 2005-10-06 | 2007-12-16 | Astrazeneca Ab | Novel compounds |
| EP1996600B1 (en) * | 2006-03-17 | 2011-09-28 | Basell Polyolefine GmbH | Metallocene compounds |
| US7834205B2 (en) | 2006-04-12 | 2010-11-16 | Basell Polyolifine GmbH | Metallocene compounds |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| WO2008150572A1 (en) * | 2007-06-04 | 2008-12-11 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
| US8318875B2 (en) * | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| EP2499168B1 (en) | 2009-11-13 | 2017-05-10 | Borealis AG | Process for recovering a transition metal compound |
| EP2322568B1 (en) | 2009-11-13 | 2013-05-15 | Borealis AG | Process for producing an olefin polymerization catalyst |
| CN102666601B (zh) | 2009-11-13 | 2014-04-23 | 博瑞立斯有限公司 | 烯烃聚合方法 |
| US8603933B2 (en) | 2009-11-13 | 2013-12-10 | Borealis Ag | Process for recovering a transition metal compound |
| EP2330136B1 (en) | 2009-12-07 | 2013-08-28 | Borealis AG | Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins |
| ES2813282T3 (es) | 2011-03-02 | 2021-03-23 | Borealis Ag | Conjunto de reactor de alto rendimiento para la polimerización de olefinas |
| PT2495038T (pt) | 2011-03-02 | 2020-11-06 | Borealis Ag | Conjunto de reator flexível para polimerização de olefinas |
| ES2605429T3 (es) | 2011-06-15 | 2017-03-14 | Borealis Ag | Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno |
| WO2013007650A1 (en) | 2011-07-08 | 2013-01-17 | Borealis Ag | Catalysts |
| US8445620B2 (en) | 2011-08-04 | 2013-05-21 | Exxonmobil Research And Engineering Company | Elastic propylene-alpha-olefin copolymer compositions and processes to produce them |
| EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
| CN104582829B (zh) | 2012-08-29 | 2016-12-28 | 博里利斯股份公司 | 用于烯烃聚合的反应器装置和方法 |
| ES2674576T3 (es) | 2012-12-21 | 2018-07-02 | Borealis Ag | Catalizador |
| EP3301098B1 (en) | 2012-12-21 | 2020-02-19 | Borealis AG | Process for the preparation of a ligand for a catalyst |
| ES2645256T3 (es) | 2012-12-21 | 2017-12-04 | Borealis Ag | Catalizadores |
| EP2745926A1 (en) | 2012-12-21 | 2014-06-25 | Borealis AG | Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor |
| EP2745927A1 (en) | 2012-12-21 | 2014-06-25 | Borealis AG | Fluidized bed reactor with internal moving bed reaction unit |
| EP2759554A1 (en) * | 2013-01-23 | 2014-07-30 | Total Research & Technology Feluy | Process for producing olefin / 3-methyl-1-butene copolymers |
| SG10201802959WA (en) | 2013-07-17 | 2018-05-30 | Exxonmobil Chemical Patents Inc | Cyclopropyl substituted metallocene catalysts |
| US9249239B2 (en) | 2013-07-17 | 2016-02-02 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| ES2703344T3 (es) | 2013-07-17 | 2019-03-08 | Exxonmobil Chemical Patents Inc | Metalocenos y composiciones catalíticas derivadas de ellos |
| EP3022236B1 (en) | 2013-07-17 | 2017-11-15 | ExxonMobil Chemical Patents Inc. | Process using substituted metallocene catalysts and products therefrom |
| EP3023450B1 (en) | 2014-11-21 | 2017-07-19 | Borealis AG | Process for producing pellets of soft copolymers |
| EP3124567A1 (en) | 2015-07-30 | 2017-02-01 | Borealis AG | Polypropylene based hot-melt adhesive composition |
| EP3178853B1 (en) | 2015-12-07 | 2018-07-25 | Borealis AG | Process for polymerising alpha-olefin monomers |
| EP3243622B1 (en) | 2016-05-13 | 2020-09-09 | Borealis AG | Process for hydraulic conveying of polyolefin pellets |
| CN110177798B (zh) | 2016-11-18 | 2022-08-30 | 博里利斯股份公司 | 催化剂 |
| EP3555149B1 (en) | 2016-12-15 | 2025-11-12 | Borealis GmbH | New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| KR102534541B1 (ko) | 2016-12-15 | 2023-05-18 | 보레알리스 아게 | 고온 용액 중합 공정으로 폴리에틸렌 공중합체를 제조하기 위한 촉매 시스템 |
| US11807655B2 (en) | 2016-12-29 | 2023-11-07 | Borealis Ag | Catalysts |
| JP7027988B2 (ja) | 2017-04-27 | 2022-03-02 | 住友化学株式会社 | プロピレン重合体組成物 |
| JP7297782B2 (ja) | 2018-03-19 | 2023-06-26 | ボレアリス エージー | オレフィン重合用触媒 |
| CN112424241B (zh) | 2018-06-28 | 2023-06-06 | 博里利斯股份公司 | 催化剂 |
| EP3608364A1 (en) | 2018-08-06 | 2020-02-12 | Borealis AG | Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition |
| US20210277290A1 (en) | 2018-08-06 | 2021-09-09 | Borealis Ag | Propylene random copolymer based hot melt adhesive composition |
| ES2986685T3 (es) | 2018-11-30 | 2024-11-12 | Borealis Ag | Proceso de lavado |
| US20220389133A1 (en) | 2019-10-30 | 2022-12-08 | China Petroleum & Chemical Corporation | Metallocene compound, and preparation method therefor and application thereof |
| KR20230175305A (ko) | 2021-04-25 | 2023-12-29 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 프로필렌계 공중합체, 이의 제조 공정 및 용도, 및 이를 함유하는 폴리프로필렌 조성물 |
| EP4144435A1 (en) | 2021-09-01 | 2023-03-08 | Borealis AG | Gas phase polymerization process with improved gas recycling |
| EP4389783A1 (en) | 2022-12-20 | 2024-06-26 | Borealis AG | Catalyst transition process |
| EP4389776A1 (en) | 2022-12-20 | 2024-06-26 | Borealis AG | Process |
| CN120380039A (zh) | 2022-12-23 | 2025-07-25 | 北欧化工股份公司 | 聚丙烯共聚物的生产方法 |
| TW202438539A (zh) | 2022-12-23 | 2024-10-01 | 奧地利商柏列利斯股份公司 | 高流動性聚丙烯均聚物的製造方法 |
| KR20250126808A (ko) | 2022-12-23 | 2025-08-25 | 보레알리스 아게 | 폴리프로필렌 단독중합체 또는 공중합체의 제조방법 |
| CN121175162A (zh) | 2023-05-23 | 2025-12-19 | 博里利斯有限责任公司 | 用于生产聚烯烃的粒料的方法和由此生产的粒料 |
| EP4735486A1 (en) | 2023-06-30 | 2026-05-06 | Borealis GmbH | Process |
| WO2025219533A1 (en) | 2024-04-18 | 2025-10-23 | Borealis Gmbh | Process for the preparation of a propylene homopolymer |
| WO2025219537A1 (en) | 2024-04-18 | 2025-10-23 | Borealis Gmbh | Process for propylene polymerization with optimized prepolymerization conditions |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59204646A (ja) * | 1983-05-09 | 1984-11-20 | Japan Synthetic Rubber Co Ltd | ポリプロピレン樹脂組成物 |
| DE3769528D1 (de) * | 1986-06-30 | 1991-05-29 | Rexene Prod Co | Propylenpolymere und ihre herstellung. |
| CA1327673C (en) * | 1988-06-16 | 1994-03-08 | Sigmund Floyd | Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system |
| JP3402473B2 (ja) * | 1991-08-20 | 2003-05-06 | 日本ポリケム株式会社 | オレフィン重合用触媒 |
| TW294669B (enExample) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| ATE177436T1 (de) * | 1992-08-15 | 1999-03-15 | Targor Gmbh | Verfahren zur herstellung von polyolefinen |
| DE69431222T2 (de) * | 1993-06-07 | 2003-04-17 | Mitsui Chemicals, Inc. | Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator |
| DE69427999T3 (de) * | 1993-06-07 | 2012-09-27 | Mitsui Chemicals, Inc. | Übergangsmetallverbindung, diese enthaltende Olefinpolymerisationskatalysator, Verfahren zur Olefinpolymerisation damit und Homo- und Copolymere des Propylens |
| US5414027A (en) * | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| DE4333128A1 (de) * | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
| DE4333569A1 (de) * | 1993-10-01 | 1995-04-06 | Hoechst Ag | Verfahren zur Olefinpolymerisation |
| JP3423378B2 (ja) * | 1993-11-12 | 2003-07-07 | 三井化学株式会社 | 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法 |
| DE4340018A1 (de) * | 1993-11-24 | 1995-06-01 | Hoechst Ag | Metallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| DE59409642D1 (de) * | 1993-11-24 | 2001-03-01 | Targor Gmbh | Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren |
| FI945958L (fi) * | 1993-12-21 | 1995-06-22 | Hoechst Ag | Menetelmä polyolefiinien valmistamiseksi |
| DE4344688A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| CN1147822A (zh) * | 1994-12-20 | 1997-04-16 | 蒙特尔技术有限公司 | 反应器掺混聚丙烯，其制备方法和金属茂配位体的制备方法 |
| TW383314B (en) * | 1994-12-20 | 2000-03-01 | Mitsui Petrochemical Ind | Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer |
-
1995
- 1995-12-01 DE DE19544828A patent/DE19544828A1/de not_active Ceased
-
1996
- 1996-11-26 DE DE59610907T patent/DE59610907D1/de not_active Expired - Lifetime
- 1996-11-26 AT AT02019624T patent/ATE456589T1/de not_active IP Right Cessation
- 1996-11-26 DE DE59611505T patent/DE59611505D1/de not_active Expired - Lifetime
- 1996-11-26 EP EP96118856A patent/EP0776913B1/de not_active Expired - Lifetime
- 1996-11-26 ES ES96118856T patent/ES2216031T3/es not_active Expired - Lifetime
- 1996-11-26 EP EP02019624A patent/EP1270614B1/de not_active Expired - Lifetime
- 1996-11-26 AT AT96118856T patent/ATE258940T1/de not_active IP Right Cessation
- 1996-11-28 TW TW085114702A patent/TW454021B/zh not_active IP Right Cessation
- 1996-11-29 CA CA002191661A patent/CA2191661A1/en not_active Abandoned
- 1996-11-29 NO NO19965106A patent/NO310877B1/no not_active IP Right Cessation
- 1996-11-29 ZA ZA9610051A patent/ZA9610051B/xx unknown
- 1996-12-02 BR BR9605779A patent/BR9605779A/pt active Search and Examination
- 1996-12-02 JP JP32180896A patent/JP4519952B2/ja not_active Expired - Lifetime
-
1998
- 1998-04-13 US US09/058,828 patent/US6057408A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE59610907D1 (de) | 2004-03-11 |
| ATE258940T1 (de) | 2004-02-15 |
| BR9605779A (pt) | 1998-08-25 |
| DE19544828A1 (de) | 1997-06-05 |
| JPH09176222A (ja) | 1997-07-08 |
| ZA9610051B (en) | 1997-06-01 |
| EP0776913A2 (de) | 1997-06-04 |
| TW454021B (en) | 2001-09-11 |
| NO310877B1 (no) | 2001-09-10 |
| EP0776913B1 (de) | 2004-02-04 |
| NO965106D0 (no) | 1996-11-29 |
| EP1270614A3 (de) | 2004-12-22 |
| EP1270614A2 (de) | 2003-01-02 |
| CA2191661A1 (en) | 1997-06-02 |
| DE59611505D1 (de) | 2010-03-18 |
| EP1270614B1 (de) | 2010-01-27 |
| NO965106L (no) | 1997-06-02 |
| ATE456589T1 (de) | 2010-02-15 |
| EP0776913A3 (de) | 1998-09-02 |
| US6057408A (en) | 2000-05-02 |
| JP4519952B2 (ja) | 2010-08-04 |
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