ES2202869T3 - Composiciones detergentes de soltura, en forma de particulas. - Google Patents
Composiciones detergentes de soltura, en forma de particulas.Info
- Publication number
- ES2202869T3 ES2202869T3 ES98929352T ES98929352T ES2202869T3 ES 2202869 T3 ES2202869 T3 ES 2202869T3 ES 98929352 T ES98929352 T ES 98929352T ES 98929352 T ES98929352 T ES 98929352T ES 2202869 T3 ES2202869 T3 ES 2202869T3
- Authority
- ES
- Spain
- Prior art keywords
- surfactant
- weight
- detergent composition
- composition according
- detergency
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 109
- 239000003599 detergent Substances 0.000 title claims abstract description 68
- 239000002245 particle Substances 0.000 title claims description 35
- 239000004094 surface-active agent Substances 0.000 claims abstract description 81
- 239000008187 granular material Substances 0.000 claims description 90
- 239000000843 powder Substances 0.000 claims description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 239000003945 anionic surfactant Substances 0.000 claims description 34
- 239000002585 base Substances 0.000 claims description 32
- 239000002736 nonionic surfactant Substances 0.000 claims description 29
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 26
- -1 alkali metal aluminosilicate Chemical class 0.000 claims description 19
- 125000000129 anionic group Chemical group 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 16
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 12
- 239000012876 carrier material Substances 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 5
- 229920005646 polycarboxylate Polymers 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 229910052816 inorganic phosphate Inorganic materials 0.000 claims 1
- 150000003628 tricarboxylic acids Chemical class 0.000 claims 1
- 239000000344 soap Substances 0.000 abstract description 10
- 239000002671 adjuvant Substances 0.000 abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 abstract description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052910 alkali metal silicate Inorganic materials 0.000 abstract description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 55
- 229910021536 Zeolite Inorganic materials 0.000 description 39
- 239000010457 zeolite Substances 0.000 description 39
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 31
- 239000004615 ingredient Substances 0.000 description 29
- 239000000463 material Substances 0.000 description 21
- 239000002253 acid Substances 0.000 description 19
- 238000004061 bleaching Methods 0.000 description 19
- 238000000034 method Methods 0.000 description 18
- 239000002243 precursor Substances 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 16
- 238000001035 drying Methods 0.000 description 16
- 229910000029 sodium carbonate Inorganic materials 0.000 description 15
- 238000009472 formulation Methods 0.000 description 14
- 239000011734 sodium Substances 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 10
- 238000001816 cooling Methods 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
- 239000000975 dye Substances 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 7
- 238000001694 spray drying Methods 0.000 description 7
- 239000000428 dust Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000003472 neutralizing effect Effects 0.000 description 6
- 235000011152 sodium sulphate Nutrition 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 5
- 108090000790 Enzymes Proteins 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229940088598 enzyme Drugs 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 241001538234 Nala Species 0.000 description 4
- GBFLZEXEOZUWRN-VKHMYHEASA-N S-carboxymethyl-L-cysteine Chemical compound OC(=O)[C@@H](N)CSCC(O)=O GBFLZEXEOZUWRN-VKHMYHEASA-N 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 239000003570 air Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 235000011837 pasties Nutrition 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229940045872 sodium percarbonate Drugs 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 3
- 150000008041 alkali metal carbonates Chemical class 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 150000001860 citric acid derivatives Chemical class 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003623 enhancer Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 239000001509 sodium citrate Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 208000035484 Cellulite Diseases 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 206010049752 Peau d'orange Diseases 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 150000008051 alkyl sulfates Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001768 cations Chemical group 0.000 description 2
- 230000036232 cellulite Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 229940071087 ethylenediamine disuccinate Drugs 0.000 description 2
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000002366 lipolytic effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052914 metal silicate Inorganic materials 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 230000002797 proteolythic effect Effects 0.000 description 2
- 229940071207 sesquicarbonate Drugs 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 229940038773 trisodium citrate Drugs 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- MPJQXAIKMSKXBI-UHFFFAOYSA-N 2,7,9,14-tetraoxa-1,8-diazabicyclo[6.6.2]hexadecane-3,6,10,13-tetrone Chemical compound C1CN2OC(=O)CCC(=O)ON1OC(=O)CCC(=O)O2 MPJQXAIKMSKXBI-UHFFFAOYSA-N 0.000 description 1
- 229910000632 Alusil Inorganic materials 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- WJSLZXMQHNTOBA-UHFFFAOYSA-N C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.OCC(O)CO Chemical class C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.OCC(O)CO WJSLZXMQHNTOBA-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 102000005701 Calcium-Binding Proteins Human genes 0.000 description 1
- 108010045403 Calcium-Binding Proteins Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical class OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
- WFRXSOIFNFJAFL-UHFFFAOYSA-N P1(OCCCCO1)=O.C(CN)N Chemical compound P1(OCCCCO1)=O.C(CN)N WFRXSOIFNFJAFL-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
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- 239000012190 activator Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005466 alkylenyl group Chemical group 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
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- 238000006243 chemical reaction Methods 0.000 description 1
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- ZXQKFOFUXLKTGK-UHFFFAOYSA-N cyclononane manganese Chemical class [Mn].C1CCCCCCCC1 ZXQKFOFUXLKTGK-UHFFFAOYSA-N 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
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- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
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- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000004966 inorganic peroxy acids Chemical class 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229940055076 parasympathomimetics choline ester Drugs 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9711352 | 1997-05-30 | ||
| GB9711359 | 1997-05-30 | ||
| GBGB9711352.6A GB9711352D0 (en) | 1997-05-30 | 1997-05-30 | Detergent composition |
| GBGB9711359.1A GB9711359D0 (en) | 1997-05-30 | 1997-05-30 | Detergent powder composition |
| GB9808897 | 1998-04-24 | ||
| GBGB9808897.4A GB9808897D0 (en) | 1997-05-30 | 1998-04-24 | Detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2202869T3 true ES2202869T3 (es) | 2004-04-01 |
Family
ID=27268871
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98929352T Expired - Lifetime ES2202869T3 (es) | 1997-05-30 | 1998-05-11 | Composiciones detergentes de soltura, en forma de particulas. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6221831B1 (en:Method) |
| EP (1) | EP0985024B1 (en:Method) |
| CN (1) | CN1131300C (en:Method) |
| AU (1) | AU724226B2 (en:Method) |
| BR (1) | BR9809511A (en:Method) |
| DE (1) | DE69817811T2 (en:Method) |
| ES (1) | ES2202869T3 (en:Method) |
| HU (1) | HUP0002906A3 (en:Method) |
| ID (1) | ID29296A (en:Method) |
| IN (1) | IN190314B (en:Method) |
| PL (1) | PL337039A1 (en:Method) |
| TR (1) | TR199902896T2 (en:Method) |
| WO (1) | WO1998054289A1 (en:Method) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9711356D0 (en) † | 1997-05-30 | 1997-07-30 | Unilever Plc | Particulate detergent composition |
| GB9825558D0 (en) * | 1998-11-20 | 1999-01-13 | Unilever Plc | Granular detergent components and particulate detergent compositions containing them |
| GB9825563D0 (en) | 1998-11-20 | 1999-01-13 | Unilever Plc | Particulate laundry detergent compositions containing anionic surfactant granules |
| GB9826097D0 (en) | 1998-11-27 | 1999-01-20 | Unilever Plc | Detergent compositions |
| US6271298B1 (en) | 1999-04-28 | 2001-08-07 | Southern Clay Products, Inc. | Process for treating smectite clays to facilitate exfoliation |
| DE19936613B4 (de) | 1999-08-04 | 2010-09-02 | Henkel Ag & Co. Kgaa | Verfahren zur Herstellung eines Waschmittels mit löslichem Buildersystem |
| US6787592B1 (en) | 1999-10-21 | 2004-09-07 | Southern Clay Products, Inc. | Organoclay compositions prepared from ester quats and composites based on the compositions |
| GB0023489D0 (en) | 2000-09-25 | 2000-11-08 | Unilever Plc | Production of anionic surfactant granules by in situ neutralisation |
| GB0023487D0 (en) * | 2000-09-25 | 2000-11-08 | Unilever Plc | Production of anionic surfactant granules by in situ neutralisation |
| GB0023488D0 (en) | 2000-09-25 | 2000-11-08 | Unilever Plc | Production of anionic surfactant granules by in situ neutralisation |
| EP1366109B1 (en) | 2001-03-02 | 2006-05-03 | Southern Clay Products, Inc. | Preparation of polymer nanocomposites by dispersion destabilization |
| GB0409959D0 (en) * | 2004-05-05 | 2004-06-09 | Unilever Plc | Detergent composition |
| US7459422B2 (en) * | 2004-08-11 | 2008-12-02 | The Procter & Gamble Company | Process for making a granular detergent composition having improved solubility |
| JP5020482B2 (ja) * | 2005-01-13 | 2012-09-05 | 花王株式会社 | アニオン界面活性剤粉粒体 |
| EP1754781B1 (en) * | 2005-08-19 | 2013-04-03 | The Procter and Gamble Company | A solid laundry detergent composition comprising anionic detersive surfactant and a calcium-augmented technology |
| EP1918362A1 (en) * | 2006-10-16 | 2008-05-07 | The Procter & Gamble Company | Low builder, highly water-soluble, low-density solid laundry detergent composition |
| EP1914297B1 (en) * | 2006-10-16 | 2011-03-09 | The Procter & Gamble Company | A spray-drying process for preparing a low density, low builder, highly water-soluble spray-dried detergent powder |
| BR112012026915A2 (pt) * | 2010-04-19 | 2016-07-12 | Procter & Gamble Comapny | composição detergente |
| CN101955855A (zh) * | 2010-09-17 | 2011-01-26 | 中轻化工股份有限公司 | 一种圆球形洗涤剂组合物及其制造方法 |
| EP2669361B1 (en) * | 2012-06-01 | 2015-01-14 | The Procter & Gamble Company | Spray-dried detergent powder |
| ES2647109T3 (es) * | 2012-06-01 | 2017-12-19 | The Procter & Gamble Company | Composición detergente para lavado de ropa |
| CN103468447B (zh) * | 2012-06-06 | 2018-07-13 | 上海和黄白猫有限公司 | 一种高密度洗衣粉及其制造方法 |
| WO2015003358A1 (en) * | 2013-07-11 | 2015-01-15 | The Procter & Gamble Company | Laundry detergent composition |
| BR112015026833A2 (pt) | 2013-07-18 | 2017-07-25 | Galaxy Surfactants Ltd | processo para preparar sulfatos de éteres de alquilas muito ativos, sólidos, de fluxo livre, composições de sulfato de éter de alquila muito ativo, sólidas, de fluxo livre, composição detergente para lavar roupa, composição detergente para lavar louça e uso das composições de sulfato de éter de alquila muito ativo, sólidas, de fluxo livre |
| BR112020015174A2 (pt) * | 2018-01-26 | 2021-01-26 | Ecolab Usa Inc. | mistura de tensoativo solidificada métodos para formar a mistura de tensoativo solidificada, para limpar uma superfície e para distribuir uma composição de limpeza, e, composição de limpeza sólida |
| CN111655828A (zh) | 2018-01-26 | 2020-09-11 | 埃科莱布美国股份有限公司 | 用载体固化液体氧化胺、甜菜碱和/或磺基甜菜碱表面活性剂 |
| JP7485606B2 (ja) | 2018-01-26 | 2024-05-16 | エコラボ ユーエスエー インコーポレイティド | 液体アニオン性界面活性剤の固化 |
| EP4603568A3 (en) | 2018-01-26 | 2025-09-10 | Ecolab USA Inc. | Solidifying liquid amine oxide surfactant with urea binder and optional carrier |
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| US3849327A (en) | 1971-11-30 | 1974-11-19 | Colgate Palmolive Co | Manufacture of free-flowing particulate heavy duty synthetic detergent composition containing nonionic detergent and anti-redeposition agent |
| AT330930B (de) | 1973-04-13 | 1976-07-26 | Henkel & Cie Gmbh | Verfahren zur herstellung von festen, schuttfahigen wasch- oder reinigungsmitteln mit einem gehalt an calcium bindenden substanzen |
| DE2433485A1 (de) | 1973-07-16 | 1975-02-06 | Procter & Gamble | Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher |
| IT1080880B (it) | 1976-06-30 | 1985-05-16 | Church & Dwight Co Inc | Composizione detergente miscelata a secco e metodo di suo impiego |
| DE3151536A1 (de) * | 1981-12-28 | 1983-07-07 | Henkel KGaA, 4000 Düsseldorf | Starkschaeumendes, koerniges waschmittel mit erhoehter kornstabilitaet und verfahren zu dessen herstellung |
| CA1202854A (en) | 1982-06-10 | 1986-04-08 | Muthumi Kuroda | Bleaching detergent composition |
| GB8311865D0 (en) | 1983-04-29 | 1983-06-02 | Procter & Gamble Ltd | Bleach compositions |
| DE3413571A1 (de) | 1984-04-11 | 1985-10-24 | Hoechst Ag, 6230 Frankfurt | Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung |
| DE3424987A1 (de) | 1984-07-06 | 1986-02-06 | Unilever N.V., Rotterdam | Verfahren zur herstellung eines pulverfoermigen waschmittels mit erhoehtem schuettgewicht |
| GB8522621D0 (en) | 1985-09-12 | 1985-10-16 | Unilever Plc | Detergent powder |
| CA1275019A (en) | 1985-10-09 | 1990-10-09 | The Procter & Gamble Company | Granular detergent compositions having improved solubility |
| GB8525269D0 (en) * | 1985-10-14 | 1985-11-20 | Unilever Plc | Detergent composition |
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| DE3545947A1 (de) | 1985-12-23 | 1987-07-02 | Henkel Kgaa | Phosphatfreies, granulares waschmittel |
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| DE3827895A1 (de) | 1988-08-17 | 1990-02-22 | Henkel Kgaa | Verfahren zur herstellung phosphatreduzierter waschmitteltabletten |
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| CA2001927C (en) | 1988-11-03 | 1999-12-21 | Graham Thomas Brown | Aluminosilicates and detergent compositions |
| GB8907187D0 (en) | 1989-03-30 | 1989-05-10 | Unilever Plc | Detergent compositions and process for preparing them |
| GB8907100D0 (en) | 1989-03-29 | 1989-05-10 | Unilever Plc | Particulate detergent additive product,preparation and use thereof in detergent compositions |
| GB8922018D0 (en) | 1989-09-29 | 1989-11-15 | Unilever Plc | Detergent compositions and process for preparing them |
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| GB8926718D0 (en) * | 1989-11-27 | 1990-01-17 | Unilever Plc | Process for the preparation of detergent compositions |
| JP2777920B2 (ja) | 1989-12-20 | 1998-07-23 | 富士通株式会社 | 半導体装置及びその製造方法 |
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| CA2053293A1 (en) | 1990-02-26 | 1991-08-27 | Hiroshi Kuroshima | Humidity-sensing element |
| GB9008013D0 (en) | 1990-04-09 | 1990-06-06 | Unilever Plc | High bulk density granular detergent compositions and process for preparing them |
| EP0477974B1 (en) | 1990-09-28 | 1995-09-13 | Kao Corporation | Nonionic powdery detergent composition |
| GB9022660D0 (en) | 1990-10-18 | 1990-11-28 | Unilever Plc | Detergent compositions |
| US5108646A (en) | 1990-10-26 | 1992-04-28 | The Procter & Gamble Company | Process for agglomerating aluminosilicate or layered silicate detergent builders |
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| GB9120657D0 (en) | 1991-09-27 | 1991-11-06 | Unilever Plc | Detergent powders and process for preparing them |
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| GB9205189D0 (en) | 1992-03-10 | 1992-04-22 | Procter & Gamble | Granular detergent compositions |
| TW240243B (en:Method) | 1992-03-12 | 1995-02-11 | Kao Corp | |
| AU3524093A (en) | 1992-03-27 | 1993-09-30 | Kao Corporation | Nonionic powdery detergent composition and process for producing the same |
| GB9208062D0 (en) | 1992-04-03 | 1992-05-27 | Procter & Gamble | Detergent compositions |
| GB9214890D0 (en) | 1992-07-14 | 1992-08-26 | Procter & Gamble | Washing process |
| TW244358B (en:Method) | 1992-10-12 | 1995-04-01 | Kao Corp | |
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| DE69325014T2 (de) | 1993-03-30 | 2000-01-20 | The Procter & Gamble Co., Cincinnati | Natrium-Aluminiumsilikat und hydrophobe Kieselsäure enthaltende Fliesshilfe für Waschmittelpulver |
| US5691294A (en) * | 1993-03-30 | 1997-11-25 | The Procter & Gamble Company | Flow aids for detergent powders comprising sodium aluminosilicate and hydrophobic silica |
| JPH0753992A (ja) * | 1993-07-12 | 1995-02-28 | Procter & Gamble Co:The | 低投与量洗剤組成物 |
| DE4326129A1 (de) | 1993-08-04 | 1995-02-09 | Huels Chemische Werke Ag | Waschmittelformulierungen |
| EP0639639B2 (en) | 1993-08-17 | 2010-07-28 | The Procter & Gamble Company | Detergent compositions comprising percarbonate bleaching agents |
| EP0639637A1 (en) | 1993-08-17 | 1995-02-22 | The Procter & Gamble Company | Detergent compositions comprising percarbonate bleaching agents |
| DE69422675T3 (de) | 1993-09-13 | 2008-05-21 | The Procter & Gamble Company, Cincinnati | Granuläre Waschmittelzusammensetzungen, umfassend nichtionisches Tensid, und Verfahren zur Herstellung solcher Zusammensetzungen |
| EP0653481A1 (en) | 1993-11-11 | 1995-05-17 | The Procter & Gamble Company | Granular detergent composition |
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| JP2954487B2 (ja) | 1994-07-13 | 1999-09-27 | 花王株式会社 | 非イオン性粉末洗浄剤組成物 |
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| GB9417356D0 (en) | 1994-08-26 | 1994-10-19 | Unilever Plc | Detergent particles and process for their production |
| DE4434500A1 (de) | 1994-09-27 | 1996-03-28 | Henkel Kgaa | Verbessertes Extrusionsverfahren zur Herstellung von Waschmitteln |
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| DE19519139A1 (de) | 1995-05-30 | 1996-12-05 | Henkel Kgaa | Granulares Wasch- oder Reinigungsmittel mit hoher Schüttdichte |
| US5707959A (en) | 1995-05-31 | 1998-01-13 | The Procter & Gamble Company | Processes for making a granular detergent composition containing a crystalline builder |
| US5573697A (en) | 1995-05-31 | 1996-11-12 | Riddick; Eric F. | Process for making high active, high density detergent granules |
| GB2301835A (en) * | 1995-06-08 | 1996-12-18 | Procter & Gamble | Detergent Compositions |
| GB2304726A (en) | 1995-09-04 | 1997-03-26 | Unilever Plc | Granular adjuncts containing soil release polymers, and particulate detergent compositions containing them |
| US5726142A (en) | 1995-11-17 | 1998-03-10 | The Dial Corp | Detergent having improved properties and method of preparing the detergent |
| GB9604000D0 (en) | 1996-02-26 | 1996-04-24 | Unilever Plc | Production of anionic detergent particles |
| GB9604022D0 (en) * | 1996-02-26 | 1996-04-24 | Unilever Plc | Anionic detergent particles |
| WO1997032952A1 (en) | 1996-03-08 | 1997-09-12 | The Procter & Gamble Company | Preparation of secondary alkyl sulfate particles with improved solubility |
-
1998
- 1998-05-11 HU HU0002906A patent/HUP0002906A3/hu unknown
- 1998-05-11 DE DE69817811T patent/DE69817811T2/de not_active Expired - Lifetime
- 1998-05-11 AU AU79144/98A patent/AU724226B2/en not_active Ceased
- 1998-05-11 PL PL98337039A patent/PL337039A1/xx unknown
- 1998-05-11 TR TR1999/02896T patent/TR199902896T2/xx unknown
- 1998-05-11 EP EP98929352A patent/EP0985024B1/en not_active Expired - Lifetime
- 1998-05-11 CN CN98807601A patent/CN1131300C/zh not_active Expired - Fee Related
- 1998-05-11 ES ES98929352T patent/ES2202869T3/es not_active Expired - Lifetime
- 1998-05-11 BR BR9809511-0A patent/BR9809511A/pt not_active IP Right Cessation
- 1998-05-11 WO PCT/EP1998/002987 patent/WO1998054289A1/en active IP Right Grant
- 1998-05-11 ID IDW991470A patent/ID29296A/id unknown
- 1998-05-20 IN IN317BO1998 patent/IN190314B/en unknown
- 1998-05-26 US US09/084,567 patent/US6221831B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69817811T2 (de) | 2004-04-01 |
| PL337039A1 (en) | 2000-07-31 |
| HUP0002906A2 (hu) | 2001-01-29 |
| EP0985024A1 (en) | 2000-03-15 |
| HUP0002906A3 (en) | 2003-02-28 |
| IN190314B (en:Method) | 2003-07-12 |
| US6221831B1 (en) | 2001-04-24 |
| BR9809511A (pt) | 2000-06-20 |
| ID29296A (id) | 2001-08-16 |
| DE69817811D1 (de) | 2003-10-09 |
| EP0985024B1 (en) | 2003-09-03 |
| CN1265138A (zh) | 2000-08-30 |
| WO1998054289A1 (en) | 1998-12-03 |
| TR199902896T2 (xx) | 2000-06-21 |
| AU724226B2 (en) | 2000-09-14 |
| AU7914498A (en) | 1998-12-30 |
| CN1131300C (zh) | 2003-12-17 |
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