ES2170963T3 - Ligandos fosfinicos. - Google Patents

Ligandos fosfinicos.

Info

Publication number
ES2170963T3
ES2170963T3 ES97941092T ES97941092T ES2170963T3 ES 2170963 T3 ES2170963 T3 ES 2170963T3 ES 97941092 T ES97941092 T ES 97941092T ES 97941092 T ES97941092 T ES 97941092T ES 2170963 T3 ES2170963 T3 ES 2170963T3
Authority
ES
Spain
Prior art keywords
phosphinical
links
compounds
complexes
well
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97941092T
Other languages
English (en)
Inventor
Mario Eugenio Cosamino Polywka
Edwin Moses
Daniel John Bayston
Anthony David Baxter
Mark Richard Ashton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EVOTEC OAI Ltd
Original Assignee
EVOTEC OAI Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EVOTEC OAI Ltd filed Critical EVOTEC OAI Ltd
Application granted granted Critical
Publication of ES2170963T3 publication Critical patent/ES2170963T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • B01J31/2457—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/63—Esters of sulfonic acids
    • C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
    • C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/202—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring the aromatic ring being a naphthalene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/575—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/94—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of polycyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6536—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and sulfur atoms with or without oxygen atoms, as the only ring hetero atoms
    • C07F9/6539—Five-membered rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C40—COMBINATORIAL TECHNOLOGY
    • C40B—COMBINATORIAL CHEMISTRY; LIBRARIES, e.g. CHEMICAL LIBRARIES
    • C40B40/00—Libraries per se, e.g. arrays, mixtures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

ESTA INVENCION SE REFIERE A UNOS COMPUESTOS REPRESENTADOS POR LA FORMULA (I) EN LA CUAL R, R 1 , R 2 , Y R SUP, 3 SON TAL COMO SE REIVINDICAN. ESTA INVENCION SE REFIERE TAMBIEN A UNOS PROCESOS DE ELABORACION DE ESTOS COMPUESTOS ASI COMO A COMPLEJOS DE METALES DE TRANSICION QUE INTEGRAN DICHOS COMPUESTOS. ESTOS COMPLEJOS, QUE PUEDEN UNIRSE A UNOS SOPORTES INSOLUBLES, CONVIENEN ESPECIALMENTE COMO CATALIZADORES ASIMETRICOS.
ES97941092T 1996-09-20 1997-09-22 Ligandos fosfinicos. Expired - Lifetime ES2170963T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9619684.5A GB9619684D0 (en) 1996-09-20 1996-09-20 Phosphine ligands

Publications (1)

Publication Number Publication Date
ES2170963T3 true ES2170963T3 (es) 2002-08-16

Family

ID=10800265

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97941092T Expired - Lifetime ES2170963T3 (es) 1996-09-20 1997-09-22 Ligandos fosfinicos.

Country Status (6)

Country Link
EP (1) EP0938488B1 (es)
JP (1) JP2000507604A (es)
DE (1) DE69709897T2 (es)
ES (1) ES2170963T3 (es)
GB (1) GB9619684D0 (es)
WO (1) WO1998012202A1 (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5800212A (en) 1997-02-28 1998-09-01 Hsu; Min-Hsun Plug-in type light bulb
US6307087B1 (en) 1998-07-10 2001-10-23 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
US7223879B2 (en) 1998-07-10 2007-05-29 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
DE19840255A1 (de) * 1998-09-03 2000-03-09 Basf Ag Katalysator umfassend einen wasserlöslichen Übergangsmetallkomplex
EP1593431A3 (en) * 1998-10-13 2008-11-26 E.I. Du Pont De Nemours And Company Polymer-supported phosphorus ligands for catalysis
ATE428500T1 (de) * 1998-10-13 2009-05-15 Du Pont Kunststoff-geträgerte phosphorliganden verwendbar in der katalyse
CA2290009A1 (en) 1998-11-19 2000-05-19 Rhony Niklaus Aufdenblatten Chiral diphenyldiphosphines and d-8 metal complexes thereof
FR2789992B1 (fr) * 1999-02-19 2001-05-25 Rhodia Chimie Sa Procede de preparation de diphosphines chirales utiles comme ligands dans la synthese de complexes destines a la catalyse asymetrique
FR2790477B1 (fr) * 1999-03-01 2001-05-25 Rhodia Chimie Sa Polymere lineaire optiquement actif utilisable comme ligand dans la preparation de complexes metalliques destines a la catalyse asymetrique
JP4275795B2 (ja) 1999-03-30 2009-06-10 高砂香料工業株式会社 ビニル基を有するホスフィン誘導体、それをモノマーとするポリマー及びそれらの遷移金属錯体
ATE297807T1 (de) * 1999-06-17 2005-07-15 Firmenich & Cie Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden
FR2802121A1 (fr) * 1999-12-14 2001-06-15 Expansia Sa Supports polymeriques organiques possedant des ligands mono- ou bi-dentates et leur utilisation en catalyse supportee
DE10002976A1 (de) * 2000-01-24 2001-07-26 Degussa Molekulargewichtsvergrößerte Liganden für asymmetrische homogen lösliche Hydrierkatalysatoren, Verfahren zu deren Herstellung und Verwendung
FR2807042B1 (fr) * 2000-04-03 2002-07-05 Rhodia Chimie Sa Diphosphines chirales hydrosolubles utiles comme ligands dans la synthese de complexes hydrosolubles destines a la catalyse asymetrique
WO2002040573A1 (en) * 2000-11-17 2002-05-23 Mitsubishi Rayon Co., Ltd. Solid-supported optically active binaphthyls and process for preparing asymmetric amino nitrile derivatives with the same
EP1375534A4 (en) * 2001-03-12 2004-11-24 Zeria Pharm Co Ltd SOLID-PHASE TRANSITIONAL METAL CATALYSTS
US6660876B2 (en) 2001-11-26 2003-12-09 E. I. Du Pont De Nemours And Company Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions
JP2004161963A (ja) 2002-11-15 2004-06-10 Takasago Internatl Corp 高分子担持光学活性ビナフチル型オキサゾリン化合物
FR2853652A1 (fr) * 2003-04-09 2004-10-15 Rhodia Chimie Sa Diphosphines chirales, leur preparation et leurs utilisations comme ligands dans la synthese de complexes destines a la catalyse asymetrique
DE102004052725B4 (de) * 2004-10-27 2007-07-12 Technische Universität Chemnitz Verfahren zur Herstellung substituierter Phosphane und nach dem Verfahren hergestellte substituierte Phosphane
JP5124210B2 (ja) * 2007-08-24 2013-01-23 日本化学工業株式会社 ビアリールホスフィン化合物の製造方法
JP5666596B2 (ja) * 2009-09-28 2015-02-12 ザ ガバナーズ オブ ザ ユニバーシティ オブ アルバータ 不均一系ロジウム金属触媒
CN103059064B (zh) * 2012-09-08 2015-08-19 青岛科技大学 手性双膦配体与手性催化剂及制备、应用方法
KR101601936B1 (ko) 2013-11-19 2016-03-09 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법
JP6980269B2 (ja) * 2018-01-22 2021-12-15 大学共同利用機関法人自然科学研究機構 キラルロジウム錯体、及び光学活性β−置換カルボニル化合物の製造方法
JP7231574B2 (ja) * 2020-02-27 2023-03-01 国立大学法人九州大学 新規な多孔性架橋ポリマー、それを用いた固定化触媒および装置

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4178313A (en) * 1978-07-14 1979-12-11 Conoco, Inc. Olefin isomerization and hydroformylation process
US4506030A (en) * 1984-02-17 1985-03-19 The Board Of Regents, University Of Texas System Catalysts for hydrogenation of aromatic compounds
JP2584498B2 (ja) * 1988-09-05 1997-02-26 工業技術院長 新規なクラウンエーテル化合物及び分離剤
US6333435B1 (en) * 1995-05-18 2001-12-25 Merck & Co., Inc. Process of synthesizing binaphthyl derivatives

Also Published As

Publication number Publication date
EP0938488A1 (en) 1999-09-01
WO1998012202A1 (en) 1998-03-26
GB9619684D0 (en) 1996-11-06
DE69709897D1 (de) 2002-02-28
EP0938488B1 (en) 2002-01-02
JP2000507604A (ja) 2000-06-20
DE69709897T2 (de) 2002-06-20

Similar Documents

Publication Publication Date Title
ES2170963T3 (es) Ligandos fosfinicos.
AU2002360982A1 (en) Support-fixed bleaching catalyst complex compounds suitable as catalysts for peroxide compounds
PL356486A1 (en) Catalysts for hydrosilylation reactions
GT199900055A (es) Nuevas dihidropirimidinas2 heterocìclicamente sustituidas.
ES2001416A6 (es) Procedimiento de carbonilacion,particularmente hidroformilacion de compuestos organicos para producir aldehidos.
MXPA03011204A (es) Metodo para telomerizar olefinas no ciclicas.
MY134758A (en) Multidentate phosphite ligands, catalyst compositions made therefrom and catalytic processes employing such multidentate phosphite ligands
PL344475A1 (en) Bridged indenopyrrolocarbazoles
DK0841344T3 (da) 1-(2-Desoxy-2-fluor-4-thio-Beta-D-arabinofuranosyl)cytosiner
ES2188984T3 (es) Procedimiento de enriquecimiento en r de epimeros de derivados de 16,17-acetales de derivados de 21-aciloxi-pregnano-1,4-dieno-11-beta, 16alfa-triol-3,20-dionas.
DE69906307D1 (de) Übergangsmetallkomplexe als linkergruppe
ES2195544T3 (es) Proceso para la preparacion de bisfosfinas.
DE50214495D1 (de) Neue übergangsmetall-komplexe und deren einsatz in übergangsmetall-katalysierten reaktionen
ES2192334T3 (es) Procedimiento mejorado para preparar un agente antiparasitario.
DK1047669T3 (da) Perfluor-N-alkylsulfonsyrederivater
BR9916460A (pt) Produção de ácido ascórbico usando levedura
ZA976251B (en) Ligands for asymmetric catalysis
NO176717C (no) Analogifremgangsmåte ved fremstilling av målsökende anti-tumorforbindelser
ATE246172T1 (de) Verfahren zur herstellung von hydroxy-25-ene vitamin d verbindungen
TR200002755T2 (tr) Aracı hazırlamak için süreç.
AR023979A1 (es) Procesos para preparar compuestos intermedios de plaguicidas
AR020785A1 (es) Nuevos procedimientos quimicos
ATE196292T1 (de) Zwischenprodukte um 2-imidazolin-5onederivate herzustellen.
ID27733A (id) Metoksiminofenilasetamida
FR2823174B1 (fr) Tracteur enjambeur, notamment pour le travail de la vigne

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 938488

Country of ref document: ES