ES2195544T3 - Proceso para la preparacion de bisfosfinas. - Google Patents

Proceso para la preparacion de bisfosfinas.

Info

Publication number
ES2195544T3
ES2195544T3 ES99909108T ES99909108T ES2195544T3 ES 2195544 T3 ES2195544 T3 ES 2195544T3 ES 99909108 T ES99909108 T ES 99909108T ES 99909108 T ES99909108 T ES 99909108T ES 2195544 T3 ES2195544 T3 ES 2195544T3
Authority
ES
Spain
Prior art keywords
compound
group
formula
optionally substituted
atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99909108T
Other languages
English (en)
Inventor
Paul David Newman
Richard Anthony Campbell
Robert Paul Tooze
Graham Ronald Eastham
Jamie Michael Thorpe
Peter Gerald Edwards
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical UK Ltd
Original Assignee
Lucite International UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite International UK Ltd filed Critical Lucite International UK Ltd
Application granted granted Critical
Publication of ES2195544T3 publication Critical patent/ES2195544T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5063—Preparation; Separation; Purification; Stabilisation from compounds having the structure P-H or P-Heteroatom, in which one or more of such bonds are converted into P-C bonds
    • C07F9/5068—Preparation; Separation; Purification; Stabilisation from compounds having the structure P-H or P-Heteroatom, in which one or more of such bonds are converted into P-C bonds from starting materials having the structure >P-Hal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un método para elaborar un compuesto de fórmula general (R3-C)2P-L1-X-L2-P-(C-R3)2, en el que cada R es independientemente un grupo orgánico colgante, opcionalmente sustituido, a través del cual el grupo está unido a un átomo de carbono terciario C; L1 y L2 son independientemente un grupo de enlace seleccionado entre una cadena de alquileno de C1-C4 opcionalmente sustituida que conecta el respectivo átomo de fósforo al grupo X, y X es un grupo de puente que comprende un resto arilo opcionalmente sustituido al que están unidos los átomos de fósforo en átomos de carbono adyacentes disponibles, que comprende: i) hacer reaccionar conjuntamente un compuesto de fórmula H-L1-X-L2-H con un compuesto organometálico para formar un compuesto intermedio de fórmula M-L1-X-L2-M donde la que M es un átomo de metal alcalino, ii) hacer reaccionar dicho compuesto intermedio con un compuesto de fórmula (R3-C)2P-A donde A es un átomo de halógeno, para formar dicho compuesto de fórmula general (R3-C)2P-L 1 -X-L2 -P-(C-R3)2.
ES99909108T 1998-03-16 1999-03-16 Proceso para la preparacion de bisfosfinas. Expired - Lifetime ES2195544T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9805348.1A GB9805348D0 (en) 1998-03-16 1998-03-16 Compound

Publications (1)

Publication Number Publication Date
ES2195544T3 true ES2195544T3 (es) 2003-12-01

Family

ID=10828473

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99909108T Expired - Lifetime ES2195544T3 (es) 1998-03-16 1999-03-16 Proceso para la preparacion de bisfosfinas.

Country Status (14)

Country Link
US (1) US6376715B1 (es)
EP (1) EP1064288B1 (es)
JP (1) JP4283443B2 (es)
KR (1) KR100421627B1 (es)
CN (1) CN1140532C (es)
AU (1) AU742029B2 (es)
CA (1) CA2323906C (es)
DE (1) DE69907433T2 (es)
ES (1) ES2195544T3 (es)
GB (1) GB9805348D0 (es)
MY (1) MY120565A (es)
TW (1) TWI249534B (es)
WO (1) WO1999047528A1 (es)
ZA (1) ZA200004914B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6743911B2 (en) † 2000-03-14 2004-06-01 Shell Oil Company Process for the carbonylation of pentenenitrile
MXPA02001147A (es) * 2001-03-19 2004-04-21 Warner Lambert Co Sintesis de ligandos bisfosina no-c2-simetricos como catalizadores para la hidrogenacion asimetrica.
TWI301481B (en) 2002-08-10 2008-10-01 Lucite Int Uk Ltd A catalyst system
ATE435230T1 (de) * 2002-12-04 2009-07-15 Ciba Holding Inc Verfahren zur synthese von cycloorganylphosphanen und von di(alkali/erdalkalimetall)oligophosphandiiden
JP2007516197A (ja) 2003-07-03 2007-06-21 ルーサイト インターナショナル ユーケー リミテッド エチレン性不飽和化合物のヒドロホルミル化方法
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
GB0516556D0 (en) 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
KR101633325B1 (ko) 2005-11-17 2016-06-24 루사이트 인터내셔널 유케이 리미티드 에틸렌성 불포화 화합물의 카르보닐화
WO2008065448A1 (en) 2006-12-02 2008-06-05 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
GB2467163B (en) * 2009-01-26 2013-11-06 Rhodia Operations Ligands
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
EP2734498A1 (en) * 2011-07-22 2014-05-28 DSM IP Assets B.V. Process for the isomerisation of substituted alkenes
CA3029934A1 (en) 2016-07-04 2018-01-11 Hokko Chemical Industry Co., Ltd. Organic magnesium phosphide and manufacturing method thereof, organic magnesium phosphide complex and manufacturing method thereof, and manufacturing method of organic phosphorus compound using said phosphide
CN107098932A (zh) * 2017-06-29 2017-08-29 管德新 一种可用于氢甲酰化反应的苄基类配体的合成方法
CN114805434B (zh) * 2021-01-18 2024-07-05 广东欧凯新材料有限公司 一种新型四齿膦配体化合物及其合成方法与应用
CN114835746A (zh) * 2021-02-01 2022-08-02 惠州凯特立斯科技有限公司 一种新型四齿膦配体化合物及其合成方法与应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB877592A (en) * 1959-03-26 1961-09-13 Ici Ltd Preparation of diphosphines
US4879008A (en) * 1987-11-09 1989-11-07 Eastman Kodak Company Preparation of bidentate ligands
DE4134772A1 (de) * 1990-10-31 1992-05-07 Basf Ag Verfahren zur herstellung von bis(di-tert.-butylphosphino)methan
AU686918B2 (en) * 1994-12-09 1998-02-12 Griffith University Anti-tumour agents
GB9425911D0 (en) * 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
GB9717059D0 (en) * 1997-08-13 1997-10-15 Ici Plc Method of manufacturing phosphine compound

Also Published As

Publication number Publication date
CN1293675A (zh) 2001-05-02
GB9805348D0 (en) 1998-05-06
CN1140532C (zh) 2004-03-03
ZA200004914B (en) 2001-08-10
CA2323906A1 (en) 1999-09-23
KR100421627B1 (ko) 2004-03-10
AU2847599A (en) 1999-10-11
JP2002506872A (ja) 2002-03-05
AU742029B2 (en) 2001-12-13
JP4283443B2 (ja) 2009-06-24
DE69907433T2 (de) 2004-05-06
MY120565A (en) 2005-11-30
CA2323906C (en) 2009-02-17
KR20010041885A (ko) 2001-05-25
US6376715B1 (en) 2002-04-23
WO1999047528A1 (en) 1999-09-23
EP1064288A1 (en) 2001-01-03
EP1064288B1 (en) 2003-05-02
DE69907433D1 (de) 2003-06-05
TWI249534B (en) 2006-02-21

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