ES2174126T3 - Metodo para la produccion en continuo de dialquil carbonato y dioles. - Google Patents
Metodo para la produccion en continuo de dialquil carbonato y dioles.Info
- Publication number
- ES2174126T3 ES2174126T3 ES96942612T ES96942612T ES2174126T3 ES 2174126 T3 ES2174126 T3 ES 2174126T3 ES 96942612 T ES96942612 T ES 96942612T ES 96942612 T ES96942612 T ES 96942612T ES 2174126 T3 ES2174126 T3 ES 2174126T3
- Authority
- ES
- Spain
- Prior art keywords
- dialquil
- distillation column
- point
- carbonate
- diol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/128—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/96—Esters of carbonic or haloformic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
- C07C68/065—Preparation of esters of carbonic or haloformic acids from organic carbonates from alkylene carbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
SE DESCRIBE UN METODO PARA PRODUCIR EN CONTINUO UN DIALQUIL CARBONATO Y UN DIOL, QUE INCLUYE: (1) ALIMENTAR UN CARBONATO CICLICO Y UN ALCOHOL ALIFATICO MONOHIDRICO A UNA COLUMNA DE DESTILACION CONTINUA EN MULTIPLES ETAPAS, Y EFECTUAR UNA TRANSESTERIFICACION EN PRESENCIA DE UN CATALIZADOR EN LA COLUMNA DE DESTILACION EN ETAPAS MULTIPLES Y/O AL MENOS UN REACTOR DE TRANSESTERIFICACION QUE COMUNICA EN FORMA ESTANCA A FLUIDOS CON LA COLUMNA DE DESTILACION, MIENTRAS SE RETIRAN DE FORMA CONTINUA UNA MEZCLA GASEOSA DE BAJO PUNTO DE EBULLICION QUE CONTIENE EL DIALQUIL CARBONATO PRODUCIDO DE UNA PORCION SUPERIOR DE LA COLUMNA DE DESTILACION Y UNA MEZCLA LIQUIDA DE ALTO PUNTO DE EBULLICION DE UNA PORCION INFERIOR DE LA COLUMNA DE DESTILACION; Y (2) ALIMENTAR DE FORMA CONTINUA AGUA Y LA MEZCLA DE ALTO PUNTO DE EBULLICION A UN REACTOR DE HIDROLISIS, PARA ASI EFECTUAR UNA HIDROLISIS EN CONTINUO DEL CARBONATO CICLICO SIN REACCIONAR QUE EN ELLA SE CONTIENE Y PRODUCIR UN DIOL Y DIOXIDO DE CARBONO. MEDIANTEEL METODO DE LA PRESENTE INVENCION, SE HACE POSIBLE PRODUCIR UN DIALQUIL CARBONATO Y UN DIOL DE ALTA PUREZA, CON ALTA PRODUCTIVIDAD, AUN CUANDO LA ALIMENTACION DE ALCOHOL ALIFATICO MONOHIDRICO CONTENGA UN DIALQUIL CARBONATO CONCOMITANTE.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33492895 | 1995-12-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2174126T3 true ES2174126T3 (es) | 2002-11-01 |
Family
ID=18282815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96942612T Expired - Lifetime ES2174126T3 (es) | 1995-12-22 | 1996-12-20 | Metodo para la produccion en continuo de dialquil carbonato y dioles. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5847189A (es) |
EP (1) | EP0889025B1 (es) |
JP (1) | JP3686086B2 (es) |
KR (1) | KR100293341B1 (es) |
CN (1) | CN1076339C (es) |
CA (1) | CA2234155C (es) |
DE (1) | DE69620470T2 (es) |
ES (1) | ES2174126T3 (es) |
MY (1) | MY114041A (es) |
TW (1) | TW359668B (es) |
WO (1) | WO1997023445A1 (es) |
Families Citing this family (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999064382A1 (fr) * | 1998-06-10 | 1999-12-16 | Asahi Kasei Kogyo Kabushiki Kaisha | Procede de production continue de diol et de carbonate dialcoyle |
US6479689B1 (en) | 1999-03-03 | 2002-11-12 | Asahi Kasei Kabushiki Kaisha | Process for continuously producing dialkyl carbonate and diol |
US6207850B1 (en) | 1999-11-03 | 2001-03-27 | Mobil Oil Corporation | Process for co-production of dialkyl carbonate and alkanediol |
US6407279B1 (en) | 1999-11-19 | 2002-06-18 | Exxonmobil Chemical Patents Inc. | Integrated process for preparing dialkyl carbonates and diols |
US6162940A (en) * | 1999-12-14 | 2000-12-19 | Mobil Oil Corporation | Process for co-production of dialkyl carbonate and alkanediol |
JP3659109B2 (ja) | 2000-01-19 | 2005-06-15 | 三菱化学株式会社 | エチレングリコールと炭酸エステルの併産方法 |
US6342623B1 (en) | 2000-02-04 | 2002-01-29 | Exxonmobil Chemical Patents Inc. | Process for co-production of dialkyl carbonate and alkanediol |
US6166240A (en) * | 2000-02-22 | 2000-12-26 | Mobil Oil Corporation | Process for co-production of dialkyl carbonate and alkanediol |
US6774256B2 (en) * | 2001-06-22 | 2004-08-10 | Exxonmobil Chemical Patents Inc. | Low corrosive integrated process for preparing dialkyl carbonates |
US6620958B2 (en) * | 2001-06-26 | 2003-09-16 | Exxonmobil Chemical Patents Inc. | Use of membranes to separate organic liquids having different polarities |
US6573396B2 (en) | 2001-10-12 | 2003-06-03 | Exxonmobil Chemical Patents Inc. | Co-production of dialkyl carbonates and diols with treatment of hydroxy alkyl carbonate |
MY132428A (en) * | 2001-11-13 | 2007-10-31 | Shell Int Research | Method for catalytic conversion of organic carbonate and the use of a lanthanum catalyst therefor |
US6620959B1 (en) * | 2002-04-16 | 2003-09-16 | Exxonmobil Chemical Patents Inc. | Process for the production of unsymmetric and/or symmetric dialkyl carbonates and diols |
TW200503997A (en) * | 2002-12-20 | 2005-02-01 | Shell Int Research | Process for the preparation of alkylene glycol |
US20040220433A1 (en) * | 2003-03-28 | 2004-11-04 | Evert Van Der Heide | Process for the preparation of propylene glycol |
CN100400495C (zh) * | 2003-04-09 | 2008-07-09 | 国际壳牌研究有限公司 | 链烷二醇的制备方法 |
CA2560101A1 (en) * | 2004-06-17 | 2005-12-29 | Asahi Kasei Chemicals Corporation | Method for producing a dialkyl carbonate and a diol |
JP4292210B2 (ja) | 2004-08-25 | 2009-07-08 | 旭化成ケミカルズ株式会社 | 高純度ジフェニルカーボネートの工業的製造方法 |
WO2006035642A1 (ja) | 2004-09-27 | 2006-04-06 | Asahi Kasei Chemicals Corporation | 芳香族カーボネートの工業的製造方法 |
EP1801095B1 (en) | 2004-10-14 | 2012-07-18 | Asahi Kasei Chemicals Corporation | Process for production of high-purity diaryl carbonate |
CN101044109B (zh) | 2004-10-22 | 2011-07-06 | 旭化成化学株式会社 | 高纯度碳酸二芳基酯的工业制备方法 |
BRPI0616303B1 (pt) | 2005-09-20 | 2015-12-01 | Asahi Kasei Chemicals Corp | processo para a produção contínua de um carbonato de dialquila e de um diol |
US20090207687A1 (en) * | 2005-10-03 | 2009-08-20 | Honeywell International Inc. | Apparatus and method for preparing ultrapure solvent blends |
US20090253939A1 (en) * | 2005-11-25 | 2009-10-08 | Asahi Kasei Chemicals Corporation | Process for industrially producing dialkyl carbonate and diol |
WO2007060894A1 (ja) | 2005-11-25 | 2007-05-31 | Asahi Kasei Chemicals Corporation | ジアルキルカーボネートとジオール類の工業的製造方法 |
EA012027B1 (ru) * | 2005-12-12 | 2009-06-30 | Асахи Касеи Кемикалз Корпорейшн | Способ промышленного получения диалкилкарбоната и диола |
TWI308911B (en) * | 2005-12-13 | 2009-04-21 | Asahi Kasei Chemcials Corp | Process for industrially producing dialkyl carbonate and diol |
TW200732291A (en) * | 2005-12-14 | 2007-09-01 | Asahi Kasei Chemicals Corp | Process for production of dialkyl carbonate and diol in industrial scale and with high yield |
TWI314549B (en) | 2005-12-26 | 2009-09-11 | Asahi Kasei Chemicals Corp | Industrial process for separating out dialkyl carbonate |
TW200738601A (en) * | 2005-12-27 | 2007-10-16 | Asahi Kasei Chemicals Corp | Industrial process for production of dialkyl carbonate and diol |
TWI334410B (en) | 2006-01-10 | 2010-12-11 | Asahi Kasei Chemicals Corp | Industrial process for production of high-purity diol |
TWI327998B (en) | 2006-01-26 | 2010-08-01 | Asahi Kasei Chemicals Corp | Industrial process for production of diol |
TW200738602A (en) * | 2006-02-01 | 2007-10-16 | Asahi Kasei Chemicals Corp | Industrial process for producing high-purity diol |
TWI378087B (en) * | 2006-02-22 | 2012-12-01 | Shell Int Research | Process for the preparation of an alkanediol and a dialkyl carbonate |
TWI382979B (zh) * | 2006-02-22 | 2013-01-21 | Shell Int Research | 碳酸伸烷酯之生產方法及由此生產的碳酸伸烷酯於烷二醇及碳酸二烷酯之製造中的用途 |
TWI383976B (zh) * | 2006-02-22 | 2013-02-01 | Shell Int Research | 製備碳酸二烷酯及烷二醇的方法 |
TW200740731A (en) * | 2006-02-22 | 2007-11-01 | Shell Int Research | Process for the preparation of alkanediol |
TW200740749A (en) * | 2006-02-22 | 2007-11-01 | Shell Int Research | Process for the preparation of an alkanediol and a dialkyl carbonate |
TWI387584B (zh) * | 2006-03-13 | 2013-03-01 | Shell Int Research | 碳酸伸烷酯之生產方法及由此生產之碳酸伸烷酯於烷二醇及碳酸二烷酯之製造中之用途 |
US7462748B2 (en) | 2006-09-07 | 2008-12-09 | Shell Oil Company | Process for the preparation of alkylene glycol |
US7465840B2 (en) | 2006-09-07 | 2008-12-16 | Shell Oil Company | Process for the preparation of alkylene glycol |
EP2121566B1 (en) * | 2007-01-23 | 2012-10-31 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of an alkanediol and a dialkyl carbonate |
WO2008090108A1 (en) * | 2007-01-23 | 2008-07-31 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of an alkanediol and a dialkyl carbonate |
KR100735861B1 (ko) * | 2007-03-23 | 2007-07-04 | 삼전순약공업(주) | 고순도 및 고수율 디메틸카보네이트의 정제 방법 |
DE102009030680A1 (de) * | 2009-06-26 | 2010-12-30 | Bayer Materialscience Ag | Verfahren zur Herstellung von Dialkylcarbonaten aus Alkylencarbonaten und Alkoholen |
IT1396205B1 (it) | 2009-10-13 | 2012-11-16 | Eni Spa | Composizione di gasolio comprendente dietil carbonato da bioetanolo. |
IT1397623B1 (it) | 2009-12-16 | 2013-01-18 | Eni Spa | Composizione di gasolio comprendente dietil carbonato da bioetanolo ed olio vegetale idrotrattato |
IT1396959B1 (it) | 2009-12-18 | 2012-12-20 | Eni Spa | Composizione di gasolio comprendente biodiesel e dietil carbonato da bioetanolo |
AU2011225700B2 (en) * | 2010-03-12 | 2014-09-11 | Institute Of Chemical Technology | Improved thermodynamic cycle |
DE102010042937A1 (de) | 2010-10-08 | 2012-04-12 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Herstellung von Diarylcarbonaten aus Dialkylcarbonaten |
CN102381996A (zh) * | 2011-08-23 | 2012-03-21 | 里光 | 一种甲基丙烯酸二乙基氨基乙酯的制备方法 |
WO2013083618A1 (de) | 2011-12-05 | 2013-06-13 | Basf Se | Verfahren zur gewinnung eines dialkylcarbonats und eines alkylenglykols |
EP2650278A1 (de) | 2012-04-11 | 2013-10-16 | Bayer MaterialScience AG | Verfahren zur Herstellung von Diarylcarbonaten aus Dialkylcarbonaten |
EP2852568B1 (en) | 2012-05-22 | 2016-08-17 | Council of Scientific & Industrial Research | Process for making dimethyl carbonate |
TW201439146A (zh) * | 2012-11-17 | 2014-10-16 | Mitsubishi Gas Chemical Co | 高分子量化之芳香族聚碳酸酯樹脂之製造方法 |
US9475751B2 (en) | 2012-11-21 | 2016-10-25 | Covestro Deutschland Ag | Process for producing dialkyl carbonates |
CN105344376B (zh) * | 2015-11-04 | 2017-07-14 | 常州大学 | 一种用于合成乙二醇的固体催化剂及其制备方法 |
EP3386630B1 (en) * | 2015-12-09 | 2023-08-30 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of glycols |
KR102160060B1 (ko) * | 2018-05-18 | 2020-09-28 | 한국과학기술원 | 디알킬카보네이트의 제조방법 |
US11479524B1 (en) * | 2018-10-23 | 2022-10-25 | E3Tec Services, Llc | System and method for synthesis of dialkyl carbonates using carbon dioxide reaction with methanol and ammonia |
CN110105174B (zh) * | 2019-05-22 | 2021-10-08 | 胜华新能源科技(东营)有限公司 | 一种以碳酸乙烯酯和甲醇为原料生产乙二醇的方法 |
US10941105B1 (en) | 2019-05-24 | 2021-03-09 | E3Tec Service, Llc | Method for direct conversion of carbon dioxide to dialkyl carbonates using ethylene oxide as feedstock |
CN113402393A (zh) * | 2021-07-14 | 2021-09-17 | 张文进 | 一个生产碳酸酯的半连续反应蒸馏工艺 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6431737A (en) * | 1986-01-03 | 1989-02-02 | Texaco Development Corp | Manufacture of ethylene glycol and dimethyl carbonate |
US4691041A (en) * | 1986-01-03 | 1987-09-01 | Texaco Inc. | Process for production of ethylene glycol and dimethyl carbonate |
JP2529025B2 (ja) * | 1990-11-29 | 1996-08-28 | 旭化成工業株式会社 | ジアルキルカ―ボネ―トとジオ―ル類の連続的製造法 |
DE4129316A1 (de) * | 1991-09-03 | 1993-03-04 | Bayer Ag | Verfahren zur kontinuierlichen herstellung von dialkylcarbonaten |
DE4216121A1 (de) * | 1992-05-15 | 1993-11-18 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von Dialkylcarbonaten |
-
1996
- 1996-12-20 EP EP96942612A patent/EP0889025B1/en not_active Expired - Lifetime
- 1996-12-20 CA CA002234155A patent/CA2234155C/en not_active Expired - Lifetime
- 1996-12-20 WO PCT/JP1996/003746 patent/WO1997023445A1/ja active IP Right Grant
- 1996-12-20 ES ES96942612T patent/ES2174126T3/es not_active Expired - Lifetime
- 1996-12-20 CN CN96198027A patent/CN1076339C/zh not_active Expired - Lifetime
- 1996-12-20 KR KR1019980703145A patent/KR100293341B1/ko not_active IP Right Cessation
- 1996-12-20 US US08/930,700 patent/US5847189A/en not_active Expired - Lifetime
- 1996-12-20 DE DE69620470T patent/DE69620470T2/de not_active Expired - Lifetime
- 1996-12-20 JP JP52350497A patent/JP3686086B2/ja not_active Expired - Lifetime
- 1996-12-21 TW TW085115840A patent/TW359668B/zh not_active IP Right Cessation
- 1996-12-23 MY MYPI96005449A patent/MY114041A/en unknown
Also Published As
Publication number | Publication date |
---|---|
DE69620470T2 (de) | 2002-11-21 |
MY114041A (en) | 2002-07-30 |
DE69620470D1 (de) | 2002-05-08 |
EP0889025B1 (en) | 2002-04-03 |
US5847189A (en) | 1998-12-08 |
CN1076339C (zh) | 2001-12-19 |
CA2234155A1 (en) | 1997-07-03 |
JP3686086B2 (ja) | 2005-08-24 |
KR100293341B1 (ko) | 2001-09-07 |
WO1997023445A1 (fr) | 1997-07-03 |
EP0889025A1 (en) | 1999-01-07 |
CN1201448A (zh) | 1998-12-09 |
TW359668B (en) | 1999-06-01 |
CA2234155C (en) | 2002-09-10 |
KR19990067194A (ko) | 1999-08-16 |
EP0889025A4 (en) | 1999-03-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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