ES2178670T3 - Materiales polimeros multicomponentes biodegradables basados en polisacaridos del tipo de almidon no modificados. - Google Patents

Materiales polimeros multicomponentes biodegradables basados en polisacaridos del tipo de almidon no modificados.

Info

Publication number
ES2178670T3
ES2178670T3 ES95912817T ES95912817T ES2178670T3 ES 2178670 T3 ES2178670 T3 ES 2178670T3 ES 95912817 T ES95912817 T ES 95912817T ES 95912817 T ES95912817 T ES 95912817T ES 2178670 T3 ES2178670 T3 ES 2178670T3
Authority
ES
Spain
Prior art keywords
starch
unmodified
water
polyacarids
almidon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95912817T
Other languages
English (en)
Inventor
Mohan Krishnan
Ramani Narayan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michigan State University MSU
Original Assignee
Michigan State University MSU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michigan State University MSU filed Critical Michigan State University MSU
Application granted granted Critical
Publication of ES2178670T3 publication Critical patent/ES2178670T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Multicomponent Fibers (AREA)

Abstract

MEZCLAS COMPATIBILIZADAS DE UN POLIESTER HIDROFOBICO BIODEGRADABLE, ALMIDON NO MODIFICADO U OTRO POLISACARIDO SIMILAR CONTENIENDO MENOS DE UN 1% DE AGUA EN PESO, OTROS POLIMEROS BIODEGRADABLES QUE PUEDEN SER HIDROFOBO, UN PLASTIFICANTE, Y OTROS ADITIVOS. LAS MEZCLAS SON PRODUCIDAS EN AUSENCIA DE AGUA. EL POLIMERO DE POLIESTER PREFERIDO ES POLI({EP}-CAPROLACTONA) Y EL ALMIDON PREFERIDO PROCEDE DEL MAIZ. UNA PEQUEÑA CANTIDAD DE UN AGENTE DE ESTIRAMIENTO UNICO ES INCORPORADA PARA SUMINISTRAR ALTAS ELONGACIONES EN LA ROTURA, ESPECIALMENTE EN LAS COMPOSICIONES SUPERFICIACTIVAS QUE CONTIENEN UNA CANTIDAD SIGNIFICATIVA DE ALMIDON. EL ALMIDON ES UNA FASE DISCONTINUA QUE PUEDE SER COMPLETA O PARCIALMENTE PLASTIFICADA Y EL POLIMERO DE POLIESTER ES LA FASE CONTINUA. LOS POLIMEROS PREFERIDOS TIENEN PROPIEDADES SUPERFICIACTIVAS Y SON RESISTENTES AL AGUA Y A LA HUMEDAD.
ES95912817T 1994-03-10 1995-03-06 Materiales polimeros multicomponentes biodegradables basados en polisacaridos del tipo de almidon no modificados. Expired - Lifetime ES2178670T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/208,563 US5500465A (en) 1994-03-10 1994-03-10 Biodegradable multi-component polymeric materials based on unmodified starch-like polysaccharides

Publications (1)

Publication Number Publication Date
ES2178670T3 true ES2178670T3 (es) 2003-01-01

Family

ID=22775056

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95912817T Expired - Lifetime ES2178670T3 (es) 1994-03-10 1995-03-06 Materiales polimeros multicomponentes biodegradables basados en polisacaridos del tipo de almidon no modificados.

Country Status (10)

Country Link
US (1) US5500465A (es)
EP (1) EP0749460B1 (es)
JP (1) JP2813470B2 (es)
AT (1) ATE219783T1 (es)
CA (1) CA2183772C (es)
DE (1) DE69527191T2 (es)
DK (1) DK0749460T3 (es)
ES (1) ES2178670T3 (es)
PT (1) PT749460E (es)
WO (1) WO1995024447A1 (es)

Families Citing this family (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5844023A (en) 1992-11-06 1998-12-01 Bio-Tec Biologische Naturverpackungen Gmbh Biologically degradable polymer mixture
US5739244A (en) * 1994-03-23 1998-04-14 Fisk; Donald Polymer composition containing prime starch
IT1272871B (it) * 1995-01-10 1997-07-01 Novamont Spa Composizioni termoplastiche compredenti amido ed altre componenti di origine naturale
DK0819147T3 (da) 1995-04-07 2003-09-29 Biotec Biolog Naturverpack Polymerblanding, som kan nedbrydes biologisk
US5609817A (en) * 1995-06-06 1997-03-11 The United States Of America As Represented By The Secretary Of Agriculture Extrusion-blown films from graft polymers prepared from cereal flour
US6071984A (en) * 1995-09-26 2000-06-06 Bayer Aktiengesellschaft Biodegradable plastics filled with reinforcing materials
US5801224A (en) * 1996-04-26 1998-09-01 Board Of Trustees Operating Michigan State University Bulk reactive extrusion polymerization process producing aliphatic ester polymer compositions
JPH09294482A (ja) * 1996-05-07 1997-11-18 Nippon Shokuhin Kako Co Ltd 生分解性育苗用ポット
DE19624641A1 (de) 1996-06-20 1998-01-08 Biotec Biolog Naturverpack Biologisch abbaubarer Werkstoff, bestehend im wesentlichen aus oder auf Basis thermoplastischer Stärke
IL129745A0 (en) * 1996-11-05 2000-02-29 Novamont Spa Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
US5952088A (en) * 1996-12-31 1999-09-14 Kimberly-Clark Worldwide, Inc. Multicomponent fiber
US6119567A (en) * 1997-07-10 2000-09-19 Ktm Industries, Inc. Method and apparatus for producing a shaped article
US6089009A (en) 1997-08-28 2000-07-18 Belmont Textile Machinery Co., Inc. Fluid-jet false-twisting method and product
US6268434B1 (en) 1997-10-31 2001-07-31 Kimberly Clark Worldwide, Inc. Biodegradable polylactide nonwovens with improved fluid management properties
US6201068B1 (en) 1997-10-31 2001-03-13 Kimberly-Clark Worldwide, Inc. Biodegradable polylactide nonwovens with improved fluid management properties
DE19750846C1 (de) * 1997-11-17 2000-01-27 Biop Biopolymer Gmbh Verfahren zur Herstellung einer Komponente für die Herstellung von Polymermischungen auf der Basis von Stärke
US6261677B1 (en) 1997-12-22 2001-07-17 Kimberly-Clark Worldwide, Inc. Synthetic fiber
US6544455B1 (en) 1997-12-22 2003-04-08 Kimberly-Clark Worldwide, Inc. Methods for making a biodegradable thermoplastic composition
US6309988B1 (en) 1997-12-22 2001-10-30 Kimberly-Clark Worldwide, Inc. Biodisintegratable nonwovens with improved fluid management properties
US6135987A (en) * 1997-12-22 2000-10-24 Kimberly-Clark Worldwide, Inc. Synthetic fiber
US6306782B1 (en) 1997-12-22 2001-10-23 Kimberly-Clark Worldwide, Inc. Disposable absorbent product having biodisintegratable nonwovens with improved fluid management properties
ITTO980524A1 (it) * 1998-06-17 1999-12-17 Novamont Spa Composizioni contenenti amido aventi elevata resistenza all'invecchiam ento.
US6194483B1 (en) 1998-08-31 2001-02-27 Kimberly-Clark Worldwide, Inc. Disposable articles having biodegradable nonwovens with improved fluid management properties
US6197860B1 (en) 1998-08-31 2001-03-06 Kimberly-Clark Worldwide, Inc. Biodegradable nonwovens with improved fluid management properties
EP1029890B1 (en) * 1999-02-18 2004-07-28 Mitsui Chemicals, Inc. Aliphatic polyester composition and stretched film obtained from said composition
US7384993B2 (en) * 1999-12-13 2008-06-10 Plantic Technologies Ltd Biodegradable polymer
DE10010826A1 (de) 2000-03-08 2001-09-13 Basf Ag Verfahren zur Reduktion der Wasserdampfpermeabilität von Folien oder Beschichtungen
JP4552315B2 (ja) * 2000-12-07 2010-09-29 東レ株式会社 熱可塑性樹脂組成物およびその成形体
JP3748832B2 (ja) * 2001-06-19 2006-02-22 理研ビタミン株式会社 脂肪族ポリエステル組成物及び可撓性成形物
US20030220436A1 (en) * 2002-01-22 2003-11-27 Gencer Mehmet A. Biodegradable polymers containing one or more inhibitors and methods for producing same
US8008373B2 (en) * 2002-01-22 2011-08-30 Northern Technologies International Corp. Biodegradable polymer masterbatch, and a composition derived therefrom having improved physical properties
US7261839B2 (en) * 2002-01-22 2007-08-28 Northern Technologies International Corp. Tarnish inhibiting composition and article containing it
US7270775B2 (en) 2002-01-22 2007-09-18 Northern Technologies International Corp. Corrosion inhibiting composition and article containing it
WO2003074604A1 (en) * 2002-02-28 2003-09-12 Board Of Trustees Of The University Of Arkansas Biodegradable materials from starch-grafted polymers
ITMI20020866A1 (it) * 2002-04-22 2003-10-22 Novamont Spa Copoliesteri termoplastici saturi/insaturi biodegradabili
ITMI20020865A1 (it) * 2002-04-22 2003-10-22 Novamont Spa Poliesteri biodegradabili ottenuti mediante estrusione reattiva
US20050020945A1 (en) * 2002-07-02 2005-01-27 Tosaya Carol A. Acoustically-aided cerebrospinal-fluid manipulation for neurodegenerative disease therapy
DE10258227A1 (de) * 2002-12-09 2004-07-15 Biop Biopolymer Technologies Ag Biologisch abbaubare Mehrschichtfolie
EP1640406A4 (en) * 2003-06-27 2008-01-23 Unitika Ltd ALIPHATIC POLYESTER RESIN COMPOSITION, PROCESS FOR PRODUCING THE RESIN COMPOSITION, MOLDED ARTICLE, AND EXPANDED ARTICLE COMPRISING THE RESIN COMPOSITION
US7393590B2 (en) * 2004-02-27 2008-07-01 Cereplast, Inc. Biodegradable poly(lactic acid) polymer composition and films, coatings and products comprising Biodegradable poly(lactic acid) polymer compositions
EP1724300A1 (en) * 2004-03-10 2006-11-22 Agri Future Joetsu Co., Ltd. Starch-blended resin composition, molding thereof and process for producing the same
KR20070084032A (ko) * 2004-10-05 2007-08-24 플랜틱 테크놀로지스 리미티드 성형가능한 생분해성 폴리머
US20090160095A1 (en) * 2004-11-19 2009-06-25 Board Of Trustees Of Michigan State University Biodegradable thermoplasticized starch-polyester reactive blends for thermoforming applications
US7153354B2 (en) * 2004-11-19 2006-12-26 Board Of Trustees Of Michigan State University Chemically modified plasticized starch compositions by extrusion processing
US7629405B2 (en) * 2004-11-19 2009-12-08 Board Of Trustees Of Michigan State University Starch-polyester biodegradable graft copolyers and a method of preparation thereof
TW200712120A (en) * 2005-07-28 2007-04-01 Biograde Hong Kong Pty Ltd Biodegradable polymer composition
US20070082982A1 (en) * 2005-10-11 2007-04-12 The Procter & Gamble Company Water stable compositions and articles comprising starch and methods of making the same
US7931778B2 (en) * 2005-11-04 2011-04-26 Cargill, Incorporated Lecithin-starches compositions, preparation thereof and paper products having oil and grease resistance, and/or release properties
US20070129467A1 (en) * 2005-12-02 2007-06-07 Frederic Scheer Bio based biodegradable polymer compositions and use of same
US7666946B2 (en) * 2006-01-27 2010-02-23 Arkema Inc. Blends of biopolymers with acrylic copolymers
FR2916203B1 (fr) * 2007-05-14 2012-07-20 Arkema Liants de coextrusion sur base renouvelable/biodegradable
US20090048368A1 (en) * 2007-08-13 2009-02-19 Bash Thomas F Polyolefin compositions comprising bio-based starch materials
FR2934272B1 (fr) * 2008-07-24 2013-08-16 Roquette Freres Procede de preparation de compositions a base de matiere amylacee et de polymere synthetique.
US8016980B2 (en) * 2008-11-25 2011-09-13 Dixie Consumer Products Llc Paper products
US10206813B2 (en) 2009-05-18 2019-02-19 Dose Medical Corporation Implants with controlled drug delivery features and methods of using same
WO2010135369A1 (en) * 2009-05-18 2010-11-25 Dose Medical Corporation Drug eluting ocular implant
FR2947830B1 (fr) * 2009-07-13 2011-08-19 Valagro Carbone Renouvelable Poitou Charentes Composition, procede de preparation et utilisation pour ameliorer la fluidite et la resistance a la temperature de materiaux composites
PT104846A (pt) * 2009-11-26 2011-05-26 Cabopol Ind De Compostos S A Misturas polim?ricas biocompost?veis
US8466337B2 (en) * 2009-12-22 2013-06-18 Kimberly-Clark Worldwide, Inc. Biodegradable and breathable film
US20120016328A1 (en) * 2010-07-19 2012-01-19 Bo Shi Biodegradable films
CN102321249B (zh) * 2011-06-30 2013-01-16 无锡碧杰生物材料科技有限公司 一种热塑性淀粉和生物降解聚酯/淀粉复合材料及其制备
PT106563B (pt) * 2012-10-04 2014-12-04 Inst Superior Tecnico Poliésteres biocompostáveis e processo melhorado para a sua produção
JP6246521B2 (ja) * 2013-08-07 2017-12-13 ネクサス株式会社 生分解性樹脂組成物およびその製造方法
EP3677229A1 (en) 2014-05-29 2020-07-08 Glaukos Corporation Implants with controlled drug delivery features
WO2017040853A1 (en) 2015-09-02 2017-03-09 Glaukos Corporation Drug delivery implants with bi-directional delivery capacity
US11564833B2 (en) 2015-09-25 2023-01-31 Glaukos Corporation Punctal implants with controlled drug delivery features and methods of using same
AU2017252294B2 (en) 2016-04-20 2021-12-02 Dose Medical Corporation Bioresorbable ocular drug delivery device
US10975213B2 (en) 2018-08-13 2021-04-13 Erthos Inc. Composition and method of making biodegradable pellets
IT202000005242A1 (it) * 2020-03-11 2021-09-11 Massimo Silvio Morbidelli Processo di preparazione di materiali polimerici e compositi con proprieta' termo-meccaniche migliorate e materiali polimerici e compositi ottenuti con tale processo
CN113683804B (zh) * 2021-10-13 2022-12-02 山东天铭医药科技有限公司 双交联的壳聚糖聚(酯-氨酯)改性氧化淀粉及制备方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA838572A (en) * 1970-04-07 Department Of Agriculture And Inspection Of The State Of Nebraska Plasticized extrusion of amylose
US3312641A (en) * 1963-06-19 1967-04-04 Staley Mfg Co A E Polyvinyl alcohol plasticized amylose compositions
US3949145A (en) * 1975-02-27 1976-04-06 The United States Of America As Represented By The Secretary Of Agriculture Degradable starch-based agricultural mulch film
US4133784A (en) * 1977-09-28 1979-01-09 The United States Of America As Represented By The Secretary Of Agriculture Biodegradable film compositions prepared from starch and copolymers of ethylene and acrylic acid
JPS55157643A (en) * 1979-05-28 1980-12-08 Nichiden Kagaku Kk Polymer composition
US4337181A (en) * 1980-01-17 1982-06-29 The United States Of America As Represented By The Secretary Of Agriculture Biodegradable starch-based blown films
JPS60215018A (ja) * 1984-04-10 1985-10-28 Daicel Chem Ind Ltd かつらベ−ス製造用雌型材料
GB2205323B (en) * 1987-03-09 1991-01-30 Warner Lambert Co Destructurized starch and process for making same
GB2208651B (en) * 1987-08-18 1991-05-08 Warner Lambert Co Shaped articles made from pre-processed starch
GB2214918B (en) * 1988-02-03 1992-10-07 Warner Lambert Co Polymeric materials made from starch and at least one synthetic thermoplastic polymeric material
IE66735B1 (en) * 1988-11-03 1996-02-07 Biotec Biolog Naturverpack Thermoplastically workable starch and a method for the manufacture thereof
AU5921390A (en) * 1989-05-19 1990-12-18 Agri-Tech Industries, Inc. Injection molded biodegradable starch polymer composite
IT1234783B (it) * 1989-05-30 1992-05-27 Butterfly Srl Procedimento per la produzione di composizioni a base di amido destrutturato e composizioni cosi ottenute
IL94587A (en) * 1989-06-19 1997-04-15 Novon International Polymer base blend compositions containing destructurized starch
IL94589A0 (en) * 1989-06-22 1991-04-15 Warner Lambert Co Polymer base blend compositions containing destructurized starch
AU633936B2 (en) * 1989-07-11 1993-02-11 Novon International, Inc. Polymer base blend compositions containing destructurized starch
DE69220754T2 (de) * 1991-05-03 1997-12-04 Novamont S.P.A., Novara Biologisch abbaubare Polymermassen auf der Basis von Stärke und thermoplastische Polymere
ATE147995T1 (de) * 1991-06-26 1997-02-15 Procter & Gamble Saugfähige einwegartikel mit biodegradierbare schutzfolien
JPH06508868A (ja) * 1991-06-26 1994-10-06 ザ、プロクター、エンド、ギャンブル、カンパニー 生分解性液体不浸透性フィルム
DK0598048T3 (da) * 1991-08-07 1998-02-09 Clopay Corp Biologisk nedbrydelig film og fremgangsmåde til fremstilling af samme
US5256711A (en) * 1991-10-04 1993-10-26 Director-General Of Agency Of Industrial Science Starch-containing biodegradable plastic and method of producing same
US5321064A (en) * 1992-05-12 1994-06-14 Regents Of The University Of Minnesota Compositions of biodegradable natural and synthetic polymers
BE1006077A3 (fr) * 1992-07-15 1994-05-10 Solvay Compositions de moulage biodegradables comprenant au moins un amidon thermoplastique et au moins un polyester aliphatique thermoplastique.
FR2693734B1 (fr) * 1992-07-15 1994-10-07 Roquette Freres Composition thermoformable-biodécomposable à base d'un composé amylacé et d'un polyester biodégradable.

Also Published As

Publication number Publication date
DE69527191T2 (de) 2002-11-28
EP0749460A1 (en) 1996-12-27
ATE219783T1 (de) 2002-07-15
WO1995024447A1 (en) 1995-09-14
DE69527191D1 (de) 2002-08-01
DK0749460T3 (da) 2002-09-16
CA2183772A1 (en) 1995-09-14
CA2183772C (en) 2000-08-29
PT749460E (pt) 2002-11-29
JPH09505107A (ja) 1997-05-20
EP0749460A4 (en) 1998-04-08
JP2813470B2 (ja) 1998-10-22
EP0749460B1 (en) 2002-06-26
US5500465A (en) 1996-03-19

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