ES2197660T3 - Mezclas de policarbonatos con polimeros de arilato resistentes a la exposicion a la intemperie. - Google Patents
Mezclas de policarbonatos con polimeros de arilato resistentes a la exposicion a la intemperie.Info
- Publication number
- ES2197660T3 ES2197660T3 ES99938921T ES99938921T ES2197660T3 ES 2197660 T3 ES2197660 T3 ES 2197660T3 ES 99938921 T ES99938921 T ES 99938921T ES 99938921 T ES99938921 T ES 99938921T ES 2197660 T3 ES2197660 T3 ES 2197660T3
- Authority
- ES
- Spain
- Prior art keywords
- composition according
- polymer
- resorcinol
- arylate
- structural units
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 39
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 39
- 229920000642 polymer Polymers 0.000 title claims description 46
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims abstract description 31
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 9
- 229930188104 Alkylresorcinol Natural products 0.000 claims abstract description 8
- 125000002723 alicyclic group Chemical group 0.000 claims abstract description 7
- 230000014759 maintenance of location Effects 0.000 claims abstract description 7
- 150000002148 esters Chemical class 0.000 claims abstract description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 13
- 229920000728 polyester Polymers 0.000 claims description 8
- 239000000049 pigment Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 claims description 4
- IINQAVTXAIJUOI-UHFFFAOYSA-N benzene-1,3-dicarboxylic acid;benzene-1,3-diol;terephthalic acid Chemical compound OC1=CC=CC(O)=C1.OC(=O)C1=CC=C(C(O)=O)C=C1.OC(=O)C1=CC=CC(C(O)=O)=C1 IINQAVTXAIJUOI-UHFFFAOYSA-N 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- MGIAHHJRDZCTHG-UHFFFAOYSA-N benzene-1,3-dicarboxylic acid;terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1.OC(=O)C1=CC=CC(C(O)=O)=C1 MGIAHHJRDZCTHG-UHFFFAOYSA-N 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- -1 poly (alkylene terephthalate Chemical compound 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- 238000004383 yellowing Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229920001230 polyarylate Polymers 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229920001634 Copolyester Polymers 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229930185605 Bisphenol Natural products 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical group OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- NEFJPHDWZWTFQC-UHFFFAOYSA-N benzene-1,3-dicarboxylic acid;benzene-1,3-diol Chemical compound OC1=CC=CC(O)=C1.OC(=O)C1=CC=CC(C(O)=O)=C1 NEFJPHDWZWTFQC-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical group OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical compound O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000206761 Bacillariophyta Species 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 1
- LMWCJUOKWCQUIU-UHFFFAOYSA-N benzene-1,3-diol;decanedioic acid Chemical compound OC1=CC=CC(O)=C1.OC(=O)CCCCCCCCC(O)=O LMWCJUOKWCQUIU-UHFFFAOYSA-N 0.000 description 1
- XNXAGSAHKIBHBB-UHFFFAOYSA-N benzene-1,3-diol;terephthalic acid Chemical compound OC1=CC=CC(O)=C1.OC(=O)C1=CC=C(C(O)=O)C=C1 XNXAGSAHKIBHBB-UHFFFAOYSA-N 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012455 biphasic mixture Substances 0.000 description 1
- LAGGQUMAVSOYLA-UHFFFAOYSA-N bis(2-chlorophenyl) benzene-1,3-dicarboxylate Chemical compound ClC1=CC=CC=C1OC(=O)C1=CC=CC(C(=O)OC=2C(=CC=CC=2)Cl)=C1 LAGGQUMAVSOYLA-UHFFFAOYSA-N 0.000 description 1
- VBUQYFANRSVSSI-UHFFFAOYSA-N bis(2-chlorophenyl) decanedioate Chemical compound ClC1=CC=CC=C1OC(=O)CCCCCCCCC(=O)OC1=CC=CC=C1Cl VBUQYFANRSVSSI-UHFFFAOYSA-N 0.000 description 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019506 cigar Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- WMPOZLHMGVKUEJ-UHFFFAOYSA-N decanedioyl dichloride Chemical compound ClC(=O)CCCCCCCCC(Cl)=O WMPOZLHMGVKUEJ-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- HRTNCUQZHJTTFE-UHFFFAOYSA-N phenol;terephthalic acid Chemical compound OC1=CC=CC=C1.OC1=CC=CC=C1.OC(=O)C1=CC=C(C(O)=O)C=C1 HRTNCUQZHJTTFE-UHFFFAOYSA-N 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- GDESWOTWNNGOMW-UHFFFAOYSA-N resorcinol monobenzoate Chemical compound OC1=CC=CC(OC(=O)C=2C=CC=CC=2)=C1 GDESWOTWNNGOMW-UHFFFAOYSA-N 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US152877 | 1998-09-14 | ||
| US09/152,877 US6143839A (en) | 1998-09-14 | 1998-09-14 | Weatherable blends of polycarbonates with arylate polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2197660T3 true ES2197660T3 (es) | 2004-01-01 |
Family
ID=22544833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99938921T Expired - Lifetime ES2197660T3 (es) | 1998-09-14 | 1999-07-29 | Mezclas de policarbonatos con polimeros de arilato resistentes a la exposicion a la intemperie. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6143839A (enExample) |
| EP (1) | EP1115792B1 (enExample) |
| JP (1) | JP2002524646A (enExample) |
| DE (1) | DE69907235T2 (enExample) |
| ES (1) | ES2197660T3 (enExample) |
| WO (1) | WO2000015718A1 (enExample) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2214046T3 (es) | 1998-10-29 | 2004-09-01 | General Electric Company | Copoliestercarbonatos de bloque resistentes a la intemperie y mezclas que los contienen. |
| ES2251233T3 (es) | 1998-10-29 | 2006-04-16 | General Electric Company | Copoliestercarbonatos de bloque resistentes a la interperie, procedimientos para su preparacion y mezclas que los contienen. |
| US6572956B1 (en) * | 1999-04-08 | 2003-06-03 | General Electric Company | Weatherable multilayer resinous articles and method for their preparation |
| US7605221B2 (en) * | 1999-05-18 | 2009-10-20 | Sabic Innovative Plastics Ip B.V. | Weatherable, thermostable polymers having improved flow composition |
| US6861482B2 (en) | 1999-05-18 | 2005-03-01 | General Electric Company | Weatherable, thermostable polymers having improved flow composition |
| US7169859B2 (en) * | 1999-05-18 | 2007-01-30 | General Electric Company | Weatherable, thermostable polymers having improved flow composition |
| US6306507B1 (en) | 1999-05-18 | 2001-10-23 | General Electric Company | Thermally stable polymers, method of preparation, and articles made therefrom |
| US6689474B2 (en) | 1999-05-18 | 2004-02-10 | General Electric Company | Thermally stable polymers, method of preparation, and articles made therefrom |
| US7790292B2 (en) * | 1999-05-18 | 2010-09-07 | Sabic Innovative Plastics Ip B.V. | Polysiloxane copolymers, thermoplastic composition, and articles formed therefrom |
| US6414058B2 (en) | 1999-09-10 | 2002-07-02 | General Electric Company | Color stable compositions containing arylate-comprising polymers |
| US6410620B2 (en) | 1999-09-10 | 2002-06-25 | General Electric Company | Color stable compositions containing arylate-comprising polymers |
| JP2003508616A (ja) * | 1999-09-10 | 2003-03-04 | ゼネラル・エレクトリック・カンパニイ | 色安定性に優れたポリアリーレート含有組成物 |
| US8057903B2 (en) * | 2001-11-30 | 2011-11-15 | Sabic Innovative Plastics Ip B.V. | Multilayer articles comprising resorcinol arylate polyester and method for making thereof |
| US6627303B1 (en) | 2003-01-17 | 2003-09-30 | General Electric Company | High modulus weatherable polyester carbonate articles |
| US6916528B2 (en) | 2003-05-30 | 2005-07-12 | General Electric Company | Methods for manufacturing silver multilayered films and the articles obtained therefrom |
| US7060217B2 (en) * | 2003-06-12 | 2006-06-13 | General Electric Company | Composite articles comprising resorcinol arylate polyester and method for making thereof |
| US20040253428A1 (en) * | 2003-06-12 | 2004-12-16 | General Electric Company | Weatherable multilayer articles and method for their preparation |
| US20050003208A1 (en) * | 2003-07-01 | 2005-01-06 | Graf John Frederick | Method of reducing the color contribution of a coated top layer in a multi-layer material |
| US20050048401A1 (en) * | 2003-08-29 | 2005-03-03 | Chisholm Bret Ja | Methods of photoaddressing a polymer composition and the articles derived therefrom |
| US7214432B2 (en) * | 2003-09-30 | 2007-05-08 | General Electric Company | Coating compositions, their preparation, and coated articles made therefrom |
| US20090266991A1 (en) * | 2003-11-26 | 2009-10-29 | Sabic Innovative Plastics Ip B.V. | Method of authenticating tagged polymers |
| US7094364B2 (en) * | 2003-11-26 | 2006-08-22 | General Electric Company | Method of authenticating polymers, authenticatable polymers, methods of making authenticatable polymers and authenticatable articles, and articles made there from |
| US20050110978A1 (en) * | 2003-11-26 | 2005-05-26 | Radislav Potyrailo | Method of authenticating articles, authenticatable polymers, and authenticatable articles |
| US20050112768A1 (en) * | 2003-11-26 | 2005-05-26 | Thomas Evans | Method of authenticating tagged polymers |
| US7169615B2 (en) * | 2003-11-26 | 2007-01-30 | General Electric Company | Method of authenticating polymers, authenticatable polymers, methods of making authenticatable polymers and authenticatable articles, and articles made there from |
| US7153576B2 (en) * | 2004-01-20 | 2006-12-26 | General Electric Company | Weatherable multilayer article assemblies and method for their preparation |
| US7109274B2 (en) * | 2004-06-28 | 2006-09-19 | General Electric Company | Polyarylate compositions |
| US20060019099A1 (en) * | 2004-07-20 | 2006-01-26 | General Electric Company | Method for making multilayer film, sheet and articles therefrom |
| US7323536B2 (en) * | 2005-05-20 | 2008-01-29 | General Electric Company | Transparent compositions, methods for the preparation thereof, and articles derived therefrom |
| US7326764B2 (en) * | 2005-05-20 | 2008-02-05 | General Electric Company | Transparent compositions, methods for the preparation thereof, and articles derived therefrom |
| US7273917B2 (en) * | 2005-05-20 | 2007-09-25 | General Electric Company | Transparent compositions, methods for the preparation thereof, and articles derived therefrom |
| US7323535B2 (en) * | 2005-05-20 | 2008-01-29 | General Electric Company | Transparent compositions, methods for the preparation thereof, and articles derived therefrom |
| US7652107B2 (en) * | 2005-10-31 | 2010-01-26 | Sabic Innovative Plastics Ip B.V. | Flame resistant polymer blends |
| US7655737B2 (en) * | 2006-11-16 | 2010-02-02 | Sabic Innovative Plastics Ip B.V. | Polycarbonate-polyester blends, methods of manufacture, and methods of use |
| US7691950B2 (en) * | 2007-04-30 | 2010-04-06 | Sabic Innovative Plastics Ip B.V. | Polyester polycarbonate compositions, methods of making, and articles formed therefrom |
| CN101808798A (zh) | 2007-09-28 | 2010-08-18 | 巴斯夫欧洲公司 | 用于制备阻燃热塑性成型材料的方法 |
| EP2219843B1 (de) | 2007-12-04 | 2012-08-22 | Styrolution GmbH | Verfahren zur herstellung von formteilen mit verringerter belagsbildung |
| EP2216352A1 (de) | 2009-02-10 | 2010-08-11 | Bayer MaterialScience AG | 2K-Polyurethan-Lack für Trägerfolien |
| EP2216353A1 (de) | 2009-02-10 | 2010-08-11 | Bayer MaterialScience AG | Trägerfolie mit Polyurethan-Beschichtung |
| WO2011039301A1 (de) | 2009-10-01 | 2011-04-07 | Basf Se | Funktionalisierte expandierbare graphiteinlagerungsverbindungen |
| WO2011039292A1 (de) | 2009-10-01 | 2011-04-07 | Basf Se | Verfahren zur herstellung funktionalisierter expandierbarer graphiteinlagerungsverbindungen |
| WO2012049264A2 (de) | 2010-10-15 | 2012-04-19 | Basf Se | Verfahren zur herstellung flammgeschützter thermoplastischer formmassen |
| US9708465B2 (en) | 2013-05-29 | 2017-07-18 | Sabic Global Technologies B.V. | Color-stable thermoplastic composition |
| US9982130B2 (en) | 2014-08-20 | 2018-05-29 | Sabic Global Technologies B.V. | Thermoplastic compositions, methods of their manufacture, and articles thereof |
| EP3224313B1 (en) | 2014-11-25 | 2020-02-05 | SABIC Global Technologies B.V. | Thermoplastic compositions, method of manufacture, and articles therefrom |
| CN107001782B (zh) | 2014-11-25 | 2019-07-05 | 沙特基础工业全球技术有限公司 | 耐候性热塑性组合物、制备方法及其制品 |
| KR101743352B1 (ko) | 2015-06-30 | 2017-06-16 | 롯데첨단소재(주) | 폴리카보네이트계 수지 및 이의 제조방법 |
| EP3383952B1 (en) | 2015-12-03 | 2020-06-17 | SABIC Global Technologies B.V. | Heat resistant, weatherable polyester - polycarbonate composition |
| WO2018116245A1 (en) | 2016-12-23 | 2018-06-28 | Sabic Global Technologies B.V. | Electrically-conductive copolyestercarbonate-based material |
| CN110382592B (zh) | 2017-03-10 | 2021-03-26 | 沙特基础工业全球技术有限公司 | 聚碳酸酯共聚物、由其形成的制品及制造方法 |
| KR102668910B1 (ko) | 2018-03-06 | 2024-05-24 | 바스프 에스이 | 섬유상 충전제를 포함하는 코어 물질에 기초한 필라멘트 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5027061B1 (enExample) * | 1971-03-08 | 1975-09-04 | ||
| JPS5356251A (en) * | 1976-11-02 | 1978-05-22 | Sumitomo Chem Co Ltd | Prevention of devitrifiction of aromatic polyester |
| US4246381A (en) * | 1979-06-18 | 1981-01-20 | Union Carbide Corporation | Polyarylate blends with copolyesters |
| DE3408709A1 (de) * | 1984-03-09 | 1985-09-12 | Union Carbide Corp., Danbury, Conn. | Mischung, enthaltend ein polyarylat und ein poly(estercarbonat) |
| JPH01201326A (ja) * | 1988-02-04 | 1989-08-14 | Teijin Ltd | ポリエステル成形材料及び成形品 |
| US5552463A (en) * | 1992-04-24 | 1996-09-03 | Alliedsignal Inc. | Semicrystalline blends of polyalkylene terephthalates and polyarylates |
| US5916997A (en) * | 1998-02-25 | 1999-06-29 | General Electric Company | Weatherable copolymers |
-
1998
- 1998-09-14 US US09/152,877 patent/US6143839A/en not_active Expired - Lifetime
-
1999
- 1999-07-29 DE DE69907235T patent/DE69907235T2/de not_active Expired - Lifetime
- 1999-07-29 JP JP2000570250A patent/JP2002524646A/ja active Pending
- 1999-07-29 ES ES99938921T patent/ES2197660T3/es not_active Expired - Lifetime
- 1999-07-29 WO PCT/US1999/017397 patent/WO2000015718A1/en not_active Ceased
- 1999-07-29 EP EP99938921A patent/EP1115792B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1115792B1 (en) | 2003-04-23 |
| JP2002524646A (ja) | 2002-08-06 |
| US6143839A (en) | 2000-11-07 |
| EP1115792A1 (en) | 2001-07-18 |
| WO2000015718A1 (en) | 2000-03-23 |
| DE69907235T2 (de) | 2004-02-26 |
| DE69907235D1 (de) | 2003-05-28 |
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