ES2196821T3 - Procedimiento para la obtencion de polisobutenos altamente reactivos. - Google Patents
Procedimiento para la obtencion de polisobutenos altamente reactivos.Info
- Publication number
- ES2196821T3 ES2196821T3 ES99929127T ES99929127T ES2196821T3 ES 2196821 T3 ES2196821 T3 ES 2196821T3 ES 99929127 T ES99929127 T ES 99929127T ES 99929127 T ES99929127 T ES 99929127T ES 2196821 T3 ES2196821 T3 ES 2196821T3
- Authority
- ES
- Spain
- Prior art keywords
- highly reactive
- obtaining highly
- polisobutens
- procedure
- boron trifluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
- C08F110/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C08F10/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
- C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
Abstract
Procedimiento para la obtención de poliisobutenos altamente reactivos con un contenido de agrupaciones de vinilideno dispuestas en los extremos de más de un 80 % en mol y con un peso molecular medio de 500 hasta 5000 Dalton mediante polimerización catiónica de isobuteno en fase líquida en presencia de un complejo de trifluoruro de boro, a temperaturas desde +40°C hasta -60°C, caracterizado porque se polimeriza en presencia de un complejo de trifluoruro de boro y a) un alcohol primario con 1 a 20 átomos de carbono o un alcohol secundario con 3 a 20 átomos de carbono o una mezcla, constituida por estos alcoholes, y b) un éter exento de grupos alquilo terciarios de la fórmula I R1-O-R2, en la cual significan Rl y R2 grupos alquilo primarios o secundarios con 3 a 10 átomos de carbono, con la condición, que al menos uno de los grupos Rl y R2 es un grupo alquilo secundario.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19825334A DE19825334A1 (de) | 1998-06-05 | 1998-06-05 | Verfahren zur Herstellung hochreaktiver Polyisobutene |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2196821T3 true ES2196821T3 (es) | 2003-12-16 |
Family
ID=7870130
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES99929127T Expired - Lifetime ES2196821T3 (es) | 1998-06-05 | 1999-06-02 | Procedimiento para la obtencion de polisobutenos altamente reactivos. |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP1095070B1 (es) |
JP (1) | JP2002517575A (es) |
KR (1) | KR100575510B1 (es) |
CN (1) | CN1139607C (es) |
AU (1) | AU4604899A (es) |
CA (1) | CA2334263A1 (es) |
DE (2) | DE19825334A1 (es) |
ES (1) | ES2196821T3 (es) |
MY (1) | MY122369A (es) |
WO (1) | WO1999064482A1 (es) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001019873A1 (en) * | 1999-09-16 | 2001-03-22 | Texas Petrochemicals Lp | Process for preparing polyolefin products |
US6884858B2 (en) | 1999-10-19 | 2005-04-26 | Texas Petrochemicals Lp | Process for preparing polyolefin products |
US6562913B1 (en) * | 1999-09-16 | 2003-05-13 | Texas Petrochemicals Lp | Process for producing high vinylidene polyisobutylene |
US7037999B2 (en) * | 2001-03-28 | 2006-05-02 | Texas Petrochemicals Lp | Mid-range vinylidene content polyisobutylene polymer product and process for producing the same |
US6992152B2 (en) | 1999-10-19 | 2006-01-31 | Texas Petrochemicals Lp | Apparatus and method for controlling olefin polymerization process |
JP3808758B2 (ja) * | 2001-03-22 | 2006-08-16 | 株式会社カネカ | イソブチレン系重合体の製造方法 |
DE10211418A1 (de) | 2002-03-15 | 2003-09-25 | Bayer Ag | Verfahren zur Herstellung hochreaktiver Polyisobutene |
DE10243576A1 (de) | 2002-09-19 | 2004-04-01 | Basf Ag | Verfahren zur Herstellung von Polyisobuten |
CA2413611C (en) * | 2002-12-05 | 2012-11-13 | Bayer Inc. | Process for production of high-isoprene butyl rubber |
DE102009001700A1 (de) | 2008-03-25 | 2009-12-03 | Basf Se | Verfahren zur mikrowellen-unterstützten Polymerisation von ethylenisch ungesättigten Monomeren |
CN101781377B (zh) * | 2009-01-16 | 2011-07-20 | 北京化工大学 | 用于制备高反应活性聚异丁烯的引发体系 |
US20100298507A1 (en) | 2009-05-19 | 2010-11-25 | Menschig Klaus R | Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby |
CN102639572B (zh) | 2009-11-04 | 2015-07-22 | 巴斯夫欧洲公司 | 制备均聚物或共聚物的方法 |
DE102010062374A1 (de) | 2009-12-04 | 2011-06-09 | Basf Se | Verfahren zur Herstellung von Homo- oder Copolymeren |
US8349977B2 (en) | 2010-02-17 | 2013-01-08 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
CN102762610A (zh) * | 2010-02-17 | 2012-10-31 | 巴斯夫欧洲公司 | 生产高反应性异丁烯均聚物或共聚物的方法 |
CN101921352B (zh) * | 2010-09-28 | 2011-10-26 | 潍坊滨海石油化工有限公司 | 一种低分子量高活性聚异丁烯的生产方法 |
EP2646478A2 (de) | 2010-11-30 | 2013-10-09 | Basf Se | Herstellung von isobutenhomo- oder -copolymer-derivaten |
US9562117B2 (en) | 2010-11-30 | 2017-02-07 | Basf Se | Preparation of derivatives of isobutene copolymers |
WO2012072536A2 (de) | 2010-11-30 | 2012-06-07 | Basf Se | Herstellung von derivaten von isobutencopolymerisaten |
US9296841B2 (en) | 2010-11-30 | 2016-03-29 | Basf Se | Preparation of isobutene homo- or copolymer derivatives |
US8697820B2 (en) | 2011-08-11 | 2014-04-15 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
RU2608510C2 (ru) * | 2011-08-11 | 2017-01-18 | Басф Се | Способ получения высокореакционноспособных гомополимеров или сополимеров изобутилена |
JP6211008B2 (ja) | 2012-02-17 | 2017-10-11 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 三フッ化ホウ素触媒錯体および高反応性イソブテンホモポリマーの製造法 |
US8853336B2 (en) | 2012-02-17 | 2014-10-07 | Basf Se | Boron trifluoride-catalyst complex and process for preparing high-reactivity isobutene homopolymers |
CN103724465B (zh) * | 2012-10-16 | 2016-05-25 | 中国石油化工股份有限公司 | 一种烯烃聚合物组合物及其制备方法 |
US9156924B2 (en) * | 2013-03-12 | 2015-10-13 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
KR101523568B1 (ko) * | 2013-05-16 | 2015-05-28 | 대림산업 주식회사 | 반응성 폴리부텐 및 비반응성 폴리부텐의 선택적 제조장치 및 방법 |
JP2016526091A (ja) * | 2013-06-05 | 2016-09-01 | テリム インダストリアル カンパニー リミテッド | 多様な分子量を有するポリブテンの製造装置および方法 |
DK3016976T3 (da) | 2013-07-01 | 2020-12-07 | Csl Behring Ag | Proces |
KR101628897B1 (ko) * | 2014-06-18 | 2016-06-09 | 대림산업 주식회사 | 노르말 프로판올을 포함한 촉매를 이용한 폴리부텐의 제조방법 |
CN104945545A (zh) * | 2015-06-30 | 2015-09-30 | 清华大学 | 一种高反应活性聚异丁烯的制备方法 |
SG11201806357PA (en) | 2016-02-16 | 2018-08-30 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
CN113698514B (zh) | 2016-02-16 | 2023-11-10 | 巴斯夫欧洲公司 | 制备高反应性异丁烯均聚物或共聚物的方法 |
MY194378A (en) | 2016-07-22 | 2022-11-30 | Basf Se | Process for preparing high-reactivity isobutene homo-or copolymers |
EP3444283B1 (en) | 2017-08-17 | 2020-02-26 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
KR102203006B1 (ko) * | 2019-04-24 | 2021-01-13 | 대림산업 주식회사 | 고반응성 폴리부텐의 제조 방법 |
EP4001321A1 (en) | 2020-11-17 | 2022-05-25 | Basf Se | Process for preparation of polyisobutene derivatives |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2702604C2 (de) * | 1977-01-22 | 1984-08-30 | Basf Ag, 6700 Ludwigshafen | Polyisobutene |
GB8329082D0 (en) * | 1983-11-01 | 1983-12-07 | Bp Chem Int Ltd | Low molecular weight polymers of 1-olefins |
BE1006694A5 (fr) * | 1991-06-22 | 1994-11-22 | Basf Ag | Procede de preparation de polyisobutenes extremement reactifs. |
EP0646103B1 (en) * | 1991-11-18 | 1997-08-27 | Amoco Corporation | Bf3-tertiary etherate complexes for isobutylene polymerization |
DE19520078A1 (de) * | 1995-06-07 | 1996-12-12 | Basf Ag | Verfahren zur Herstellung von niedermolekularem, hochreaktivem Polyisobuten |
-
1998
- 1998-06-05 DE DE19825334A patent/DE19825334A1/de not_active Withdrawn
-
1999
- 1999-06-02 AU AU46048/99A patent/AU4604899A/en not_active Abandoned
- 1999-06-02 ES ES99929127T patent/ES2196821T3/es not_active Expired - Lifetime
- 1999-06-02 CN CNB998070661A patent/CN1139607C/zh not_active Expired - Lifetime
- 1999-06-02 CA CA002334263A patent/CA2334263A1/en not_active Abandoned
- 1999-06-02 KR KR1020007013688A patent/KR100575510B1/ko not_active IP Right Cessation
- 1999-06-02 WO PCT/EP1999/003829 patent/WO1999064482A1/de active IP Right Grant
- 1999-06-02 JP JP2000553486A patent/JP2002517575A/ja not_active Withdrawn
- 1999-06-02 EP EP99929127A patent/EP1095070B1/de not_active Expired - Lifetime
- 1999-06-02 DE DE59904860T patent/DE59904860D1/de not_active Expired - Lifetime
- 1999-06-07 MY MYPI99002311A patent/MY122369A/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR100575510B1 (ko) | 2006-05-03 |
EP1095070B1 (de) | 2003-04-02 |
CN1139607C (zh) | 2004-02-25 |
JP2002517575A (ja) | 2002-06-18 |
EP1095070A1 (de) | 2001-05-02 |
DE19825334A1 (de) | 1999-12-09 |
KR20010052539A (ko) | 2001-06-25 |
MY122369A (en) | 2006-04-29 |
AU4604899A (en) | 1999-12-30 |
CA2334263A1 (en) | 1999-12-16 |
DE59904860D1 (de) | 2003-05-08 |
CN1304418A (zh) | 2001-07-18 |
WO1999064482A1 (de) | 1999-12-16 |
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